JPH04358588A - Water purifier of porous hollow fiber membrane type and active carbon composition used therefor - Google Patents
Water purifier of porous hollow fiber membrane type and active carbon composition used thereforInfo
- Publication number
- JPH04358588A JPH04358588A JP13486291A JP13486291A JPH04358588A JP H04358588 A JPH04358588 A JP H04358588A JP 13486291 A JP13486291 A JP 13486291A JP 13486291 A JP13486291 A JP 13486291A JP H04358588 A JPH04358588 A JP H04358588A
- Authority
- JP
- Japan
- Prior art keywords
- hollow fiber
- fiber membrane
- porous hollow
- water
- activated carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 125
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000012528 membrane Substances 0.000 title claims abstract description 53
- 239000012510 hollow fiber Substances 0.000 title claims abstract description 51
- 239000000203 mixture Substances 0.000 title claims description 9
- 229910052799 carbon Inorganic materials 0.000 title abstract 4
- 238000000746 purification Methods 0.000 claims abstract description 5
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000003232 water-soluble binding agent Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 abstract description 8
- 238000009434 installation Methods 0.000 abstract description 7
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000002985 plastic film Substances 0.000 abstract 1
- 229920006255 plastic film Polymers 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 8
- 230000001877 deodorizing effect Effects 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-YPZZEJLDSA-N carbon-10 atom Chemical class [10C] OKTJSMMVPCPJKN-YPZZEJLDSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011134 resol-type phenolic resin Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、多孔質中空糸膜型浄水
器及びそれに使用する活性炭組成物に関するものである
。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a porous hollow fiber membrane type water purifier and an activated carbon composition used therein.
【０００２】0002
【従来の技術】近年、水に対する関心が高まり、ミネラ
ル水が大ブームとなってきているがその要因のいくつか
に水源池における水質の低下による水道水の水質低下や
、都市の人工増加に伴い、マンションなどにおける受水
槽利用による異物侵入の恐れなどがあげられ、その対策
として家庭用浄水器が普及してきている。[Background Art] In recent years, interest in water has increased, and mineral water has become a big boom. Some of the reasons for this are the decline in the quality of tap water due to a decline in the quality of water in water source ponds, and the increase in population in cities. , there is a risk of foreign substances entering water tanks in condominiums, etc., and household water purifiers are becoming popular as a countermeasure.
【０００３】家庭用浄水器は一般に活性炭を内蔵し、水
道水中に含まれるカルキ分やある種の有機物を吸着せし
め、もって水の味の向上を図っている。しかし、このよ
うな浄水器では通水を停止し長い間放置すると活性炭に
カルキ分が吸着され、カルキによる殺菌力が低下し、更
に活性炭に吸着された有機物質が富栄養状態を形成し一
般細菌が繁殖する。このような状態で通水を再開すると
浄化水出口から多量の一般細菌が見出される。そこで活
性炭層に繁殖した一般細菌を浄化水出口から流出させな
いため多孔質中空糸膜が利用されている。[0003] Household water purifiers generally contain activated carbon, which absorbs calcium and certain organic substances contained in tap water, thereby improving the taste of the water. However, in such water purifiers, if the water flow is stopped and the water is left for a long time, the activated carbon will adsorb chlorine, reducing the sterilizing power of the chlorine, and furthermore, the organic substances adsorbed on the activated carbon will form a eutrophic state, which will inhibit general bacteria. breeds. When water flow is resumed in this condition, a large amount of common bacteria is found at the purified water outlet. Therefore, porous hollow fiber membranes are used to prevent the general bacteria that have grown in the activated carbon layer from flowing out from the purified water outlet.
【０００４】しかし、繁殖により多量に発生した一般細
菌は多孔質中空糸膜で阻止され、多孔質中空糸膜上で、
更に繁殖を繰り返し脱栄養状態となりついには一般細菌
が死滅し硫化水素臭を発生する。そこで脱臭効果を目的
とし粉末活性炭を系内に加え一般細菌の死滅により発生
する硫化水素を脱臭する多孔質中空糸膜型浄水器が開発
されている。[0004] However, the general bacteria generated in large quantities due to reproduction are blocked by the porous hollow fiber membrane, and on the porous hollow fiber membrane,
As it continues to multiply, it becomes denutrientd and eventually the general bacteria die, producing a hydrogen sulfide odor. Therefore, porous hollow fiber membrane type water purifiers have been developed that add powdered activated carbon to the system to deodorize hydrogen sulfide generated by killing common bacteria.
