JPH04304353A - Production of corrosion resistant hot rolled steel sheet having excellent r value - Google Patents
Production of corrosion resistant hot rolled steel sheet having excellent r valueInfo
- Publication number
- JPH04304353A JPH04304353A JP8921491A JP8921491A JPH04304353A JP H04304353 A JPH04304353 A JP H04304353A JP 8921491 A JP8921491 A JP 8921491A JP 8921491 A JP8921491 A JP 8921491A JP H04304353 A JPH04304353 A JP H04304353A
- Authority
- JP
- Japan
- Prior art keywords
- steel sheet
- steel plate
- hot
- steel
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 79
- 239000010959 steel Substances 0.000 title claims abstract description 79
- 230000007797 corrosion Effects 0.000 title claims abstract description 19
- 238000005260 corrosion Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 40
- 239000002184 metal Substances 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 40
- 238000007747 plating Methods 0.000 claims abstract description 35
- 230000003746 surface roughness Effects 0.000 claims abstract description 11
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 238000005507 spraying Methods 0.000 claims abstract description 8
- 238000005266 casting Methods 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011247 coating layer Substances 0.000 claims abstract description 4
- 238000003618 dip coating Methods 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims description 15
- 230000008018 melting Effects 0.000 claims description 15
- 239000011701 zinc Substances 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
- 239000010410 layer Substances 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000004804 winding Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 12
- 150000002739 metals Chemical class 0.000 abstract description 9
- 238000005098 hot rolling Methods 0.000 abstract description 8
- 229910052748 manganese Inorganic materials 0.000 abstract description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 description 18
- 238000002347 injection Methods 0.000 description 9
- 239000007924 injection Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000012545 processing Methods 0.000 description 5
- 238000005275 alloying Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- -1 lead or their alloys Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 238000001241 arc-discharge method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、亜鉛、アルミニウム、
鉛等の単一金属或いはその合金のめっきを生産性良く、
経済的に施した▲r▼値の優れた加工用耐食性熱間圧延
鋼板の製造方法に関するものである。[Industrial Application Field] The present invention is directed to zinc, aluminum,
Highly productive plating of single metals such as lead or their alloys,
The present invention relates to an economical method for producing a corrosion-resistant hot-rolled steel sheet for processing with an excellent ▲r▼ value.
【0002】0002
【従来の技術】従来、熱間圧延鋼板等に亜鉛等の金属を
めっきするには、熱間圧延工程後に一旦冷却後、酸洗し
た酸洗板を亜鉛や合金などの金属の溶融浴に浸漬する溶
融メッキ法や、該酸洗板をめっきしようとする金属の塩
を含んだ溶液中に浸漬し直流電解する電気めっき法等が
用いられていた。しかし、これらの方法では、酸洗設備
及び大型のめっき装置が必要となり、多大の設備費と広
大な設置場所が必要となり、また、溶融めっきでは鋼板
を加熱するための燃料費がかかり、電気めっきでは電解
を行うための電気代がかかるので、経済性の改善が望ま
れていた。[Prior Art] Conventionally, in order to plate hot-rolled steel sheets with metals such as zinc, the pickled sheets were cooled once after the hot-rolling process, and then the pickled sheets were immersed in a molten bath of metals such as zinc or alloys. The hot-dip plating method, in which the pickled plate is immersed in a solution containing the salt of the metal to be plated, and electrolyzed with direct current, etc., have been used. However, these methods require pickling equipment and large-scale plating equipment, requiring large equipment costs and a large installation space.In addition, hot-dip plating requires fuel costs to heat the steel plate, and electroplating However, since electricity costs are required for electrolysis, improvements in economic efficiency have been desired.
【0003】これらの欠点を補う金属めっき方法として
、特開昭54−146230号公報において、熱間圧延
工程中或いは精整ライン中を走行する圧延鋼材外表面に
溶融金属を溶射し、鋼材表層面に均一なめっき層を形成
する方法が提案されている。しかし、この方法は熱間圧
延工程中に形成されるスケールの影響を考慮しておらず
、この方法を実施した場合、スケールの上から溶融金属
を溶射することになるためめっき密着性が悪く、製造後
にプレス加工等が行われる薄鋼板の場合、加工後にめっ
きがはがれて耐食性が悪化する。その上これ等の問題を
克服するために必要な溶射金属の種類や溶射する際の鋼
板温度、密着性を向上させるための鋼板表面の適性粗度
、溶射を行う熱間圧延工程中又は精整ライン上での望ま
しい位置等については記載がなく、実用的な密着性を保
証するめっき層を得るための具体的条件について全く開
示も示唆もない。[0003] As a metal plating method that compensates for these drawbacks, Japanese Patent Application Laid-Open No. 146230/1983 discloses a method in which molten metal is sprayed onto the outer surface of a rolled steel material running in a hot rolling process or in a finishing line, and the surface layer of the steel material is coated with molten metal. A method of forming a uniform plating layer has been proposed. However, this method does not take into account the influence of scale formed during the hot rolling process, and when this method is implemented, the plating adhesion is poor because molten metal is sprayed over the scale. In the case of thin steel sheets that are subjected to press working or the like after manufacturing, the plating peels off after processing, resulting in poor corrosion resistance. In addition, in order to overcome these problems, the type of sprayed metal, the temperature of the steel plate during spraying, the appropriate roughness of the steel plate surface to improve adhesion, and the roughness during the hot rolling process or refining during the spraying process. There is no description of desirable positions on the line, etc., and there is no disclosure or suggestion of specific conditions for obtaining a plating layer that guarantees practical adhesion.
