JPH0450111A - Production of active carbonized coal - Google Patents
Production of active carbonized coalInfo
- Publication number
- JPH0450111A JPH0450111A JP2160659A JP16065990A JPH0450111A JP H0450111 A JPH0450111 A JP H0450111A JP 2160659 A JP2160659 A JP 2160659A JP 16065990 A JP16065990 A JP 16065990A JP H0450111 A JPH0450111 A JP H0450111A
- Authority
- JP
- Japan
- Prior art keywords
- coal
- low
- closed
- heated
- dirt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003245 coal Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000003077 lignite Substances 0.000 claims abstract description 7
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 5
- 239000003610 charcoal Substances 0.000 claims description 5
- 238000005554 pickling Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000011148 porous material Substances 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 238000010000 carbonizing Methods 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は褐炭、低品位炭を低温乾溜して酸洗し表面内部
に無数の細孔隙を形成し、浄化に用いる活性乾溜炭の製
法に関する。[Detailed Description of the Invention] [Industrial Field of Application] The present invention relates to a method for producing activated dry distilled coal for use in purification by dry distilling lignite or low-rank coal at a low temperature and pickling it to form countless pores inside the surface. .
［従来の技術］
従来浄化に用いるために灰分を減除した低品位炭を粒度
１６０〜２００メツシユにした石炭の表面、内部に微細
孔隙を形成した微細炭を用いて海水の石油系汚物を吸着
させるようにしたものが存在する。[Conventional technology] Petroleum-based filth from seawater is adsorbed using fine charcoal, which has fine pores formed on the surface and inside of the coal, which is made from low-grade coal with a particle size of 160 to 200 mesh and whose ash content has been reduced for conventional purification. There is something that makes it so.
［発明が解決しようとする課題］
前記使用される活性化、石炭は微細粒であって、そのた
め流れのある場所での浄化には有効ではない。[Problems to be Solved by the Invention] The activated coal used is fine grained, and therefore is not effective for purification in places with flow.
［課題を解決するための手段］
本発明は斯様な実情に鑑み、この課題に対処するため５
〜２５ｍｍ程度の褐炭、低品位炭を密閉しポーラス状に
なるまで４５０℃以下で低温乾溜し、無機酸類で酸洗し
活性化すると共に無数の細孔隙を形成した活性乾溜炭を
撒き散らし汚物を吸着させて有効に浄化する事を目的に
提供するものである。[Means for Solving the Problems] In view of the above-mentioned circumstances, the present invention has five features to solve the problems.
~25 mm of lignite or low-rank coal is hermetically sealed and dry-distilled at a low temperature below 450℃ until it becomes porous, then pickled with inorganic acids to activate it, and the activated dry-distilled coal, which has formed countless pores, is scattered to remove filth. It is provided for the purpose of effective purification by adsorption.
［作 用］
５〜２５ｍｍ程度の活性乾溜炭を濾材として川面等に撒
き散らすと汚水は乾溜炭に接触及び細孔を通って流れ、
その間に水と共に流れる汚物は吸着され浄化される。[Function] When activated dry distilled carbon of about 5 to 25 mm is sprinkled on the surface of a river as a filter medium, sewage comes into contact with the dry distilled coal and flows through the pores.
During this time, the dirt flowing with the water is absorbed and purified.
［実 施 例］
本発明は５〜２５ｍｍ程度の褐炭、低品位炭等を容器内
に密閉し、空気との接触を断つと共に、外部から４５０
℃以下の低温で加熱して分解し、内容物がポーラス状に
なるまで１回若しくは複数回低温加熱し、冷却後酸洗槽
内で無機酸類によって酸洗いし、無数の細孔隙が形成さ
れる。またイオン交換樹脂性格を示すようになって活性
化する。[Example] The present invention involves sealing lignite, low-grade coal, etc. of about 5 to 25 mm in a container, cutting off contact with air, and exposing it to 450 mm from the outside.
It decomposes by heating at a low temperature below ℃, then it is heated at a low temperature once or multiple times until the contents become porous, and after cooling, it is pickled with inorganic acids in a pickling tank, forming countless pores. . It also becomes activated and exhibits ion exchange resin properties.
［効 果コ
本発明は上述のように、５〜２５ｍｍ程度の褐炭、低品
位炭を空気との接触を断つように密閉すると共に外部か
ら４５０″Ｃ以下の低温で加熱して熱分解し、この密閉
炭がポーラス状になるまで１回若しくは複数回加熱し、
冷却後無機酸類で酸洗し、無数の細孔隙を形成した活性
乾溜炭の製法で、活性乾溜炭は、５〜２５ｍｍ程度の大
きさで、しかも低温乾溜により無数の細孔隙が形成され
、更に酸洗することで接触面が非常に大きく更に活性化
することで汚物の吸着量が多く、浄化効果がよい。[Effects] As mentioned above, in the present invention, lignite or low-grade coal of about 5 to 25 mm is sealed to prevent contact with air, and heated from the outside at a low temperature of 450"C or less to thermally decompose it. This sealed charcoal is heated once or multiple times until it becomes porous,
This method is used to produce activated dry-distilled charcoal, which is cooled and then pickled with inorganic acids to form countless pores. By pickling, the contact surface becomes very large and is further activated, which allows a large amount of dirt to be adsorbed and a good purification effect.
Claims (1)
つように密閉すると共に、これを外部から４５０℃以下
の低温で加熱して熱分解し、この密閉炭がポーラス状に
なるまで１回若しくは複数回加熱し、冷却後無機酸類で
酸洗し活性化すると共に無数の微細孔隙を形成した事を
特徴とした活性乾溜炭の製法。Lignite or low-grade coal of about 5 to 25 mm is sealed to prevent contact with air, and it is heated from the outside at a low temperature of 450°C or less to pyrolyze it, and the sealed coal is heated until it becomes porous. A method for producing activated dry-distilled charcoal, which is characterized by heating the charcoal one or more times, cooling it, pickling it with an inorganic acid to activate it, and forming countless micropores.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2160659A JPH0450111A (en) | 1990-06-19 | 1990-06-19 | Production of active carbonized coal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2160659A JPH0450111A (en) | 1990-06-19 | 1990-06-19 | Production of active carbonized coal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0450111A true JPH0450111A (en) | 1992-02-19 |
Family
ID=15719717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2160659A Pending JPH0450111A (en) | 1990-06-19 | 1990-06-19 | Production of active carbonized coal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0450111A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4830702A (en) * | 1971-08-23 | 1973-04-23 | ||
| JPS4896453A (en) * | 1972-02-11 | 1973-12-10 |
-
1990
- 1990-06-19 JP JP2160659A patent/JPH0450111A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4830702A (en) * | 1971-08-23 | 1973-04-23 | ||
| JPS4896453A (en) * | 1972-02-11 | 1973-12-10 |
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