JPH0445305A - Sleeve for fuel injection nozzle - Google Patents

Sleeve for fuel injection nozzle

Info

Publication number
JPH0445305A
JPH0445305A JP15153090A JP15153090A JPH0445305A JP H0445305 A JPH0445305 A JP H0445305A JP 15153090 A JP15153090 A JP 15153090A JP 15153090 A JP15153090 A JP 15153090A JP H0445305 A JPH0445305 A JP H0445305A
Authority
JP
Japan
Prior art keywords
cylinder
metal
abrasion
sleeve
fuel injection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15153090A
Other languages
Japanese (ja)
Inventor
Shizuo Kawanami
河波 静男
Hideo Tsunoda
英雄 角田
Hikari Motomura
光 本村
Yoshishige Uematsu
良茂 植松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP15153090A priority Critical patent/JPH0445305A/en
Publication of JPH0445305A publication Critical patent/JPH0445305A/en
Pending legal-status Critical Current

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Landscapes

  • Nozzles For Spraying Of Liquid Fuel (AREA)
  • Spray-Type Burners (AREA)

Abstract

PURPOSE:To improve abrasion resistance and crack resistance by providing a cylinder of thin metal plate outside a cylinder of abrasion-resisting nonmetallic material such as ceramics, filling brazing filler metal into a gap between both the cylinders and heating and melting said metal to fill said gap. CONSTITUTION:A sleeve 20 comprises a cylinder 3 of abrasion-proof nonmetallic material such as ceramics having a layer of brazing filler metal 8 over its outer surface and a cylinder 4 of thin metal which is fitted onto said layer. The sleeve 20 is heated in a furnace to melt the metal 8, so that the gap between the cylinders 3 and 4 is filled with the molten metal and further a through hole 11 communicating with a through hole 10a of a body 5 of fuel injection nozzle is provided. Although the sleeve 20 is fitted into a mixing chamber 5' of two-liquid-mixing type formed in the body 5, where mixed flow of two liquids causes violent abrasion, by the use of the cylinder 3 of abrasion-resisting material, the abrasion can be reduced. Furthermore, since the cylinder 3 is compressed by large thermal contraction forces of the cylinder 4 through the metal 8, compressive stresses remain in the cylinder 3, thereby preventing cracks from occurring therein.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、石炭・石油混合物(以下eOMという)焚、
及び石炭・水混合物(以下CWMという)焚ボイラ等に
適用される摩耗が大きい2流体混合型の燃料噴射ノズル
用のスリープに関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention provides a coal-oil mixture (hereinafter referred to as eOM)-fired,
The present invention also relates to sleep for a two-fluid mixture type fuel injection nozzle that is subject to large wear and is applied to coal-water mixture (hereinafter referred to as CWM)-fired boilers.

〔従来の技術〕[Conventional technology]

COM焚及びCWM焚ボイラに使用される噴射ノズルと
しては通常、蒸気等との2流体混合型が用いられるが、
一般に耐摩耗性と熱衝撃に対する耐割れ性が要求される
。すなわち、この噴射ノズルでは、石炭の粒子が高速で
衝突して通過することによる通路壁の摩耗に耐えること
及び火炉のふく射熱による加熱と発停に伴う冷却とKよ
シ熱衝撃を受けることKよる割れを防ぐことが必要であ
る。
The injection nozzles used in COM-fired and CWM-fired boilers are usually of the two-fluid mixing type with steam, etc.
Generally, wear resistance and cracking resistance against thermal shock are required. In other words, this injection nozzle has the ability to withstand wear on the passage walls caused by coal particles colliding and passing through at high speed, heating due to radiant heat from the furnace, cooling due to start and stop, and being subjected to thermal shock. It is necessary to prevent cracking.

