JPH04300616A - Deodorizing filter for air conditioner - Google Patents
Deodorizing filter for air conditionerInfo
- Publication number
- JPH04300616A JPH04300616A JP3091673A JP9167391A JPH04300616A JP H04300616 A JPH04300616 A JP H04300616A JP 3091673 A JP3091673 A JP 3091673A JP 9167391 A JP9167391 A JP 9167391A JP H04300616 A JPH04300616 A JP H04300616A
- Authority
- JP
- Japan
- Prior art keywords
- filter
- activated carbon
- deodorizing
- adhesive
- pressure loss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 48
- 239000000853 adhesive Substances 0.000 claims abstract description 38
- 230000001070 adhesive effect Effects 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 36
- 239000000758 substrate Substances 0.000 claims abstract description 27
- 239000003063 flame retardant Substances 0.000 claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 7
- 150000002367 halogens Chemical class 0.000 claims abstract description 7
- 239000003463 adsorbent Substances 0.000 claims description 24
- 239000012796 inorganic flame retardant Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 86
- 210000004027 cell Anatomy 0.000 description 34
- 238000012360 testing method Methods 0.000 description 22
- 235000019645 odor Nutrition 0.000 description 10
- 239000000123 paper Substances 0.000 description 10
- 239000000417 fungicide Substances 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 7
- 239000000428 dust Substances 0.000 description 6
- 230000000855 fungicidal effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000003429 antifungal agent Substances 0.000 description 4
- 229940121375 antifungal agent Drugs 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 108010085462 tomicide Proteins 0.000 description 2
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- RVHUMFJSCJBNGS-UHFFFAOYSA-N 2-[2,6-dibromo-4-[2-[3,5-dibromo-4-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C(Br)=C(OCCO)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(OCCO)C(Br)=C1 RVHUMFJSCJBNGS-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 206010002653 Anosmia Diseases 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241001465318 Aspergillus terreus Species 0.000 description 1
- 210000004128 D cell Anatomy 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 235000019558 anosmia Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 210000003719 b-lymphocyte Anatomy 0.000 description 1
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Landscapes
- Separation Of Gases By Adsorption (AREA)
- Filtering Materials (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明はエアコンディショナ用脱
臭フィルタに関し、より具体的には圧力損失の低く且つ
防黴性能を備えたこの種フィルタに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorizing filter for air conditioners, and more specifically to a filter of this type that has low pressure loss and anti-mold performance.
【0002】0002
【従来の技術】従来のエアコンディショナには粗目の除
塵フィルタしか装着されていないのが一般的であり、同
フィルタの圧力損失は0.1 −0.2 mmAq(エ
ア流速1m/sec における測定値、以下同じ)程度
であった。これに対して近年たばこの煙り、花粉等のサ
ブミクロン粒子を除去する要望が強くなったことから、
圧力損失2−3mmAq程度の高密度のフィルタがオプ
ショナルに使用されるようになった。しかし上記高密度
のフィルタの使用は、圧力損失が大きいことから、これ
に起因して、風量が低下する、或いは騒音が大きくなる
等の問題が生じた。そこでこの問題に対応する為、電気
集塵機や、エレクトレット繊維(半永久的に分極された
ポリオレフィン系繊維、特公昭56−47299等に開
示される)を用いたフィルタ等の、低圧力損失の除塵機
構が用いられるようになった。[Prior Art] Conventional air conditioners are generally equipped with only a coarse dust removal filter, and the pressure loss of the filter is 0.1 - 0.2 mmAq (measured at an air flow rate of 1 m/sec). (the same applies hereafter). In response to this, in recent years there has been a strong desire to remove submicron particles such as cigarette smoke and pollen.
High-density filters with a pressure loss of about 2-3 mmAq have come to be used as an option. However, the use of the above-mentioned high-density filter causes a large pressure loss, which causes problems such as a decrease in air volume or an increase in noise. To deal with this problem, low pressure loss dust removal mechanisms such as electrostatic precipitators and filters using electret fibers (semi-permanently polarized polyolefin fibers, disclosed in Japanese Patent Publication No. 56-47299, etc.) have been developed. came to be used.
【0003】上記低圧力損失の除塵機構はしかし、本来
的に脱臭を目的とするものではない為、その脱臭能力は
低い。[0003] However, since the above-mentioned low pressure loss dust removal mechanism is not originally intended for deodorization, its deodorization ability is low.
【0004】他方、活性炭が接着されたフィルタは従来
より種々のタイプのものが提案されている。例えば、1
)特公昭59−19727、特開昭53−64675、
実開昭57−119724 等には、微粉状活性炭を抄
紙段階で紙に混抄させ、ハニカム或いは片段ボール積層
状に成形したフィルタが開示される。2)特開昭58−
175560 、特開昭63−88014、実開昭62
−79522等には、繊維状活性炭をハニカム状に成形
したフィルタが開示される。3)特開昭57−4832
5、特開昭59−142843 、特開昭59−227
704 等には、粉末活性炭とバインダとの混合物を押
出して格子状またはハニカム状とし、これを焼成して活
性化したフィルタが開示される。On the other hand, various types of filters to which activated carbon is bonded have been proposed. For example, 1
) Japanese Patent Publication No. 59-19727, Japanese Patent Publication No. 53-64675,
Japanese Utility Model Application Publication No. 57-119724 discloses a filter in which finely powdered activated carbon is mixed with paper at the paper-making stage and formed into a honeycomb or single-layer corrugated cardboard shape. 2) Japanese Patent Application Publication No. 1983-
175560, JP-A-63-88014, JP-A-62
-79522 and the like discloses a filter in which fibrous activated carbon is formed into a honeycomb shape. 3) Japanese Patent Publication No. 57-4832
5, JP-A-59-142843, JP-A-59-227
No. 704, etc., discloses a filter in which a mixture of powdered activated carbon and a binder is extruded into a lattice shape or a honeycomb shape, which is activated by firing.