【０００５】以下に従来の多孔質中空糸膜型浄水器及び
それに使用する粉末活性炭について説明する。図２は従
来の多孔質中空糸膜型浄水器の断面図である。１は浄水
器本体、２は下部に粒状活性炭室２１、上部に多孔質中
空糸膜室２２が形成され浄水器本体内１に設置されたカ
ートリッジ、３は水道水などの原水が入ってくる原水入
口、４は粒状活性炭を保持するためのフィルタ、５は原
水中のカルキ分や有機物などの吸着する粒状活性炭、６
は粒状活性炭を保持するためのフィルタ、７は一般細菌
の死滅により発生する硫化水素臭を取り除くために粉状
で装入された粉末活性炭、８は一般細菌を通過せしめな
い多孔質中空糸膜である。[0005] A conventional porous hollow fiber membrane type water purifier and powdered activated carbon used therein will be explained below. FIG. 2 is a sectional view of a conventional porous hollow fiber membrane type water purifier. 1 is the main body of the water purifier, 2 is a cartridge with a granular activated carbon chamber 21 in the lower part and a porous hollow fiber membrane chamber 22 in the upper part, which is installed in the main body of the water purifier; 3 is the raw water into which raw water such as tap water enters. Inlet, 4 is a filter for retaining granular activated carbon, 5 is granular activated carbon that adsorbs calcium and organic matter in raw water, 6
7 is a filter for retaining granular activated carbon, 7 is powdered activated carbon charged in powder form to remove hydrogen sulfide odor generated by killing general bacteria, and 8 is a porous hollow fiber membrane that does not allow general bacteria to pass through. be.
【０００６】以上のように構成された多孔質中空糸膜型
浄水器について、以下その動作を説明する。The operation of the porous hollow fiber membrane type water purifier constructed as described above will be explained below.
【０００７】原水は原水入口３より浄水器カートリッジ
内に侵入し、粒状活性炭５を通過してカルキ分や有機物
が吸着される。さらに水は上方へ流れて粉末活性炭７が
水流により多孔質中空糸膜８にコーティングされ脱臭作
用をする。[0007] Raw water enters the water purifier cartridge through the raw water inlet 3, passes through granular activated carbon 5, and adsorbs calcium and organic matter. Further, the water flows upward, and the powdered activated carbon 7 is coated on the porous hollow fiber membrane 8 by the water flow, thereby deodorizing the membrane.
【０００８】[0008]
【発明が解決しようとする課題】しかしながら上記従来
の構成では、多孔質中空糸膜型浄水器の搬送中や据付時
に多孔質中空糸膜が粉状で装入された粉末活性炭で覆わ
れて、多孔質中空糸膜に使用されている親水化剤が粉末
活性炭に吸着され多孔質中空糸膜が疏水化するという問
題点があった。また、その結果、通水時に水の出量が減
少し、使用者に不快感を与えるという問題点があった。However, in the above conventional configuration, the porous hollow fiber membrane is covered with powdered activated carbon charged in powder form during transportation or installation of the porous hollow fiber membrane type water purifier. There was a problem in that the hydrophilic agent used in the porous hollow fiber membrane was adsorbed by the powdered activated carbon, causing the porous hollow fiber membrane to become hydrophobic. Furthermore, as a result, the amount of water flowing out during water flow is reduced, causing discomfort to the user.
【０００９】本発明は上記従来の問題点を解決するもの
で、搬送時や据付時の衝撃や振動で粉末の活性炭が飛び
散り、多孔質中空糸膜に付着するのを防止し、活性炭の
脱臭能を最大限発揮させるとともに浄水器使用時流水量
を減少させることがなく、更に運搬据付作業等の作業性
を改善した多孔質中空糸膜型浄水器及びそれに使用する
取扱いに便利で活性炭の耐久性を著しく向上させた活性
炭組成物を提供することを目的とする。The present invention solves the above-mentioned conventional problems, and prevents powdered activated carbon from scattering and adhering to the porous hollow fiber membrane due to shocks and vibrations during transportation and installation, and improves the deodorizing ability of activated carbon. A porous hollow fiber membrane type water purifier that maximizes water purification, does not reduce the amount of water flowing when using the water purifier, and improves workability such as transportation and installation work, and the durability of activated carbon that is convenient to handle. The object of the present invention is to provide an activated carbon composition with significantly improved properties.