【0004】一方、熱延鋼板の▲r▼値の向上について
は、特開昭59−226149号公報に記載のごとく、
Tiを用いた極低炭素鋼を油潤滑圧延で製造する方法、
または特開昭62−192539号公報に記載のごとく
、Nb、Ti等の合金を添加して製造する方法がある。
しかし、前者に関しては、油潤滑で使用する圧延油は高
濃度であり、必然的に圧延自体がスリップ限界ぎりぎり
の条件で行うことになり、圧延温度、圧延速度、圧延可
能なサイズ等の制約が大きく生産効率の悪化が否定でき
ない。また、ロールに付着した油を取り除く等の手間が
必要になり作業性、生産性が悪いという欠点もある。一
方後者に関しては、Nb、Ti等の合金を使用するので
合金コストが高く経済的でないという問題もある。On the other hand, regarding the improvement of the ▲r▼ value of hot rolled steel sheets, as described in Japanese Patent Application Laid-Open No. 59-226149,
A method for producing ultra-low carbon steel using Ti by oil-lubricated rolling,
Alternatively, there is a method of manufacturing by adding alloys such as Nb and Ti, as described in JP-A-62-192539. However, regarding the former, the rolling oil used for oil lubrication has a high concentration, and rolling itself is inevitably carried out under conditions at the very edge of the slip limit, and there are restrictions such as rolling temperature, rolling speed, and the size that can be rolled. A significant deterioration in production efficiency cannot be denied. Further, there is also the disadvantage that workability and productivity are poor because it requires time and effort to remove oil adhering to the rolls. On the other hand, regarding the latter, since alloys such as Nb and Ti are used, there is a problem that the alloy cost is high and it is not economical.
【0005】[0005]
【発明が解決しようとする課題】本発明は、上記の問題
点を伴わずに経済的に、作業性よく、亜鉛等の単一金属
あるいはその合金からなるめっき密着性の良いめっき層
を有する耐食性に優れた高▲r▼値耐食性熱間圧延鋼板
を製造する方法提供を課題とするものである。[Problems to be Solved by the Invention] The present invention does not involve the above-mentioned problems, is economical, has good workability, and has a corrosion-resistant plating layer made of a single metal such as zinc or an alloy thereof and has good plating adhesion. An object of the present invention is to provide a method for producing a hot rolled steel sheet with high corrosion resistance and excellent ▲r▼ value.
【0006】[0006]
【課題を解決するための手段】本発明は、上記の課題を
解決するため、重量%で、Mn:0.10〜0.60%
、S:0.001〜0.012%を含み、その他Fe及
び不可避的成分からなる鋼の1400℃〜1200℃の
温度範囲を≧5.0℃/分の冷却速度で鋳造凝固して鋳
片とし、該鋳片の仕上げ圧延を前記鋳造開始から60分
以内に開始してAr3 点以上で終了し、その後鋼板を
巻取るまでの間に、該鋼板表面のスケールをドライデス
ケーリングまたは高圧水デスケーリングを用いて除去す
ると供に、表面粗度をRa値で0.5μm以上とし、引
き続き亜鉛、アルミニウム、鉛等の単一金属或いはその
合金等の金属粉末を前記鋼板の所要の面に前記金属粉末
の融点よりも30℃以上200℃以下の範囲の鋼板温度
において噴射して該鋼板の所要の面に溶融めっき層を形
成する事を特徴とする耐食性熱間圧延鋼板の製造方法を
第1の手段とし、重量%で、Mn:0.10〜0.60
%、S:0.001〜0.012%を含み、その他Fe
及び不可避的成分からなる鋼の1400℃〜1200℃
の温度範囲を≧5.0℃/分の冷却速度で鋳造凝固して
鋳片とし、該鋳片の仕上げ圧延を前記鋳造開始から60
分以内に開始してAr3 点以上で終了し、その後鋼板
を巻取るまでの間に、該鋼板表面のスケールをドライデ
スケーリングまたは高圧水デスケーリングを用いて除去
すると供に、表面粗度をRa値で0.5μm以上とし、
引き続き亜鉛、アルミニウム、鉛等の単一金属或いはそ
の合金等の粒度150メッシュ以上の金属粉末を前記鋼
板の所要の面に前記金属粉末の融点よりも30℃以上2
00℃以下の範囲の鋼板温度において噴射して該鋼板の
所要の面に溶融めっき層を形成する事を特徴とする耐食
性熱間圧延鋼板の製造方法を第2の手段とするものであ
る。[Means for Solving the Problems] In order to solve the above problems, the present invention provides Mn: 0.10 to 0.60% by weight.
