JPH0451938B2 - - Google Patents

Info

Publication number
JPH0451938B2
JPH0451938B2 JP59204150A JP20415084A JPH0451938B2 JP H0451938 B2 JPH0451938 B2 JP H0451938B2 JP 59204150 A JP59204150 A JP 59204150A JP 20415084 A JP20415084 A JP 20415084A JP H0451938 B2 JPH0451938 B2 JP H0451938B2
Authority
JP
Japan
Prior art keywords
frame
thickness
power generation
exterior film
generation element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59204150A
Other languages
Japanese (ja)
Other versions
JPS6185766A (en
Inventor
Yoshihisa Hino
Hiroyuki Takayanagi
Miche Yoshioka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FDK Corp
Original Assignee
FDK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FDK Corp filed Critical FDK Corp
Priority to JP59204150A priority Critical patent/JPS6185766A/en
Publication of JPS6185766A publication Critical patent/JPS6185766A/en
Publication of JPH0451938B2 publication Critical patent/JPH0451938B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/552Terminals characterised by their shape
    • H01M50/553Terminals adapted for prismatic, pouch or rectangular cells
    • H01M50/555Window-shaped terminals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/547Terminals characterised by the disposition of the terminals on the cells
    • H01M50/548Terminals characterised by the disposition of the terminals on the cells on opposite sides of the cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Description

【発明の詳細な説明】 《産業上の利用分野》 この発明は、一般にシート形電池とかペーパー
形電池と称されている薄形電池の製造方法の改良
に関する。
DETAILED DESCRIPTION OF THE INVENTION <<Industrial Application Field>> The present invention relates to an improvement in a method for manufacturing a thin battery generally referred to as a sheet type battery or a paper type battery.

《従来の技術》 薄形電池の代表的な構造の1つに、外装フイル
ムの周縁シール部に額縁状の枠体を介在させる構
成のものがある。この構成の薄形電池の従来の製
造工程を第4図に示している。
<<Prior Art>> One typical structure of a thin battery is one in which a frame-like frame is interposed in the peripheral seal portion of an exterior film. A conventional manufacturing process for a thin battery having this configuration is shown in FIG.

まず第4図Aのように、プラスチツクを主体に
したラミネートフイルムからなる四角形の外装フ
イルム10を用意し、その周縁部を除く上面側に
負極集電板12を接着するとともに、このフイル
ム10とほぼ同じ外径寸法の合成樹脂製の枠体1
4を外装フイルム10の上面周縁部に接着する。
First, as shown in FIG. 4A, a rectangular exterior film 10 made of a laminate film mainly made of plastic is prepared, a negative electrode current collector plate 12 is adhered to the upper surface side excluding the peripheral edge, and the film 10 is approximately Synthetic resin frame 1 with the same outer diameter dimensions
4 is adhered to the upper peripheral edge of the exterior film 10.

次にBのように、枠体14の内部における負極
集電板12の上面にゲル状負極18、セパレータ
20、正極合剤22を順に積層してなる薄層の発
電要素を装填する。次に、前記外装フイルム10
と同様なもう1枚の外装フイルム24の下面側に
正極集電板26を接着しておき、それを前記発電
要素および枠体14の上面側に被せる。
Next, as shown in B, a thin-layer power generation element formed by laminating the gelled negative electrode 18, the separator 20, and the positive electrode mixture 22 in this order is loaded on the upper surface of the negative electrode current collector plate 12 inside the frame 14. Next, the exterior film 10
A positive electrode current collector plate 26 is adhered to the lower surface side of another exterior film 24 similar to the above, and the positive electrode current collector plate 26 is placed over the upper surface side of the power generating element and the frame body 14.

そしてCに示すように、上記2枚の外装フイル
ム10と24の周縁部を上記枠体14の上下面に
熱圧着して電池内部を密封する。なお、外装フイ
ルム10,24の中央には端子窓孔16,28が
形成されていて、その部分にそれぞれ負極集電板
12、正極集電板26が露出し、ここが外部接続
用の端子部となる。
Then, as shown in C, the peripheral edges of the two exterior films 10 and 24 are thermocompression bonded to the upper and lower surfaces of the frame 14 to seal the inside of the battery. Note that terminal window holes 16 and 28 are formed in the centers of the exterior films 10 and 24, and the negative electrode current collector plate 12 and the positive electrode current collector plate 26 are exposed in these portions, respectively, and these serve as terminal portions for external connection. becomes.

