JPH0440948Y2 - - Google Patents
Info
- Publication number
- JPH0440948Y2 JPH0440948Y2 JP1988143266U JP14326688U JPH0440948Y2 JP H0440948 Y2 JPH0440948 Y2 JP H0440948Y2 JP 1988143266 U JP1988143266 U JP 1988143266U JP 14326688 U JP14326688 U JP 14326688U JP H0440948 Y2 JPH0440948 Y2 JP H0440948Y2
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- film
- heat
- transfer sheet
- paper tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 8
- 239000002390 adhesive tape Substances 0.000 description 6
- 229920006267 polyester film Polymers 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- BUZRAOJSFRKWPD-UHFFFAOYSA-N isocyanatosilane Chemical class [SiH3]N=C=O BUZRAOJSFRKWPD-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- 239000004209 oxidized polyethylene wax Substances 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【考案の詳細な説明】
(A) 産業上の利用分野
本考案は熱転写記録装置に記録媒体として用い
られる熱転写記録体に関する。更に詳しくは、熱
転写記録体を形成する熱転写シートの熱転写イン
ク層と、熱転写シートの終端に接着してあるフイ
ルムが高温保存時にブロツキングすることを防止
した熱転写記録体に関する。[Detailed Description of the Invention] (A) Industrial Application Field The present invention relates to a thermal transfer recording medium used as a recording medium in a thermal transfer recording device. More specifically, the present invention relates to a thermal transfer recording material in which the thermal transfer ink layer of the thermal transfer sheet forming the thermal transfer recording material and the film adhered to the end of the thermal transfer sheet are prevented from blocking during high temperature storage.
(B) 従来の技術
熱転写記録装置では記録を行おうとする受像紙
を熱転写シートと重ね合わせ、熱転写シートを画
像情報に応じて選択的に加熱して、熱転写インク
層を受像紙に転写し、情報の記録を行なう。(B) Conventional technology In a thermal transfer recording device, an image receiving paper on which recording is to be performed is superimposed on a thermal transfer sheet, the thermal transfer sheet is selectively heated according to the image information, and a thermal transfer ink layer is transferred to the image receiving paper, and the information is transferred to the image receiving paper. record.
かかる熱転写シートは、紙管にロール状に巻か
れて使用されるが、熱転写シートが通常10μ前後
と薄い為、紙管とは接着しづらく、25μ程度の厚
手のフイルムを介して接着する。 Such a thermal transfer sheet is used by being rolled around a paper tube, but since the thermal transfer sheet is usually thin, around 10μ thick, it is difficult to adhere to the paper tube, so it is adhered through a thick film of about 25μ.
以下、エンドフイルムと称する。 Hereinafter, it will be referred to as an end film.
このようにすれば、熱転写シートは紙管にしわ
がなく、巻かれ、ロール状の熱転写記録体が形成
される。 In this way, the thermal transfer sheet is rolled onto the paper tube without wrinkles, and a roll-shaped thermal transfer recording material is formed.
第２図は、紙管１に熱転写シート２をロール状
に巻いた熱転写記録体３の外観を示すものであ
る。 FIG. 2 shows the external appearance of a thermal transfer recording material 3 in which a thermal transfer sheet 2 is wound around a paper tube 1 in the form of a roll.
第３図は、従来の熱転写記録体のエンドフイル
ム４近傍の外観を示しており、エンドフイルム４
は紙管１と接着テープ８で接着され、又、熱転写
シート２とは接着テープ５で接着されている。７
は熱転写シート２の耐熱層、６は熱転写インク層
を示す。 FIG. 3 shows the appearance of the vicinity of the end film 4 of a conventional thermal transfer recording medium.
is adhered to the paper tube 1 with an adhesive tape 8, and is adhered to the thermal transfer sheet 2 with an adhesive tape 5. 7
indicates a heat-resistant layer of the thermal transfer sheet 2, and 6 indicates a thermal transfer ink layer.
(C) 考案の詳細な説明
エンドフイルムは25μ程度のポリエステルフイ
ルム等が用いられるが、55℃程度の高温で保存す
ると、熱転写インク層６がエンドフイルム４にブ
ロツキングすることがあつた。特に熱転写インク
層６の融点が55℃程度と近い時程、起こりやすか
つた。(C) Detailed explanation of the invention A polyester film or the like with a thickness of about 25 μm is used as the end film, but when stored at a high temperature of about 55° C., the thermal transfer ink layer 6 sometimes blocks on the end film 4. This phenomenon was particularly likely to occur when the melting point of the thermal transfer ink layer 6 was close to 55°C.