【0005】[0005]
【発明が解決しようとする課題】上記1のフィルタは、
活性炭の使用量が上げられず、また紙の表面で有効に脱
臭に寄与している活性炭が少なく、脱臭効果が低い。上
記2のフィルタは、繊維状活性炭が高価で大量に使えず
、また繊維状活性炭は吸着速度は高いが脱着も速く、直
ぐにフィルタからに臭気が漏れてくるという欠点がある
。上記3のフィルタは、脱臭効果は高いがフィルタ自体
が高価であり、また成形時に歪みが生じるので広い面積
に使用できない。従って、エアコンディショナに使用す
るのに適当な脱臭フィルタは見出だすことができない。[Problem to be solved by the invention] The above filter 1 is
The amount of activated carbon used cannot be increased, and the amount of activated carbon that effectively contributes to deodorization on the paper surface is small, so the deodorizing effect is low. The above-mentioned filter 2 has the disadvantage that the fibrous activated carbon is expensive and cannot be used in large quantities, and although the fibrous activated carbon has a high adsorption rate, it also desorbs quickly, and odor immediately leaks from the filter. The above filter 3 has a high deodorizing effect, but the filter itself is expensive, and distortion occurs during molding, so it cannot be used over a large area. Therefore, it is not possible to find a deodorizing filter suitable for use in air conditioners.
【0006】本発明はかかる観点に基づいてなされたも
のであり、上記除塵機構と併用若しくは単独で使用でき
、且つ低圧力損失(1.0 mmAq以下、望ましくは
0.5 mmAq以下)で、煙草の臭い等の室内臭気を
脱臭できるエアコンディショナ用の脱臭フィルタを提供
することを目的とする。The present invention has been made based on this viewpoint, and can be used in combination with the above-mentioned dust removal mechanism or alone, and has a low pressure loss (1.0 mmAq or less, preferably 0.5 mmAq or less). To provide a deodorizing filter for an air conditioner that can deodorize indoor odors such as odors.
【0007】また、従来の活性炭を基体に接着する為の
粘着剤には、それ自信の変質を防止する目的の防腐剤し
か使用されていない。従って、これをエアコンディショ
ナ用の脱臭フィルタに利用した場合には、梅雨時期等、
高湿度の季節にエアコンディショナの不使用期間が長く
なると、フィルタに黴が発生する虞がある。フィルタに
黴が発生すると、次に使用した時に、異臭が感じられた
り、胞子が飛散したりする原因となる。またフィルタ交
換時にフィルタ上に黴が顕著に認められることは、外観
上からも好ましくない。[0007] In addition, conventional adhesives for adhering activated carbon to substrates only contain preservatives for the purpose of preventing deterioration of the adhesive itself. Therefore, when this is used as a deodorizing filter for air conditioners, it can be used during the rainy season, etc.
If the air conditioner is not used for a long time during the high humidity season, there is a risk of mold forming on the filter. If mold grows on the filter, it may cause an unpleasant odor or scattering of spores the next time it is used. Furthermore, it is not desirable from the appearance point of view that mold is noticeably observed on the filter when the filter is replaced.
【0008】更にまた、上記粘着剤としては、アクリル
系等の可燃性高分子ポリマーが用いられている。しかし
、家電製品は、より安全性を確保する為に、使用部品を
可能な限り難燃化する必要が生じており、その規制も年
々厳しくなっている。Furthermore, flammable polymers such as acrylic are used as the adhesive. However, in order to ensure greater safety in home appliances, it has become necessary to make the parts used in them as flame-retardant as possible, and regulations are becoming stricter year by year.
【0009】従って本発明はまた、この種フィルタにお
いて発黴の防止、難燃性の向上を達成することを目的と
する。[0009] Accordingly, another object of the present invention is to prevent mold generation and improve flame retardancy in this type of filter.
【0010】0010
【課題を解決するための手段】上記目的を達成する為、
本発明にあっては、格子状のフィルタ基体と、粘着剤に
よりフィルタ基体に接着されたガス吸着剤粒子とからな
るエアコンディショナ用脱臭フィルタであって、上記粘
着剤に難燃剤が添加されていることを特徴とする。[Means for solving the problem] In order to achieve the above purpose,
The present invention provides a deodorizing filter for air conditioners comprising a lattice-shaped filter base and gas adsorbent particles adhered to the filter base with an adhesive, wherein a flame retardant is added to the adhesive. It is characterized by the presence of
【0011】望ましい態様において、上記難燃剤がハロ
ゲン系難燃剤と無機系難燃剤とを含む。また、上記粘着
剤に防黴剤が添加されている。In a desirable embodiment, the flame retardant includes a halogen flame retardant and an inorganic flame retardant. Furthermore, an antifungal agent is added to the above adhesive.
【0012】0012
【作用】上記構成により本発明に係る脱臭フィルタによ
れば、上記エア流速条件において1.0 mmAq以下
の圧力損失を達成することが可能となる。また本脱臭フ
ィルタの脱臭効果は脱臭フィルタとしての一般的条件に
適うものとなり、脱臭効果の継続性はエアコンディショ
ナに対して使用されるフィルタとしての条件に適うもの
となる。
しかも、フィルタの発黴の防止、難燃性の向上が達成さ
れる。[Function] According to the deodorizing filter according to the present invention having the above structure, it is possible to achieve a pressure loss of 1.0 mmAq or less under the above air flow rate conditions. Further, the deodorizing effect of the present deodorizing filter meets the general conditions for a deodorizing filter, and the continuity of the deodorizing effect meets the conditions for a filter used in an air conditioner. Moreover, prevention of mold generation and improvement of flame retardancy of the filter can be achieved.
【0013】[0013]
【実施例】[構造及び材質]図1は本発明に係る脱臭フ
ィルタ10の一実施例を示す平面図である。このフィル
タは、格子状のフィルタ基体12と、フィルタ基体12
に接着されたガス吸着剤粒子14とからなる。Embodiment [Structure and Materials] FIG. 1 is a plan view showing an embodiment of a deodorizing filter 10 according to the present invention. This filter includes a grid-like filter base 12 and a filter base 12.
and gas adsorbent particles 14 adhered to the gas adsorbent particles 14.