《発明が解決しようとする問題点》 上記の薄形電池において、2枚の外装フイルム
10と24で内部の発電要素を挾み込み、発電要
素の各層間の密着性を良好にするために、第4図
Cに示すように、電池組立後の枠体14の厚さは
内部の発電要素の厚さよりある程度小さくしなけ
ればならない。
<<Problems to be Solved by the Invention>> In the thin battery described above, in order to sandwich the internal power generation element between the two exterior films 10 and 24 and improve the adhesion between each layer of the power generation element, As shown in FIG. 4C, the thickness of the frame 14 after the battery is assembled must be somewhat smaller than the thickness of the power generation element inside.

そのため従来は第4図Bのように、発電要素の
厚さ(集電板も含む)Hよりも小さな厚さhの枠
体14を用いていた。
Therefore, conventionally, as shown in FIG. 4B, a frame 14 having a thickness h smaller than the thickness H of the power generation element (including the current collector plate) has been used.

ところが、枠体14の初期の厚さhが発電要素
の厚さHより小さいことから、第4図Bに示す組
立工程や前述の熱圧着工程で次のような問題を生
じていた。
However, since the initial thickness h of the frame 14 is smaller than the thickness H of the power generation element, the following problems have occurred in the assembly process shown in FIG. 4B and the above-mentioned thermocompression bonding process.

枠体14の内部空間に薄層状の発電要素を順次
装填する際に、正極合剤22の粉末や電解液など
を枠体14の上面に付着させてしまつたり、セパ
レータ20の端部の繊維を枠体14の上面と外装
フイルム24の間に挾み込んだりしやすい。枠体
14の上面を不純物で汚染したり、あるいは繊維
を噛み込んだりしたままで枠体14と外装フイル
ム24とが熱圧着で接合しても、その部分でシー
ル不良が発生しやすい。
When sequentially loading thin-layer power generation elements into the internal space of the frame 14, powder of the positive electrode mixture 22, electrolyte, etc. may adhere to the upper surface of the frame 14, or the fibers at the ends of the separator 20 may can be easily inserted between the upper surface of the frame 14 and the exterior film 24. Even if the frame 14 and the exterior film 24 are bonded by thermocompression bonding while the upper surface of the frame 14 is contaminated with impurities or fibers are caught, sealing failure is likely to occur in that part.

つまり、枠体14の上面の高さが発電要素の厚
さより低くなるため、枠体14の大切な上面シー
ル部を汚染したり、不要な繊維を噛み込んだりし
やすく、外装フイルム24との接着不良が生じや
すい。そのような接着不良部分からは電解液など
が容易に漏出するため、耐漏液性能が著しく低下
する。
In other words, since the height of the upper surface of the frame body 14 is lower than the thickness of the power generation element, the important upper sealing part of the frame body 14 is easily contaminated, unnecessary fibers are easily caught, and the adhesion with the exterior film 24 is increased. Defects are likely to occur. Since electrolytic solution and the like easily leak from such a portion with poor adhesion, the leakage resistance performance is significantly reduced.

この発明は前述した従来の問題点に鑑みなされ
たものであり、その目的は、特に製造工程を煩雑
なものにすることなく、枠体の上面と外装フイル
ムとの間のシール不良を少くすることができ、耐
漏液性能に優れた薄形電池を歩留り良く生産でき
るようにする点にある。
This invention was made in view of the above-mentioned conventional problems, and its purpose is to reduce seal failure between the upper surface of the frame and the exterior film without particularly complicating the manufacturing process. The object of the present invention is to enable the production of thin batteries with high yield and excellent leakage resistance.

《問題点を解決するための手段》 この発明に係る薄形電池の製造方法は、上記熱
圧着工程前の上記枠体の厚さが上記発電要素の厚
さより大きくしておき、熱圧着工程で枠体を圧縮
変形することで、最終的な枠体の厚さが発電要素
の厚さより小さくなるようにした。
<Means for Solving the Problems> In the method for manufacturing a thin battery according to the present invention, the thickness of the frame body before the thermocompression bonding process is made larger than the thickness of the power generation element, and the thickness of the frame body before the thermocompression bonding process is By compressively deforming the frame, the final thickness of the frame was made smaller than the thickness of the power generation element.

