JPH0469318A - Manicure - Google Patents
ManicureInfo
- Publication number
- JPH0469318A JPH0469318A JP17917690A JP17917690A JPH0469318A JP H0469318 A JPH0469318 A JP H0469318A JP 17917690 A JP17917690 A JP 17917690A JP 17917690 A JP17917690 A JP 17917690A JP H0469318 A JPH0469318 A JP H0469318A
- Authority
- JP
- Japan
- Prior art keywords
- silicone
- graft copolymer
- water
- nail
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 35
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 12
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 10
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 6
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract 2
- 230000003796 beauty Effects 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract description 12
- 229920005989 resin Polymers 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000000049 pigment Substances 0.000 abstract description 4
- 239000004014 plasticizer Substances 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 2
- 238000001035 drying Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 acrylic compound Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical group CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000035597 cooling sensation Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 150000008282 halocarbons Chemical group 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical group COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical group CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- YWLXLRUDGLRYDR-ZHPRIASZSA-N 5beta,20-epoxy-1,7beta,10beta,13alpha-tetrahydroxy-9-oxotax-11-ene-2alpha,4alpha-diyl 4-acetate 2-benzoate Chemical compound O([C@H]1[C@H]2[C@@](C([C@H](O)C3=C(C)[C@@H](O)C[C@]1(O)C3(C)C)=O)(C)[C@@H](O)C[C@H]1OC[C@]12OC(=O)C)C(=O)C1=CC=CC=C1 YWLXLRUDGLRYDR-ZHPRIASZSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical group CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Chemical group CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- WPPDXAHGCGPUPK-UHFFFAOYSA-N red 2 Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=2C=3C4=CC=C5C6=CC=C7C8=C(C=9C=CC=CC=9)C9=CC=CC=C9C(C=9C=CC=CC=9)=C8C8=CC=C(C6=C87)C(C=35)=CC=2)C4=C1C1=CC=CC=C1 WPPDXAHGCGPUPK-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000001797 sucrose acetate isobutyrate Substances 0.000 description 1
- 235000010983 sucrose acetate isobutyrate Nutrition 0.000 description 1
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 description 1
- SYDJVRWZOWPNNO-UHFFFAOYSA-N sucrose-benzoate Natural products OCC1OC(OC2(COC(=O)c3ccccc3)OC(CO)C(O)C2O)C(O)C(O)C1O SYDJVRWZOWPNNO-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は、新規な美爪料に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a novel nail beauty product.
さらに詳しくは、乳化安定性、塗り易さ、乾燥性、塗膜
の光沢、はがれ特性に優れ、かつ爪に対する安全性の高
いW10乳化型美爪料に関する。More specifically, the present invention relates to a W10 emulsified nail polish that has excellent emulsion stability, ease of application, drying properties, gloss of a coating film, and peeling properties, and is highly safe for nails.
[従来の技術]
近年、美爪料は特にニトロセルロースラッカーの進歩に
よって、その品質は著しく向上し、メイクアップ化粧料
のひとつとして欠くべからざるものとなってきている。[Prior Art] In recent years, the quality of nail beauty products has significantly improved, especially with advances in nitrocellulose lacquer, and they have become indispensable as make-up cosmetics.
その品質の中で、爪に対する安全性は特に重要なもので
ある。Among these qualities, safety for nails is particularly important.
従来、美爪料の爪への安全性を向上させるための樹脂、
溶剤組成に関連した技術か開示されている。樹脂の安全
性向上に関する技術として特公昭50−13336号公
報には、分散してホルマリンを放出し爪に悪影響を及ぼ
すスルホンアミド樹脂の代わりにシュークローズベーン
ゾエート・シュークローズアセテートイソブチレートを
配合する技術が記載されている。溶剤の安全性に関する
技術としては特開昭54−160753号公報に、トル
エン、キシレン等の芳香族炭化水素を含有しない美爪料
が開示されている。これらの技術においては、何れも溶
剤型美爪料に関するものであり爪への水分補給が不可能
である点で安全性が充分ではないという欠点があった。Conventionally, resins have been used to improve the safety of nail polishes on nails.