【００１０】0010
【課題を解決するための手段】この目的を達成するため
に本発明の多孔質中空糸膜型浄水器は、粒状活性炭室と
多孔質中空糸膜室を有する浄水カートリッジを具備した
多孔質中空糸膜型浄水器であって、多孔質中空糸膜室に
水溶性の紙又は樹脂製フィルムに包装又は係止された粉
末活性炭又は錠剤型等に凝集された粉末活性炭が配設さ
れた構成を有し、また、錠剤型粉末活性炭が水溶性接着
剤にて凝集成形されたものである構成を有している。更
に本発明の活性炭組成物は、粉末活性炭１００重量部と
、水溶性接着剤０．１〜５．０重量部、好ましくは１．
０〜３．０重量部と、及び／又は水溶性結着剤の３〜２
０％水溶液２〜１００重量部と、からなる構成を有して
いる。[Means for Solving the Problems] In order to achieve this object, the porous hollow fiber membrane water purifier of the present invention comprises a porous hollow fiber membrane equipped with a water purification cartridge having a granular activated carbon chamber and a porous hollow fiber membrane chamber. A membrane-type water purifier, which has a structure in which powdered activated carbon wrapped or secured in water-soluble paper or resin film, or powdered activated carbon aggregated in a tablet shape, etc. is arranged in a porous hollow fiber membrane chamber. Moreover, it has a structure in which tablet-shaped powdered activated carbon is agglomerated and molded using a water-soluble adhesive. Furthermore, the activated carbon composition of the present invention contains 100 parts by weight of powdered activated carbon and 0.1 to 5.0 parts by weight, preferably 1.0 parts by weight, of a water-soluble adhesive.
0 to 3.0 parts by weight and/or 3 to 2 parts by weight of a water-soluble binder
It has a structure consisting of 2 to 100 parts by weight of a 0% aqueous solution.
【００１１】ここで、また、水溶性樹脂フィルムとして
は、水溶性ポリマーを乾燥して作ったフィルムであって
、例えばポリビニルアルコールフィルム，ポリエチレン
オキシドフィルム，メチルセルロースフィルム等があげ
られる。また、水溶性接着剤としては、セルロース等や
、レゾール形フェノール樹脂，ユリア樹脂初期縮合物，
メラミン樹脂初期縮合物，ポリビニルアルコール，ポリ
エチレンオキシド，ＣＭＣ等があげられる。水溶性結着
剤としては、デキストリン、サッカロース、アルギン酸
ナトリウム、デンプン、カンテン等が使用される。[0011] Also, the water-soluble resin film is a film made by drying a water-soluble polymer, such as polyvinyl alcohol film, polyethylene oxide film, methyl cellulose film, and the like. In addition, water-soluble adhesives include cellulose, resol type phenolic resin, urea resin initial condensate, etc.
Examples include melamine resin initial condensate, polyvinyl alcohol, polyethylene oxide, and CMC. As the water-soluble binder, dextrin, sucrose, sodium alginate, starch, agar, etc. are used.
【００１２】0012
【作用】この構成によって、粉末活性炭による多孔質中
空糸膜の親水化剤の吸着を防止することができる。また
、多孔質中空糸膜の親水性が維持されるので浄化水流量
の低下を防止できる。更に、活性炭の脱臭能の低下を防
止するので、常に硫化水素等の異臭のない水を供給でき
る。また、活性炭組成物を通常の加圧成形法等で容易に
水分散性の錠剤型等の粉末活性炭を作ることができる。[Operation] With this structure, it is possible to prevent the powdered activated carbon from adsorbing the hydrophilic agent for the porous hollow fiber membrane. Furthermore, since the hydrophilicity of the porous hollow fiber membrane is maintained, a decrease in the flow rate of purified water can be prevented. Furthermore, since deterioration of the deodorizing ability of activated carbon is prevented, water free from foreign odors such as hydrogen sulfide can be constantly supplied. In addition, water-dispersible tablet-shaped powder activated carbon can be easily produced from the activated carbon composition using a conventional pressure molding method or the like.