【0014】本発明に係る脱臭フィルタ10は開口率(
図1の紙面に対して平行な平面における)が約50−約
80%で、この値は後述する種々の条件に従う結果とし
て得られる。またフィルタ10の厚さ(図1の紙面に対
して垂直な方向)は15mm以下で望ましくは約3mm
以上となっている。本フィルタ10は、図1図示の如く
ガス吸着剤粒子14の寸法が比較的大きく、またフィル
タ10の厚さが小さい点で、従来のフィルタと異なる。
これらの特徴は、エアコンディショナ用の脱臭フィルタ
として、低圧力損失、適当な脱臭能力、長寿命等の条件
を満たす為の鍵となる。The deodorizing filter 10 according to the present invention has an aperture ratio (
(in a plane parallel to the plane of the paper of FIG. 1) is about 50% to about 80%, and this value is obtained as a result of complying with various conditions described below. The thickness of the filter 10 (in the direction perpendicular to the plane of the paper in FIG. 1) is 15 mm or less, preferably about 3 mm.
That's all. The present filter 10 differs from conventional filters in that the size of the gas adsorbent particles 14 is relatively large and the thickness of the filter 10 is small, as shown in FIG. These characteristics are the key to satisfying the requirements of low pressure loss, appropriate deodorizing ability, and long life as a deodorizing filter for air conditioners.
【0015】基体12は、紙、アルミ、プラスチック等
の薄肉の材料からなる。紙を材料として用いる場合は、
フェノール樹脂等を含浸させて強度を補強することもで
きる。また基体12には不燃化処理を施すこともできる
。基体12の厚さは実質的に本フィルタ10の厚さとな
るから、約15mm以下で望ましくは3mm以上となる
。この厚さは、本フィルタ10が最終的に図2図示の如
くエアコンディショナの筐体内に収納されることから決
定される。The base 12 is made of a thin material such as paper, aluminum, or plastic. When using paper as a material,
The strength can also be reinforced by impregnating it with phenol resin or the like. Further, the base body 12 can also be subjected to a non-combustible treatment. The thickness of the base 12 is substantially the same as that of the present filter 10, and is therefore approximately 15 mm or less, preferably 3 mm or more. This thickness is determined because the present filter 10 will eventually be housed in the casing of the air conditioner as shown in FIG.
【0016】図示実施例において、基体12の格子のパ
ターン形状は6角形のいわゆるハニカム状となっている
が、このパターン形状は、例えば矩形、3角形等いかな
る形状とすることもできる。但し、格子の1つのセル1
6の平面積(図1の紙面に対して平行な平面における)
は約0.20−約0.35cm2 となる。この数値は
、ガス吸着剤粒子14を支持する為の区画壁18の密度
を実質的に意味することとなる。この数値の選択理由は
後述する。In the illustrated embodiment, the pattern shape of the lattice on the base body 12 is a hexagonal so-called honeycomb shape, but the pattern shape can be any shape such as a rectangle or a triangle. However, one cell 1 of the grid
6 (in a plane parallel to the plane of the paper in Figure 1)
is approximately 0.20 to approximately 0.35 cm2. This value essentially means the density of the partition wall 18 for supporting the gas adsorbent particles 14. The reason for selecting this value will be described later.
【0017】ガス吸着剤粒子14は活性炭からなるが、
添着活性炭等他のタイプのものを使用することも可能で
ある。また石油ストーブ等室内のCO発生源に対処する
為、COを接触酸化処理できる触媒を脱臭剤と併用する
ことができる。この触媒としては、水分があっても死活
しない金/酸化物触媒(特開昭60−238148 等
で開示される)が望ましい。The gas adsorbent particles 14 are made of activated carbon,
It is also possible to use other types such as impregnated activated carbon. Further, in order to deal with indoor CO generation sources such as oil stoves, a catalyst capable of catalytically oxidizing CO can be used in combination with a deodorizer. As this catalyst, a gold/oxide catalyst (disclosed in JP-A No. 60-238148, etc.) which does not become inactive even in the presence of moisture is desirable.
【0018】ガス吸着剤粒子14の寸法は約20−約6
0メッシュ、基体12の平面単位面積当りのガス吸着剤
粒子14の使用量は約400 −約2000g/m2
である。この数値の選択理由は後述する。The size of the gas adsorbent particles 14 is from about 20 to about 6
0 mesh, the amount of gas adsorbent particles 14 used per plane unit area of the base 12 is about 400 to about 2000 g/m2
It is. The reason for selecting this value will be described later.
【0019】ガス吸着剤粒子14を基体12に接着する
為のバインダは、粒子の脱落を防止する為に粘着剤が使
用されることが望ましい。上記バインダは、フィルタ製
造時に、ブランク基体に供された後に乾燥され、粘性が
高められる。上記乾燥作業により溶媒の匂いが飛び、活
性炭が溶媒の匂いを吸着しなくなる。As the binder for adhering the gas adsorbent particles 14 to the substrate 12, an adhesive is preferably used to prevent the particles from falling off. The binder is applied to the blank substrate during filter manufacture and then dried to increase its viscosity. The drying process removes the odor of the solvent, and the activated carbon no longer adsorbs the odor of the solvent.
