JPH0452239A - Alloy having high transmitting property and connector for connecting to audio-video equipment using the above - Google Patents

Alloy having high transmitting property and connector for connecting to audio-video equipment using the above

Info

Publication number
JPH0452239A
JPH0452239A JP16353490A JP16353490A JPH0452239A JP H0452239 A JPH0452239 A JP H0452239A JP 16353490 A JP16353490 A JP 16353490A JP 16353490 A JP16353490 A JP 16353490A JP H0452239 A JPH0452239 A JP H0452239A
Authority
JP
Japan
Prior art keywords
alloy
added
improvement
connector
audio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16353490A
Other languages
Japanese (ja)
Inventor
Yasumutsu Nagai
康睦 永井
Shuji Sakai
修二 酒井
Yasuo Ota
康夫 太田
Kazuo Sugaya
菅谷 和雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Cable Ltd
Original Assignee
Hitachi Cable Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Cable Ltd filed Critical Hitachi Cable Ltd
Priority to JP16353490A priority Critical patent/JPH0452239A/en
Publication of JPH0452239A publication Critical patent/JPH0452239A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To improve the mechanical strength (electrical contact by elasticity) of an alloy without deteriorating its electrical characteristic and to improve its signal transmitting capacity by mixing oxygen free copper with specified amounts of Au, Ag, Pt and Pd having an atomic size close to that of copper. CONSTITUTION:This alloy having high transmitting properties is formed by mixing oxygen free copper having <=10ppm oxygen concn. with 0.2 to 3atomic% of one or more kinds among Au, Ag, Pt and Pd. Concerning to the amounts to be added, as for Ag, as the amt. to be added increases, the improvement of sound quality in acoustic sense such as the expansion of the area of audible sounds, the improvement or resolution and the improvement of dynamic range can be recognized. But, even if the amt. of the lower limit is added, the above degrees are made low, and in the case of the upper limit or above, the improvement of sound quality is bunted, and the effect corresponding to the cost can not be obtd. Furthermore, as for the other elements to be added, the similar relationship can be shown between the amounts to be added and the improvement of sound. By using this alloy to a connector for connecting audio-video equipment, its transmitting capacity can be improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は高伝送特性合金およびそれを用いたオーディオ
・ビデオ機器接続用コネクタ(ケーブル端末プラグ、ジ
ャック、スピーカケーブル接続用ターミナル等を含む)
に関し、特に、接続部の機械的強度(を気的接触)を低
下させずに信号伝送特性を向上したコネクタ用無酸素銅
合金およびそれを用いたオーディオ・ビデオ機器接続用
コネクタに関する。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to an alloy with high transmission properties and a connector for connecting audio/video equipment using the same (including cable terminal plugs, jacks, terminals for connecting speaker cables, etc.)
In particular, the present invention relates to an oxygen-free copper alloy for connectors that has improved signal transmission characteristics without reducing the mechanical strength (gas contact) of the connection part, and a connector for connecting audio/video equipment using the same.

〔従来の技術〕[Conventional technology]

近年のオーディオ・ビデオ機器の飛躍的進歩により、高
音質・高画質の音楽、音声、映像が視聴者に提供されて
いる。
BACKGROUND OF THE INVENTION Due to the dramatic advances in audio and video equipment in recent years, high-quality music, audio, and video are now available to viewers.

これらの質的向上の要因の一つには、配線材料の進歩が
挙げられる。具体的には、タフピッチ銅から無酸素銅へ
、そして線形結晶無酸素銅(LCOFC)や単結晶状無
酸素銅(pc−occ)への移行等、導電材料の面から
伝送性能の向上が図られている。
One of the factors behind these qualitative improvements is advances in wiring materials. Specifically, improvements in transmission performance are expected from the perspective of conductive materials, such as the transition from tough pitch copper to oxygen-free copper, and then to linear crystalline oxygen-free copper (LCOFC) and single-crystal oxygen-free copper (PC-OCC). It is being