, S: 0.001 to 0.012%, and other Fe and other unavoidable components are cast and solidified in the temperature range of 1400°C to 1200°C at a cooling rate of ≧5.0°C/min to obtain a slab. Finish rolling of the slab is started within 60 minutes from the start of casting and completed at the Ar3 point or higher, and then the scale on the surface of the steel plate is removed by dry descaling or high-pressure water descaling until the steel plate is wound. At the same time, the surface roughness is set to 0.5 μm or more in terms of Ra value, and then a metal powder such as a single metal such as zinc, aluminum, or lead or an alloy thereof is applied to the required surface of the steel plate. A first method for producing a corrosion-resistant hot-rolled steel sheet is characterized in that a hot-dip coating layer is formed on a required surface of the steel sheet by spraying at a temperature of 30° C. or higher and 200° C. or lower than the melting point of the powder. Means, weight %, Mn: 0.10 to 0.60
%, S: 0.001 to 0.012%, and other Fe
and 1400°C to 1200°C for steel consisting of unavoidable components.
The slab is cast and solidified at a cooling rate of ≧5.0°C/min, and the slab is finished rolled for 60 minutes from the start of casting.
After starting within minutes and finishing at the Ar3 point or higher, the scale on the surface of the steel plate is removed using dry descaling or high-pressure water descaling, and the surface roughness is reduced to Ra. The value is 0.5 μm or more,
Subsequently, a metal powder such as a single metal such as zinc, aluminum, or lead or an alloy thereof with a particle size of 150 mesh or more is applied to the required surface of the steel plate at a temperature of 30°C or higher than the melting point of the metal powder.
The second means is a method for manufacturing a corrosion-resistant hot-rolled steel sheet, which is characterized in that a hot-dip coating layer is formed on a required surface of the steel sheet by spraying at a steel sheet temperature of 00° C. or lower.
【0007】なお、本発明でいう加工用熱延鋼板とは、
加工用熱延鋼板を製造し、使用している分野で、該鋼板
用として通常用いられている鋼、例えば重量%で、C:
0.01%〜0.10%、Mn:0.10%〜0.60
%、Si:0.001〜0.06%およびP:0.00
1%〜0.050%、S:0.001%〜0.012%
を含み、その他Feおよび不可避的成分からなる鋼をさ
す。[0007] Note that the hot-rolled steel sheet for processing in the present invention refers to
In the field of manufacturing and using hot-rolled steel sheets for processing, steels commonly used for such steel sheets, for example, C:
0.01% to 0.10%, Mn: 0.10% to 0.60
%, Si: 0.001-0.06% and P: 0.00
1% ~ 0.050%, S: 0.001% ~ 0.012%
This refers to steel that contains Fe and other unavoidable components.
【0008】[0008]
【作用】本発明者等は、前記した課題を達成するために
種々の実験検討を行い以下の知見を得た。[Operation] In order to achieve the above-mentioned object, the present inventors conducted various experimental studies and obtained the following knowledge.
【0009】上記成分の鋼の1400℃〜1200℃の
温度域を5℃/分以上の冷却速度で鋳造凝固して鋳片と
し、該鋳片の仕上げ圧延を前記凝固開始から60分以内
に開始し、Ar3 点以下で該圧延を終了すると、Mn
Sとして析出するS量が該圧延までの間に充分固溶状態
で確保され、該圧延時に微細なMnSとなって析出し、
この析出した微細なMnSによりオーステナイトの再結
晶が抑制されて充分に発達したオーステナイトの圧延集
合組織を形成し、これが(112)面の集積が高いフェ
ライトに変態し、▲r▼値の高い鋼板が得られる事を知
見した。[0009] Steel having the above components is cast and solidified in the temperature range of 1400°C to 1200°C at a cooling rate of 5°C/min or more to form a slab, and finish rolling of the slab is started within 60 minutes from the start of solidification. However, when the rolling is finished below the Ar3 point, Mn
The amount of S that precipitates as S is ensured in a solid solution state until the rolling, and precipitates as fine MnS during the rolling,
The precipitated fine MnS suppresses austenite recrystallization and forms a fully developed austenite rolling texture, which transforms into ferrite with a high concentration of (112) planes, resulting in a steel sheet with a high ▲r▼ value. I found out what I can get.