【0020】望ましくは、本フィルタ10は、ガス吸着
剤粒子14の粒径よりも目の細かな不織布、紙等で形成
された通気性カバー(図示せず)により覆って使用する
ようにする。この通気性カバーにはまた不燃化処理、防
黴、防菌処理を施すことが望ましい。
[使用態様]図2は本フィルタ10をエアコンディショ
ナの室内機30の筐体32内に組込んだ状態を示す側面
図である。図中矢印はエアの流れ方向を示す。本フィル
タ10は、通常用いられている除塵フィルタ34に続い
て、エアの導入通路に配設される。本フィルタ10を通
過して脱臭されたエアは、熱交換器36で加熱若しくは
冷却され、送風機40の作用により室内に供給される。
本フィルタ10はまた、エアの導入通路の代わりに、熱
交換器36後のエアの排出通路に配設することも可能で
ある。なお図中符号38は露受け皿である。
[製造方法]図3は本フィルタ10の製造工程の一例を
示す図である。先ず基体供給機52から所定の厚さのブ
ランク基体が供給され、バインダ浸漬部54において、
粘着剤が全体に塗布される。次にブランク基体は10分
間程度乾燥機56に掛けられ、バインダに所定の粘性が
付与されると共に、バインダの溶剤の匂いが飛ばされる
。乾燥後、ブランク基体は吸着剤添着部62に送込まれ
る。Preferably, the present filter 10 is used while being covered with a breathable cover (not shown) made of nonwoven fabric, paper, or the like whose mesh is finer than that of the gas adsorbent particles 14. This breathable cover is also desirably treated to be nonflammable, mildewproof, and antibacterial. [Usage Mode] FIG. 2 is a side view showing the present filter 10 installed in a casing 32 of an indoor unit 30 of an air conditioner. Arrows in the figure indicate the direction of air flow. The present filter 10 is disposed in the air introduction passage following the normally used dust removal filter 34. The deodorized air that has passed through the filter 10 is heated or cooled by a heat exchanger 36, and then supplied into the room by the blower 40. The present filter 10 can also be disposed in the air discharge passage after the heat exchanger 36 instead of in the air introduction passage. Note that the reference numeral 38 in the figure is a dew pan. [Manufacturing Method] FIG. 3 is a diagram showing an example of the manufacturing process of the present filter 10. First, a blank substrate of a predetermined thickness is supplied from the substrate supplying machine 52, and in the binder dipping section 54,
Adhesive is applied all over. Next, the blank substrate is placed in a dryer 56 for about 10 minutes to impart a predetermined viscosity to the binder and to remove the odor of the binder's solvent. After drying, the blank substrate is sent to the adsorbent application section 62.
【0021】他方、吸着剤添着部62に対しては、吸着
剤供給機58から所定サイズの吸着剤が供給され、ブラ
ンク基体表面にバインダを介して接着される。次に、基
体や吸着剤に不完全に付着している余分な吸着剤は払落
とし部64で除去される。そして上記吸着剤が十分に基
体に接着した後、切断機66により1次製品の基体が所
望の寸法に切断され、最終製品フィルタ10が完成とな
る。またその後必要に応じ、包装部68でフィルタ10
の両面或いは片面に通気性カバーを積層させてもよい。
[本脱臭フィルタの脱臭機能試験の方法]脱臭フィルタ
の圧力損失の測定は、内寸10×10cm、長さ220
cm の角形透明アクリル製風胴を用い、この中央部に
脱臭フィルタを装着して行った。フィルタの通過風速は
1.0 m/sec とし、フィルタ前後の静圧差を測
定した。On the other hand, an adsorbent of a predetermined size is supplied to the adsorbent adhering section 62 from an adsorbent supplying device 58, and is adhered to the surface of the blank substrate via a binder. Next, excess adsorbent that is incompletely attached to the substrate or adsorbent is removed by a scraping section 64. After the adsorbent has sufficiently adhered to the substrate, the substrate of the primary product is cut into desired dimensions by the cutting machine 66, and the final product filter 10 is completed. Thereafter, if necessary, the filter 10 is
A breathable cover may be laminated on both sides or one side. [Method for testing the deodorizing function of this deodorizing filter] The pressure loss of the deodorizing filter was measured using a filter with inner dimensions of 10 x 10 cm and length of 220 cm.
A rectangular transparent acrylic wind cylinder measuring 1.5 cm was used, and a deodorizing filter was attached to the center of the cylinder. The air velocity passing through the filter was 1.0 m/sec, and the static pressure difference before and after the filter was measured.
【0022】また脱臭効果を確認する為の官能試験に関
しては次の通りである。先ず容積が17m3 のステン
レス鋼製チャンバ内において、2本の市販の煙草を自然
燃焼させた。15分後にチャンバ内の扇風機を作動させ
、内部を均一な状態にした後、市販の空気清浄機のフィ
ルタ装着部に本脱臭フィルタを取付けて運転を行った。
フィルタの開口部は0.065 m2 、処理風量は3
.9 m3 /min である。空気清浄機運転開始3
0分後に、チャンバ内の空気を無臭の10リットル容量
プラスチックバッグに捕集し、官能試験に供した。官能
試験は予め嗅覚異常者を除外した15名により行われた
。The sensory test for confirming the deodorizing effect is as follows. First, two commercially available cigarettes were spontaneously combusted in a stainless steel chamber with a volume of 17 m3. After 15 minutes, the electric fan in the chamber was activated to make the interior uniform, and then the present deodorizing filter was attached to the filter attachment part of a commercially available air cleaner and the chamber was operated. Filter opening is 0.065 m2, processing air volume is 3
.. 9 m3/min. Air purifier operation start 3
After 0 minutes, the air in the chamber was collected in an odorless 10 liter plastic bag and subjected to a sensory test. The sensory test was conducted by 15 people, excluding those with anosmia in advance.
【0023】またCO濃度の低減効果に関しては次の通
りである。先ず上記官能試験と同一のチャンバ内を、C
O濃度が100 ppm となるように調整した。次に
上記官能試験と同一の空気清浄機及び条件下において本
脱臭フィルタを使用し、CO濃度の減衰を測定した。使
用測定器は、ガステック製CM2510である。
[本脱臭フィルタの条件の検討]基体12の格子のセル
サイズ、ガス吸着剤粒子14の寸法及びその使用量等の
条件は以下の通りに検討した。
a.格子のセルサイズ
図5は格子のセルサイズの変化に基づく活性炭担持量と
圧力損失との関係を示すグラフである。実験に使用され
たフィルタは図3図示の本発明に係る工程により製造さ
れた。基体12は全て図4に示すようなハニカム状の格
子構造をなし、厚さは5mmである。格子のセルサイズ
という用語はここでは図4中の「l」を指示する。また
ガス吸着剤として活性炭が使用された。The effect of reducing CO concentration is as follows. First, inside the same chamber as the above sensory test, C
The O concentration was adjusted to 100 ppm. Next, this deodorizing filter was used under the same air purifier and conditions as in the above sensory test, and the attenuation of the CO concentration was measured. The measuring instrument used is CM2510 manufactured by Gastec. [Study of conditions for the present deodorizing filter] Conditions such as the cell size of the lattice of the substrate 12, the dimensions of the gas adsorbent particles 14, and the amount used thereof were studied as follows. a. Cell size of the lattice FIG. 5 is a graph showing the relationship between the amount of supported activated carbon and the pressure loss based on the change in the cell size of the lattice. The filter used in the experiment was manufactured by the process according to the present invention shown in FIG. The base body 12 has a honeycomb-like lattice structure as shown in FIG. 4, and has a thickness of 5 mm. The term grid cell size refers here to "l" in FIG. Activated carbon was also used as a gas adsorbent.