更に、伝送性能を向上させるためには、機能別に分化し
ている複数の機器(例えば、アンプ、CDプレーヤー、
カセットデツキ等)を一体にし、これらを接続するため
のコネクタを排除するのが最も好ましいが、オーディオ
・ビデオ機器は、高級機はと機能が細分化して音楽や映
像の鑑賞に必要となる機器の数が増加する傾向にあるこ
と、また、衛星放送に代表されるようなプログラムソー
スのマルチメディア化や、ビデオテープレコーダ(VT
R)にみられる記録フォーマットの乱立によりプログラ
ムソース供給源が増加していること等からますます機器
間の接続を必要とし、コネクタ数の増加を余儀なくされ
ている。このため、高音質化・高画質化と相反するコネ
クタは必要悪として存在し、最終的にはコネクタ自身の
材質の向上が求められている。
Furthermore, in order to improve transmission performance, it is necessary to use multiple devices that are differentiated by function (for example, amplifiers, CD players,
It is most preferable to integrate all cassette decks (cassette decks, etc.) and eliminate the connectors used to connect them. In addition, the number of program sources is increasing, and program sources such as satellite broadcasting are becoming multimedia, and video tape recorders (VT) are becoming increasingly popular.
R) Due to the proliferation of recording formats and the increase in program source sources, connections between devices are becoming increasingly necessary and the number of connectors has been forced to increase. For this reason, connectors that conflict with higher sound quality and higher image quality exist as a necessary evil, and ultimately there is a need to improve the quality of the material of the connector itself.

従来のオーディオ・ビデオ機器のコネクタは、はとんど
の場合、黄銅やリン青銅をプレスや引抜き加工して成形
(高級品では削り出し)されている。即ち、前述した無
酸素銅をはじめとする純銅系の素材は、音響、映像上の
質的向上には効果があるものの、素材自身が柔らかいた
め、材料の弾性により電気的接触を維持するコネクタに
は接触圧の点で不適当であるため用いることができない
Connectors for conventional audio and video equipment are usually made of brass or phosphor bronze by pressing or drawing (machining for high-end products). In other words, although pure copper-based materials such as the aforementioned oxygen-free copper are effective in improving audio and visual quality, the material itself is soft, so it cannot be used as a connector that maintains electrical contact due to the material's elasticity. cannot be used because the contact pressure is inadequate.

一部に、接続コードの端末プラグのコンタクト材料とし
てLC−OFCやPC−OCCを用いた製品もあるが、
両材料とも基本的には無酸素銅の強加工材であり、ばね
性に必要な硬さに限界があるため、コネクタの受は側(
ジャック7あるいはレセプタクル)に応用した例はない
が、プラグ側に応用されることがある。
There are some products that use LC-OFC or PC-OCC as the contact material for the terminal plug of the connection cord.
Both materials are basically strongly processed oxygen-free copper materials, and there is a limit to the hardness required for springiness, so the connector socket is placed on the side (
Although there is no example of this being applied to the jack 7 or receptacle, it may be applied to the plug side.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、従来のオーディオ・ビデオ機器接続用コネクタ
によると、黄銅やリン青銅から成形されるため、いくら
他の配線部の材料に無酸素銅等を使用して高品質化を図
っても伝送性能の向上に限界があるという不都合がある
。また、無酸素銅の強加工材を使用したとしても、高い
ばね力を要求されるコネクタの受は側に応用することが
できないため、やはり伝送性能の向上に限界がある。
However, conventional connectors for connecting audio/video equipment are molded from brass or phosphor bronze, so no matter how high the quality is achieved by using other materials such as oxygen-free copper for the wiring parts, the transmission performance remains low. The disadvantage is that there are limits to improvement. Further, even if a strongly processed material of oxygen-free copper is used, there is still a limit to the improvement in transmission performance because it cannot be applied to the side of a connector that requires a high spring force.

従って、本発明の目的は無酸素銅の電気性能を低下させ
ずに機械的強度(弾性による電気的接触)を向上させる
ことにより、信号伝送性能を向上させることができる高
伝送特性合金およびそれを用いたオーディオ・ビデオ機
器接続用コネクタを提供することである。
Therefore, the object of the present invention is to provide an alloy with high transmission properties that can improve signal transmission performance by improving the mechanical strength (electrical contact due to elasticity) without reducing the electrical performance of oxygen-free copper. An object of the present invention is to provide a connector for connecting audio/video equipment using the present invention.