本考案は上記事情に鑑みてなされたもので、55
℃程度の高温保存時でも熱転写インク層６がエン
ドフイルムにブロツキングすることを防止するこ
とを目的とする。 This invention was made in view of the above circumstances, and 55
The purpose is to prevent the thermal transfer ink layer 6 from blocking on the end film even when stored at a high temperature of about .degree.
(D) 課題を解決するための手段
本考案は、エンドフイルム４として離型性フイ
ルムを用いることにより、前記目的を達成した。(D) Means for Solving the Problems The present invention has achieved the above object by using a releasable film as the end film 4.
エンドフイルム４の離型層面は、熱転写シート
２の耐熱層７と同一面側となる。 The release layer surface of the end film 4 is on the same side as the heat resistant layer 7 of the thermal transfer sheet 2.
なお、本考案において、離型性フイルムは離型
層を片面に設けた場合で説明しているが、紙管と
の接着の点から片面を非離型性とするのが好まし
い。 In the present invention, the case where the release film is provided with a release layer on one side is explained, but from the viewpoint of adhesion to the paper tube, it is preferable that one side is non-releaseable.
しかしながら、紙管との接着を可能とする限り
においては両面離型性フイルムでも何らさしつか
えない。 However, a double-sided releasable film may be used as long as it can be bonded to the paper tube.
以下、図面に従つて、本考案を説明する。 The present invention will be described below with reference to the drawings.
第３図は、本考案の熱転写記録体のエンドフイ
ルム近傍の断面図を示したものである。 FIG. 3 shows a sectional view of the vicinity of the end film of the thermal transfer recording medium of the present invention.
紙管１は両面テープ１１でエンドフイルム４と
接着されている。エンドフイルム４はベースフイ
ルム１０と離型層９とから構成される。ベースフ
イルム１０は、例えば25μ程度のPETフイルムが
好適に用いられる。離型層９は、例えばシリコン
樹脂が好適に用いられ、厚さは0.1〜0.5μ程度で
ある。 The paper tube 1 is adhered to the end film 4 with double-sided tape 11. The end film 4 is composed of a base film 10 and a release layer 9. As the base film 10, for example, a PET film of about 25 μm is preferably used. The release layer 9 is preferably made of silicone resin, for example, and has a thickness of about 0.1 to 0.5 μm.
第３図の５は接着テープでエンドフイルム４と
熱転写シート２を接着するものである。 Reference numeral 5 in FIG. 3 is an adhesive tape for bonding the end film 4 and the thermal transfer sheet 2 together.
接着テープとして市販のセロテープ、メンデイ
ングテープ等が用いることができる。 Commercially available cellophane tape, mending tape, etc. can be used as the adhesive tape.
熱転写シート２は、ベースフイルム１２、熱転
写インク層６、耐熱層７とから構成されている。 The thermal transfer sheet 2 is composed of a base film 12, a thermal transfer ink layer 6, and a heat-resistant layer 7.
エンドフイルム１２は、従来使用されているも
のが使用でき、特に制限はなく、例えば、ポリエ
ステルフイルム、ポリカーボネートフイルム、ポ
リプロピレンフイルム、ポリイミドフイルム、ア
セテートフイルムなどである。ベースフイルム１
２の厚さは、２〜16μ、好ましくは３〜7μのもの
が使用できる。 As the end film 12, conventionally used end films can be used, and there are no particular limitations, and examples thereof include polyester film, polycarbonate film, polypropylene film, polyimide film, acetate film, and the like. base film 1
The thickness of 2 can be 2 to 16 microns, preferably 3 to 7 microns.
熱転写インク層６は着色剤、ワツクス類、樹脂
類から構成される。 The thermal transfer ink layer 6 is composed of colorants, waxes, and resins.
着色剤としては、例えばイエローはベンジジン
イエローＧ、アゼンタはローダミンレーキＹ、シ
アンはフタロシアニンブルー、ブラツクはカーボ
ンブラツク等が用いられる。 As the colorant, for example, benzidine yellow G is used for yellow, rhodamine lake Y for agenta, phthalocyanine blue for cyan, and carbon black for black.