Techniques related to solvent composition are disclosed. As a technology related to improving the safety of resins, Japanese Patent Publication No. 13336/1983 incorporates sucrose bene zoate and sucrose acetate isobutyrate instead of sulfonamide resin, which disperses and releases formalin, which has a negative effect on nails. The technology to do so is described. As a technology related to the safety of solvents, Japanese Patent Application Laid-open No. 160753/1983 discloses a nail polish that does not contain aromatic hydrocarbons such as toluene and xylene. These techniques all relate to solvent-based nail polishes and have the disadvantage that they are not sufficiently safe in that they cannot replenish moisture to the nails.
また、溶剤を含有しない美爪料の技術としては、特開昭
54−28836号公報に、特定モノマーの水性乳化重
合により得た水性乳濁液状ポリマーよりなる美爪塗膜剤
が記載されている。しかしながら、水系美爪料は、溶剤
と比較して蒸発熱、比熱が非常に大きい水を多量に含有
しているため、塗布時に「ひんやり感jが強く、爪の薄
い人にとっては、この「ひんやり感」が強い刺激となる
という欠点があった。さらに、これらの水系美爪料は溶
剤型美爪料と比較して耐水性、爪への接着性が劣り、は
がれ特性が充分でないという欠点があった。Furthermore, as a technology for nail beauty products that does not contain a solvent, Japanese Patent Application Laid-Open No. 54-28836 describes a nail beauty coating agent that is made of an aqueous emulsion liquid polymer obtained by aqueous emulsion polymerization of specific monomers. . However, water-based nail polishes contain a large amount of water, which has a much higher heat of evaporation and specific heat than solvents, so they give a strong cooling sensation when applied, which may be a problem for people with thin nails. It had the disadvantage that the ``feeling'' was a strong stimulus. Furthermore, these water-based nail preparations have the drawbacks of being inferior in water resistance and adhesion to nails, and insufficient peeling properties, compared to solvent-based nail preparations.
さらに、特開昭62−111909号公報には、溶剤型
美爪料の塗り易さ、塗膜の光沢、はがれ特性等を維持し
たまま、爪に対する安全性を向上させる目的で、通常の
溶剤型美爪料に水を配合したW10乳化型美爪料に関す
る技術が記載されている。Furthermore, Japanese Patent Application Laid-open No. 111909/1989 discloses that a solvent-based nail polish has been developed to improve nail safety while maintaining ease of application, gloss of the paint film, peeling properties, etc. A technique related to a W10 emulsified nail beauty product containing water is described.
[発明が解決しようとする課題]
しかしながら、W10乳化型美爪料の乳化安定性に関し
ては、未だ充分ではなく、また蒸発速度の遅い水を含有
していることから乾燥速度が遅いという欠点があった。[Problems to be Solved by the Invention] However, the emulsion stability of the W10 emulsified nail polish is still not sufficient, and it also has the drawback of slow drying speed because it contains water with a slow evaporation rate. Ta.
本発明者らは、こうした事情にかんがみ上記の欠点を解
決すべく鋭意研究を重ねた結果、W10乳化型美爪料に
アクリル変性シリコーンとラジカル重合性単量体をラジ
カル重合させてなるシリコーン系グラフト共重合体を配
合したならば、乳化安定性および塗膜の乾燥性に優れ、
しかも美爪料としての他の緒特性をも満足することを見
出し、この知見に基づいて本発明を完成するに至った。In view of these circumstances, the present inventors have conducted extensive research to solve the above-mentioned drawbacks, and as a result, we have developed a silicone-based graft made by radically polymerizing acrylic-modified silicone and a radically polymerizable monomer to W10 emulsified nail polish. If the copolymer is blended, it will have excellent emulsion stability and drying properties of the coating film.
Moreover, it was discovered that it also satisfies other properties as a nail beautifying agent, and based on this knowledge, the present invention was completed.
上記シリコーン系グラフト共重合体を皮膜形成剤として
配合した化粧料が特開平2−25411号公報に開示さ
れている。これに対し、本発明では化粧料の中でも特に
W10乳化型の美爪料において、その乳化安定性や塗膜
の乾燥性に優れた効果を発揮するものである。A cosmetic containing the above-mentioned silicone-based graft copolymer as a film-forming agent is disclosed in JP-A-2-25411. In contrast, the present invention exhibits excellent effects on emulsion stability and drying properties of the coating film, especially in the W10 emulsion type nail polish among cosmetics.