【0010】一方発明者等は、種々の温度まで加熱した
熱延鋼板のスケールを除去した後、純亜鉛粉末、純アル
ミニウム粉末、亜鉛とアルミニウムの合金粉末など種々
の金属粉末を噴射する実験を行い、鋼板の温度が噴射す
る金属粉末の融点よりも30℃以上高い場合に、密着性
の良いめっき層を形成することが可能であり、また鋼板
の温度が該融点よりも200℃を超える温度になると酸
化層が発達して外観を損ない、また、めっき量を制御で
きなくなることを見出した。これ等の知見から、金属粉
末の噴射を受ける鋼板の温度を粉末の融点よりも30℃
〜200℃の範囲に高くすると、粉末を溶かす融解熱と
、合金反応を起こすために十分な時間溶融状態を維持す
る熱が供給され、酸化層の発達も防止できることが判明
した。[0010] On the other hand, the inventors conducted experiments in which various metal powders such as pure zinc powder, pure aluminum powder, and zinc-aluminum alloy powder were injected after removing scale from hot-rolled steel sheets heated to various temperatures. It is possible to form a plating layer with good adhesion when the temperature of the steel plate is 30°C or more higher than the melting point of the metal powder to be injected, and when the temperature of the steel plate is 200°C or more higher than the melting point. It was discovered that if this happens, an oxidized layer develops, impairing the appearance, and making it impossible to control the amount of plating. Based on these findings, the temperature of the steel plate that receives the injection of metal powder is set to 30°C higher than the melting point of the powder.
It has been found that increasing the temperature to a range of ˜200° C. provides the heat of fusion to melt the powder and maintain the molten state for a sufficient period of time to initiate the alloying reaction, while also preventing the development of an oxidized layer.
【0011】耐食用途のめっき層を形成する金属として
は、亜鉛、アルミニウム、鉛、亜鉛とアルミニウムの合
金、鉄の含有量が5重量%以下程度の亜鉛と鉄の合金な
どがある。これらの金属の融点は327℃以上で約70
0℃以下程度の温度範囲にあり、これ等の融点よりも3
0℃〜200℃高い温度範囲は、熱間圧延工程では仕上
げ圧延終了から巻取りまでの間にあり、その間で噴射に
使用する金属の融点を基に生産性と経済性の良い位置を
噴射位置とすれば良いことが判明した。[0011] Metals forming a plating layer for corrosion-resistant purposes include zinc, aluminum, lead, an alloy of zinc and aluminum, and an alloy of zinc and iron with an iron content of about 5% by weight or less. The melting point of these metals is approximately 70°C above 327°C.
It is in the temperature range of about 0°C or less, and is 3° below the melting point of these.
The temperature range from 0℃ to 200℃ higher is the period from the end of finish rolling to the winding in the hot rolling process, and during that time, the injection position is determined based on the melting point of the metal used for injection, and the position that is most productive and economical. It turned out to be a good thing to do.
【0012】また、めっきの前処理としては、生産性と
経済性の点からは、めっき層と地鉄との間にスケールが
あるとその部分で剥がれ易くなりめっき密着性が悪化す
るので、それを防止するスケール除去と、地鉄とめっき
層との接触面積を拡大して合金化反応を促進するための
鋼板表面の粗度の適性化とを同時に行うことが良い。そ
れには高圧水デスケーリングや液体を用いないドライデ
スケーリングが良く、ドライデスケーリングについて具
体的には、ショットブラスト、グリットブラスト、ブラ
ッシングロール、真空アーク放電法などが良いことが判
明した。ただし、高圧水デスケーリングの場合、デスケ
ーリング後に鋼板上に水が残っていると新たなスケール
の発生を促進し、更に粉末噴射時の合金化反応を妨げる
ので、デスケーリング直後に高圧水または高圧ガスによ
り十分な水切りを行う必要がある。[0012] In addition, from the viewpoint of productivity and economy, as a pre-treatment for plating, if there is scale between the plating layer and the base metal, it will easily peel off in that area and the adhesion of the plating will deteriorate. It is better to simultaneously remove scale to prevent this and optimize the roughness of the steel plate surface to increase the contact area between the base steel and the plating layer and promote the alloying reaction. High-pressure water descaling or dry descaling that does not use a liquid is effective for this purpose, and specifically, shot blasting, grit blasting, brushing roll, vacuum arc discharge methods, etc. have been found to be effective for dry descaling. However, in the case of high-pressure water descaling, if water remains on the steel plate after descaling, it will promote the generation of new scale and further impede the alloying reaction during powder injection. It is necessary to drain the water sufficiently using gas.