第5図は、従来の2流体混合型のボイラの燃料噴射ノズ
ルの断面図の一部を示す。図において、1aはノズルの
噴射孔で、例えば、一方が蒸気、他方がCOM又はCW
Mである2流体4a、5gが同ノズルla内で混合され
て、ボイラの火炉へ噴出される。2aは噴射ノズル本体
3aの噴孔(混合室)内壁へ装着された耐摩耗性を有す
る非金属材のスリープである。
FIG. 5 shows a part of a sectional view of a fuel injection nozzle of a conventional two-fluid mixing boiler. In the figure, 1a is the injection hole of the nozzle, for example, one is steam and the other is COM or CW.
Two fluids 4a and 5g of M are mixed in the same nozzle la and are ejected to the furnace of the boiler. Reference numeral 2a denotes a sleeve made of a wear-resistant non-metallic material that is attached to the inner wall of the injection hole (mixing chamber) of the injection nozzle body 3a.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

前記の従来の非金属材のスリープ2aKは、一般に% 
5iCe8’5PJaなどのセラミックスやWCなどの
超硬合金が使用されている。
The sleep 2aK of the conventional non-metallic materials mentioned above is generally %
Ceramics such as 5iCe8'5PJa and cemented carbide such as WC are used.

しかし、一般に材料特性上、耐摩耗性の良好表高硬度の
ものは靭性に乏しく、ボイラの発停に伴う加熱・冷却に
よって発生する熱衝撃による耐割れ性が悪く、逆に耐割
れ性が良好なものは耐摩耗性が劣るという一長一短があ
る。
However, due to material properties, materials with high hardness that have good wear resistance generally have poor toughness and poor cracking resistance due to thermal shock caused by heating and cooling when the boiler starts and stops; It has the advantage and disadvantage that it has poor wear resistance.

例えば、SiCは、耐摩耗性は極めて良好であるが、ボ
イラ運転中の発停に伴う熱衝撃によって割れが発生し不
具合となる。一方、Si、N4やWCなどは、耐割れ性
は極めて良好であるが、耐摩耗性が劣化し短寿命となシ
ネ具合となる。
For example, SiC has extremely good wear resistance, but cracks occur due to thermal shock caused by starting and stopping during boiler operation, resulting in problems. On the other hand, Si, N4, WC, and the like have extremely good cracking resistance, but their wear resistance deteriorates, resulting in a short life.

以上の両方の不具合点を解決するための材料開発は極め
て困難であシ、「硬くて割れにくいスリープ」を製作す
ることは、技術的にかなυ困難視されていた。
It was extremely difficult to develop materials to solve both of the above problems, and it was considered technically difficult to create a ``sleep'' that was hard and hard to break.

このような状決に鑑み、本発明は耐摩耗性に優れて、か
つ耐割れ性の良好な燃料噴射ノズル用スリープ管提供し
ようとする本のである。
In view of this situation, the present invention is an attempt to provide a sleep pipe for a fuel injection nozzle that has excellent wear resistance and good crack resistance.

〔課題を解決するための手段〕 本発明は、2流体混合型の燃料噴射ノズルの混合室内壁
に挿入して固定する燃料噴射ノズル用スリープにおいて
セラミックスなどの耐摩耗性の非金属材の筒体の外側に
薄肉の金属材よシなる筒体を配し、両者の間隙にろう材
を装着して、これを加熱溶融して両スリープの間隙上皿
めたことを特徴とする。
[Means for Solving the Problems] The present invention provides a cylinder body made of a wear-resistant non-metallic material such as ceramics in a sleeve for a fuel injection nozzle that is inserted and fixed into the mixing chamber wall of a two-fluid mixing type fuel injection nozzle. A cylinder made of a thin metal material is disposed on the outside of the sleeve, a brazing material is installed in the gap between the two, and this is heated and melted to fit over the gap between the two sleeves.

〔作用〕[Effect]

一般に、物体に圧縮の応力が残留していれば、その物体
は割れにくいことはよく知られている。
Generally, it is well known that if compressive stress remains in an object, that object is less likely to break.

本発明では、その圧縮応力を負荷する手段として耐摩耗
性に富むが割れやすいセラミックスなどの非金属材の筒
体の外側に靭性に富む金属材の薄肉の筒体を配し、両筒
体の間隙にろう材を装着し、これt加熱溶融して両筒体
間の間隙を埋めたものである。
In the present invention, as a means for applying the compressive stress, a thin-walled cylinder made of a metal material with high toughness is arranged on the outside of a cylinder made of a non-metallic material such as ceramics, which has high wear resistance but is easily broken. A brazing material is placed in the gap and heated and melted to fill the gap between the two cylinders.