〔課題を解決するための手段〕[Means to solve the problem]

本発明は以上述べた目的を実現するため、酸素濃度10
ppm以下の無酸素銅に、Au、AgPt、Pdの何れ
か一種類以上を0.2〜3at%添加した高伝送特性合
金を提供するものである。
In order to achieve the above-mentioned object, the present invention has an oxygen concentration of 10
The present invention provides an alloy with high transmission characteristics in which 0.2 to 3 at% of one or more of Au, AgPt, and Pd is added to oxygen-free copper of ppm or less.

また、上記目的を実現するため、酸素濃度10ppm以
下の無酸素銅に、Au、Ag、Pt、Pdの何れか一種
類以上を0.2〜3at%添加して成る高伝送特性合金
から成形したオーディオ・ビデオ機器接続用プラグを提
供するものである。
In addition, in order to achieve the above object, an alloy with high transmission characteristics is formed by adding 0.2 to 3 at% of one or more of Au, Ag, Pt, and Pd to oxygen-free copper with an oxygen concentration of 10 ppm or less. It provides a plug for connecting audio/video equipment.

この材料が信号伝送性能を向上させる理由は定かではな
いが、本発明で用いる添加元素の原子半径は、黄銅やリ
ン青銅に添加されているZn(亜鉛)、Sn(錫)、P
(燐)等に比べて小さく、ベースであるCu(銅)のそ
れと15%以内の差に収まっているため、結晶相互の乱
れを緩やかに整合し、添加量自身も3at%以下と少な
いこともあって、伝送特性の劣化を少なくしているので
はないかと推測される。
Although it is not clear why this material improves signal transmission performance, the atomic radius of the additive elements used in the present invention is similar to that of Zn (zinc), Sn (tin), and P, which are added to brass and phosphor bronze.
(phosphorus), etc., and the difference is within 15% from that of the base Cu (copper), so it gently matches the mutual disorder of the crystals, and the amount itself can be as small as 3 at% or less. It is speculated that this may reduce deterioration of transmission characteristics.

なお、添加量に関して、Agについて見ると、添加量が
多くなるほど、可聴音域の拡大1分解能の向上、ダイナ
ミックレンジの向上等、聴感上の音質向上が確認される
が、0,01at%を添加してもその程度は小さく、添
加の降下的な範囲は0.2at%以上といえる。しかし
、約3at%以上添加した場合の音質向上が鈍化してい
くため、コスト的に見合う効果が得られない。従って、
適切な添加量は0.2〜3at%といえる。他の添加元
素(Au、Pt、Pd)についても、添加量と音質向上
の間に同様な関係が見られ、適切な添加範囲はAgとほ
ぼ同じである。
Regarding the amount of Ag added, as the amount of Ag added increases, it is confirmed that the audible sound quality improves, such as the expansion of the audible range, the improvement of the resolution, and the improvement of the dynamic range. However, the degree of decrease is small, and the range of decreasing addition can be said to be 0.2 at% or more. However, if more than about 3 at% is added, the improvement in sound quality slows down, so no cost-effective effect can be obtained. Therefore,
It can be said that an appropriate amount of addition is 0.2 to 3 at%. Regarding other additive elements (Au, Pt, Pd), a similar relationship is seen between the amount of addition and improvement in sound quality, and the appropriate range of addition is almost the same as that of Ag.

〔実施例〕〔Example〕

以下、本発明の高伝送特性合金およびそれを用いたオー
ディオ・ビデオ機器接続用コネクタを詳細に説明する。
Hereinafter, the high transmission property alloy of the present invention and the connector for connecting audio/video equipment using the same will be explained in detail.