【0024】図5のグラフ中、曲線aは活性炭粒子寸法
が32−60メッシュのフィルタ、曲線bは活性炭粒子
寸法が20−42メッシュのフィルタに関する結果を示
す。また直線Dは圧力損失一次限界(0.5 mmAq
)線、直線Lは圧力損失の二次限界線(1.0 mmA
q)を示す。In the graph of FIG. 5, curve a shows the results for a filter with an activated carbon particle size of 32-60 mesh, and curve b shows the results for a filter with an activated carbon particle size of 20-42 mesh. In addition, the straight line D is the primary limit of pressure loss (0.5 mmAq
) line, straight line L is the secondary limit line of pressure loss (1.0 mmA
q) is shown.
【0025】図5のグラフ中、各プロット記号が指示す
るところは下記の通りである。In the graph of FIG. 5, each plot symbol indicates the following.
【0026】
「×」…セルサイズ3/8 in(セル平面積約0.8
cm2 )「△」…セルサイズ1/4 in(セル平
面積約0.35cm2 )「○」…セルサイズ3/16
in (セル平面積約0.2 cm2)「□」…セル
サイズ1/8 in(セル平面積約0.09cm2 )
同図から分かるように、「□」で示されるセルサイズ1
/8 inの基板では、圧力損失が二次限界線Lをも越
えてしまう。他方「×」で示されるセルサイズ3/8
inの基板では、十分な活性炭担持量が得られない。従
って、基板格子のセルサイズは約1/4 −約3/16
inの範囲が適当となる。前述の如く格子の形状はハニ
カム状に限定される必要はない為、上記サイズをセル平
面積で表すと、この範囲は約0.2−約0.35cm2
となる。
b.ガス吸着剤の粒子寸法と使用量
図6は活性炭の粒子寸法の変化に基づく活性炭担持量と
圧力損失との関係を示すグラフである。実験に使用され
たフィルタは図3図示の本発明に係る工程により製造さ
れた。基体12は全て図4に示すようなハニカム状の格
子構造をなす。"×"...Cell size 3/8 inch (cell planar area approximately 0.8 inch)
cm2) "△"...Cell size 1/4 in (cell plane area approximately 0.35cm2) "○"...Cell size 3/16
in (Cell flat area approximately 0.2 cm2) "□"...Cell size 1/8 in (Cell flat area approximately 0.09 cm2)
As can be seen from the figure, cell size 1 indicated by “□”
/8 inch substrate, the pressure loss even exceeds the secondary limit line L. On the other hand, cell size 3/8 indicated by “×”
In the case of an in-type substrate, a sufficient amount of activated carbon cannot be supported. Therefore, the cell size of the substrate grid is about 1/4 - about 3/16
A range of in is appropriate. As mentioned above, the shape of the lattice does not need to be limited to a honeycomb shape, so if the above size is expressed in terms of cell planar area, this range is about 0.2 to about 0.35 cm2.
becomes. b. Particle Size and Usage Amount of Gas Adsorbent FIG. 6 is a graph showing the relationship between the amount of supported activated carbon and pressure loss based on changes in the particle size of activated carbon. The filter used in the experiment was manufactured by the process according to the present invention shown in FIG. The entire base body 12 has a honeycomb-like lattice structure as shown in FIG.
【0027】図6のグラフ中、曲線cはセルサイズ3/
16in(セル平面積約0.2 cm2 )で厚さ5m
mの基板のフィルタ、曲線dはセルサイズ1/4 in
(セル平面積約0.35cm2 )で厚さ5mmの基板
のフィルタ、曲線eはセルサイズ3/16 in (セ
ル平面積約 0.2cm2 )で厚さ10mmの基板
のフィルタ、曲線fはセルサイズ1/4 in(セル平
面積約0.35cm2 )で厚さ10mmの基板のフィ
ルタに関する結果を示す。また直線Dは圧力損失一次限
界(0.5 mmAq)線、直線Lは圧力損失の二次限
界線(1.0 mmAq)を示す。In the graph of FIG. 6, curve c indicates cell size 3/
16 inches (cell plane area approximately 0.2 cm2) and thickness 5 m
m substrate filter, curve d is cell size 1/4 in
(Cell plane area is about 0.35 cm2) and 5 mm thick substrate. Curve e is a filter with cell size 3/16 inch (cell plane area about 0.2 cm2) and 10 mm thick substrate. Curve f is cell size. The results are shown for a filter with a substrate of 1/4 inch (cell plane area approximately 0.35 cm2) and 10 mm thick. Further, the straight line D shows the first pressure loss limit line (0.5 mmAq), and the straight line L shows the second pressure loss limit line (1.0 mmAq).
【0028】図6のグラフ中、各プロット記号が指示す
るところは下記の通りである。In the graph of FIG. 6, each plot symbol indicates the following.