すなわち、本発明において、両方の筒体の間に装着され
たろう材は、所定の温度に加熱することによって溶融し
、両筒体間の間隙な埋めると共に1両筒体の熱膨張の差
によって生じ九間隙の増加分が埋められる。
That is, in the present invention, the brazing material installed between both cylinders is melted by heating to a predetermined temperature, fills the gap between both cylinders, and eliminates the gap caused by the difference in thermal expansion between the two cylinders. The increase in nine gaps is filled.

しかる後、冷却過程でろう材は凝固し、両筒体ともその
直径が温度の低下と共に収縮していくが、両筒体の収縮
量の差に見合った分だけ外側の収縮量の大きな金属材の
筒体が、溶融→凝固したろう材を介して内側の非金属材
の筒体金線め付けて、いわゆる焼嵌めと同一効果ヲ本た
らし、内側筒体に圧縮の残留応力を負荷す−ることにな
る。
After that, the brazing filler metal solidifies during the cooling process, and the diameter of both cylinders shrinks as the temperature decreases, but the metal material with the larger contraction amount on the outside corresponds to the difference in the amount of contraction between the two cylinders. The cylindrical body is plated with gold wire to the inner non-metallic cylindrical body through the molten and solidified brazing filler metal, producing the same effect as so-called shrink fitting, and applying compressive residual stress to the inner cylindrical body. -It will happen.

このようにして、本発明では、2流体が通過し摩耗の生
じやすい内側に耐摩耗性の筒体を備え九割れにくい燃料
噴射ノズル用筒体が提供される。
In this manner, the present invention provides a cylinder for a fuel injection nozzle that is hard to break and has a wear-resistant cylinder on the inside where two fluids pass and is prone to wear.

ま九、両筒体の間にろう材を配することによって、両筒
体の嵌合のn度を甘くできることになる。さらに、軟質
のろう材がいわゆるクツション(緩衝材)の役目をして
、局部的に高い圧縮応力の発生を防止し、割れの危険が
解除される。
Ninth, by disposing the brazing material between the two cylinders, the fit between the two cylinders can be made tighter. Furthermore, the soft brazing material acts as a so-called cushion (buffering material) to prevent localized high compressive stress from occurring, eliminating the risk of cracking.

一方、耐摩耗性の非金属材の筒体の外側に金属材の筒体
を配して、両筒体を焼嵌めすることも考えられるが、こ
の方法では、 (1)両筒体の寸法精度を極めて高くする必要がある。
On the other hand, it is also possible to arrange a metal cylinder outside of a wear-resistant non-metallic cylinder and shrink-fit both cylinders, but in this method: (1) Dimensions of both cylinders Accuracy must be extremely high.

(2)焼嵌め代を確保するために、相当の高温中で焼嵌
め作業を実施する必要がある。
(2) In order to secure the shrink-fitting allowance, it is necessary to carry out the shrink-fitting work at a considerably high temperature.

など、精度上及び生産性上の制約があると共に、(3)
圧縮応力を均一に負荷することが極めてむずかしく、局
部的に高い圧縮力が加わると、却ってスリープが割れる
危険がある。
There are constraints on accuracy and productivity, such as (3)
It is extremely difficult to apply compressive stress uniformly, and if a high compressive force is applied locally, there is a risk that the sleeve will crack.

等の問題点があるが、本発明では、以上のように1両筒
体の間隙にろう材を装着して、これを加熱溶融して両筒
体の間+1を埋めるようにすることによって、以上の焼
嵌めに伴う問題点も解消することができる。
However, in the present invention, as described above, by attaching the brazing material to the gap between the two cylinders and heating and melting it to fill the gap +1 between the two cylinders, The problems associated with the above-mentioned shrink fitting can also be solved.

