JPH0442424B2 - - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an emulsion-type modified recycled additive composition for paving recycled asphalt mixtures intended for high-grade pavements, simple pavements, bridge pavements, airport pavements, and the like.

BACKGROUND ART In recent years, with resource and energy conservation efforts, asphalt mixtures from aged or unused waste materials have been recycled.

The asphalt in the asphalt mixture, which is aged pavement waste, is produced by oxidation or polymerization of the maltene fraction (consisting of n-pentane-soluble polar fraction, aromatic fraction, and saturated fraction) in the asphalt. As a result, the maltene fraction is relatively insufficient in terms of chemical composition compared to the original asphalt. This causes the physical properties of the asphalt mixture to deteriorate and the stress relaxation performance to deteriorate. To this end, by adding to the asphalt mixture a regenerating additive that has physical properties close to those of the maltene fraction, the asphalt mixture is restored and regenerated to bring the physical properties close to those of the original asphalt.

There are two main types of regeneration for asphalt mixtures: central plant methods and on-road methods.

The central plant method is a method of recycling in a special or conventional type of plant, in which the waste asphalt mixture is accumulated in a stockyard, then it is loosened and classified by crushing equipment or thermal crushing, and then it is recycled alone or as new aggregate, Add and mix straight asphalt and supplementary materials such as recycled additives.

In addition, in the on-road method, part or all of the asphalt mixture of the existing pavement is cut on-site, and the cutting waste alone or the missing supplementary materials such as aggregate, straight asphalt, asphalt mixture, and recycled additives are added. It is added, mixed, and then spread and compacted.

However, in the case of central plant systems and on-road systems that use recycled additives, the recycled additives, which are supplementary materials when producing recycled asphalt mixtures, have a viscosity that allows them to be melted by heating and sprayed through a nozzle. In addition, since the viscosity of the supplementary material is lowered to a level that allows it to form a film with the aggregate before use, there is a drawback that extra fuel and steps are required to heat the supplementary material.

In addition, in order to regenerate aged asphalt mixtures having such physical properties, if a regeneration additive mainly consisting of maltene fraction is added in the above-mentioned central plant method or on-the-road method, the asphalt mixtures will flow more easily at high temperatures than new asphalt mixtures. Deformation phenomena are more likely to occur, and abrasion phenomena are more likely to occur at low temperatures. Therefore, when a recycled asphalt mixture containing recycled additives is used as an asphalt mixture for paving, it is more likely than ordinary asphalt mixtures to cause flow deformation and abrasion phenomena on the road surface when subjected to repeated loads due to automobile traffic. This has the disadvantage that it is difficult to maintain a flat road surface for a long time.

The present invention solves the above-mentioned drawbacks, and has a wide range of applicability regardless of the degree of aging of the waste asphalt mixture. In addition, when producing a recycled asphalt mixture, the recycled additive material, which is a supplementary material, can be kept at room temperature without heating. The object of the present invention is to provide an emulsion-type modified regenerating additive composition for pavement use.

In order to achieve this object, the present invention is characterized in that a resin and rubber are added to a petroleum-based softener and then emulsified using an emulsion liquid to obtain an emulsion-type modified recycled additive composition for pavement.

The emulsion-type modified recycled additive composition for pavement according to the present invention will be explained below.

The present invention differs depending on the type of emulsifier used for emulsification, and includes anionic type petroleum softener emulsion, nonionic type petroleum softener emulsion, cationic type petroleum softener emulsion, clay type petroleum softener emulsion, etc. It is an oil-in-water emulsion made by emulsifying a petroleum softener in water.

First, the petroleum softener which is the main ingredient of the present invention is
Distillate oil is obtained by separating low-boiling fractions from crude oil using an atmospheric distillation column, and distilling the heavy crude oil remaining at the bottom of the atmospheric distillation column under reduced pressure.
They are classified into paraffinic softeners, naphthenic softeners, and aromatic softeners depending on the treatment process and formulation, but all of these can be used in the present invention.

Among petroleum-based softeners, it is preferable to use one having a chemical composition close to that of the maltene fraction in asphalt.

The resins include ethylene, vinyl acetate copolymer, ethylene/acrylate copolymer, polyacrylate, polyethylene, polyvinyl acetate, vinyl chloride/vinyl acetate copolymer, polyvinylidene chloride,
Styrene/acrylate copolymer, vinyl acetate polymer, acrylic ester/vinyl acetate copolymer, maleate/vinyl acetate copolymer,
Acrylic acid ester copolymers, vinylidene chloride polymers, etc. These thermoplastic polymer resins can be used alone or in combination of two or more, but
All are selected in consideration of compatibility and adhesiveness with petroleum-based softeners.

As the rubber, various synthetic rubbers including natural rubber can be used, and one type or a mixture of two or more types can be used. The rubber may be in any form such as solid, solution, or latex type, and good results are obtained when the rubber has a Mooney viscosity of about 10 to 100.