【００１３】[0013]
【実施例】以下本発明の一実施例について、図面を参照
しながら説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings.
【００１４】図１は本発明の一実施例における多孔質中
空糸膜型浄水器の要部断面図である。FIG. 1 is a sectional view of a main part of a porous hollow fiber membrane water purifier according to an embodiment of the present invention.
【００１５】１は浄水器本体、２はカートリッジ、２１
は粒状活性炭室、２２は多孔質中空糸膜室、３は原水入
口、４はフィルタ、５は粒状活性炭、６はフィルタ、８
は多孔質中空糸膜であり、これらは従来例と同様のもの
であるので、同一の番号を付し説明を省略する。９は粉
末活性炭を錠剤状に凝集させた錠剤型粉末活性炭、１０
は錠剤型粉末活性炭を固定するための水溶性樹脂フィル
ムである。1 is a water purifier body, 2 is a cartridge, 21
is a granular activated carbon chamber, 22 is a porous hollow fiber membrane chamber, 3 is a raw water inlet, 4 is a filter, 5 is a granular activated carbon, 6 is a filter, 8
are porous hollow fiber membranes, and since these are the same as those in the conventional example, the same numbers will be assigned and the explanation will be omitted. 9 is a tablet-shaped powdered activated carbon obtained by agglomerating powdered activated carbon into a tablet shape, 10
is a water-soluble resin film for fixing tablet-shaped powdered activated carbon.
【００１６】次に、活性炭組成物を用いた錠剤型粉末活
性炭の製造方法の一例について説明すると、粉末活性炭
（武田薬品（株）製 白鷺Ｍ）１００重量部に対し、
水溶性接着剤としてカルボキシメチルセルロース２重量
部、混合し、またはデキストリンの１０％水溶液６０〜
７０ｍｌを添加、混合した後、ボールミルにて回転速度
２００〜５００ｒｐｍ、１時間で造粒したものを、一軸
プレスにてプレス圧５００〜１０００ｋｇ／ｃｍ２で成
形し、乾燥器にて水分を蒸発させて錠剤型粉末活性炭が
作成される。[0016] Next, an example of a method for producing tablet-shaped powdered activated carbon using an activated carbon composition will be explained.
2 parts by weight of carboxymethyl cellulose as a water-soluble adhesive, or 60 to 60% of a 10% aqueous solution of dextrin.
After adding and mixing 70 ml, the mixture was granulated in a ball mill at a rotation speed of 200 to 500 rpm for 1 hour, then molded in a uniaxial press at a pressure of 500 to 1000 kg/cm2, and the water was evaporated in a dryer. Tablet-shaped powdered activated carbon is created.
【００１７】以上のように構成された多孔質中空糸膜型
浄水器について、以下その動作を説明する。The operation of the porous hollow fiber membrane type water purifier constructed as described above will be explained below.
【００１８】粉状活性炭は錠剤状に成形され、かつ、水
溶性紙で固定されているので浄水器を工場等からの運搬
中や据付時の衝撃や振動でも破砕して粉末活性炭が飛び
散り多孔質中空糸膜に接触することがない。使用時にお
いては、原水は原水入口３より浄水器カートリッジ内に
侵入し、粒状活性炭５を通過してカルキ分や有機物が吸
着される。さらに水は上方へ流れて錠剤型粉末活性炭９
を通過するが、その際に錠剤型粉末活性炭９を固定して
いた水溶紙１０は溶解し、また錠剤型粉末活性炭９は水
流により崩壊し粉末状となって、多孔質中空糸膜８にコ
ーティングされ脱臭作用をする。Powdered activated carbon is shaped into a tablet and fixed with water-soluble paper, so even when the water purifier is being transported from a factory or installed, shocks and vibrations can cause it to shatter, causing the powdered activated carbon to scatter and become porous. There is no contact with the hollow fiber membrane. During use, raw water enters the water purifier cartridge through the raw water inlet 3, passes through the granular activated carbon 5, and adsorbs calcium and organic matter. Furthermore, water flows upward and tablet-shaped powdered activated carbon 9
At this time, the water-soluble paper 10 that fixed the tablet-shaped powdered activated carbon 9 is dissolved, and the tablet-shaped powdered activated carbon 9 is disintegrated by the water flow and becomes powder, and is coated on the porous hollow fiber membrane 8. It has a deodorizing effect.
