JPH0431490A - Manufacture of soil conditioner - Google Patents
Manufacture of soil conditionerInfo
- Publication number
- JPH0431490A JPH0431490A JP13750490A JP13750490A JPH0431490A JP H0431490 A JPH0431490 A JP H0431490A JP 13750490 A JP13750490 A JP 13750490A JP 13750490 A JP13750490 A JP 13750490A JP H0431490 A JPH0431490 A JP H0431490A
- Authority
- JP
- Japan
- Prior art keywords
- soil
- salt
- silicon
- iron
- soil conditioner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003516 soil conditioner Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000002689 soil Substances 0.000 claims abstract description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 9
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 235000014633 carbohydrates Nutrition 0.000 claims description 6
- 150000002505 iron Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 abstract description 10
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 238000009335 monocropping Methods 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 159000000014 iron salts Chemical class 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000035558 fertility Effects 0.000 description 3
- -1 organic acid salts Chemical class 0.000 description 3
- 239000002364 soil amendment Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241000219315 Spinacia Species 0.000 description 2
- 235000009337 Spinacia oleracea Nutrition 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229910009112 xH2O Inorganic materials 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 229930091051 Arenine Natural products 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-N iron;hydrochloride Chemical class Cl.[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Landscapes
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は地力の向上に有効な土壌改質剤に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a soil conditioner effective for improving soil fertility.
近年、農業用土壌の連作障害や地力の劣化が問題となっ
ているが、従来ではこのような連作障害や地力の劣化に
対する有効な手段が見出せないでいた。In recent years, continuous cropping damage and deterioration of soil fertility in agricultural soil have become a problem, but until now no effective means have been found for dealing with such continuous cropping damage and soil fertility deterioration.
本発明は上記従来の課題を解決するための手段として、
二価二価鉄塩と、鉄および/またはケイ素を含有する土
壌と、糖質を含有する材料との混合物を加熱することを
骨子とする土壌改質剤の製造方法に関するものである。The present invention, as a means for solving the above-mentioned conventional problems,
The present invention relates to a method for producing a soil conditioner, the main feature of which is heating a mixture of a divalent iron salt, soil containing iron and/or silicon, and a material containing carbohydrates.
以下本発明について詳細に説明する。The present invention will be explained in detail below.
本発明の土壌改質剤に使用する一価三価鉄塩は、二価鉄
塩と三価鉄塩の中間の性質を示す鉄の塩酸塩、硫酸塩、
燐酸塩、硝酸塩などの無機塩類および蟻V塩、酢酸塩、
プロピオン酸塩などの有機酸塩類がある。例えば公知の
ものとしてはFe3C1□・xH2O,Fe、C1,、
−xH7Oなどの二価鉄と三価鉄の錯塩などが上げら九
るが、本発明に最も好ましい二価三価鉄塩としては、特
開昭59−1.90226号および特開昭60−186
581号に記載されているFe2C1,・xH2Oが挙
げられる。これらの二価二価鉄塩は土壌に混合した場合
、各種のイオン反応を抑制することにより、通常の水系
におけるイオン反応とは著しく異なる反応を誘導すると
思われ1本発明の二価三価鉄塩配合の土壌改質剤を適用
すれば、土壌中の正規の非イオン反応系が回復して土壌
を正常な状態に復帰させることが出来る。The monovalent and trivalent iron salts used in the soil conditioner of the present invention include iron hydrochlorides, sulfates, and
Inorganic salts such as phosphates, nitrates, ant V salts, acetates,
There are organic acid salts such as propionate. For example, the known ones are Fe3C1□・xH2O, Fe, C1,...
There are nine complex salts of divalent iron and trivalent iron such as -xH7O, but the most preferred divalent and trivalent iron salts for the present invention include JP-A-59-1.90226 and JP-A-60- 186
Examples include Fe2C1,.xH2O described in No. 581. When these divalent iron salts are mixed with soil, they are thought to inhibit various ionic reactions, thereby inducing reactions that are significantly different from those in ordinary aqueous systems. By applying a soil amendment containing salt, the normal nonionic reaction system in the soil can be restored and the soil can be returned to its normal state.
本発明の土壌改質剤に使用する土壌は、鉄および/また
はケイ素を含有するものであり、鉄を含有する土壌とし
ては赤土、ゼオライト等が使用可能であり、ケイ素を含
有する土壌としては、海砂。The soil used in the soil conditioner of the present invention contains iron and/or silicon. As the iron-containing soil, red clay, zeolite, etc. can be used, and as the silicon-containing soil, Sea sand.
川砂、ゼオライト、シラス等が使用可能である。River sand, zeolite, whitebait, etc. can be used.
本発明の土壌改質剤に使用する糖質を含有する材料とし
ては、砂糖、バカス、精密等が使用可能である。As the carbohydrate-containing material used in the soil conditioner of the present invention, sugar, Bacas, Seishin, etc. can be used.
本発明の土壌改質剤において、二価三価鉄塩と、鉄およ
び/またはケイ素を含有する土壌と、糖質を含有する材
料との混合割合は通常鉄および/またはケイ素を含有す
る土壌100gに対して糖質を含有する材料は0.03
g以上、二価三価鉄塩は10−11 g以上程度添加
される。In the soil amendment of the present invention, the mixing ratio of the divalent and trivalent iron salt, the soil containing iron and/or silicon, and the material containing carbohydrates is usually 100 g of soil containing iron and/or silicon. whereas materials containing carbohydrates are 0.03
The divalent and trivalent iron salt is added in an amount of about 10-11 g or more.