【0029】「×」…粒子寸法 60 −100 メッ
シュ「△」…粒子寸法 32 − 60 メッシュ「○
」…粒子寸法 20 − 42 メッシュ「□」…粒子
寸法 6 − 10 メッシュ同図から分かるように
、「□」で示される6−10メッシュの活性炭では、圧
力損失が二次限界線Lをも遥かに越えてしまう。他方「
×」で示される 60 −100メッシュの活性炭では
、十分な活性炭担持量が得られない。従って、活性炭の
粒子寸法は約20−60メッシュの範囲が適当となる。"×"...Particle size 60-100 mesh "△"...Particle size 32-60 mesh "○
”…Particle size 20-42 mesh “□”…Particle size 6-10 mesh As can be seen from the same figure, in activated carbon of 6-10 mesh indicated by “□”, the pressure loss is far beyond the secondary limit line L. It exceeds. On the other hand, “
Activated carbon of 60 to 100 mesh indicated by "x" does not support a sufficient amount of activated carbon. Therefore, the particle size of the activated carbon is suitably in the range of about 20-60 mesh.
【0030】また図6は、基板の全面に活性炭が接着さ
れた状態における、各条件での基体平面単位面積当りの
活性炭の担持量(即ち使用量)が示される。この使用量
の範囲を、フィルタの厚さ15mmまで考慮した場合、
上記活性炭の粒子寸法の範囲における使用量は約200
0g/m2 以下と考えられる。また同使用量は、脱臭
効果を考慮した場合、少なくとも約400 g/m2
必要となる。この値は約3mmの厚さの基板における使
用量に対応する。Further, FIG. 6 shows the amount of activated carbon supported (ie, the amount used) per unit area of the substrate plane under various conditions in a state where activated carbon is adhered to the entire surface of the substrate. When considering this usage range up to a filter thickness of 15 mm,
The amount of activated carbon used within the particle size range is approximately 200.
It is considered to be less than 0g/m2. In addition, the amount used is at least about 400 g/m2 when taking into account the deodorizing effect.
It becomes necessary. This value corresponds to the usage on a substrate of approximately 3 mm thickness.
【0031】また図6から、上記本発明に係る活性炭の
粒子寸法の範囲において、基板の厚さの変化により圧力
損失は大きな影響を受けないことが分かる。Furthermore, from FIG. 6, it can be seen that within the particle size range of the activated carbon according to the present invention described above, the pressure loss is not significantly affected by changes in the thickness of the substrate.
【0032】活性炭の寸法とセルサイズとの関係による
脱臭フィルタの機能評価は図7に示される通りである。
同図中斜線で示される部分が本発明に係るフィルタの条
件範囲となる。
[例及び脱臭機能試験結果]空気清浄機を設置しなかっ
た場合と、本発明の条件範囲内のフィルタA、B、C、
D、Eを取付けた空気清浄機を用いた場合とについて、
脱臭効果の比較を前記官能試験により行った結果を第2
表に示す。同表中の数値は、6段階臭気強度法(第1表
参照)に基づく。下記比較結果から、1%の危険率で有
意差が認められ、本発明に係るフィルタA−Eの脱臭に
対する有効性が証明された。The functional evaluation of the deodorizing filter based on the relationship between the dimensions of the activated carbon and the cell size is as shown in FIG. The shaded area in the figure is the condition range of the filter according to the present invention. [Example and deodorizing function test results] Case where no air purifier was installed and filters A, B, C, within the condition range of the present invention,
Regarding the case of using an air purifier with D and E installed,
The results of the sensory test to compare the deodorizing effect are shown in the second
Shown in the table. The numerical values in the same table are based on the 6-stage odor intensity method (see Table 1). From the comparison results below, a significant difference was recognized at a risk rate of 1%, proving the effectiveness of filters A-E according to the present invention in deodorizing.
【0033】またフィルタEについては、上記CO濃度
低減試験も合わせて行われた。その結果、図8に示され
るように、フィルタEのCO濃度低減に対する有効性が
証明された。図8中、曲線hはフィルタEを取付けた場
合、曲線iはフィルタを取付けなかった場合の結果を示
す。[0033] Regarding Filter E, the above-mentioned CO concentration reduction test was also conducted. As a result, as shown in FIG. 8, the effectiveness of Filter E in reducing CO concentration was proven. In FIG. 8, curve h shows the result when filter E was installed, and curve i shows the result when filter was not installed.
【0034】使用したフィルタの製造条件は次の通りで
ある。
a.フィルタA、B
セルサイズ3/16in(セル平面積約0.2 cm2
)、厚さ5mmの紙製ハニカムコアを手で展張後、市
販のエマルジョン系粘着剤(綜研化学製SKダインE−
3008B)の槽中に入れて粘着剤を塗布した。乾燥機
に入れて100 ℃で2時間かけて乾燥し、重量を測定
したところ、粘着剤の塗布量は1300g/m2 であ
った。これに市販の活性炭(クラレケミカル製GG)の
、2種類の粒度(20−42メッシュ、32−60メッ
シュ)のものを添着させた。粒度20−42メッシュの
活性炭を添着したものをフィルタA、粒度32−60メ
ッシュの活性炭を添着したものをフィルタBとした。フ
ィルタA、Bの活性炭使用量は夫々790 、600
g/m2 、圧力損失は夫々0.43、0.23mmA
qであった。
b.フィルタC、D
セルサイズ1/4in (セル平面積約0.35cm2
)、厚さ10mmの展張済みのアルミニウム製ハニカ
ムコアを、市販の溶剤系粘着剤(綜研化学製SKダイン
E−1200)の槽中に入れて粘着剤を塗布した。乾燥
機に入れて120 ℃で3時間かけて乾燥し、重量を測
定したところ、粘着剤の塗布量は500 g/m2 で
あった。これに市販の活性炭(クラレケミカル製GG)
の、2種類の粒度(20−42メッシュ、32−60メ
ッシュ)のものを添着させた。粒度20−42メッシュ
の活性炭を添着したものをフィルタC、粒度32−60
メッシュの活性炭を添着したものをフィルタDとした。
フィルタC、Dの活性炭使用量は夫々1300、100
0g/m2 、圧力損失は夫々0.32、0.13mm
Aqであった。
c.フィルタE
セルサイズ3/16in(セル平面積約0.2 cm2
)、厚さ10mmの展張済みのアルミニウム製ハニカ
ムコアを、市販の溶剤系粘着剤(綜研化学製SKダイン
E−1200)の槽中に入れて粘着剤を塗布した。乾燥
機に入れて100 ℃で2時間かけて乾燥し、重量を測
定したところ、粘着剤の塗布量は600 g/m2 で
あった。これに夫々粒度20−42メッシュの市販の活
性炭(クラレケミカル製GG)と、金/酸化物触媒(東
洋CCI製)とを体積比で8:2の割合で添着させた。
活性炭の使用量は約1200g/m2 、圧力損失は0
.59mmAqであった。The manufacturing conditions of the filter used are as follows. a. Filters A and B cell size 3/16 inch (cell planar area approximately 0.2 cm2
), after manually spreading a paper honeycomb core with a thickness of 5 mm, using a commercially available emulsion adhesive (SK Dyne E-
3008B) and coated with adhesive. It was placed in a dryer and dried at 100° C. for 2 hours, and the weight was measured, and the amount of adhesive applied was 1300 g/m 2 . Two types of particle sizes (20-42 mesh and 32-60 mesh) of commercially available activated carbon (GG manufactured by Kuraray Chemical Co., Ltd.) were attached to this. Filter A was impregnated with activated carbon having a particle size of 20-42 mesh, and Filter B was impregnated with activated carbon having a particle size of 32-60 mesh. The amount of activated carbon used in filters A and B is 790 and 600, respectively.