〔実施例〕〔Example〕

本発明の一実施例を、第1図ないし第4図によって説明
する。
An embodiment of the present invention will be explained with reference to FIGS. 1 to 4.

第1図は、本実施例に係るスリープの燃料噴射ノズルへ
の装着状況の一例を示すもので、従来の燃料噴射バーナ
用ノズルのスリープを示す纂5図に対応するものである
FIG. 1 shows an example of how the sleeper according to this embodiment is attached to a fuel injection nozzle, and corresponds to Figure 5, which shows the sleeper of a conventional fuel injection burner nozzle.

燃料噴射ノズル本体5に形成された2液混合皺の混合室
5aの壁には噴孔1が設けられ、耐割れ性を重視した超
硬合金(WC)又は5jsN4などで製作されたスリー
プ2が噴孔1付近にリング状のバネ9で装着され、以下
説明する本実施例に係るセラミックスなどの非金属材の
円筒体3と金属材の円筒体4をろう材8を介して接合し
たスリープ20が、最も摩耗の激しい混合室5aの内方
の2液6,7の合流部に装着されている。2液の一方の
液6は、燃料噴射ノズル本体5に設けられた通孔10a
とスリープ20に設けられ九通孔11を経てスリープ2
0内に供給され、他方の液7は燃料噴射ノズル本体5に
設けられた通孔10bi経てスリープ20の一端からス
リープ20内に供給されるようになっている。この2液
6.7としては、例えはCOM焚の場合にはCOMと蒸
気、CWM焚の場合にはCWMと蒸気がそれぞれ使用さ
れる。なお、前趨のスリープ2を省略して、本実施例に
係るスリープ20のみを装着するようにしてもよい。
A nozzle hole 1 is provided in the wall of the mixing chamber 5a of the two-liquid mixing wrinkle formed in the fuel injection nozzle body 5, and a sleeve 2 made of cemented carbide (WC) or 5jsN4 with emphasis on crack resistance is provided. A sleeve 20 is attached to the vicinity of the nozzle hole 1 with a ring-shaped spring 9, and is made by joining a cylindrical body 3 made of a non-metallic material such as ceramics and a cylindrical body 4 made of a metal material via a brazing material 8 according to the present embodiment described below. is installed at the junction of the two liquids 6 and 7 inside the mixing chamber 5a where the wear is most severe. One of the two liquids 6 passes through a through hole 10a provided in the fuel injection nozzle body 5.
and the sleep 2 through the nine holes 11 provided in the sleep 20.
The other liquid 7 is supplied into the sleeve 20 from one end of the sleeve 20 through a through hole 10bi provided in the fuel injection nozzle body 5. As the two liquids 6.7, for example, COM and steam are used in the case of COM firing, and CWM and steam are used in the case of CWM firing. Note that the previous sleeper 2 may be omitted and only the sleeper 20 according to this embodiment may be attached.

本実施例に係るスリープ20は、第2図及び第3図に示
すように、耐摩耗性のセラミックス等の非金属材の円筒
体3の外周面にろう材8を装着し、第3図矢印に示すよ
うに、その外側に薄肉の金属材の円筒体4f:嵌合して
、第2図に示す状態とした上、図示しない炉内で加熱し
てろう材8を溶融させて円筒体3と円筒体4との間隙を
埋め、夏に燃料噴°射ノズルの本体5の前記通孔10a
に連通ずる通孔11を設けることによって構成される。
As shown in FIGS. 2 and 3, the sleeve 20 according to the present embodiment has a brazing material 8 attached to the outer circumferential surface of a cylindrical body 3 made of a non-metallic material such as wear-resistant ceramics, and the sleeve 20 shown in FIG. As shown in FIG. 2, a thin metal cylindrical body 4f is fitted on the outside thereof to form the state shown in FIG. and the cylindrical body 4, and the through hole 10a of the main body 5 of the fuel injection nozzle is filled in the summer.
It is constructed by providing a through hole 11 that communicates with the.