〔作用]
鉄および/またはケイ素を含有する土壌および糖質を含
有する材料は、二価三価鉄塩の担体となり、二価三価鉄
塩を安定化させ、土壌中における二価三価鉄塩の効果を
長期にわたり持続せしめる。[Action] Soil containing iron and/or silicon and materials containing carbohydrates serve as carriers for divalent and trivalent iron salts, stabilize the divalent and trivalent iron salts, and reduce the amount of divalent and trivalent iron in the soil. Prolongs the effects of salt over a long period of time.
二価三価鉄塩は土壌に混合され、土壌中の各種のイオン
反応を抑制して、正規の非イオン反応系を回復せしめる
。Divalent and trivalent iron salts are mixed with soil to suppress various ionic reactions in the soil and restore normal nonionic reaction systems.
実施例1(土壌改質剤の製造)
赤土10kg、ゼオライト10kg、精密iog、ピー
トモスiokgの混合物をFe2Cl5のIQ−12g
/111溶液ICIに一昼夜浸漬した後、90℃、3時
間加熱攪拌した。その後、風乾し褐色の土壌改質剤を得
た。Example 1 (Production of soil conditioner) A mixture of 10 kg of red soil, 10 kg of zeolite, precision iog, and peat moss was mixed with IQ-12 g of Fe2Cl5.
After being immersed in ICI/111 solution for one day and night, the mixture was heated and stirred at 90° C. for 3 hours. Thereafter, it was air-dried to obtain a brown soil amendment.
実施例2(連作障害の解:/l′4)
連作障害の激しいホウレンソウ畑に実施例1の土壌改質
剤を1−Oa当り60kg散布し、耕起後ホウレンソウ
栽培をしたところ、連作障害は改善され、生育は全く正
常であった。収量指数は対照区の100に対して処理区
では185であった。Example 2 (Solution for continuous cropping failure: /l'4) When the soil conditioner of Example 1 was sprayed at 60 kg per Oa in a spinach field with severe continuous cropping failure, and spinach was cultivated after plowing, there was no continuous cropping failure. The growth was completely normal. The yield index was 185 in the treated plot compared to 100 in the control plot.
実施例3(連作障害の解消)
フザリウムの繁殖を伴った強度の連作障害土壌に実施例
1の土壌改質剤を10a当り60kg散布し、耕起後大
根を作付けしたところ、収量指数は対照区の100に対
して処理区では350であった。Example 3 (Resolution of continuous cropping disorder) When the soil conditioner of Example 1 was sprayed at 60 kg per 10 a on soil with severe continuous cropping disorder accompanied by Fusarium proliferation and radish was planted after plowing, the yield index was lower than that of the control group. The number was 350 in the treated area compared to 100 in the treated area.
実施例3(土壌改質)
火山灰性土壌2Qに実施例1の土壌改質剤20gを混ぜ
、〕−ケ月に一度潅水し、3ケ月後に検体を採取した。Example 3 (Soil Modification) 20 g of the soil modifier of Example 1 was mixed with 2Q of volcanic ash soil, watered once every - months, and samples were collected after 3 months.
検体土壌の粒径分析をしたところ第1表の改善を認めた
。When the sample soil was analyzed for particle size, the improvements shown in Table 1 were observed.
上記実施例にみられるように本発明の土壌改質剤は、土
壌中の各種のイオン反応を抑制して、正規の非イオン反
応系が回復されるので、土壌を改良し作物の連作障害防
止に著しい効果を示した。As seen in the above examples, the soil conditioner of the present invention suppresses various ionic reactions in the soil and restores the normal nonionic reaction system, thereby improving the soil and preventing damage to continuous cropping of crops. showed a remarkable effect on
特許出願人 有限会社 アイ・ビー・イー検体土壌のリ
ン酸吸収係数を測定したところ第2表の改善を認めた。Patent applicant I.B.I. Ltd. When the phosphoric acid absorption coefficient of the sample soil was measured, the improvement shown in Table 2 was observed.
第2表 〔発明の効果〕Table 2 〔Effect of the invention〕
Claims (1)
壌と、糖質を含有する材料との混合物を加熱することを
特徴とする土壌改質剤の製造方法A method for producing a soil conditioner, which comprises heating a mixture of a divalent and trivalent iron salt, soil containing iron and/or silicon, and a material containing carbohydrates.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13750490A JPH0431490A (en) | 1990-05-28 | 1990-05-28 | Manufacture of soil conditioner |
HU364591A HU209689B (en) | 1990-05-28 | 1991-11-21 | A method of producing a soil conditioner |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13750490A JPH0431490A (en) | 1990-05-28 | 1990-05-28 | Manufacture of soil conditioner |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0431490A true JPH0431490A (en) | 1992-02-03 |
Family
ID=15200214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13750490A Pending JPH0431490A (en) | 1990-05-28 | 1990-05-28 | Manufacture of soil conditioner |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0431490A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009100481A (en) * | 2001-09-12 | 2009-05-07 | Panasonic Corp | Image decoding method and image decoding device |
JP2009213446A (en) * | 2008-03-12 | 2009-09-24 | Hirohito Morifuji | Culture soil improving agent containing artificial zeolite, and culture soil |
-
1990
- 1990-05-28 JP JP13750490A patent/JPH0431490A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009100481A (en) * | 2001-09-12 | 2009-05-07 | Panasonic Corp | Image decoding method and image decoding device |
US7583731B2 (en) | 2001-09-12 | 2009-09-01 | Panasonic Corporation | Picture coding method and picture decoding method |
US8184722B2 (en) | 2001-09-12 | 2012-05-22 | Panasonic Corporation | Coding method |
US8194759B2 (en) | 2001-09-12 | 2012-06-05 | Panasonic Corporation | Picture coding method and picture decoding method |
JP2009213446A (en) * | 2008-03-12 | 2009-09-24 | Hirohito Morifuji | Culture soil improving agent containing artificial zeolite, and culture soil |
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