JPH0469783B2 - - Google Patents
Info
- Publication number
- JPH0469783B2 JPH0469783B2 JP7741784A JP7741784A JPH0469783B2 JP H0469783 B2 JPH0469783 B2 JP H0469783B2 JP 7741784 A JP7741784 A JP 7741784A JP 7741784 A JP7741784 A JP 7741784A JP H0469783 B2 JPH0469783 B2 JP H0469783B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- resin
- substrate
- electrophotographic photoreceptor
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000049 pigment Substances 0.000 claims description 24
- 108091008695 photoreceptors Proteins 0.000 claims description 20
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 15
- 238000012546 transfer Methods 0.000 claims description 4
- 230000031700 light absorption Effects 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229920006122 polyamide resin Polymers 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 230000003595 spectral effect Effects 0.000 description 6
- -1 blue Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 239000012463 white pigment Substances 0.000 description 3
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- VPUGDVKSAQVFFS-UHFFFAOYSA-N coronene Chemical compound C1=C(C2=C34)C=CC3=CC=C(C=C3)C4=C4C3=CC=C(C=C3)C4=C2C3=C1 VPUGDVKSAQVFFS-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229940097275 indigo Drugs 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 108091005944 Cerulean Proteins 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- YFPSDOXLHBDCOR-UHFFFAOYSA-N Pyrene-1,6-dione Chemical compound C1=CC(C(=O)C=C2)=C3C2=CC=C2C(=O)C=CC1=C32 YFPSDOXLHBDCOR-UHFFFAOYSA-N 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- ZMJPCIAEJKVKMQ-UHFFFAOYSA-M [4-[[4-[benzyl(methyl)amino]phenyl]-[4-(dimethylamino)phenyl]methylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)CC=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 ZMJPCIAEJKVKMQ-UHFFFAOYSA-M 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- CTAPFRYPJLPFDF-UHFFFAOYSA-N isoxazole Chemical compound C=1C=NOC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- INAAIJLSXJJHOZ-UHFFFAOYSA-N pibenzimol Chemical compound C1CN(C)CCN1C1=CC=C(N=C(N2)C=3C=C4NC(=NC4=CC=3)C=3C=CC(O)=CC=3)C2=C1 INAAIJLSXJJHOZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UXSNCWGPJRPDHI-UHFFFAOYSA-N violet-quinone Natural products O=C1C2=C(O)C=C(C)C=C2C(=O)C2=C1OC1=C2C=C(OC)C2=C(O)C=C(C)C=C21 UXSNCWGPJRPDHI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/14—Inert intermediate or cover layers for charge-receiving layers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
本発明は改良された電子写真感光体に関し、さ
らにくわしくは赤原稿に対する電子写真感光体上
の潜像を鮮明にする為に電子写真感光体の基体と
電荷発生層の間に中間層を設けた電子写真感光体
に関するものである。
従来電荷移動層と電荷発生層から成る積層型の
電子写真感光体において電荷発生層の分光吸収が
620nm以上に及ぶ場合、ハロゲンランプなどで分
光反射率のピークが620nm以上にあるような赤色
原稿を複写すると、電子写真感光体への相対感度
が大きくなり、感光体上の潜像が黒色原稿に比べ
て形成しにくいという欠点がある。
赤色原稿による潜像を形成させやすくする為に
は感光体に当たる像露光軸に赤側の分光波長をカ