[課題を解決するための手段]
すなわち、本発明は、ニトロセルロース、溶剤、水溶性
高分子、水を含有するW10乳化型美爪料において、ア
クリル変性シリコーンとラジカル重合性単量体をラジカ
ル重合させてなるシリコーン系グラフト共重合体を含有
することを特徴とするW10乳化型美爪料を提供するも
のである。[Means for Solving the Problems] That is, the present invention provides a W10 emulsified nail polish containing nitrocellulose, a solvent, a water-soluble polymer, and water, in which acrylic-modified silicone and a radically polymerizable monomer are radically polymerized. The present invention provides a W10 emulsified nail polish containing a silicone-based graft copolymer.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明で用いられるシリコーン系グラフト共重合体は、
アクリル変性シリコーン(A)とラジカル重合性単量体
(B)をラジカル共重合させることによって合成される
ものである。The silicone-based graft copolymer used in the present invention is
It is synthesized by radical copolymerization of acrylic-modified silicone (A) and radically polymerizable monomer (B).
(A)のアクリル変成シリコーンは、下記の一般式(1
)で示されるシリコーンと一般式(II)で示されるア
クリル化合物とを(1)の5i−0旧当量あたり (I
I)の5i−Xを0.25〜1当量の比で縮合反応させ
て得ることができる。The acrylic modified silicone (A) has the following general formula (1
) and the acrylic compound represented by general formula (II) per 5i-0 old equivalent of (1) (I
It can be obtained by condensation reaction of 5i-X of I) at a ratio of 0.25 to 1 equivalent.
(I)R+ (Si ○)、H
(R+は炭素数1〜10の一価の脂肪族炭化水素基、フ
ェニル基、−価のハロゲン化炭化水素基又は水酸基。R
2およびR3は炭素数1−10の一価の脂肪族炭化水素
基、フェニル基又は−価のハロゲン化炭化水素基。nは
1以上の整数。)R4Re
(II) CH2=CC−ORs Si
Xo R6
および/または
CH2=CCORM Si X3(R4は水素
原子又はメチル基。R5は直鎖状又は分岐鎖状の炭素鎖
を有する炭素原子1〜10個の2価の飽和炭化水素基で
場合によりエーテル結合1個又は2個で遮断されている
。R6はメチル基、エチル基又はフェニル基。Xは塩素
原子、メトキシ基又はエトキシ基。)
一方(B)のラジカル重合性単量体としては、メタクリ
ル酸、メタクリル酸メチル、メタクリル酸エチノベメタ
クリル酸ブチル、メタクリル酸2エチルへキシル、メタ
クリル酸シクロヘキシル、メタクリル酸ステアリル、ア
クリル酸、アクリル酸メチル、アクリル酸エチル、アク
リル酸ブチル、スチレン、スチレン置換体、酢酸ビニル
の如き有機酸のビニルエステル、エチレン、プロピレン
の如き低分子量直鎖炭化水素、塩化ビニル、塩化ビニリ
デン、ポリオキシエチレンモノメタクリレート等が挙げ
られる。(I) R+ (Si ○), H (R+ is a monovalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, a phenyl group, a -valent halogenated hydrocarbon group, or a hydroxyl group. R
2 and R3 are a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, a phenyl group, or a -valent halogenated hydrocarbon group. n is an integer of 1 or more. )R4Re (II) CH2=CC-ORs Si
Xo R6 and/or CH2=CCORM Si (B) is blocked by one or two ether bonds. R6 is a methyl group, ethyl group, or phenyl group. X is a chlorine atom, methoxy group, or ethoxy group. Methacrylic acid, methyl methacrylate, ethinomethacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, stearyl methacrylate, acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, styrene, styrene substituted product , vinyl esters of organic acids such as vinyl acetate, low molecular weight linear hydrocarbons such as ethylene and propylene, vinyl chloride, vinylidene chloride, polyoxyethylene monomethacrylate, and the like.