第1図(a)、 (b)は本発明の一実施例であり、(
a)はオーディオ・ビデオ機器の接続ケーブル用プラグ
3を、(ハ)は機器のパネルに取付けられて内部配線と
接続されるジャック4をそれぞれ示す。このプラグ3お
よびジャック4は最も普及しているRCAタイプと呼ば
れるものであり、信号が不平衡型と呼ばれる2線弐の伝
送方式により受は渡される。
FIGS. 1(a) and 1(b) show an embodiment of the present invention, and (
A) shows a plug 3 for a connecting cable of audio/video equipment, and (c) shows a jack 4 that is attached to a panel of the equipment and connected to internal wiring. The plug 3 and jack 4 are of the most popular type called RCA type, and signals are received by a two-wire transmission method called an unbalanced type.

プラグ3は導体Iが、無酸素銅CM素濃度10ppm以
下〕にAg(銀)を3at%添加した合金から成形され
、ホット側の信号を伝えるセンタービン1bと、コール
ド側の信号を伝える円筒状のスリーブ1aの2つのコン
タクト材を有し、センタービン1bとスリーブ1aの間
に絶縁体2aが設けられている。
The plug 3 has a conductor I made of an alloy containing 3 at% Ag (silver) added to oxygen-free copper CM with an elementary concentration of 10 ppm or less, and has a center bin 1b that transmits a hot side signal and a cylindrical shape that transmits a cold side signal. The sleeve 1a has two contact materials, and an insulator 2a is provided between the center pin 1b and the sleeve 1a.

一方、ジャック4の導体1も、コネクタ3と同様に無酸
素置(酸素濃度1oppm以下)にAg(銀)を3at
%添加した合金から成形され、センタービン1bが挿入
される挿入孔1c(ホット側)と、スリーブ1aに挿入
される嵌入筒1d(コールド側)の2つのコンタクト材
を有し、挿入孔1cと嵌入筒1dの間に絶縁体2bが設
けられている。
On the other hand, similarly to the connector 3, the conductor 1 of the jack 4 is also coated with 3at of Ag (silver) in an oxygen-free environment (oxygen concentration 1 oppm or less).
It has two contact materials: an insertion hole 1c (hot side) into which the center bottle 1b is inserted, and a fitting tube 1d (cold side) into which the sleeve 1a is inserted. An insulator 2b is provided between the fitting tubes 1d.

このようなプラグ3とジャック4は、第2図に示すよう
に、プラグ3のセンタービン1bがジャック4の挿入孔
ICに、ジャンク4の嵌入筒1dがプラグ3のスリーブ
1aにそれぞれ挿入され、嵌合するようになっている。
As shown in FIG. 2, the plug 3 and jack 4 are such that the center pin 1b of the plug 3 is inserted into the insertion hole IC of the jack 4, and the insertion tube 1d of the junk 4 is inserted into the sleeve 1a of the plug 3. They are designed to fit together.

両者の接触圧は材料の弾性係数とプラグ3とジャック4
の寸法精度に依存する嵌合度に左右され、プラグ3とジ
ャック4の電気的接続によりケーブルからの信号は機器
に伝送される。
The contact pressure between the two is determined by the elastic modulus of the material and the plug 3 and jack 4.
The signal from the cable is transmitted to the device by the electrical connection between the plug 3 and the jack 4, depending on the degree of fit which depends on the dimensional accuracy of the plug 3 and the jack 4.

次に、本発明のプラグ3およびジャック4の信号伝送性
能を調べるために、Cuに33a t%Zn(亜鉛)を
添加した合金(黄銅)の圧延材(厚さ0.5mm)を用
いたプラグおよびジャックを製造して、両者を音響機器
に適用し、比較試聴した。
Next, in order to investigate the signal transmission performance of the plug 3 and jack 4 of the present invention, a plug using a rolled material (thickness 0.5 mm) of an alloy (brass) in which 33a t% Zn (zinc) is added to Cu. and a jack were manufactured, and both were applied to audio equipment for comparative listening.

即ち、プラグを接続用の同軸シールドケーブルの両端に
スポット溶接で取付け、また、ジャックはCD (co
lipact disk)プレーヤの音声出力端子およ
びアンプの入力端子に用い、アンプに接続したスピーカ
から音質を判断した。
That is, the plugs are spot welded to both ends of the coaxial shielded cable for connection, and the jack is a CD (co
lipact disk) was used as the audio output terminal of the player and the input terminal of the amplifier, and the sound quality was determined from the speaker connected to the amplifier.