ツトするフイルターを入れる事が行われている
が、この方法ではコスト的に割高になるという欠
点があつた。
本発明は上述の欠点を除去し、フイルターを機
械本体に入れる事なく赤色原稿の潜像形成が容易
にできる電子写真感光体を与えるものである。す
なわち本発明は、基体、および電荷発生層と電荷
移動層を有する感光層を有する電子写真感光体に
おいて、基体と感光層の間に、620nm以上の長波
長域に最大光吸収ピークを有する着色顔料および
導電性白色顔料を含有する樹脂層を有することを
特徴とする電子写真感光体である。
本発明は電荷発生層の吸収分光分布によらず赤
色原稿の潜像形成を容易にする為に電荷発生層と
基体の間に中間層として620nm以上の長波長光を
吸収する着色顔料を含んだ樹脂層を設けるもので
ある。即ちこの中間層としては青色系の着色顔料
をバインダー樹脂に分散させたものを用いるもの
であり、青色の着色顔料としては、例えば群ジヨ
ウ、コバルトブルー、エメラルドグリーン、セル
リアンブルー等の無機顔料又はフタロシアニンブ
ルー、ピグメントグリーン、フアストスカイブル
ー等の有機顔料が挙げられる。
又、これらの青色系の着色顔料を分散する樹脂
としては、例えば
(1) 基体に対する密着性が強固であること、
(2) 粉体の分散性が良好であること、
(3) 耐溶剤性が十分であること、
などの条件を満たすものであれば使用できるが、
特に、硬化性ゴム、ポリウレタン樹脂、エポキシ
樹脂、アルキド樹脂、ポリエステル樹脂、シリコ
ーン樹脂、アクリル−メラミン樹脂等の熱硬化性
樹脂が好適である。
分散には、ロールミル、ボールミル、振動ボー
ルミル、アトライター、サンドミル、コロイドミ
ルなどの常法による。塗布には基体がシート状で
ある場合には、ワイヤーバーコート、ブレードコ
ート、ナイフコート、ロールコート、スクリーン
コートなどが適しており、基体が円筒状である場
合には、浸漬塗布法が適している。
本発明においてこの中間層を基体に塗布した際
にその体積抵抗が1012Ω・cm以上であると電子写
真感光体を作成した際に、残留電位の上昇により
画像形成が困難となることがあるので、本発明に
おいては、中間層用の塗料に着色顔料と共に酸化
スズのような導電性白色顔料を加える。
前述の着色顔料又は着色顔料と導電性白色顔料
を分散した塗膜の上に電荷発生層を直接、塗布す
ると電荷発生層の顔料粒子が微細孔の内に埋没し
てしまつたり、あるいは感光特性が変化する。そ
のために、前述の顔料を分散した樹脂層の上に導
電性粉体を含まない樹脂層を設けることが好適で
ある。そのような樹脂としては例えばポリビニル
アルコール、ポリビニルメチルエーテル、ポリビ
ニルエチルエーテル、ポリビニルピリジン、ポリ
ビニルピロリドン、ポリエチレンオキシド、ポリ
アクリル酸類、メチルセルロース、エチルセルロ
ース、ポリグルタミン酸、カゼイン、ゼラチン、
でんぷん等の水溶性樹脂、ポリアミド樹脂、フエ
ノール樹脂、ポリビニルホルマール、ポリウレタ
ンエラストマー、アルキド樹脂、エチレン−酢酸
ビニルコポリマー、ビニルピロリドン−酢酸ビニ
ルコポリマー等の樹脂が挙げられる。本発明者の
実験の結果ではポリアミド樹脂が最適であつた。
ポリアミド樹脂は線状のポリアミドであり、いわ
ゆるナイロンおよび共重合ナイロンで代表され
る。本発明では、溶液状態で基体の上に塗布する
ことが適しているので、低ないし非結晶のものが
好ましい。かかる樹脂は、2種以上のナイロンの
原料を混合して共重合により得ることができる。
ナイロンの原料としては、例えばナイロン6の
原料であるカプロラクタムないし6−アミノカプ
ロン酸、ナイロン66、ナイロン610の原料である
ヘキサメチレンジアミンとアジピン酸、セバシン
酸などのジカルボン酸、ナイロン11の原料である
11−アミノウンデカン酸、ナイロン12の原料であ
るω−ラウロラクタムないし12−アミノドデカン
酸などが挙げられる。
ポリアミド樹脂層の塗布厚は0.3〜2μ程度が好
適である。この導電性粉体を含まない樹脂層上に
下述の電荷発生層および電荷輸送層が形成されて
電子写真感光体が得られる。
本発明における電荷発生層は、スーダンレツ
ド、ダイアンブルー、ジエナスグリーンBなどの
アゾ顔料、アルゴールイエロー、ピレンキノン、
インダンスレン、ブリリアントバイオレツト
RRPなどのキノン顔料、キノシアニン顔料、ペ
リレン顔料、インジゴ、チオインジゴ等のインジ
ゴ顔料、インドフアーストオレンジトナーなどの
ビスベンゾイミダゾール顔料、銅フタロシアニン
などのフタロシアニン顔料、キナクドリン顔料、
キナクドリン顔料等の電荷発生性物質を、ポリエ
ステル、ポリスチレン、ポリビニルブチラール、
ポリビニルピロリドン、メチルセルロース、ポリ
アクリル酸エステル類、セルロースエステルなど
の結着剤樹脂に分散して形成される。その厚さは
0.01〜1μ、好ましくは0.05〜0.5μ程度である。
また、電荷輸送層は主鎖又は側鎖にアントラセ
ン、ピレン、フエナントレン、コロネンなどの多
環芳香族化合物又はインドール、カルバゾール、
オキサゾール、イソオキサゾール、チアゾール、
イミダゾール、ピラゾール、オキサジアゾール、
ピラゾリン、チアジアゾール、トリアゾールなど
の含窒素環式化合物を有する化合物、ヒドラゾン
化合物等の正孔輸送性物質を成膜性のある樹脂に
溶解させて形成される。これは電荷輸送性物質が
一般適に低分子量で、それ自身では成膜性に乏し
いためである。そのような樹脂としては、ポリカ
ーボネート、ポリメタクリル酸エステル類、ポリ
アリレート、ポリスチレン、ポリエステル、ポリ
サルホン、スチレン−アクリロニトリルコポリマ
ー、スチレン−メタクリル酸メチルコポリマー等
が挙げられる。電荷輸送層の厚さは5〜20μであ
る。
又、本発明は基体として広範な導電性のものか
ら選択することができる。具体的には、アルミニ
ウム、黄銅、ステンレス、ニツケルなどの金属を
シリンダーやプレート形状にしたもの、あるいは
アルミニウム、酸化インジウム、酸化スズをプラ
スチツクや紙に蒸着又はラミネートしたものなど
を挙げることができる。
実施例 1
基体として60φ×260mmのアルミニウムシリン
ダーを用意する。
一方群ジヨウ(Na6Al6(SiO4)6・2Na2SO4)80
部(重量部、以下同じ)と酸化スズ粉体20部をア
クリル樹脂(商品名:アクリデイツクA405、大
日本インキ(株)製)80部(固型分50%)、メラミン
樹脂(商品名:スーパーベツカミンL121、大日
本インキ(株)製)20部(固型分60%)およびトルエ
