JPH04313047A - Odor sensor - Google Patents
Odor sensorInfo
- Publication number
- JPH04313047A JPH04313047A JP6296691A JP6296691A JPH04313047A JP H04313047 A JPH04313047 A JP H04313047A JP 6296691 A JP6296691 A JP 6296691A JP 6296691 A JP6296691 A JP 6296691A JP H04313047 A JPH04313047 A JP H04313047A
- Authority
- JP
- Japan
- Prior art keywords
- cyclodextrin
- derivative
- odor
- molecular film
- odor sensor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical class O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002120 nanofilm Substances 0.000 claims abstract description 9
- 239000013078 crystal Substances 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 150000004033 porphyrin derivatives Chemical class 0.000 claims description 5
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 abstract description 16
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 abstract description 8
- 230000007423 decrease Effects 0.000 abstract description 7
- 230000035945 sensitivity Effects 0.000 abstract description 4
- 238000005192 partition Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 3
- 229920000858 Cyclodextrin Polymers 0.000 description 12
- 239000001116 FEMA 4028 Substances 0.000 description 7
- 229960004853 betadex Drugs 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000010355 oscillation Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003012 bilayer membrane Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 125000005131 dialkylammonium group Chemical class 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229940099898 chlorophyllin Drugs 0.000 description 3
- 235000019805 chlorophyllin Nutrition 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 3
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 2
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 239000000232 Lipid Bilayer Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 229940098773 bovine serum albumin Drugs 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- 229930002868 chlorophyll a Natural products 0.000 description 1
- 229930002869 chlorophyll b Natural products 0.000 description 1
- NSMUHPMZFPKNMZ-VBYMZDBQSA-M chlorophyll b Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C=O)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 NSMUHPMZFPKNMZ-VBYMZDBQSA-M 0.000 description 1
- ANWUQYTXRXCEMZ-NYABAGMLSA-L chlorophyllide a Chemical compound C1([C@H](C2=O)C(=O)OC)=C(N3[Mg]N45)C2=C(C)\C3=C\C(=N2)C(CC)=C(C)\C2=C\C4=C(C=C)C(C)=C5\C=C/2[C@@H](C)[C@H](CCC(O)=O)C1=N\2 ANWUQYTXRXCEMZ-NYABAGMLSA-L 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は臭い物質の濃度測定用の
臭気センサ−に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an odor sensor for measuring the concentration of odorous substances.
【０００２】0002
【従来の技術】図２は例えば刊行物（岡畑惠雄著、「セ
ンサ技術」Ｖｏｌ．９，Ｎｏ．２，ｐ４９（１９８９）
）に記載の臭気センサ−の断面図である。図において、
１は水晶発振子、２は脂質２分子膜である。３は周波数
カウンタ、４はレコ−ダ、５はビ−カ−である。[Prior Art] Fig. 2 shows, for example, a publication (written by Keio Okahata, "Sensor Technology" Vol. 9, No. 2, p. 49 (1989)).
) is a sectional view of the odor sensor described in FIG. In the figure,
1 is a crystal oscillator, and 2 is a lipid bilayer membrane. 3 is a frequency counter, 4 is a recorder, and 5 is a beaker.
【０００３】従来の臭気センサ−は上記のように構成さ
れ、例えば臭気物質（β−ヨノン５．１ｍｇ）をビ−カ
−５（５０ｍｌ）の中に入れると、水晶発振子１の発振
数は低下を始め５分後には７２０Ｈｚ低くなって一定と
なる。この発振子では１ｍｇの物質が吸着すると０．９
５Ｈｚ振動数が低下するので、約７６０ｍｇのβ−ヨノ
ンが２分子膜中に入ったことになる。A conventional odor sensor is constructed as described above. For example, when an odorous substance (5.1 mg of β-ionone) is placed in a beaker 5 (50 ml), the number of oscillations of the crystal oscillator 1 is After 5 minutes, the frequency starts to decrease and becomes constant at 720 Hz. In this oscillator, when 1 mg of substance is adsorbed, 0.9
Since the 5 Hz vibration frequency decreased, approximately 760 mg of β-ionone entered the bilayer membrane.
【０００４】0004
【発明が解決しようとする課題】上記のような従来の臭
気センサ−では１００ｐｐｍ程度の感度しかもっていな
いので、空気清浄機のモニタとしての臭気濃度の測定に
は向いていないという問題点があった。[Problems to be Solved by the Invention] Conventional odor sensors as described above have a sensitivity of only about 100 ppm, so there is a problem that they are not suitable for measuring odor concentration as a monitor for air purifiers. Ta.
【０００５】この発明はかかる問題点を解決するために
なされたものであり、低い臭気濃度においても十分感応
する臭気センサを提供することを目的としている。[0005] The present invention has been made to solve these problems, and an object of the present invention is to provide an odor sensor that is sufficiently sensitive even at low odor concentrations.