アクリル変性シリコーンとラジカル重合性単量体の共重
合は、きわめて円滑に進行し、シリコーン系グラフト共
重合体を得ることができる。また、その分子量は公知の
重合技術によりコントロール可能である。このようにし
て製造されるシリコーン系グラフト共重合体におけるア
クリル変性シリコーンとラジカル重合性単量体との共重
合割合は、得られるシリコーン系クラフト共重合体中の
シリコーン含有量が5〜80重量%、好ましくは10〜
70重量%であることが望ましい。シリコーン系クラフ
ト共重合体の分子量はGPCにおけるポリスチレン換算
の重量平均分子量において、 約3、000〜約20
0,000 、より好ましくは約5.000〜約100
.000の範囲にあることが望ましい。The copolymerization of the acrylic-modified silicone and the radically polymerizable monomer proceeds extremely smoothly, and a silicone-based graft copolymer can be obtained. Further, its molecular weight can be controlled by known polymerization techniques. The copolymerization ratio of the acrylic modified silicone and the radically polymerizable monomer in the silicone-based graft copolymer produced in this way is such that the silicone content in the resulting silicone-based craft copolymer is 5 to 80% by weight. , preferably 10~
It is desirable that it be 70% by weight. The molecular weight of the silicone-based kraft copolymer is about 3,000 to about 20 in terms of weight average molecular weight in terms of polystyrene determined by GPC.
0,000, more preferably about 5,000 to about 100
.. It is desirable that the value be in the range of 000.
上記したアクリル変性シリコーンや該アクリル変性シリ
コーンとラジカル重合単量体をラジカル重合させてなる
シリコーン系グラフト共重合体は、たとえば特公昭60
−30715.特公平1−60162等に開示されてい
る方法により製造することできる。The above-mentioned acrylic-modified silicone and silicone-based graft copolymers obtained by radically polymerizing the acrylic-modified silicone and a radically polymerizable monomer are, for example,
-30715. It can be manufactured by the method disclosed in Japanese Patent Publication No. 1-60162.
シリコーン系グラフト共重合体の市販品としては、東亜
合成(a)類アロンG5−30等が挙げられる。Commercially available silicone graft copolymers include Toagosei (a) Aron G5-30 and the like.
配合量はシリコーン系グラフト共重合体の分子量にもよ
るが、GPCにおけるポリスチレン換算の重量平均分子
量か約30.000の場合、美爪料全量中0.2%〜1
0重量%の範囲で選択されるか、好ましくは1〜3重量
%である。0.2重量%未満では、乳化安定性、乾燥性
向上の効果が充分ではなく、10重量%を越えると塗り
易さが不良となるので好ましくない。The blending amount depends on the molecular weight of the silicone-based graft copolymer, but if the weight average molecular weight in terms of polystyrene in GPC is about 30.000, it will be 0.2% to 1% of the total amount of nail polish.
It is selected in the range of 0% by weight, preferably 1-3% by weight. If it is less than 0.2% by weight, the effects of improving emulsion stability and drying properties will not be sufficient, and if it exceeds 10% by weight, the ease of application will be poor, which is not preferable.
本発明で用いられるニトロセルロースは、通常用いられ
る周知のものを使用することができる。As the nitrocellulose used in the present invention, commonly used and well-known nitrocellulose can be used.
たとえばニトロセルロース1/2秒、ニトロセルロース
l /’ 4秒、ニトロセルロース1/8秒、ニトロセ
ルロース1/4秒等が挙げられる。これらの中から1種
または2種以上が任意に選択される。配合量は一般的に
は30%のイソプロピルアルコールで湿潤させた状態(
以下、30%イソプロピルアルコール湿潤度と称する)
で美爪料全量中5〜25重量%である。Examples include nitrocellulose 1/2 sec, nitrocellulose l/' 4 sec, nitrocellulose 1/8 sec, nitrocellulose 1/4 sec, and the like. One or more types are arbitrarily selected from these. The amount of compounding is generally moistened with 30% isopropyl alcohol (
(hereinafter referred to as 30% isopropyl alcohol wetness)
It accounts for 5 to 25% by weight of the total amount of nail polish.
本発明で用いられる溶剤は、通常用いられるエステル系
、アルコール系、炭化水素系等の周知のものを使用する
ことができる。たとえば酢酸エチル、酢酸ブチル、酢酸
アミル、エチルアルコール、イソプロピルアルコール、
ブチルアルコール、トルエン等が挙げられる。これらの
中から1種または2種以上か任意に選択される。配合量
は一般的には美爪料全量中50〜85重量%である。As the solvent used in the present invention, commonly used ester-based, alcohol-based, hydrocarbon-based, and other well-known solvents can be used. For example, ethyl acetate, butyl acetate, amyl acetate, ethyl alcohol, isopropyl alcohol,
Examples include butyl alcohol and toluene. One or more types may be arbitrarily selected from these. The blending amount is generally 50 to 85% by weight based on the total amount of the nail polish.