【0013】デスケーリング時に形成する鋼板の表面粗
度については、表面粗度が粗い方が表面積が大きくなり
合金化反応を起こし易いので、めっき密着性向上のため
に好ましい。鋼板の表面粗度がめっき密着性に与える影
響を調べるため、粒度150メッシュ以上のZn粉末ま
たはAl粉末を、該金属の融点よりも30〜200℃高
い温度に加熱した粗度調整済みの鋼板に噴射する実験を
行った。図2はその結果の一例で、Zn粉末をその融点
より100℃高い鋼板に噴射した場合の実験結果を示し
たものであるが、このようにRa値で0.5μm以上あ
ればBl評点(ボールインパクトテストによる評点)で
1が得られ、0.3〜0.4μmでも評点2が得られ実
用上問題のない充分なめっき密着性が得られることが判
明した。上記したBl評点は1が最もめっき密着性の良
いことを示し、値が大きくなるほどめっき密着性が悪い
ことを示す。加工用途の耐食性熱延鋼板としては、この
Bl評点で1を得ることが最も望ましい。Regarding the surface roughness of the steel plate formed during descaling, a coarser surface roughness is preferable for improving plating adhesion, since the surface area becomes larger and alloying reactions are more likely to occur. In order to investigate the effect of the surface roughness of a steel plate on plating adhesion, Zn powder or Al powder with a particle size of 150 mesh or more was heated to a temperature 30 to 200 °C higher than the melting point of the metal on a roughness-adjusted steel plate. We conducted an experiment to spray the liquid. Figure 2 shows an example of the results, and shows the experimental results when Zn powder was injected onto a steel plate 100°C higher than its melting point. A score of 1 was obtained in the impact test, and a score of 2 was obtained even at 0.3 to 0.4 μm, indicating that sufficient plating adhesion without any practical problems could be obtained. As for the Bl rating described above, 1 indicates the best plating adhesion, and the larger the value, the worse the plating adhesion. For a corrosion-resistant hot-rolled steel sheet for processing purposes, it is most desirable to obtain a Bl rating of 1.
【0014】デスケーリング後の新たなスケールの生成
を防ぐため、デスケーリング後に粉末を噴射する必要が
ある。デスケーリングと粉末噴射との間をアルゴン、窒
素等の不活性ガス雰囲気、不活性ガスと水素の混合雰囲
気、水素雰囲気等の非酸化性もしくは還元性雰囲気中に
維持すれば更に望ましい。この場合、非酸化性もしくは
還元性雰囲気中でデスケーリングあるいは粉末噴射を実
施してもよいことはいうまでもない。[0014] In order to prevent the formation of new scale after descaling, it is necessary to inject powder after descaling. It is more preferable to maintain a non-oxidizing or reducing atmosphere between descaling and powder injection, such as an inert gas atmosphere such as argon or nitrogen, a mixed atmosphere of an inert gas and hydrogen, or a hydrogen atmosphere. In this case, it goes without saying that descaling or powder injection may be carried out in a non-oxidizing or reducing atmosphere.
【0015】また、吹き付ける金属粉末の粒度について
は、あまり粉末が大きいと熱伝導が悪く溶融し難くなる
ため、飛散消耗せず、多大の微粉化費を要しない範囲で
小さい粉末の方が良い。金属粉末の粒度がめっき密着性
に与える影響を調べるため、Zn粉末またはAl粉末を
、該金属の融点よりも30〜200℃高い温度に加熱し
、表面粗度をRa値で0.5μm以上に調整済みの鋼板
に噴射する実験を行った。図1はその結果の一例で、Z
n粉末をその融点より100℃高い鋼板に噴射した場合
の実験結果を示したものであるが、このように粉末の粒
度が150メッシュ以上あれば迅速適確に溶融して、B
l評点で1が得られめっき密着性が良好となり、50以
上150メッシュ未満でもBl評点で2が得られ実用上
問題とならない密着性が得られることが判明した。Regarding the particle size of the metal powder to be sprayed, if the powder is too large, heat conduction will be poor and it will be difficult to melt, so it is better to use a small powder as long as it does not scatter and consume and does not require a large amount of pulverization cost. In order to investigate the influence of the particle size of metal powder on plating adhesion, Zn powder or Al powder was heated to a temperature 30 to 200 °C higher than the melting point of the metal, and the surface roughness was adjusted to an Ra value of 0.5 μm or more. An experiment was conducted in which spraying was applied to a prepared steel plate. Figure 1 shows an example of the results, and Z
This shows the experimental results when N powder was injected onto a steel plate whose melting point was 100°C higher than the melting point of the B powder.