本実施例で使用されるろう材8は、使用条件によっても
異なるが、一般には銀ろうなどのように軟質のものが適
し、その厚みは0.05〜02鵬程度が適当である。さ
らに両筒体3.4の間隙は、装着するろう材8の厚みよ
り大きくする必要があるが、あまシ大きすぎると、その
間隙をろう材8が埋めることができなくなるので、一般
には、ろう材8の厚み+0.05〜0,1鵬程度が適当
である。
The brazing material 8 used in this embodiment varies depending on the conditions of use, but in general, a soft material such as silver solder is suitable, and its thickness is suitably about 0.05 to 0.02 mm. Furthermore, the gap between the two cylindrical bodies 3.4 needs to be larger than the thickness of the brazing filler metal 8 to be installed, but if the gap is too large, the filler filler metal 8 will not be able to fill that gap. Appropriately, the thickness of the material 8 is +0.05 to 0.1.

以上のように構成された本実施例は、前記したように、
例えば第1図に示されるようKして燃料噴射ノズル本体
5に形成された2液温合型の混合室5aの最も摩耗の激
しい2液の合流部に装着されるが、耐摩耗性の高い非金
属材の円筒体3によって、その摩耗を低減させるこ−と
ができる。
As described above, this embodiment configured as above has the following features:
For example, as shown in FIG. 1, it is installed at the confluence of the two liquids that undergoes the most wear in the two-liquid warming type mixing chamber 5a formed in the fuel injection nozzle body 5, but is highly wear-resistant. By using the cylindrical body 3 made of a non-metallic material, its wear can be reduced.

しかも実施例に係るスリープは、第4図中の矢印に示す
ように、外側の金属材の円筒体4の大きな熱収縮力によ
って、ろう材8全弁して、非金属材の円筒体3に締付力
が負荷され、該円筒体3には圧縮の応力が残留し、本来
割れやすかった円筒体3を割れに〈<シている。
Moreover, as shown by the arrow in FIG. 4, the sleep according to the embodiment fully valves the brazing material 8 due to the large heat shrinkage force of the outer metal cylinder 4 and presses it into the non-metal cylinder 3. A tightening force is applied, and compressive stress remains in the cylindrical body 3, causing the cylindrical body 3, which was originally prone to cracking, to crack.

また、両筒体3,40間にろう材8を配することによっ
て、両日筒体3,4の嵌合の精度を甘くすることができ
、またこのろう材8がクツシロンの役目をして、局部的
に高い圧縮応力の発生を防止し、割れの危険性全解除す
ることができる。
In addition, by disposing the brazing material 8 between the two cylindrical bodies 3 and 40, the accuracy of the fitting of the two cylindrical bodies 3 and 4 can be reduced, and this brazing material 8 acts as a cutter, It is possible to prevent the occurrence of locally high compressive stress and completely eliminate the risk of cracking.

本実施例(非金属材の円筒体の材料としてSiCを使用
)と従来のスリープの耐熱衝撃温度(スリープに割れが
発生する迄の最高加熱温度)を比較した例を表IK示す
Table IK shows an example comparing the thermal shock resistance temperature (maximum heating temperature until cracks occur in the sleeve) of this example (SiC is used as the material of the non-metallic cylindrical body) and the conventional sleeve.

これによると、本実施例は耐熱衝撃温度が従来のスリー
プと比して250℃も寓く、割れが発生しKくいことが
示されている。
According to this, it is shown that the thermal shock resistance temperature of this example is 250° C. higher than that of the conventional SLEEP, and that cracks are less likely to occur.

表   1 〔発明の効果〕 本発明は、次の効果を挙げることができる。Table 1 〔Effect of the invention〕 The present invention can have the following effects.

(11耐摩耗性が寓<、割れやすいセラミックスなどの
非金属材の筒体に圧縮の残留応力が負荷されるため、使
用時の発停に伴う加熱・冷却による熱応力などによる割
れ発生が生じKくくなる。
(11) Abrasion resistance is poor. Because compressive residual stress is applied to the cylindrical body made of non-metallic materials such as ceramics, which are prone to breakage, cracks may occur due to thermal stress caused by heating and cooling as they start and stop during use. K becomes harder.