ワツクス類としては例えば、パラフインワツク
ス、カルナバワツクス、マイクロクリスタリンワ
ツクス、低分子量ポリエチレンワツクス、酸化ポ
リエチレンワツクス、合成ワツクス等が用いられ
る。 Examples of waxes that can be used include paraffin wax, carnauba wax, microcrystalline wax, low molecular weight polyethylene wax, oxidized polyethylene wax, and synthetic wax.
樹脂類としては、例えば、エチレン酢酸ビニル
共重合体、エチレンエチルアクリレート共重合
体、脂肪族系炭化水素樹脂、芳香族系炭化水素樹
脂等が用いられる。 As the resin, for example, ethylene vinyl acetate copolymer, ethylene ethyl acrylate copolymer, aliphatic hydrocarbon resin, aromatic hydrocarbon resin, etc. are used.
その他、添加剤として、必要に応じて帯電防止
剤、分散剤等を添加してもよい。 In addition, as an additive, an antistatic agent, a dispersant, etc. may be added as necessary.
耐熱層７は以下のものに限られないが、例え
ば、シリコン共重合体、アルコキシシラン加水分
解物、メラミン系樹脂、シリコングラフト重合
体、ケイ素官能型シリルイソシアネート等よりな
る群の１種又は２種以上を主要成分として構成さ
れる。又、必要に応じて微粒子を添加すること
で、耐熱層面を粗面化させることにより、更に耐
熱性を向上させることができる。 The heat-resistant layer 7 is not limited to the following materials, but includes, for example, one or two of the group consisting of silicone copolymers, alkoxysilane hydrolysates, melamine resins, silicone graft polymers, silicon-functional silyl isocyanates, etc. It is composed of the above as the main components. Further, by adding fine particles as necessary, the heat-resistant layer surface can be roughened, thereby further improving heat resistance.
以下に本考案の実施例を示すが、これらに限定
されるものではない。 Examples of the present invention are shown below, but the present invention is not limited thereto.
(E) 実施例
厚さ6μのポリエステルフイルムの片面に、下
記の耐熱層用塗料をグラビアコーターで塗抹し、
120℃で20秒間乾燥し、固型塗目方が0.2ｇ／m2の
耐熱層を形成した。(E) Example The following heat-resistant layer paint was applied on one side of a 6μ thick polyester film using a gravure coater.
It was dried at 120° C. for 20 seconds to form a heat-resistant layer with a solid coating area of 0.2 g/m 2 .
（耐熱層用塗料）
メチルシリルトリイソシアネート 5.0重量部
モノブチル酸性リン酸エステル 0.2 〃
酢酸エチル 94.8重量部
次に前記ポリエステルフイルムの耐熱層と反対
面に下記組成を有する熱転写インクを塗融塗抹
し、塗目方3.5ｇ／m2の熱転写インク層を形成し
た。かくして熱転写シートを得た。(Paint for heat-resistant layer) Methylsilyl triisocyanate 5.0 parts by weight Monobutyl acidic phosphate ester 0.2 Ethyl acetate 94.8 parts by weight Next, a thermal transfer ink having the following composition was smeared on the opposite side of the heat-resistant layer of the polyester film. A thermal transfer ink layer having a weight of 3.5 g/m 2 was formed. A thermal transfer sheet was thus obtained.
（熱転写インク）
パラフインワツクス（融点60℃） 60重量部
カルナバワツクス 20 〃
エチレン酢酸ビニル共重合体 ５ 〃
カーボンブラツク 15 〃
一方、厚さ25μのポリエステルフイルムの片面
に脱水素縮重合型シリコンワニス（ダウコーニン
グ社製、シリコンワニスFSXF2560、触媒Ｋ−
1638）の固形分2.7％溶液をグラビアコーターに
よつて塗布量約５ｇ／m2塗布し、乾燥した。乾燥
後のシリコン塗布厚さは0.1〜0.2μｍである。か
くして離型性フイルムを得た。離型性フイルムを
裁断して、エンドフイルムを得た。熱転写フイル
ムを裁断して、エンドフイルムを得た。熱転写シ
ートをエンドフイルムを介して紙管に巻いて、ロ
ール状の本考案の熱転写記録体を得た。(Thermal transfer ink) Parafine wax (melting point 60°C) 60 parts by weight Carnauba wax 20 〃 Ethylene vinyl acetate copolymer 5 〃 Carbon black 15 〃 On the other hand, dehydrogenated condensation type silicone varnish was applied to one side of a 25μ thick polyester film. (Manufactured by Dow Corning, silicone varnish FSXF2560, catalyst K-
A 2.7% solids solution of 1638) was applied using a gravure coater in an amount of approximately 5 g/m 2 and dried. The silicon coating thickness after drying is 0.1 to 0.2 μm. A releasable film was thus obtained. The releasable film was cut to obtain an end film. The thermal transfer film was cut to obtain an end film. The thermal transfer sheet was wound around a paper tube via an end film to obtain a roll-shaped thermal transfer recording material of the present invention.