《作用》 この発明の方法による組立過程においては、枠
体の上面がその内部に装填される発電要素の高さ
より高くなつているので、枠体の上面の合剤粉末
や電解液などを付着させることが少くなり、また
セパレータ端部の繊維を枠体の上面に挾み込んだ
りすることが少くなる。
<<Operation>> In the assembly process according to the method of the present invention, since the upper surface of the frame is higher than the height of the power generation element loaded inside the frame, it is difficult for the mixture powder, electrolyte, etc. to adhere to the upper surface of the frame. In addition, the fibers at the ends of the separator are less likely to be caught in the upper surface of the frame.

《実施例》 第1図は本発明の一実施例による薄形電池の製
造方法を示す図、第4図の従来のものと同一およ
び対応する部分には同一の符号を付している。
<<Example>> FIG. 1 is a diagram showing a method for manufacturing a thin battery according to an embodiment of the present invention, and parts that are the same as and corresponding to the conventional one in FIG. 4 are given the same reference numerals.

まず第1図Aに示すように、ポリエステル層
12μm+アルミニウム箔9μm+ナイロン層15μm+
ポリエチレン層50μmのラミネートフイルムから
なる外装フイルム10を用意し、その電池内面側
(上記ポリエチレン層側)に銅箔からなる負極集
電板12をエポキシ樹脂接着剤およびホツトメル
ト接着剤を介して接着する。外装フイルム10の
上面周縁部には負極集電板12は接着されておら
ず、その部分にポリエチレンの一体成形品である
枠体14を接着しておく。この枠体14の厚さh
1は従来の同寸法の薄形電池のものより十分に大
きく、ご述する発電要素の厚さより大きい。な
お、外装フイルム10の中央には端子窓孔16が
形成されていて、その部分に負極集電板12が露
出している。
First, as shown in Figure 1A, a polyester layer
12μm + aluminum foil 9μm + nylon layer 15μm +
An exterior film 10 made of a laminate film with a polyethylene layer of 50 μm is prepared, and a negative electrode current collector plate 12 made of copper foil is adhered to the inner surface of the battery (the polyethylene layer side) via an epoxy resin adhesive and a hot melt adhesive. The negative electrode current collector plate 12 is not bonded to the upper peripheral edge of the exterior film 10, and a frame 14, which is an integrally molded polyethylene product, is bonded to that portion. Thickness h of this frame 14
1 is sufficiently larger than that of a conventional thin battery of the same size, and is larger than the thickness of the power generating element described above. Note that a terminal window hole 16 is formed in the center of the exterior film 10, and the negative electrode current collector plate 12 is exposed at that portion.

次に第1図Bに示すように、枠体14の内部の
負極集電板12上にゲル状負極18、セパレータ
20、正極合剤22からなる薄層状の発電要素を
順次装填する。この実施例はアルカリ電池で、ゲ
ル状負極18はアマルガム化した亜鉛粉とポリア
クリル酸ソーダと水酸化カリウム溶液とからなる
ゲル状のものである。セパレータ20はビニロン
不織布からなる。正極合剤22は二酸化マンガン
と黒鉛などの合剤からなり、薄いペレツト状に形
成されている。これらを順次枠体14の内部に積
層装填する訳である。
Next, as shown in FIG. 1B, a thin-layer power generation element consisting of the gelled negative electrode 18, the separator 20, and the positive electrode mixture 22 is sequentially loaded onto the negative electrode current collector plate 12 inside the frame 14. This embodiment is an alkaline battery, and the gel negative electrode 18 is a gel made of amalgamated zinc powder, sodium polyacrylate, and potassium hydroxide solution. Separator 20 is made of vinylon nonwoven fabric. The positive electrode mixture 22 is made of a mixture of manganese dioxide, graphite, etc., and is formed into a thin pellet shape. These are stacked and loaded into the frame 14 one after another.

ここで注目すべきことは、枠体14の厚さh1
が発電要素全体の厚さHより大きくなつている点
である。そのために、正極合剤22の粉末や電解
液などを枠体14の上面に付着させることが少く
なり、またセパレータ20の端部繊維を枠体14
の上面側に載せてしまうことも極めて少くなる。
What should be noted here is the thickness h1 of the frame 14
is larger than the thickness H of the entire power generation element. Therefore, the powder of the positive electrode mixture 22, the electrolyte, etc. are less likely to adhere to the upper surface of the frame 14, and the end fibers of the separator 20 are less likely to be attached to the upper surface of the frame 14.
It is also extremely unlikely to be placed on the top side of the screen.