内外の2個の筒体の嵌め合いの寸法精度をゆるやかKで
きるため、生産性と作業性が向上する。
Productivity and workability are improved because the dimensional accuracy of the fit between the two inner and outer cylindrical bodies can be moderately adjusted.

(3)さらに、ろう材が緩衝材となシ局部的な高い圧縮
力の発生を防止することができ、割れ発生を防止するこ
とができる。
(3) Furthermore, since the brazing filler metal acts as a cushioning material, it is possible to prevent the generation of localized high compressive force, thereby preventing the occurrence of cracks.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例に係るスリープを装着した燃
料噴射ノズルの一部を示す断面図、第2図は同実施例の
構成要素を示す縦断面図、第3図は同実施例の製造工程
を示す説明図、第4図は同実施例の作用効果上水すため
のスIJ−ブの横断面図、第5図は従来の燃料噴射ノズ
ルの一部を示す断面図である。 1・・・噴孔、3・・・非金属材の円筒体、4・・・金
属材のH筒体、5・・・燃料噴射ノズル本体、8・・・
ろう材、20・・・スリープ。 代理人 弁理士  坂 間    暁     外2名
第1図 第3rXi 第5肥 第2足 第4回
Fig. 1 is a sectional view showing a part of a fuel injection nozzle equipped with a sleeper according to an embodiment of the present invention, Fig. 2 is a longitudinal sectional view showing the components of the embodiment, and Fig. 3 is a longitudinal sectional view of the same embodiment. FIG. 4 is a cross-sectional view of an IJ-tub for water purification according to the same embodiment, and FIG. 5 is a cross-sectional view showing a part of a conventional fuel injection nozzle. . DESCRIPTION OF SYMBOLS 1... Nozzle hole, 3... Cylindrical body made of non-metallic material, 4... H cylinder body made of metallic material, 5... Fuel injection nozzle body, 8...
Brazing material, 20...Sleep. Agent: Patent Attorney Akatsuki Sakama, 2 others, Figure 1, Figure 3rXi, Figure 5, 2nd Leg, 4th Session

Claims (1)

【特許請求の範囲】[Claims] 2流体混合型の燃料噴射ノズルの混合室内壁に挿入して
固定する燃料噴射ノズル用スリープにおいて、耐摩耗性
の非金属材の筒体の外側に薄肉の金属材の筒体を配し、
両者の間隙にろう材を装着して、これを加熱溶融して両
筒体間の間隙を埋めたことを特徴とする燃料噴射ノズル
用スリープ。
In a sleep for a fuel injection nozzle that is inserted and fixed into the mixing chamber wall of a two-fluid mixing type fuel injection nozzle, a thin-walled metal cylinder is arranged outside a wear-resistant non-metallic cylinder,
A sleeper for a fuel injection nozzle, characterized in that a brazing material is installed in the gap between the two cylinders, and is heated and melted to fill the gap between the two cylindrical bodies.
JP15153090A 1990-06-12 1990-06-12 Sleeve for fuel injection nozzle Pending JPH0445305A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15153090A JPH0445305A (en) 1990-06-12 1990-06-12 Sleeve for fuel injection nozzle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15153090A JPH0445305A (en) 1990-06-12 1990-06-12 Sleeve for fuel injection nozzle

Publications (1)

Publication Number Publication Date
JPH0445305A true JPH0445305A (en) 1992-02-14

Family

ID=15520529

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15153090A Pending JPH0445305A (en) 1990-06-12 1990-06-12 Sleeve for fuel injection nozzle

Country Status (1)

Country Link
JP (1) JPH0445305A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS644566U (en) * 1987-06-29 1989-01-12
US7094049B2 (en) * 2001-12-04 2006-08-22 Atock Co., Ltd. Quartz glass single hole nozzle for feeding fluid and quartz glass multi-hole burner head for feeding fluid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS644566U (en) * 1987-06-29 1989-01-12
JPH052301Y2 (en) * 1987-06-29 1993-01-20
US7094049B2 (en) * 2001-12-04 2006-08-22 Atock Co., Ltd. Quartz glass single hole nozzle for feeding fluid and quartz glass multi-hole burner head for feeding fluid

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