【００１９】（実施例１）本実施例の多孔質中空糸膜型
浄水器を振動機に設置し、一昼夜振動させた。カートリ
ッジ内を確認したところ粉末活性炭は多孔質中空糸膜へ
の付着は認められなかった。次いで、前記浄水器入口圧
力を１ｋｇ／ｃｍ２として、通水量１００ｌ毎の吐出側
流量を測定した。その結果を（表１）に示す。(Example 1) The porous hollow fiber membrane type water purifier of this example was installed in a vibrator and vibrated all day and night. When the inside of the cartridge was checked, no powdered activated carbon was found to be attached to the porous hollow fiber membrane. Next, the water purifier inlet pressure was set to 1 kg/cm2, and the discharge side flow rate was measured for every 100 liters of water flow. The results are shown in (Table 1).
【００２０】（比較例１）従来例の多孔質中空糸膜型浄
水器を用い実施例１と同一の条件で振動試験を行った。
カートリッジ内を確認したところ粉末活性体の微粉が多
孔質中空糸膜への付着が認められた。(Comparative Example 1) A vibration test was conducted under the same conditions as in Example 1 using a conventional porous hollow fiber membrane type water purifier. When the inside of the cartridge was checked, it was found that fine powder of the powdered active substance had adhered to the porous hollow fiber membrane.
【００２１】次いで、実施例１と同一条件で通水試験を
行った。その結果を（表１）に示す。Next, a water flow test was conducted under the same conditions as in Example 1. The results are shown in (Table 1).
【００２２】[0022]
【表１】[Table 1]
【００２３】この（表１）から明らかなように、比較例
は初期から１．５リットル／分程度しか流量がとれない
のに対し、実施例１は流量低下が認められず、通水量５
トン時でも４リットル／分も通水できた。As is clear from this (Table 1), the comparative example can only obtain a flow rate of about 1.5 liters/min from the initial stage, whereas in Example 1, no decrease in flow rate is observed and the water flow rate is 5 liters/min.
It was possible to pass water at a rate of 4 liters/minute even at ton hours.
【００２４】[0024]
【発明の効果】以上のように本発明は、粉末活性炭を水
溶性紙等で包装し、又は錠剤化等して水溶性紙等で器壁
に固定し多孔質中空糸膜と分離してカートリッジ内に配
設することにより、搬送時や据付時の衝撃や振動で粉末
活性炭が飛び散り多孔質中空糸膜に付着することがない
ので、粉末活性炭の脱臭能を最大限に発揮させ耐久性を
著しく向上させるとともに、浄水時の流水量を減少させ
ることがなく、更に運搬据付作業等の作業性を改善した
優れた多孔質中空糸膜型浄水器を実現できるものである
。また、取扱いに便利で作業性を向上させ活性炭の脱臭
能の耐久性を著しく向上させた粉末活性炭組成物を実現
できるものである。[Effects of the Invention] As described above, the present invention provides a cartridge in which powdered activated carbon is packaged with water-soluble paper, etc., or is made into tablets, etc., fixed to the vessel wall with water-soluble paper, etc., and separated from a porous hollow fiber membrane. By placing the activated carbon inside the membrane, the powdered activated carbon will not scatter due to shock or vibration during transportation or installation and will not adhere to the porous hollow fiber membrane, thereby maximizing the deodorizing ability of the powdered activated carbon and significantly increasing its durability. In addition, it is possible to realize an excellent porous hollow fiber membrane type water purifier that does not reduce the amount of water flowing during water purification and also improves workability such as transportation and installation work. Furthermore, it is possible to realize a powder activated carbon composition that is convenient to handle, has improved workability, and has significantly improved durability of the deodorizing ability of activated carbon.