In addition, examples of synthetic rubber include chloroprene rubber,
Styrene-butadiene copolymer rubber, styrene-butadiene copolymer rubber
Isoprene copolymer rubber, polyisoprene rubber,
These include polybutadiene rubber, acrylonitrile-butadiene copolymer rubber, butyl rubber, alfine rubber, styrene-butadiene block polymer rubber, styrene-isoprene block polymer rubber, butadiene rubber, nitrile rubber, ethylene propylene rubber, EPT rubber, and polyolefin rubber.

Emulsifiers used in emulsions include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, bentonite, and emulsifying aids, and these can be used alone or in combination in an aqueous solution.
By adding 0.2 to 5.0 parts by weight per 100 parts by weight, an alkali, an acid, a salt, and a protective colloid agent are added as an emulsion.

If the amount of emulsifier used is less than 0.2 parts by weight, the emulsion stability of the paving emulsion regenerating additive composition obtained by emulsification will deteriorate, making it difficult to obtain a homogeneous emulsion with good long-term stability. In addition, if the amount of emulsifier used is more than 5.0 parts by weight, it will be an economic disadvantage and the emulsion will be very stable when used at room temperature, so it will take a long curing time to obtain a reduced petroleum softener. There is a drawback.

The composition of the present invention can be obtained as follows.

A method in which a predetermined amount of solid or latex type resin and rubber is gradually added to a predetermined amount of heated and melted petroleum softener, and the resulting mixture is emulsified using an emulsifying liquid while continuing to stir. Another method is to add latex-type resin and rubber to the emulsion and emulsify it with a petroleum softener.

Next, examples of the present invention will be described.

1st Example To 100 parts by weight of tap water, 1 part by weight of a cationic emulsifier such as fatty diamine, 0.3 parts by weight of concentrated hydrochloric acid, and 0.5 parts by weight of calcium chloride were added, stirred and dissolved, and the cationic emulsion was heated to about 55°C. The emulsion obtained by
% Contains. ) was added, stirred and dissolved until homogeneous, then 4 parts by weight of chloroprene rubber latex (calculated as solid content) was added, stirred to remove water, and stirred and dissolved until homogeneous. By introducing the mixture into a Harrell type homogenizer and emulsifying it, the cationic pavement emulsion-type modified recycled additive composition of the present invention is obtained.

Second Example An anionic emulsifier such as 1.5 parts by weight of beef tallow carboxylate and 0.45 parts by weight of caustic soda was added to 100 parts by weight of tap water, and the anionic emulsion was stirred and dissolved and heated to about 60°C. Add 12 parts by weight of ethylene/ethyl acrylate resin to the emulsion and 135 parts by weight of a petroleum softener heated and melted at a temperature of 140 to 160°C, stir until homogeneous and dissolve, then add styrene/butadiene. The present invention can be made by adding 3 parts by weight of polymer rubber latex in terms of solid content, stirring to remove moisture, stirring until uniform, dissolving the mixture, introducing it into a Harrell type homogenizer and emulsifying it. An anionic emulsion type modified reclaimed additive composition for pavement is obtained.

Third Example Emulsion obtained by adding a nonionic emulsifier such as 3.0 parts by weight of POE benzyl sulfonate and 0.3 parts by weight of calcium chloride to 100 parts by weight of tap water, stirring and dissolving the nonionic emulsion and heating it to about 50°C. Add 6 parts by weight of ethylene/vinyl acetate copolymer resin (containing 28% vinyl acetate in solid content) to the liquid and 138 parts by weight of petroleum softener dissolved by heating at a temperature of 140 to 160°C. Add 6 parts by weight of block copolymer rubber (SBS type), stir until homogeneous, dissolve the mixture, introduce it into a Harrell type homogenizer, and emulsify it to obtain the nonionic paving emulsion type of the present invention. A modified regenerated additive composition is obtained.

As explained above, according to the present invention, by emulsifying the modified regenerating additive composition, it is no longer necessary to heat the modified regenerating additive composition to obtain a viscosity that can be sprayed through a nozzle and a viscosity that can be coated on the aggregate. As a result, the process is greatly shortened, the construction time can be shortened, and fuel is not required at all.

Furthermore, according to the present invention, unlike a modified recycled additive composition mainly consisting of a maltene fraction, even under repeated automobile loads, the flow deformation phenomenon is less likely to occur, similar to a new asphalt mixture, and the wear phenomenon is also less likely to occur. Therefore, it has the effect of being able to maintain a flat road surface condition for a long period of time.

Claims (1)

[Claims] 1 Petroleum-based softener 100 heated and dissolved at 140-160℃
Rubber made of chloroprene rubber latex, styrene-butadiene copolymer rubber latex, or block copolymer rubber per 100 parts by weight of resin made of ethylene/vinyl acetate copolymer resin or ethylene/ethyl acrylate resin. Add 1 to 30 parts by weight of the mixture at a ratio of 20 to 100 parts by weight, dissolve it, bring the dissolved 60 parts by weight to about 150°C, and then heat it to 50 to 60°C.
1. A method for producing an emulsion-type modified recycled additive composition for pavement, comprising emulsifying with 40 parts by weight of an emulsion.