本発明における、水の配合量は美爪料全量中0.5〜3
0重量%、好ましくは3〜15重量%である。水の配合
量が0.5%未満では爪に対する安全性の向上効果が充
分でなく30重量%を越えると塗布時の1ひんやり感」
か強くなり、特に爪が薄いひとの場合強い刺激となって
いまうので好ましくない。In the present invention, the amount of water blended is 0.5 to 3 in the total amount of nail polish.
0% by weight, preferably 3-15% by weight. If the water content is less than 0.5%, the effect of improving nail safety will not be sufficient, and if it exceeds 30% by weight, a cooling sensation will occur when applied.
It is undesirable because it becomes hard and can cause strong irritation, especially for people with thin nails.
本発明で用いられる水溶性高分子としては、例えばセル
ロース系、アクリル系、ビニル系、ポリアミド系、タン
パク系、多糖類の水溶性高分子が挙げられる。たとえば
ヒドロキシプロピルセルローズ、メタクリル酸エステル
両性重合体、ポリビニルアルコール、カセインNa %
ヒアルロン酸またはその塩類等が挙げられる。配合量
は水に対して0,3〜20重量%、好ましくは0.5〜
15重量%である。Examples of water-soluble polymers used in the present invention include cellulose-based, acrylic-based, vinyl-based, polyamide-based, protein-based, and polysaccharide-based water-soluble polymers. For example, hydroxypropyl cellulose, methacrylic acid ester amphoteric polymer, polyvinyl alcohol, casein Na%
Examples include hyaluronic acid or its salts. The blending amount is 0.3 to 20% by weight based on water, preferably 0.5 to 20% by weight.
It is 15% by weight.
本発明の美爪料には上記構成成分の他に必要に応じて、
シリコーン系グラフト共重合体以外の樹脂、可塑剤、顔
料、香料、染料、パール剤、ラメ剤、薬剤、保湿剤、紫
外線吸収剤、艶消し剤、充填剤、界面活性剤、金属石鹸
等も配合することができる。もちろん、これらは本発明
の効果を損なわない質的、量的条件下で使用されなけれ
ばならない。In addition to the above-mentioned components, the nail beauty preparation of the present invention may optionally contain:
Contains resins other than silicone graft copolymers, plasticizers, pigments, fragrances, dyes, pearl agents, glitter agents, drugs, moisturizers, ultraviolet absorbers, matting agents, fillers, surfactants, metal soaps, etc. can do. Of course, these must be used under qualitative and quantitative conditions that do not impair the effects of the present invention.
本発明で用いられるシリコーン系グラフト共重合体以外
の樹脂としては、アルキッド系樹脂、アクリル系樹脂、
スルホンアミド系樹脂、ショ糖安息香酸エステル系樹脂
等の合成樹脂、あるいはロジン、シェラツク等の天然樹
脂等が挙げられる。Resins other than the silicone graft copolymer used in the present invention include alkyd resins, acrylic resins,
Examples include synthetic resins such as sulfonamide resins and sucrose benzoate resins, and natural resins such as rosin and shellac.
配合量は一般的には美爪料全量中5〜20重量%である
。The blending amount is generally 5 to 20% by weight based on the total amount of the nail polish.
本発明で用いられる可塑剤は、フタル酸エステル系、ク
エン酸エステル系等の周知のものを使用することができ
る。たとえばジブチルフタレート、ジオクチルフタレー
ト、クエン酸アセチルトリブチル、カンファー等が挙げ
られる。これらの中から1種または2種以上が任意に選
択される。配合量は一般的に美爪料全量中2〜8重量%
である。As the plasticizer used in the present invention, well-known plasticizers such as phthalate esters and citric esters can be used. Examples include dibutyl phthalate, dioctyl phthalate, acetyl tributyl citrate, and camphor. One or more types are arbitrarily selected from these. The amount added is generally 2-8% by weight of the total amount of nail polish.
It is.
本発明で用いられる顔料としては、たとえば酸化鉄(赤
)、酸化鉄(黄)、酸化鉄(黒)、酸化チタン等の無機
顔料、黄色4号、赤色226号、赤色202号、赤色2
04号等の有機顔料か挙げられる。配合量は一般的に美
爪料全量中5重量%以下である。Pigments used in the present invention include, for example, inorganic pigments such as iron oxide (red), iron oxide (yellow), iron oxide (black), titanium oxide, Yellow No. 4, Red No. 226, Red No. 202, Red 2
Examples include organic pigments such as No. 04. The blending amount is generally 5% by weight or less based on the total amount of the nail polish.