得られた熱転写記録体を55℃、10時間保存後、
ブロツキングを観察したが、エンドフイルムに熱
転写インク層はブロツキングしていなかつた。 After storing the obtained thermal transfer recording material at 55℃ for 10 hours,
Although blocking was observed, the thermal transfer ink layer on the end film was not blocked.
(F) 考案の効果
本考案の熱転写記録体では、高温保存してもエ
ンドフイルムに熱転写インク層がブロツキングし
ないので、最後まで有効に熱転写記録ができる。(F) Effects of the invention In the thermal transfer recording medium of the invention, the thermal transfer ink layer does not block on the end film even when stored at high temperatures, so thermal transfer recording can be performed effectively to the end.
第２図は、熱転写記録体の概略斜視図である。
第３図は、従来の熱転写記録体のエンドフイルム
近傍の概略斜視図である。第１図は本考案の熱転
写記録体のエンドフイルム近傍の概略図である。
図中１は紙管、２は熱転写シート、３は熱転写
記録体、４はエンドフイルム、５は接着テープ、
６は熱転写インク層、７は耐熱層、８は接着テー
プ、９は離型層、１０はベースフイルム、１１は
両面テープ、１２は基材シートを示す。
FIG. 2 is a schematic perspective view of the thermal transfer recording medium.
FIG. 3 is a schematic perspective view of the vicinity of an end film of a conventional thermal transfer recording medium. FIG. 1 is a schematic diagram of the vicinity of the end film of the thermal transfer recording medium of the present invention. In the figure, 1 is a paper tube, 2 is a thermal transfer sheet, 3 is a thermal transfer recording medium, 4 is an end film, 5 is an adhesive tape,
6 is a thermal transfer ink layer, 7 is a heat-resistant layer, 8 is an adhesive tape, 9 is a release layer, 10 is a base film, 11 is a double-sided tape, and 12 is a base sheet.
Claims (1)
し、該基材シートの他方のサーマルヘツドが接す
る面に耐熱層を設けてなる熱転写シートと紙管が
フイルムを介して接着し、ロール状に巻回された
熱転写記録体において、該フイルムが離型性フイ
ルムであることを特徴とする熱転写記録体。 A thermal transfer sheet, which has a thermal transfer ink layer on one side of the base sheet and a heat-resistant layer on the other side of the base sheet in contact with the thermal head, is adhered to a paper tube through a film, and then rolled into a roll. 1. A wound thermal transfer recording material, wherein the film is a releasable film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1988143266U JPH0440948Y2 (en) | 1988-10-31 | 1988-10-31 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1988143266U JPH0440948Y2 (en) | 1988-10-31 | 1988-10-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0264067U JPH0264067U (en) | 1990-05-14 |
| JPH0440948Y2 true JPH0440948Y2 (en) | 1992-09-25 |
Family
ID=31409932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1988143266U Expired JPH0440948Y2 (en) | 1988-10-31 | 1988-10-31 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0440948Y2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6098949B2 (en) * | 2014-12-12 | 2017-03-22 | トヨタ自動車株式会社 | Electrolyte membrane wound body |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS557467A (en) * | 1978-07-03 | 1980-01-19 | Fuji Kagakushi Kogyo Co Ltd | Heat-sensitive transfer material |
| JPS56123877A (en) * | 1980-03-06 | 1981-09-29 | Canon Inc | Thermal copy printing device |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6193268U (en) * | 1984-11-22 | 1986-06-16 |
-
1988
- 1988-10-31 JP JP1988143266U patent/JPH0440948Y2/ja not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS557467A (en) * | 1978-07-03 | 1980-01-19 | Fuji Kagakushi Kogyo Co Ltd | Heat-sensitive transfer material |
| JPS56123877A (en) * | 1980-03-06 | 1981-09-29 | Canon Inc | Thermal copy printing device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0264067U (en) | 1990-05-14 |
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