It was found that a Bl rating of 1 was obtained and the plating adhesion was good, and even with a Bl rating of 50 or more and less than 150 mesh, a Bl rating of 2 was obtained and adhesion that did not cause any practical problems was obtained.
【0016】以上の各知見の活用により、本発明は課題
を達成している。[0016] By utilizing the above knowledge, the present invention has achieved the object.
【0017】[0017]
【実施例】表1に示す化学成分を有する鋼を表2に示す
熱延条件で製造し、金属粉末噴射に関しては、熱間圧延
ラインの仕上げ圧延機と巻取り機との間に種々のデスケ
ーリング装置で粉末噴射装置を設置し、仕上げ圧延後の
鋼板に種々のデスケーリング装置をスケール除去と粗度
調整を行った後、粉末噴射装置で金属粉末を噴射してか
ら巻取った。[Example] Steel having the chemical composition shown in Table 1 was manufactured under the hot rolling conditions shown in Table 2. Regarding metal powder injection, various devices were installed between the finishing mill and the winding machine of the hot rolling line. A powder injection device was installed in the scaling device, and various descaling devices were used to perform scale removal and roughness adjustment on the steel plate after finish rolling, after which metal powder was injected with the powder injection device and the sheet was wound up.
【0018】[0018]
【表1】[Table 1]
【0019】[0019]
【表2】 (注)■ CCS:鋳造冷却速度 ■ FTO:仕上げ圧延開始温度 ■ FTE:仕上げ圧延終了温度 ■ MST:凝固開始から圧延開始までの時間[Table 2] (Note) ■ CCS: Casting cooling rate ■ FTO: Finish rolling start temperature ■ FTE: Finish rolling end temperature ■ MST: Time from start of solidification to start of rolling
【00
20】実施例−1
表3の本発明例に示すようにめっき密着性が良く、耐食
性も良好な高▲r▼値熱延鋼板が製造できる。しかし、
本発明例に比べ、凝固時の冷却速度が本発明の下限を外
れた鋼番5、仕上げ圧延終了温度がAr3 点をきった
鋼番6、凝固から仕上げ圧延開始までの時間が上限を外
れた鋼番7、Sが本発明の下限を外れている鋼番8の各
比較例は、▲r▼値が0.90以下と低かった。00
Example 1 As shown in the invention examples in Table 3, a high r value hot rolled steel sheet with good plating adhesion and good corrosion resistance can be produced. but,
Compared to the inventive examples, Steel No. 5 had a cooling rate during solidification that was outside the lower limit of the invention, Steel No. 6 had a finish rolling finish temperature below the Ar3 point, and Steel No. 6 had a time from solidification to start of finish rolling that was outside the upper limit. Comparative examples of Steel No. 7 and Steel No. 8 in which S was outside the lower limit of the present invention had low ▲r▼ values of 0.90 or less.
【0021】[0021]
【表3】
(注)■ DDはデスケーリング法を指す。Sはショ
ットブラスト。
■ 粉末種類はZn。粒度は250メッシュ。
■ 鋼板温度は600℃。Ra値は5μm。
■ 耐食性はSSTで評価し、◎は大変良好を意味す
る。[Table 3] (Note) ■ DD refers to descaling method. S is shot blast. ■ The powder type is Zn. Particle size is 250 mesh. ■ Steel plate temperature is 600℃. Ra value is 5 μm. ■ Corrosion resistance was evaluated by SST, and ◎ means very good.
【0022】実施例−2
表4、5に示したように、本発明例のNo. 1〜11
ではBl評点1が得られ、めっき密着性がよく耐食性も
良好な耐食性熱延鋼板を得ることができた。また、本発
明例のNo. 12〜18では請求項2の要件である粉
末の粒度あるいは鋼板の表面粗度が外れているが、請求
項1の要件をすべて満たしているため、Bl評点で2が
得られ耐食性が良好な耐食性熱延鋼板を得ることができ
た。これに対し本発明の請求項1の要件である鋼板の下
限温度が外れたNo. 19,21,23、鋼板の上限
温度が外れたNo. 20,22,24の各比較例は共
にめっき密着性が悪く、所要の耐食性を有する耐食性熱
延鋼板を得ることが出来なかった。Example 2 As shown in Tables 4 and 5, the present invention example No. 1-11
In this case, a Bl rating of 1 was obtained, and a corrosion-resistant hot-rolled steel sheet with good plating adhesion and good corrosion resistance could be obtained. Moreover, No. 1 of the present invention example. In Nos. 12 to 18, the particle size of the powder or the surface roughness of the steel plate, which is the requirement of claim 2, is not met, but all the requirements of claim 1 are satisfied, so a Bl rating of 2 is obtained and the corrosion resistance is good. We were able to obtain hot-rolled steel sheets. On the other hand, in No. 1, the lower limit temperature of the steel plate, which is a requirement of claim 1 of the present invention, was not met. 19, 21, 23, No. 1 where the upper limit temperature of the steel plate was exceeded. In Comparative Examples 20, 22, and 24, the plating adhesion was poor, and it was not possible to obtain a corrosion-resistant hot-rolled steel sheet having the required corrosion resistance.