[発明の効果]
本発明のW10乳化型美爪料は、乳化安定性、塗膜の乾
燥性に優れた爪への安全性の高い美爪料で、しかも美爪
料として要求される他の緒特性を兼備するものである。[Effects of the Invention] The W10 emulsified nail beauty product of the present invention is a nail beauty product that is highly safe for nails with excellent emulsion stability and drying properties of the coating film, and also meets other requirements as a nail beauty product. It has the following characteristics.
[実施例] 次に実施例によって、本発明をさらに詳細に説明する。[Example] Next, the present invention will be explained in more detail with reference to Examples.
本発明はこれらにより限定されるものではない。配合量
は重量%である。実施例に先立ち、本発明の効果試験方
法及び評価方法を示す。The present invention is not limited to these. The blending amount is in weight%. Prior to Examples, the effectiveness testing method and evaluation method of the present invention will be described.
乳化安定性
各試料をl5rnlのガラスピン2本に各々に充填し、
これらを室温および50℃で5力月放置し、各々の分離
の状態を評価した。Emulsion stability Each sample was filled into two 15rnl glass pins,
These were left at room temperature and 50° C. for 5 months, and the state of each separation was evaluated.
両方とも全く分離しなかった・・・・・・・・・・・・
・・・・・・・・・・・・◎いずれか一方または両方が
わずかに分離した・・・○いずれか一方または両方が分
離した・・・・・・・・・・・・・・・◇いずれか一方
が非常に分離した・・・・・・・・・・・・・・・・・
・・・・△両方とも非常に分離した・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・×塗り易
さ
実際の使用において官能で評価した。Both were not separated at all...
・・・・・・・・・・・・◎One or both separated slightly・・・○One or both separated・・・・・・・・・・・・・・・◇One of the two was very separated...
・・・・・・△Both were very separated・・・・・・・・・
・・・・・・・・・・・・・・・・・・×Ease of application Sensory evaluation was performed in actual use.
非常に塗り易い・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・◎
やや塗り易い・・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・○やや塗り難い・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・・・◇塗り難い・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・△非常に塗り難い・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・×灸血11
実際の使用において、塗布直後から指先でふれた時の指
紋がつかなくなるまでの時間を測定した2〜3分
3〜4分
4〜5分
5〜6分
6分以上
(以下余白)
実施例1〜8、比較例1〜5
表−1に示す組成でW/○乳化型美爪料を製造し、それ
ぞれの品質評価を行った。Very easy to apply・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・◎
Slightly easy to apply・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・
・○ Slightly difficult to apply・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・
・・・◇Difficult to paint・・・・・・・・・・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・△Very difficult to apply・・・・・・・・・
・・・・・・・・・・・・・・・・・・・・・・・・
・・・・・・・・・× Moxibustion blood 11 In actual use, the time taken from immediately after application until no fingerprints remain when touched with a fingertip was measured: 2 to 3 minutes 3 to 4 minutes 4 to 5 minutes 5 ~6 minutes 6 minutes or more (hereinafter referred to as blank space) Examples 1 to 8, Comparative Examples 1 to 5 W/○ emulsified nail polishes were manufactured with the compositions shown in Table 1, and the quality of each was evaluated.
(製法)
クエン酸アセチルトリエチル、溶剤を攪拌混合した後、
ニトロセルロース、樹脂を添加し、攪拌溶解する。つい
で顔料、有機ベントナイト系ゲル化剤を添加して攪拌分
散した後、水溶性高分子水溶液、1.3−ブチレングリ
コールを添加し、均一に攪拌(乳化)してW10型乳化
型美爪料を得た。(Production method) After stirring and mixing acetyltriethyl citrate and a solvent,
Add nitrocellulose and resin and stir to dissolve. Next, the pigment and organic bentonite gelling agent were added and dispersed with stirring, and then the water-soluble polymer aqueous solution and 1,3-butylene glycol were added and uniformly stirred (emulsified) to form a W10 emulsified nail polish. Obtained.
表−1から明らかなようにシリコーン系グラフト共重合
体を配合した実施例1〜8は、乳化安定性、塗り易さ、
乾燥速度の各項目に優れていた。As is clear from Table 1, Examples 1 to 8 in which silicone-based graft copolymers were blended had good emulsion stability, ease of application,
It was excellent in each item of drying speed.