ン100部の溶液に混合し、次いでボールミルによ
り、6時間にわたり分散した。この分散液を基体
上に浸漬法で塗布し、150℃で30分間に亘つて熱
硬化し、25μ厚の中間層をもうけた。
次に、共重合ナイロン樹脂(商品名:アミラン
CM8000、東レ製)10部(重量部、以下同様)を
メタノール60部、ブタノール40部の混合液に溶解
し、上記中間層上に浸漬塗布して、1μ厚のポリ
アミド樹脂層をもうけた。
次に下記構造式のジスアゾ顔料を10部
酢酸酪酸セルロース樹脂(商品名:CAB−381;
イーストマン化学製)6部およびシクロヘキサノ
ン60部を1φガラスビーズを用いたサンドミル装
置で20時間分散した。この分散液にメチルエチル
ケトン100部を加えて、上記ポリアミド樹脂層上
に浸漬塗布し、100℃で10分間の加熱乾燥をして、
0.1g/m2の塗布量の電荷発生層をもうけた。
次いで、下記構造式のヒドラゾン化合物を10部
およびスチレン−メタクリル酸メチル共重合樹脂
(商品名:MS200;製鉄化学(株)製)15部をトルエ
ン80部に溶解した。この液を上記電荷発生層上に
塗布して100℃で1時間の熱風乾燥をして、16μ
厚の電荷輸送層を形成し電子写真感光体とした。
比較例 1
実施例1と同じ基体の上に中間層を設けず基体
の上に直接実施例1で用いたポリアミド樹脂層、
電荷発生層および電荷輸送層を順次形成して電子
写真感光体を作成した。
実施例1及び比較例1で製造した感光体を−
5.6KVコロナ帯電、画像露光、乾式トナー現象、
普通紙へのトナー転写、ウレタンゴムブレード
(硬度70゜、圧力10gw/cm、感光体に対する角度
20°)によるクリーニング工程等を有する電子写
真複写機に取り付けて感色性の評価を行つた。濃
度0.3(マクベスRD−514濃度測定器使用、以下同
様)の原稿を0.5の濃度に複写できる現像設定に
おいて図面の分光反射率をもつ赤色原稿を複写
し、それぞれのコピー濃度を測定した。
The present invention relates to an improved electrophotographic photoreceptor, and more particularly, an intermediate layer is provided between the base of the electrophotographic photoreceptor and a charge generation layer in order to sharpen the latent image on the electrophotographic photoreceptor for a red original. This invention relates to an electrophotographic photoreceptor. In conventional multilayer electrophotographic photoreceptors consisting of a charge transfer layer and a charge generation layer, the spectral absorption of the charge generation layer is
When copying a red original whose spectral reflectance peaks at 620nm or more using a halogen lamp, the relative sensitivity to the electrophotographic photoreceptor increases and the latent image on the photoreceptor becomes a black original. The drawback is that it is difficult to form. In order to make it easier to form a latent image from a red original, a filter is installed on the image exposure axis that hits the photoreceptor to cut out the red spectral wavelength, but this method has the disadvantage of being relatively expensive. It was hot. The present invention eliminates the above-mentioned drawbacks and provides an electrophotographic photoreceptor that can easily form a latent image on a red original without inserting a filter into the main body of the machine. That is, the present invention provides an electrophotographic photoreceptor having a substrate and a photosensitive layer having a charge generation layer and a charge transfer layer, in which a colored pigment having a maximum light absorption peak in a long wavelength region of 620 nm or more is provided between the substrate and the photosensitive layer. and an electrophotographic photoreceptor comprising a resin layer containing a conductive white pigment. The present invention includes a colored pigment that absorbs long wavelength light of 620 nm or more as an intermediate layer between the charge