【0023】[0023]
【表4】[Table 4]
【0024】[0024]
【表5】[Table 5]
【0025】[0025]
【発明の効果】以上説明した本発明によると、従来方法
のごとくTi、Nb等の合金を使用する事なく、また、
油潤滑圧延を行う事なく良好な▲r▼値を有し、かつ、
亜鉛、アルミニウム、鉛等の単一金属或いはその合金な
どのめっき層を、小規模の設備で密着性よく生産性良く
、経済的に付与することが可能となるので、当業分野に
もたらす工業的効果が極めて大きい。[Effects of the Invention] According to the present invention explained above, unlike the conventional method, alloys such as Ti and Nb are not used, and
Has a good ▲r▼ value without performing oil lubrication rolling, and
It is possible to apply plating layers of single metals such as zinc, aluminum, lead, etc. or their alloys economically with good adhesion and high productivity using small-scale equipment, which brings industrial benefits to the field. The effect is extremely large.
【図1】めっき金属の粉末を吹き付ける前の鋼板の表面
粗度Ra値とBl評点で示しためっき密着性の関係を2
水準の粉末粒度で示す図である。[Figure 1] The relationship between the surface roughness Ra value of the steel plate before spraying the plating metal powder and the plating adhesion indicated by the Bl rating.
FIG. 2 shows a level of powder particle size.
【図2】めっき金属の粉末の粒度とBl評点で示しため
っき密着性の関係を2水準の表面粗度Ra値で示す図で
ある。FIG. 2 is a diagram showing the relationship between the particle size of the plating metal powder and the plating adhesion indicated by the Bl rating using two levels of surface roughness Ra values.
Claims (2)
%、S:0.001〜0.012%を含み、その他Fe
及び不可避的成分からなる鋼の1400℃〜1200℃
の温度範囲を≧5.0℃/分の冷却速度で鋳造凝固して
鋳片とし、該鋳片の仕上げ圧延を前記鋳造開始から60
分以内に開始してAr3 点以上で終了し、その後鋼板
を巻取るまでの間に、該鋼板表面のスケールをドライデ
スケーリングまたは高圧水デスケーリングを用いて除去
し、引き続き、亜鉛、アルミニウム、鉛等の単一金属或
いはその合金等の金属粉末を前記鋼板の所要の面に前記
金属粉末の融点よりも30℃以上200℃以下の範囲の
鋼板温度において噴射して該鋼板の所要の面に溶融めっ
き層を形成する事を特徴とする耐食性熱間圧延鋼板の製
造方法。[Claim 1] Mn: 0.10 to 0.60 in weight%
%, S: 0.001 to 0.012%, and other Fe
and 1400°C to 1200°C for steel consisting of unavoidable components.
The slab is cast and solidified at a cooling rate of ≧5.0°C/min, and the slab is finished rolled for 60 minutes from the start of casting.
Start within minutes and finish at Ar3 point or above, and then remove scale on the surface of the steel plate using dry descaling or high-pressure water descaling before winding the steel plate, and then remove zinc, aluminum, lead, etc. A metal powder such as a single metal or an alloy thereof is injected onto a required surface of the steel plate at a steel plate temperature in a range of 30°C or more and 200°C or less than the melting point of the metal powder to melt it on the required surface of the steel plate. A method for producing a corrosion-resistant hot-rolled steel sheet, characterized by forming a plating layer.
%、S:0.001〜0.012%を含み、その他Fe
及び不可避的成分からなる鋼の1400℃〜1200℃
の温度範囲を≧5.0℃/分の冷却速度で鋳造凝固して
鋳片とし、該鋳片の仕上げ圧延を前記鋳造開始から60
分以内に開始してAr3 点以上で終了し、その後鋼板
を巻取るまでの間に、該鋼板表面のスケールをドライデ
スケーリングまたは高圧水デスケーリングを用いて除去
すると供に、表面粗度をRa値で0.5μm以上とし、
引き続き亜鉛、アルミニウム、鉛等の単一金属或いはそ
の合金等の粒度150メッシュ以上の金属粉末を前記鋼
板の所要の面に前記金属粉末の融点よりも30℃以上2
00℃以下の範囲の鋼板温度において噴射して該鋼板の
所要の面に溶融めっき層を形成する事を特徴とする耐食
性熱間圧延鋼板の製造方法。[Claim 2] Mn: 0.10 to 0.60 in weight%
%, S: 0.001 to 0.012%, and other Fe
and 1400°C to 1200°C for steel consisting of unavoidable components.