また、ポリエステル層13μmの片面にアルミニ
ウムを蒸着し、ナイロン層15μm+ポリエチレン
層50μmを上記蒸着面にラミネートしたフイルム
からなる外装フイルム24の内面側に、予め正極
集電板26(ニツケルメツキを施した鉄箔)をホ
ツトメルト接着剤およびエポキシ樹脂接着剤を介
して接着しておく。外装フイルム24の下面側周
囲には正極集電板26が接着されていない。また
外装フイルム24の中央に端子窓孔28が形成さ
れていて、その部分に正極集電板26が露出して
いる。この外装フイルム24を上記の発電要素お
よび枠体14の上面側に被せる。
In addition, a positive electrode current collector plate 26 (a nickel-plated iron foil ) are adhered using hot melt adhesive and epoxy resin adhesive. The positive electrode current collector plate 26 is not bonded around the lower surface of the exterior film 24 . Further, a terminal window hole 28 is formed in the center of the exterior film 24, and the positive electrode current collector plate 26 is exposed at that portion. This exterior film 24 is placed over the power generation element and the upper surface of the frame 14 .

そして第1図Cに示すように、枠体14の上下
面をそれぞれ外装フイルム10,24の周縁部で
挾み、さらに加熱治具でこの部分を挾み込んで加
熱しながら加圧する。これで外装フイルム10,
24が枠体14に熱圧着されるとともに、枠体1
4が圧縮変形される。この圧縮変形後の枠体14
の厚さh2は、発電要素の厚さHより小さくす
る。この場合従来より枠体14の圧縮量は多くな
るが、ポリエチレンなどの合成樹脂からなる枠体
14は加熱しながら加圧することで容易に圧縮す
ることができる。
Then, as shown in FIG. 1C, the upper and lower surfaces of the frame 14 are sandwiched between the peripheral edges of the exterior films 10 and 24, respectively, and these portions are further sandwiched with a heating jig and heated and pressurized. Now the exterior film is 10,
24 is thermocompression bonded to the frame 14, and the frame 1
4 is compressed and deformed. Frame 14 after this compression deformation
The thickness h2 of is made smaller than the thickness H of the power generation element. In this case, the amount of compression of the frame 14 is greater than in the past, but the frame 14 made of synthetic resin such as polyethylene can be easily compressed by applying pressure while heating.

第1図の実施例では、枠体14の断面形状が長
方形であるが、本発明はこれに限定されず、枠体
14の形状は第2図あるいは第3図に示すような
形状であつてもよい。第2図の実施例では、枠体
14の上面が内側が高くなつた傾斜面14aとな
つている。第3図の実施例では、枠体14の内側
面の上面に薄い立ち上がり周壁14bが一体的に
形成されている。第2図あるいは第3図の実施例
によれば、最大厚さh1の枠体14を加熱圧縮に
よつて第1図の厚さh2まで変形させるのが比較
的容易である。
In the embodiment shown in FIG. 1, the cross-sectional shape of the frame 14 is rectangular, but the present invention is not limited to this, and the frame 14 may have a shape as shown in FIG. 2 or 3. Good too. In the embodiment shown in FIG. 2, the upper surface of the frame 14 is an inclined surface 14a that is higher on the inside. In the embodiment shown in FIG. 3, a thin rising peripheral wall 14b is integrally formed on the upper surface of the inner surface of the frame 14. According to the embodiment shown in FIG. 2 or 3, it is relatively easy to deform the frame 14 having the maximum thickness h1 to the thickness h2 shown in FIG. 1 by heat compression.