g/m2, pressure loss is 0.43 and 0.23 mmA, respectively.
It was q. b. Filter C, D Cell size 1/4 inch (Cell plane area approximately 0.35 cm2
), a stretched aluminum honeycomb core with a thickness of 10 mm was placed in a bath of a commercially available solvent-based adhesive (SK Dyne E-1200 manufactured by Soken Chemical Co., Ltd.), and the adhesive was applied. It was placed in a dryer and dried at 120° C. for 3 hours, and the weight was measured, and the amount of adhesive applied was 500 g/m 2 . Commercially available activated carbon (GG manufactured by Kuraray Chemical)
Two types of particle sizes (20-42 mesh and 32-60 mesh) were attached. Filter C is impregnated with activated carbon of particle size 20-42 mesh, particle size 32-60.
Filter D was prepared by impregnating a mesh of activated carbon. The amount of activated carbon used in filters C and D is 1300 and 100, respectively.
0g/m2, pressure loss is 0.32 and 0.13mm respectively
It was Aq. c. Filter E Cell size 3/16 inch (Cell plane area approximately 0.2 cm2
), a stretched aluminum honeycomb core with a thickness of 10 mm was placed in a bath of a commercially available solvent-based adhesive (SK Dyne E-1200 manufactured by Soken Chemical Co., Ltd.), and the adhesive was applied. It was placed in a dryer and dried at 100° C. for 2 hours, and the weight was measured, and the amount of adhesive applied was 600 g/m 2 . Commercially available activated carbon (GG manufactured by Kuraray Chemical) and gold/oxide catalyst (manufactured by Toyo CCI) each having a particle size of 20-42 mesh were impregnated thereon at a volume ratio of 8:2. The amount of activated carbon used is approximately 1200g/m2, and the pressure loss is 0.
.. It was 59 mmAq.
【0035】[0035]
【表1】[Table 1]
【0036】[0036]
【表2】
表2に示すように、フィルタA〜Eにおいて、明らかな
臭気強度の低下が認められた。
[防黴性]下記の変更事項以外は、前記フィルタAと同
一条件で、フィルタF〜Iを形成し、フィルタの防黴性
について検討した。
a.フィルタF
粘着剤に、市販の溶媒溶解型防黴剤(北興産業製E50
A、主成分チアベンダゾール、溶媒DMSO)を粘着剤
に対する主成分の重量比で約0.4 %、及び、市販の
水溶解型防黴剤(北興産業製L100N、主成分不明)
を粘着剤に対する主成分の重量比で約0.2 %添加し
た。
b.フィルタG
粘着剤に、市販の水分散型防黴剤(吉富製薬製トミサイ
ドZ−50、主成分チンクピリチオン)を粘着剤に対す
る主成分の重量比で約0.15%、及び、市販の水溶解
型防黴剤(北興産業製L100N、主成分不明)を粘着
剤に対する主成分の重量比で約0.2 %添加した。
c.フィルタH
粘着剤に、市販の水分散型防黴剤(吉富製薬製トミサイ
ドZ−50、主成分チンクピリチオン)を粘着剤に対す
る主成分の重量比で約0.15%添加した。
d.フィルタI
粘着剤に、市販の水溶解型防黴剤(北興産業製L100
N、主成分不明)を粘着剤に対する主成分の重量比で約
0.2 %添加した。
[フィルタF、Gの脱臭性能の比較試験]フィルタF、
Gについて、「本脱臭フィルタの脱臭機能試験の方法」
の項で述べた方法に従って、脱臭性能の比較試験を行っ
た。試験結果を、前述の空気清浄機がない場合、及びフ
ィルタAの試験結果と共に表3に示す。[Table 2] As shown in Table 2, a clear decrease in odor intensity was observed in Filters A to E. [Mold Resistance] Filters F to I were formed under the same conditions as Filter A except for the following changes, and the mold resistance of the filters was examined. a. Filter F Add a commercially available solvent-soluble fungicide (Hokuko Sangyo E50) to the adhesive.
A, main component thiabendazole, solvent DMSO) at a weight ratio of the main component to the adhesive of about 0.4%, and a commercially available water-soluble fungicide (L100N manufactured by Hokuko Sangyo, main component unknown)
was added in an amount of about 0.2% by weight of the main component to the adhesive. b. Filter G Add a commercially available water-dispersible fungicide (Tomicide Z-50, manufactured by Yoshitomi Pharmaceutical Co., Ltd., main component: tinkupyrithione) to the adhesive at a weight ratio of approximately 0.15% of the main component to the adhesive, and add a commercially available water-dispersible fungicide to the adhesive. A mold-proofing agent (L100N manufactured by Hokuko Sangyo, main component unknown) was added in an amount of about 0.2% by weight of the main component to the adhesive. c. Filter H A commercially available water-dispersible antifungal agent (Tomicide Z-50 manufactured by Yoshitomi Pharmaceutical Co., Ltd., main component: tinkupyrithione) was added to the adhesive in an amount of about 0.15% by weight of the main component to the adhesive. d. Filter I Add a commercially available water-soluble fungicide (L100 manufactured by Hokuko Sangyo Co., Ltd.) to the adhesive.