The slab is cast and solidified at a cooling rate of ≧5.0°C/min, and the slab is finished rolled for 60 minutes from the start of casting.
After starting within minutes and finishing at the Ar3 point or higher, the scale on the surface of the steel plate is removed using dry descaling or high-pressure water descaling, and the surface roughness is reduced to Ra. The value is 0.5 μm or more,
Subsequently, a metal powder such as a single metal such as zinc, aluminum, or lead or an alloy thereof with a particle size of 150 mesh or more is applied to the required surface of the steel plate at a temperature of 30°C or higher than the melting point of the metal powder.
A method for producing a corrosion-resistant hot-rolled steel sheet, which comprises forming a hot-dip coating layer on a desired surface of the steel sheet by spraying at a steel sheet temperature of 00° C. or lower.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8921491A JPH04304353A (en) | 1991-03-29 | 1991-03-29 | Production of corrosion resistant hot rolled steel sheet having excellent r value |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8921491A JPH04304353A (en) | 1991-03-29 | 1991-03-29 | Production of corrosion resistant hot rolled steel sheet having excellent r value |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04304353A true JPH04304353A (en) | 1992-10-27 |
Family
ID=13964472
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8921491A Withdrawn JPH04304353A (en) | 1991-03-29 | 1991-03-29 | Production of corrosion resistant hot rolled steel sheet having excellent r value |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04304353A (en) |
-
1991
- 1991-03-29 JP JP8921491A patent/JPH04304353A/en not_active Withdrawn
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR20150051840A (en) | HOT DIP Zn-Al-Mg ALLOY PLATED STEEL SHEET HAVING EXCELLENT FORMABILITY AND ADHESION PROPERTY AND METHOD FOR MANUFACTURING THE SAME | |
EP4353860A1 (en) | Pre-coated steel plate for hot forming and preparation method therefor, and hot-formed steel member and application thereof | |
CN111549307A (en) | Production process of hot-dip aluminum-plated silicon steel plate | |
KR100342310B1 (en) | Method for manufacturing hot dip galvanized steel sheets with excellent plating adhesion and corrosion resistance | |
JPH03243751A (en) | Production of alloyed galvanized steel sheet | |
JP5070863B2 (en) | Alloyed steel sheet and manufacturing method thereof | |
JPS6056418B2 (en) | Manufacturing method of hot-dip galvanized steel sheet | |
JP2002038248A (en) | Method for manufacturing galvanized steel sheet with high tensile strength and ductility | |
JPH04304353A (en) | Production of corrosion resistant hot rolled steel sheet having excellent r value | |
CN113981324A (en) | Hot-rolled pickled steel plate with thin specification of less than 3.0mm and high-temperature oxidation resistance for hot forming and production method thereof | |
JPH04304352A (en) | Production of corrosion resistant hot rolled steel sheet having excellent r value and deltar value | |
JPH04314847A (en) | Production of hot rolled plate of corrosion resisting steel | |
JPH04304354A (en) | Production of corrosion resistant hot rolled steel sheet excellent in deep drawing property | |
CN114657348B (en) | Production method of low-carbon cold-rolled enamel steel with high anti-scaling performance | |
JPH05117829A (en) | Manufacture of corrosion resistant hot-rolled steel sheet having r (average) value and deltar value | |
CN115354211B (en) | Method for producing corrosion-resistant oxidation-resistant 1500MPa hot-formed steel by using thin strip casting and rolling process | |
JP3749487B2 (en) | Surface-treated steel sheet excellent in workability and corrosion resistance of machined part | |
JPH09316617A (en) | Production of high workability plated steel sheet | |
US11913118B2 (en) | Zinc alloy coated press-hardenable steels and method of manufacturing the same | |
JPH0615303A (en) | Manufacture of corrosion resistant hot-rolled steel sheet having excellent r average value | |
JPH04346626A (en) | Manufacture of corrosion resistant hot rolled steel sheet high in productive efficiency and excellent in deep drawability | |
JPH0413856A (en) | Production of galvannealed steel sheet having superior corrosion resistance | |
TW201809312A (en) | Method for manufacturing hot-dipping galvanized steel material with high strength and high elongation rate for providing an anti-pulling strength higher than 1400 MPa and an average elongation rate greater than 25% | |
JPH0517881A (en) | Manufacture of corrosion resistant hot rolled steel sheet | |
JPH0598461A (en) | Manufacture of corrosion resistant hot rolled steel sheet excellent in deep drawability |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A300 | Application deemed to be withdrawn because no request for examination was validly filed |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 19980514 |