generation layer and the substrate in order to facilitate the formation of a latent image on a red original regardless of the absorption spectral distribution of the charge generation layer. A resin layer is provided. That is, this intermediate layer uses a blue colored pigment dispersed in a binder resin, and examples of the blue colored pigment include inorganic pigments such as Cobalt Blue, Cobalt Blue, Emerald Green, and Cerulean Blue, or phthalocyanine. Examples include organic pigments such as blue, pigment green, and fast sky blue. In addition, the resin for dispersing these blue colored pigments must have, for example, (1) strong adhesion to the substrate, (2) good powder dispersibility, and (3) solvent resistance. It can be used as long as it satisfies the following conditions:
Particularly suitable are thermosetting resins such as curable rubber, polyurethane resin, epoxy resin, alkyd resin, polyester resin, silicone resin, and acrylic-melamine resin. For dispersion, conventional methods such as roll mills, ball mills, vibrating ball mills, attritors, sand mills, colloid mills, etc. are used. Wire bar coating, blade coating, knife coating, roll coating, screen coating, etc. are suitable for coating when the substrate is sheet-shaped, and dip coating is suitable when the substrate is cylindrical. There is. In the present invention, if the intermediate layer has a volume resistivity of 10 12 Ω·cm or more when applied to the substrate, it may become difficult to form an image due to an increase in residual potential when an electrophotographic photoreceptor is produced. Therefore, in the present invention, a conductive white pigment such as tin oxide is added to the paint for the intermediate layer together with a colored pigment. If a charge generation layer is applied directly onto a coating film in which the above-mentioned colored pigment or colored pigment and conductive white pigment are dispersed, the pigment particles of the charge generation layer may become embedded in the micropores, or the photosensitive characteristics may deteriorate. changes. For this reason, it is preferable to provide a resin layer containing no conductive powder on the resin layer in which the pigment is dispersed. Examples of such resins include polyvinyl alcohol, polyvinyl methyl ether, polyvinylethyl ether, polyvinyl pyridine, polyvinyl pyrrolidone, polyethylene oxide, polyacrylic acids, methyl cellulose, ethyl cellulose, polyglutamic acid, casein, gelatin,
Examples include water-soluble resins such as starch, polyamide resins, phenolic resins, polyvinyl formals, polyurethane elastomers, alkyd resins, ethylene-vinyl acetate copolymers, vinylpyrrolidone-vinyl acetate copolymers, and other resins. According to the results of experiments conducted by the present inventor, polyamide resin was most suitable.