その結果、本発明のCu−Ag合金を用いた方が、黄銅
のものに比べて音の透明感1重厚感、臨場感等において
明らかに聴感上好ましい結果が得られた。また、本発明
のプラグ3とジャック4の挿抜試験を行ったところ、プ
ラグ3の挿抜回数が増えても電気的接触が低下しないこ
とが判った。
As a result, the use of the Cu-Ag alloy of the present invention clearly provided better audible results than those made of brass in terms of sound transparency, depth, realism, etc. Further, when the plug 3 and jack 4 of the present invention were tested for insertion and removal, it was found that the electrical contact did not deteriorate even if the number of insertions and removals of the plug 3 increased.

第3図は本発明の第2の実施例であり、アンプとスピー
カの接続ターミナル、その中でも、−船釣な陸式ターミ
ナルと呼ばれるタイプを示し、アンプあるいはスピーカ
の筐体8に螺合したボルトネジ7にケーブル素線5をか
らげて締付けることにより、ナツトネジ6でケーブル素
線5を押圧するようになっている。このナツトネジ6お
よびボルトネジ7は無酸素銅に銀を3at%添加した合
金から成形されており、優れた信号伝送性能を提供する
ことができる。
FIG. 3 shows a second embodiment of the present invention, and shows a connection terminal for an amplifier and a speaker, and among them, a type called a land-type terminal, which is a bolt screw screwed into the housing 8 of the amplifier or speaker. By twisting and tightening the cable strand 5 on the nut 7, the cable strand 5 is pressed by the nut screw 6. The nut screw 6 and the bolt screw 7 are formed from an alloy of oxygen-free copper with 3 at % silver added, and can provide excellent signal transmission performance.

また、RCAタイプのプラグの他に、DINプラグ、ま
たは一部の高級機や業務用機器の音声信号伝送用コネク
タとして使用され、信号のホット。
In addition to the RCA type plug, it is also used as a DIN plug or as a connector for audio signal transmission in some high-end machines and commercial equipment, and is used as a connector for transmitting hot signals.

コールド、そしてアースが独立した3線式の平衡伝送方
式に対応したキャノンタイプと呼ばれるプラグに適用し
ても良い。
It may also be applied to a plug called a Cannon type that supports a three-wire balanced transmission system with independent cold and grounding.

更に、オーディオ・ビデオ機器以外の機器、例えば、O
A機器のコネクタ、端子等に適用しても良い。
Furthermore, equipment other than audio/video equipment, e.g.
It may also be applied to connectors, terminals, etc. of A equipment.

〔発明の効果〕〔Effect of the invention〕

以上説明した通り、本発明の高伝送特性合金およびそれ
を用いたオーディオ・ビデオ機器接続用プラグによると
、酸素濃度10ppm以下の無酸素銅に、銅に近い原子
径を有するAu、Ag。
As explained above, according to the high transmission characteristic alloy of the present invention and the plug for connecting audio/video equipment using the same, Au and Ag having atomic diameters close to that of copper are added to oxygen-free copper with an oxygen concentration of 10 ppm or less.

Pt、Pdの何れか一種類以上を0.2〜3at%添加
したため、電気的特性を低下させずに機械的強度(弾性
による電気的接触)を向上させ、信号伝送性能を向上さ
せることができる。
Since 0.2 to 3 at% of one or more of Pt and Pd is added, mechanical strength (electrical contact due to elasticity) can be improved without deteriorating electrical properties, and signal transmission performance can be improved. .