【０００６】[0006]
【課題を解決するための手段】この発明に係わる臭気セ
ンサーは、有機分子膜中にシクロデキストリン誘導体お
よび金属ポルフィリン誘導体のうちの少なくとも一方を
担持したものである。[Means for Solving the Problems] The odor sensor according to the present invention has at least one of a cyclodextrin derivative and a metal porphyrin derivative supported in an organic molecular film.
【０００７】[0007]
【作用】上記のように構成された臭気センサ−を臭気物
質（たとえばβ−ヨノン）中に入れると膜と空気中との
分配係数が増してシクロデキストリン誘導体あるいは金
属ポルフィリン誘導体に臭気物質が吸着し、発振周波数
の低下が著しくなる。ゆえに臭気物資に対する感度が著
しく良くなるのである。[Operation] When the odor sensor configured as described above is placed in an odorous substance (for example, β-ionone), the partition coefficient between the membrane and the air increases, and the odorous substance is adsorbed onto the cyclodextrin derivative or metal porphyrin derivative. , the oscillation frequency decreases significantly. Therefore, sensitivity to odorants is significantly improved.
【０００８】[0008]
【実施例】実施例１．図１はこの発明の一実施例を示す
断面図であり、図中、１は水晶発振子、２はジアルキル
アンモニウム塩＝ポリスチレンスルホン酸コンプレック
スによる２分子膜、１０はジメチル−β−シクロデキス
トリンを示す。センサ−の作り方は１０重量部のジアル
キルアンモニウム塩水溶液（１０％）、１０重量部のポ
リスチレンスルホン酸ナトリウム水溶液（１０％）を混
合して生じた沈殿を乾燥する。このもの１重量部と０．
３重量部のジメチル−β−シクロデキストリンを１０重
量部のクロロホルムに溶かし水晶発振子にコ−トし乾燥
する。[Example] Example 1. FIG. 1 is a cross-sectional view showing one embodiment of the present invention, in which 1 is a crystal oscillator, 2 is a bilayer membrane made of a dialkyl ammonium salt=polystyrene sulfonic acid complex, and 10 is dimethyl-β-cyclodextrin. . The sensor is made by mixing 10 parts by weight of a dialkylammonium salt aqueous solution (10%) and 10 parts by weight of a sodium polystyrene sulfonate aqueous solution (10%) and drying the resulting precipitate. 1 part by weight of this and 0.
3 parts by weight of dimethyl-β-cyclodextrin is dissolved in 10 parts by weight of chloroform, coated on a crystal oscillator, and dried.
【０００９】上記のように構成された臭気センサ−に於
いては、臭気物質はシクロデキストリン１０に包接され
膜２中の濃度がシクロデキストリン１０がない時と比べ
て増加する。故に発振周波数は臭気物質の濃度の増加に
つれて急激に減少する。この時１００ｐｐｂのβ−ヨノ
ンに対して１．２Ｈｚの発振周波数低下があった。In the odor sensor constructed as described above, the odorous substances are included in the cyclodextrin 10, and the concentration in the membrane 2 increases compared to when the cyclodextrin 10 is not present. Therefore, the oscillation frequency decreases rapidly as the concentration of odorant increases. At this time, the oscillation frequency decreased by 1.2 Hz for 100 ppb of β-ionone.
【００１０】なお、この発明に用いられる有機分子膜と
しては、ジアルキルアンモニウム＝ポリスチレンスルホ
ン酸分子コンプレックス、レシチン、ヒトの嗅覚細胞抽
出液、牛血清アルブミン、ポリビニルアルコ−ル、アセ
チルセルロ−ス、ポリ塩化ビニル等を挙げることができ
る。[0010] The organic molecular membrane used in the present invention includes dialkylammonium polystyrene sulfonic acid molecular complex, lecithin, human olfactory cell extract, bovine serum albumin, polyvinyl alcohol, acetyl cellulose, polychloride. Examples include vinyl.
【００１１】また、この発明に用いられるシクロデキス
トリン誘導体としては、α、β、γ−シクロデキストリ
ン、ジメチル−β−シクロデキストリン、ハイドロキシ
プロピル−β−シオクロデキストリン、β−シクロデキ
ストリンポリマ−，ジエチル−β−シクロデキストリン
、アンフィリックシクロデキストリンを挙げることがで
きる。Cyclodextrin derivatives used in the present invention include α, β, γ-cyclodextrin, dimethyl-β-cyclodextrin, hydroxypropyl-β-cyclodextrin, β-cyclodextrin polymer, and diethyl-cyclodextrin. Examples include β-cyclodextrin and amphilic cyclodextrin.
【００１２】さらに、この発明に用いられる金属ポルフ
ィリン誘導体としては、銅クロロフィル、銅クロロフィ
リン、クロロフィルａ，クロロフィルｂ，クロロフィラ
イドａ，銅テトラフェニルポルフィリン、鉄テトラカル
ボキシフタロシアニン等を挙げることができる。Further, the metal porphyrin derivatives used in the present invention include copper chlorophyll, copper chlorophyllin, chlorophyll a, chlorophyll b, chlorophyllide a, copper tetraphenylporphyrin, iron tetracarboxyphthalocyanine, and the like.