Polyamide resins are linear polyamides, and are typified by so-called nylons and copolymerized nylons. In the present invention, since it is suitable to apply it onto a substrate in a solution state, a low to non-crystalline one is preferable. Such a resin can be obtained by copolymerizing a mixture of two or more types of nylon raw materials. Raw materials for nylon include, for example, caprolactam or 6-aminocaproic acid, which is the raw material for nylon 6, hexamethylene diamine and dicarboxylic acids such as adipic acid and sebacic acid, which are the raw materials for nylon 66 and nylon 610, and dicarboxylic acids such as adipic acid and sebacic acid, and the raw materials for nylon 11.
Examples include 11-aminoundecanoic acid and ω-laurolactam or 12-aminododecanoic acid, which is a raw material for nylon 12. The coating thickness of the polyamide resin layer is preferably about 0.3 to 2 μm. A charge generation layer and a charge transport layer described below are formed on this resin layer containing no conductive powder to obtain an electrophotographic photoreceptor. The charge generation layer in the present invention includes azo pigments such as Sudan Red, Diane Blue, and Jenas Green B, Algol Yellow, Pyrenequinone,
Indanthrene, brilliant violet
Quinone pigments such as RRP, quinocyanine pigments, perylene pigments, indigo pigments such as indigo and thioindigo, bisbenzimidazole pigments such as India First Orange Toner, phthalocyanine pigments such as copper phthalocyanine, quinacridin pigments,
Charge-generating substances such as quinacridine pigments can be used with polyester, polystyrene, polyvinyl butyral,
It is formed by being dispersed in a binder resin such as polyvinylpyrrolidone, methylcellulose, polyacrylic esters, and cellulose ester. Its thickness is
It is about 0.01 to 1μ, preferably about 0.05 to 0.5μ. In addition, the charge transport layer may contain polycyclic aromatic compounds such as anthracene, pyrene, phenanthrene, coronene, indole, carbazole, etc. in the main chain or side chain.
Oxazole, isoxazole, thiazole,
imidazole, pyrazole, oxadiazole,
It is formed by dissolving a hole-transporting substance such as a compound having a nitrogen-containing cyclic compound such as pyrazoline, thiadiazole, or triazole, or a hydrazone compound in a resin that has film-forming properties. This is because the charge-transporting substance generally has a low molecular weight and has poor film-forming properties by itself. Examples of such resins include polycarbonates, polymethacrylates, polyarylates, polystyrene, polyesters, polysulfones, styrene-acrylonitrile copolymers, styrene-methyl methacrylate copolymers, and the like. The thickness of the charge transport layer is 5 to 20 microns. Additionally, the present invention allows the substrate to be selected from a wide variety of conductive materials. Specifically, metals such as aluminum, brass, stainless steel, and nickel can be shaped into cylinders or plates, and aluminum, indium oxide, and tin oxide can be vapor-deposited or laminated onto plastic or paper. Example 1 An aluminum cylinder of 60φ×260mm is prepared as a base. One group (Na 6 Al 6 (SiO 4 ) 6・2Na 2 SO 4 ) 80
(parts by weight, same hereinafter) and 20 parts of tin oxide powder, 80 parts of acrylic resin (product name: Acrydik A405, manufactured by Dainippon Ink Co., Ltd.) (solid content 50%), melamine resin (product name: Super The mixture was mixed with a solution of 20 parts of Betsukamine L121 (manufactured by Dainippon Ink Co., Ltd.) (solid content 60%) and 100 parts of toluene, and then dispersed in a ball mill for 6 hours. This dispersion was applied onto a substrate by a dipping method and thermally cured at 150° C. for 30 minutes to form an intermediate layer with a thickness of 25 μm. Next, copolymerized nylon resin (product name: Amilan
CM8000, manufactured by Toray Industries, Ltd.) (10 parts by weight, hereinafter the same) was dissolved in a mixed solution of 60 parts of methanol and 40 parts of butanol, and dip-coated on the above intermediate layer to form a polyamide resin layer with a thickness of 1 μm. Next, add 10 parts of the disazo pigment with the following structural formula. Cellulose acetate butyrate resin (product name: CAB-381;