【図面の簡単な説明】[Brief explanation of drawings]

第1図(a)、 (b)は本発明の一実施例を示す説明
図、第2図はコネクタとジャックの嵌合状態を示す説明
図、第3図は本発明の第2の実施例を示す説明図。 符号の説明 1〜・−・・−−−〜−−導体      1a−・−
−−一−−スリーブ1 b−−−−〜−−−−・−セン
タービン 1 c −−−−−−一挿入孔d 2a 3−・ 7−・ 嵌入筒 2 b −−−−−一絶縁体 プラグ ケーブル素線 ・−ボルトネジ ・−ジャック ナツトネジ 筐体 特許出願人 日立t&!株式会社 代理人   弁理士   平 1)忠 離開     
    酒  井  宏  明1 −導体 1a−スリーブ tb−−センターピン 1cm挿入孔 1(1−嵌入筒 2a−絶縁体 2b−一絶縁体 3−−−−プラグ 4−・−ジャック 5−−−−一ケーブル素線 6−−−−−−ナツトネジ 7−−−ポルトネジ 8−−一一−−筐体 (Q) (b) 第2図 第3図
FIGS. 1(a) and (b) are explanatory diagrams showing one embodiment of the present invention, FIG. 2 is an explanatory diagram showing a fitted state of a connector and a jack, and FIG. 3 is a second embodiment of the present invention. An explanatory diagram showing. Explanation of symbols 1~・−・・−−−~−−Conductor 1a−・−
---1--Sleeve 1 b--------------Center bin 1 c ----1 Insertion hole d 2a 3-・7-- Fitting tube 2 b ----1 Insulator plug cable bare wire/-bolt screw/-jack nut screw housing Patent applicant Hitachi t&! Agent Co., Ltd. Patent Attorney Hei 1) Tadashi Rikai
Hiroshi Sakai 1 - Conductor 1a - Sleeve tb - Center pin 1cm insertion hole 1 (1 - Insertion tube 2a - Insulator 2b - Insulator 3 - Plug 4 - Jack 5 - - - One Cable wire 6 --- Nut screw 7 --- Port screw 8 --- 11 --- Housing (Q) (b) Figure 2 Figure 3

Claims (2)

【特許請求の範囲】[Claims] (1)酸素濃度10ppm以下の無酸素銅にAu、Ag
、Pt、Pdの何れか一種類以上を、0.2〜3原子パ
ーセント(以下、at%と表す)添加して成ることを特
徴とする高伝送特性合金。
(1) Au, Ag on oxygen-free copper with an oxygen concentration of 10 ppm or less
, Pt, and Pd in an amount of 0.2 to 3 atomic percent (hereinafter referred to as at%).
(2)酸素濃度10ppm以下の無酸素銅にAu、Ag
、Pt、Pdの何れか一種類以上を、0.2〜3at%
添加して成る高伝送特性合金から成形されていることを
特徴とするオーディオ・ビデオ機器接続用コネクタ。
(2) Au, Ag on oxygen-free copper with an oxygen concentration of 10 ppm or less
, Pt, Pd, 0.2 to 3 at%
A connector for connecting audio/video equipment, characterized in that it is molded from an alloy with high transmission properties and is made of an alloy with additives.
JP16353490A 1990-06-20 1990-06-20 Alloy having high transmitting property and connector for connecting to audio-video equipment using the above Pending JPH0452239A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16353490A JPH0452239A (en) 1990-06-20 1990-06-20 Alloy having high transmitting property and connector for connecting to audio-video equipment using the above

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16353490A JPH0452239A (en) 1990-06-20 1990-06-20 Alloy having high transmitting property and connector for connecting to audio-video equipment using the above

Publications (1)

Publication Number Publication Date
JPH0452239A true JPH0452239A (en) 1992-02-20

Family

ID=15775708

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16353490A Pending JPH0452239A (en) 1990-06-20 1990-06-20 Alloy having high transmitting property and connector for connecting to audio-video equipment using the above

Country Status (1)

Country Link
JP (1) JPH0452239A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022195123A1 (en) * 2021-03-19 2022-09-22 Mundorf Eb Gmbh Copper-silver-gold alloy

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022195123A1 (en) * 2021-03-19 2022-09-22 Mundorf Eb Gmbh Copper-silver-gold alloy
DE102021106875A1 (en) 2021-03-19 2022-09-22 Mundorf Eb Gmbh Copper-Silver-Gold Alloy
DE102021106875B4 (en) 2021-03-19 2023-09-28 Mundorf Eb Gmbh Copper-silver-gold alloy

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