《発明の効果》 以上詳細に説明したように、この発明に係る薄
形電池の製造方法によれば、組立過程で枠体の上
面を合剤粉末や電解液で汚してしまつてシール性
を損つたり、枠体上面と外装フイルムとの間にセ
パレータの端部繊維を挾み込んでシール性を損つ
たりすることが非常に少くなる。すなわち、耐漏
液性能に優れた薄形電池を歩留りよく生産するこ
とができる。
<<Effects of the Invention>> As explained in detail above, according to the method for manufacturing a thin battery according to the present invention, the upper surface of the frame is contaminated with mixture powder and electrolyte during the assembly process, which impairs sealing performance. There is very little chance of the end fibers of the separator becoming trapped between the upper surface of the frame and the exterior film, which will impair the sealing performance. That is, thin batteries with excellent leakage resistance can be produced with good yield.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に係る薄形電池の製造方法の一
実施例を示す工程図、第2および第3図は本発明
が適用される枠体の他の形態を示す断面斜視図、
第4図は従来の薄形電池の製造方法を示す工程図
である。 10……外装フイルム、12……負極集電板、
14……枠体、18……ゲル状負極、20……セ
パレータ、22……正極合剤、24……外装フイ
ルム、26……正極集電板。
FIG. 1 is a process diagram showing an example of the method for manufacturing a thin battery according to the present invention, and FIGS. 2 and 3 are cross-sectional perspective views showing other forms of the frame body to which the present invention is applied.
FIG. 4 is a process diagram showing a conventional thin battery manufacturing method. 10...Exterior film, 12...Negative electrode current collector plate,
14... Frame, 18... Gel-like negative electrode, 20... Separator, 22... Positive electrode mixture, 24... Exterior film, 26... Positive electrode current collector plate.

Claims (1)

【特許請求の範囲】[Claims] 1 1枚の外装フイルムの周縁部上に額縁状のプ
ラスチツク製枠体を接着しておき、この枠体の内
部に偏平な発電要素を装填し、もう一枚の外装フ
イルムで上記発電要素と上記枠体と上面側を被包
し、上記2枚の外装フイルムの周縁部を上記枠体
の上下面に熱圧着して電池内部を密封する薄形電
池の製造方法であつて、上記熱圧着工程前の上記
枠体の厚さが上記発電要素の厚さより大きく、上
記熱圧着工程で上記枠体が圧縮変形されて、最終
的な上記枠体の厚さが上記発電要素の厚さより小
さくなるようにしたことを特徴とする薄形電池の
製造方法。
1. A frame-shaped plastic frame is glued onto the peripheral edge of one exterior film, a flat power generating element is loaded inside this frame, and the above power generating element and the above are connected using another exterior film. A method for manufacturing a thin battery, in which the frame and the upper surface are encapsulated, and the peripheral edges of the two exterior films are thermocompression bonded to the upper and lower surfaces of the frame to seal the inside of the battery, the method comprising the thermocompression bonding step. The thickness of the previous frame body is larger than the thickness of the power generation element, and the frame body is compressively deformed in the thermocompression bonding process so that the final thickness of the frame body is smaller than the thickness of the power generation element. A method for manufacturing a thin battery characterized by:
JP59204150A 1984-10-01 1984-10-01 Manufacture of thin battery Granted JPS6185766A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59204150A JPS6185766A (en) 1984-10-01 1984-10-01 Manufacture of thin battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59204150A JPS6185766A (en) 1984-10-01 1984-10-01 Manufacture of thin battery

Publications (2)

Publication Number Publication Date
JPS6185766A JPS6185766A (en) 1986-05-01
JPH0451938B2 true JPH0451938B2 (en) 1992-08-20

Family

ID=16485662

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59204150A Granted JPS6185766A (en) 1984-10-01 1984-10-01 Manufacture of thin battery

Country Status (1)

Country Link
JP (1) JPS6185766A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
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WO2021049572A1 (en) * 2019-09-12 2021-03-18 積水化学工業株式会社 Electric storage element, production method for electric storage element, and design method for electric storage element

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0443553A (en) * 1990-06-07 1992-02-13 Shin Kobe Electric Mach Co Ltd Thin type sealed battery
JPH0546025U (en) * 1991-11-19 1993-06-18 富士電気化学株式会社 Electric double layer capacitor
KR100553200B1 (en) * 2003-06-19 2006-02-22 삼성에스디아이 주식회사 Battery pack

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021049572A1 (en) * 2019-09-12 2021-03-18 積水化学工業株式会社 Electric storage element, production method for electric storage element, and design method for electric storage element
JPWO2021049572A1 (en) * 2019-09-12 2021-09-27 積水化学工業株式会社 Power storage element, manufacturing method of power storage element, and design method of power storage element

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