【００１３】検知できる臭気成分としては、β−ヨノン
、ｄ−リモネン、しょうのう、クマリン、シトラ−ル、
イソアミルアセテ−ト、メチルアセテ−ト、エ−テル、
アンモニア等を挙げることができる。[0013] Detectable odor components include β-ionone, d-limonene, camphor, coumarin, citral,
Isoamyl acetate, methyl acetate, ether,
Examples include ammonia.
【００１４】実施例２．上記実施例１では２分子膜２と
してジアルキルアンモニウム塩＝ポリスチレンスルホン
酸分子コンプレックスを用いていたが、２分子膜２とし
てレシチンを用いた時１００ｐｐｂのβ−ヨノンに対し
て０．８Ｈｚの発振周波数低下があった。Example 2. In Example 1 above, a dialkyl ammonium salt=polystyrene sulfonic acid molecular complex was used as the bilayer membrane 2, but when lecithin was used as the bilayer membrane 2, the oscillation frequency decreased by 0.8 Hz for 100 ppb of β-ionone. was there.
【００１５】実施例３．上記実施例１においてジメチル
−β−シクロデキストリンを２分子膜に添加していたが
、替りに銅クロロフィリンを添加した場合１００ｐｐｂ
のアンモニアに対して０．６Ｈｚの発振周波数低下があ
った。Example 3. In Example 1 above, dimethyl-β-cyclodextrin was added to the bilayer membrane, but when copper chlorophyllin was added instead, 100 ppb
There was a decrease in oscillation frequency of 0.6 Hz with respect to ammonia.
【００１６】参考例１．上記実施例１においてジメチル
−β−シクロデキストリンを添加しない場合、１００ｐ
ｐｂのβ−ヨノンに対して周波数の低下はみられなかっ
た。Reference example 1. When dimethyl-β-cyclodextrin is not added in Example 1 above, 100p
No decrease in frequency was observed for β-ionone of pb.
【００１７】参考例２．上記実施例３において銅クロロ
フィリンを添加しない場合１００ｐｐｂのアンモニアに
対して周波数の低下はなかった。Reference example 2. In Example 3 above, when copper chlorophyllin was not added, there was no decrease in frequency with respect to 100 ppb of ammonia.
【００１８】[0018]
【発明の効果】以上のように、この発明によれば、有機
分子膜中にシクロデキストリン誘導体および金属ポルフ
ィリン誘導体のうちの少なくとも一方を担持したので、
低い臭気濃度においても十分感応する効果がある。As described above, according to the present invention, since at least one of a cyclodextrin derivative and a metal porphyrin derivative is supported in an organic molecular film,
It has a sufficient sensitivity effect even at low odor concentrations.
【図１】この発明の一実施例を示す斜視図である。FIG. 1 is a perspective view showing an embodiment of the present invention.
【図２】従来の臭気センサ−を示す構成図であるFIG. 2 is a configuration diagram showing a conventional odor sensor.
１ 水晶発振子 ２ 有機分子膜 １０ シクロデキストリン誘導体 1 Crystal oscillator 2 Organic molecular film 10 Cyclodextrin derivative
Claims (1)
気センサ−において、上記有機分子膜中にシクロデキス
トリン誘導体および金属ポルフィリン誘導体のうちの少
なくとも一方を担持したことを特徴とする臭気センサ−
。1. An odor sensor comprising an organic molecular film formed on a crystal oscillator, characterized in that the organic molecular film supports at least one of a cyclodextrin derivative and a metal porphyrin derivative.
.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6296691A JPH04313047A (en) | 1991-03-27 | 1991-03-27 | Odor sensor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6296691A JPH04313047A (en) | 1991-03-27 | 1991-03-27 | Odor sensor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04313047A true JPH04313047A (en) | 1992-11-05 |
Family
ID=13215588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6296691A Pending JPH04313047A (en) | 1991-03-27 | 1991-03-27 | Odor sensor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04313047A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6582583B1 (en) | 1998-11-30 | 2003-06-24 | The United States Of America As Represented By The Department Of Health And Human Services | Amperometric biomimetic enzyme sensors based on modified cyclodextrin as electrocatalysts |
| WO2008114607A1 (en) * | 2007-03-22 | 2008-09-25 | Shinshu University | Water-soluble metal phthalocyanine complex, sensor element, sensor using the sensor element, and method for production of sensor element |
-
1991
- 1991-03-27 JP JP6296691A patent/JPH04313047A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6582583B1 (en) | 1998-11-30 | 2003-06-24 | The United States Of America As Represented By The Department Of Health And Human Services | Amperometric biomimetic enzyme sensors based on modified cyclodextrin as electrocatalysts |
| WO2008114607A1 (en) * | 2007-03-22 | 2008-09-25 | Shinshu University | Water-soluble metal phthalocyanine complex, sensor element, sensor using the sensor element, and method for production of sensor element |
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