【図１】本発明の一実施例における多孔質中空糸膜型浄
水器の要部断面図[Fig. 1] A sectional view of essential parts of a porous hollow fiber membrane type water purifier according to an embodiment of the present invention.
【図２】従来の多孔質中空糸膜型浄水器の要部断面図[Figure 2] Cross-sectional view of main parts of a conventional porous hollow fiber membrane water purifier
１ 浄水器本体 ２ カートリッジ ２１ 粒状活性炭室 ２２ 多孔質中空糸膜室 ３ 原水入口 ４ フィルタ ５ 粒状活性炭 ６ フィルタ ７ 粉末活性炭 ８ 多孔質中空糸膜 ９ 錠剤型粉末活性炭 １０ 水溶性樹脂フィルム 1 Water purifier body 2 Cartridge 21 Granular activated carbon chamber 22 Porous hollow fiber membrane chamber 3 Raw water entrance 4 Filter 5 Granular activated carbon 6 Filter 7 Powdered activated carbon 8 Porous hollow fiber membrane 9 Tablet-type powdered activated carbon 10 Water-soluble resin film
Claims (3)
浄水カートリッジを具備した多孔質中空糸膜型浄水器で
あって、多孔質中空糸膜室に水溶性の紙又は樹脂製フィ
ルムに包装又は係止された粉末活性炭又は錠剤型等に凝
集された粉末活性炭が配設されていることを特徴とする
多孔質中空糸膜型浄水器。Claim 1: A porous hollow fiber membrane type water purifier equipped with a water purification cartridge having a granular activated carbon chamber and a porous hollow fiber membrane chamber, wherein the porous hollow fiber membrane chamber is provided with a water-soluble paper or resin film. 1. A porous hollow fiber membrane type water purifier, characterized in that powdered activated carbon is packaged or locked, or powdered activated carbon aggregated in a tablet shape or the like is disposed.
成形されたものであることを特徴とする多孔質中空糸膜
型浄水器。2. A porous hollow fiber membrane type water purifier, characterized in that tablet-shaped powdered activated carbon is agglomerated and molded with a water-soluble adhesive.
０．１〜５．０重量部、好ましくは１．０〜３．０重量
部及び／又は水溶性結着剤の３〜２０％水溶液２〜１０
０重量部と、からなることを特徴とする活性炭組成物。3. 100 parts by weight of powdered activated carbon and 0.1 to 5.0 parts by weight, preferably 1.0 to 3.0 parts by weight of a water-soluble adhesive and/or 3 to 20% of a water-soluble binder. Aqueous solution 2-10
0 parts by weight of an activated carbon composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13486291A JPH04358588A (en) | 1991-06-06 | 1991-06-06 | Water purifier of porous hollow fiber membrane type and active carbon composition used therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13486291A JPH04358588A (en) | 1991-06-06 | 1991-06-06 | Water purifier of porous hollow fiber membrane type and active carbon composition used therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04358588A true JPH04358588A (en) | 1992-12-11 |
Family
ID=15138213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13486291A Pending JPH04358588A (en) | 1991-06-06 | 1991-06-06 | Water purifier of porous hollow fiber membrane type and active carbon composition used therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04358588A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103706805A (en) * | 2013-12-26 | 2014-04-09 | 徐剑晖 | Method for preparing carbon material carrying nanometer multi-element metal |
| CN107758897A (en) * | 2017-11-28 | 2018-03-06 | 烟台艾易网络科技有限公司 | A kind of small intelligent sewage-treatment plant |
| CN110841610A (en) * | 2019-12-11 | 2020-02-28 | 广西科技大学 | Preparation method of immobilized macromolecule heavy metal adsorbent |
-
1991
- 1991-06-06 JP JP13486291A patent/JPH04358588A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103706805A (en) * | 2013-12-26 | 2014-04-09 | 徐剑晖 | Method for preparing carbon material carrying nanometer multi-element metal |
| CN107758897A (en) * | 2017-11-28 | 2018-03-06 | 烟台艾易网络科技有限公司 | A kind of small intelligent sewage-treatment plant |
| CN110841610A (en) * | 2019-12-11 | 2020-02-28 | 广西科技大学 | Preparation method of immobilized macromolecule heavy metal adsorbent |
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