(manufactured by Eastman Chemical) and 60 parts of cyclohexanone were dispersed for 20 hours using a sand mill device using 1φ glass beads. Add 100 parts of methyl ethyl ketone to this dispersion, dip coat it onto the polyamide resin layer, heat dry at 100°C for 10 minutes,
A charge generating layer was formed with a coating weight of 0.1 g/m 2 . Next, add 10 parts of a hydrazone compound having the following structural formula. and 15 parts of styrene-methyl methacrylate copolymer resin (trade name: MS200; manufactured by Tetsu Seikagaku Co., Ltd.) were dissolved in 80 parts of toluene. This solution was coated on the charge generation layer and dried with hot air at 100℃ for 1 hour to form a 16μ
A thick charge transport layer was formed to prepare an electrophotographic photoreceptor. Comparative Example 1 The polyamide resin layer used in Example 1 was placed directly on the substrate without providing an intermediate layer on the same substrate as in Example 1,
An electrophotographic photoreceptor was prepared by sequentially forming a charge generation layer and a charge transport layer. The photoreceptors manufactured in Example 1 and Comparative Example 1 were -
5.6KV corona charging, image exposure, dry toner phenomenon,
Toner transfer to plain paper, urethane rubber blade (hardness 70°, pressure 10gw/cm, angle to photoreceptor)
The color sensitivity was evaluated by attaching it to an electrophotographic copying machine that has a cleaning process at 20°). A red original with the spectral reflectance of the drawing was copied using a development setting that allows an original with a density of 0.3 (using a Macbeth RD-514 density meter, the same applies hereinafter) to be copied to a density of 0.5, and the density of each copy was measured.
【表】
以上説明したように基体と電荷発生層の間に
620nm以上の長波長光を吸収する顔料を含む中間
層を設ける事によつて色の再現性の良い電子写真
感光体を作る事ができる。[Table] As explained above, between the substrate and the charge generation layer
By providing an intermediate layer containing a pigment that absorbs long wavelength light of 620 nm or more, an electrophotographic photoreceptor with good color reproducibility can be produced.
図面は赤色原稿の分光反射率を示す図である。 The drawing is a diagram showing the spectral reflectance of a red original.
Claims (1)
る感光層を有する電子写真感光体において、基体
と感光層の間に、620nm以上の長波長域に最大光
吸収ピークを有する着色顔料および導電性白色顔
料を含有する樹脂層を有することを特徴とする電
子写真感光体。1. In an electrophotographic photoreceptor having a substrate and a photosensitive layer having a charge generation layer and a charge transfer layer, a colored pigment having a maximum light absorption peak in a long wavelength region of 620 nm or more and a conductive white are placed between the substrate and the photosensitive layer. An electrophotographic photoreceptor characterized by having a resin layer containing a pigment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7741784A JPS60220357A (en) | 1984-04-17 | 1984-04-17 | Electrophotographic sensitivive body |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7741784A JPS60220357A (en) | 1984-04-17 | 1984-04-17 | Electrophotographic sensitivive body |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60220357A JPS60220357A (en) | 1985-11-05 |
JPH0469783B2 true JPH0469783B2 (en) | 1992-11-09 |
Family
ID=13633372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7741784A Granted JPS60220357A (en) | 1984-04-17 | 1984-04-17 | Electrophotographic sensitivive body |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60220357A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63188144A (en) * | 1987-01-30 | 1988-08-03 | Konica Corp | Photosensitive body |
JPH07295269A (en) * | 1994-04-25 | 1995-11-10 | Nec Corp | Electrophotographic photoreceptor |
-
1984
- 1984-04-17 JP JP7741784A patent/JPS60220357A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS60220357A (en) | 1985-11-05 |
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