更に、塗膜の脆さ、爪への接着力も問題なかった。それ
に対し、比較例1は、シリコーン系グラフト共重合体を
配合していないため、比較例2は、シリコーン系クラフ
ト共重合体の配合量が少ないため、乳化安定性、乾燥速
度で劣り好ましくなかった。比較例3、は、シリコーン
系グラフト共重合体の配合量か多過きるため塗り易さで
劣り好ましくなかった。ニトロセルロースおよびシリコ
ーン系クラフト共重合体以外の樹脂を減らして塗り易さ
を改善した比較例4は、塗膜の脆さ、爪への接着力の点
で劣り好ましくなかった。Furthermore, there were no problems with the brittleness of the coating film or its adhesion to nails. On the other hand, Comparative Example 1 did not contain a silicone-based graft copolymer, and Comparative Example 2 contained a small amount of silicone-based kraft copolymer, resulting in poor emulsion stability and drying speed, which was not preferable. . Comparative Example 3 was unfavorable because the amount of silicone graft copolymer was too large, resulting in poor ease of application. Comparative Example 4, in which ease of application was improved by reducing the amount of resin other than nitrocellulose and silicone-based kraft copolymer, was unfavorable in terms of brittleness of the coating film and poor adhesion to nails.
Claims (2)
有するW/O乳化型美爪料において、アクリル変性シリ
コーンとラジカル重合性単量体をラジカル重合させてな
るシリコーン系グラフト共重合体を含有することを特徴
とするW/O乳化型美爪料。(1) In a W/O emulsion type nail polish containing nitrocellulose, a solvent, a water-soluble polymer, and water, a silicone-based graft copolymer obtained by radically polymerizing an acrylic-modified silicone and a radically polymerizable monomer is used. A W/O emulsified nail beauty product characterized by containing:
をラジカル重合させてなるシリコーン系グラフト共重合
体の配合量が0.2〜10重量%である請求項1記載の
W/O乳化型美爪料。(2) W/O emulsion type beautiful nails according to claim 1, wherein the amount of the silicone graft copolymer obtained by radical polymerization of acrylic modified silicone and a radically polymerizable monomer is 0.2 to 10% by weight. fee.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17917690A JP2920661B2 (en) | 1990-07-06 | 1990-07-06 | Nail polish |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17917690A JP2920661B2 (en) | 1990-07-06 | 1990-07-06 | Nail polish |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0469318A true JPH0469318A (en) | 1992-03-04 |
JP2920661B2 JP2920661B2 (en) | 1999-07-19 |
Family
ID=16061269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17917690A Expired - Fee Related JP2920661B2 (en) | 1990-07-06 | 1990-07-06 | Nail polish |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2920661B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08143427A (en) * | 1994-11-24 | 1996-06-04 | Kose Corp | Manicure |
JP2008247795A (en) * | 2007-03-30 | 2008-10-16 | Kose Corp | Solvent-based manicure material |
FR2930143A1 (en) * | 2008-04-18 | 2009-10-23 | Oreal | Composition in an emulsion form useful for the makeup of nails, comprises a continuous phase and a dispersed phase, where the continuous phase comprises film forming polymers |
FR2930144A1 (en) * | 2008-04-18 | 2009-10-23 | Oreal | NAIL VARNISH IN THE FORM OF EMULSION, COMPRISING A PARTICULAR GELIFYING AGENT |
-
1990
- 1990-07-06 JP JP17917690A patent/JP2920661B2/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08143427A (en) * | 1994-11-24 | 1996-06-04 | Kose Corp | Manicure |
JP2008247795A (en) * | 2007-03-30 | 2008-10-16 | Kose Corp | Solvent-based manicure material |
FR2930143A1 (en) * | 2008-04-18 | 2009-10-23 | Oreal | Composition in an emulsion form useful for the makeup of nails, comprises a continuous phase and a dispersed phase, where the continuous phase comprises film forming polymers |
FR2930144A1 (en) * | 2008-04-18 | 2009-10-23 | Oreal | NAIL VARNISH IN THE FORM OF EMULSION, COMPRISING A PARTICULAR GELIFYING AGENT |
EP2158941A3 (en) * | 2008-04-18 | 2012-01-18 | L'Oréal | Emulsion Nail coating comprising a specific gelling agent |
Also Published As
Publication number | Publication date |
---|---|
JP2920661B2 (en) | 1999-07-19 |
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