N, main component unknown) was added in an amount of about 0.2% by weight of the main component to the adhesive. [Comparative test of deodorizing performance of filters F and G] Filter F,
Regarding G, "Method for testing the deodorizing function of this deodorizing filter"
A comparative test of deodorizing performance was conducted according to the method described in section. The test results are shown in Table 3 together with the test results for the case without the air cleaner described above and for Filter A.
【0037】[0037]
【表3】
表3に示すように、溶媒溶解型防黴剤を使用したフィル
タFでは、脱臭機能の低下が認められ、これは製造過程
において、有機溶剤の臭気を活性炭が吸収する為と考え
られる。これに対して、水分散型防黴剤を使用したフィ
ルタGでは、防黴剤を添加していないフィルタAとほぼ
同等の優れた脱臭性能が得られた。即ち、溶媒溶解型防
黴剤は、本発明が対象としている脱臭フィルタに適用す
るのに不向きで、水分散型及び水溶解型の防黴剤の使用
が適当であることが判明した。
[発黴試験]フィルタA(防腐剤が粘着剤原液に対して
0.2 %添加された市販の粘着剤をそのまま使用)、
並びに上述の如く防黴処理したフィルタG、H、Iにつ
いて、発黴試験を行った。[Table 3] As shown in Table 3, a decrease in the deodorizing function was observed in Filter F using a solvent-soluble fungicide, and this is thought to be due to the activated carbon absorbing the odor of the organic solvent during the manufacturing process. It will be done. On the other hand, in Filter G using a water-dispersed antifungal agent, excellent deodorizing performance almost equivalent to that of Filter A to which no antifungal agent was added was obtained. That is, it has been found that solvent-soluble fungicides are unsuitable for application to the deodorizing filter targeted by the present invention, and that water-dispersed and water-soluble fungicides are suitable for use. [Mold generation test] Filter A (using a commercially available adhesive with 0.2% preservative added to the adhesive stock solution),
In addition, a mold generation test was conducted on filters G, H, and I that had been subjected to the anti-mildew treatment as described above.
【0038】発黴試験はIEC規格68−2−10 に
準じる。
使用菌株は「Aspergillus niger 」
及び「Aspergillus terreus 」の
2種類とした。接種胞子数は約107 個/mlとし、
3cm各に切断した脱臭フィルタに2mlの胞子液をか
け、蓋付シャーレ中、30℃、90%RHの条件で28
日間培養して発黴性を観察した。発黴の基準を表4に示
す。なお、栄養源は添加しなかった。また試験結果を表
5に示す。[0038] The mold generation test conforms to IEC standard 68-2-10. The strain used is "Aspergillus niger"
and “Aspergillus terreus”. The number of inoculated spores was approximately 107/ml.
Pour 2 ml of spore solution onto a deodorizing filter cut into 3 cm pieces, and place in a petri dish with a lid at 30°C and 90% RH for 28 hours.
The cells were cultured for several days and their fungal potential was observed. Table 4 shows the criteria for mold generation. Note that no nutrient source was added. The test results are also shown in Table 5.
【0039】[0039]
【表4】[Table 4]
【0040】[0040]
【表5】
表5に示すように、水分散型防黴剤のみを使用したフィ
ルタH、水溶解型防黴剤のみを使用したフィルタIの夫
々の防黴機能は、フィルタAに比べて幾分優れている。
しかし、特に、両防黴剤を併用したフィルタGの防黴機
能は、フィルタH、Iに比べて遥かに優れることが判明
した。なおここで、水分散型防黴剤は粘着剤の防黴化に
、水溶解型防黴剤は基体である紙の防黴化に夫々寄与し
ていると推察される。
[難燃性]下記の変更事項以外は、前記フィルタAと同
一条件で、フィルタJを形成し、フィルタの難燃性につ
いて検討した。
a.フィルタJ
粘着剤(市販品の状態では固形分50%)に、その固形
分に対して、ハロゲン系難燃剤(主成分不明)を重量比
で30%と、同量の無機系難燃剤(主成分三酸化アンチ
モン)とを添加した。[Table 5] As shown in Table 5, the anti-mold function of Filter H, which uses only a water-dispersed anti-mold agent, and Filter I, which uses only a water-soluble anti-mold agent, is different from that of Filter A. It's excellent. However, in particular, it has been found that the anti-mildew function of Filter G, which uses both anti-mildew agents in combination, is far superior to that of Filters H and I. Here, it is presumed that the water-dispersible moldproofing agent contributes to the moldproofing of the adhesive, and the water-soluble moldproofing agent contributes to the moldproofing of the paper, which is the base material. [Flame retardancy] Filter J was formed under the same conditions as Filter A except for the following changes, and the flame retardance of the filter was examined. a. Filter J Adhesive (solid content 50% in commercial product state) is mixed with 30% by weight of halogen flame retardant (main ingredient unknown) and the same amount of inorganic flame retardant (main ingredient unknown) based on the solid content. component antimony trioxide) was added.
【0041】ここで上記ハロゲン系難燃剤としては、テ
トラブロモビスフェノールA(TBA)、2,2−ビス
(4−ヒドロキシ−3,5− ジブロモフェニル)プロ
パン、ヘキサブロモベンゼン(HBB)、トリス(2,
3−ジブロモプロピル)イソシアヌレート(TAIC−
6B)、2,2−ビス(4−ヒドロキシエトキシ−3,
5− ジブロモフェニル)プロパン(TBA−EO)、
デカブロモジフェニルオキサイド(DBDPO)、及び
含ハロゲンポリフォスフェート等をあげることができる
。[0041] Examples of the above-mentioned halogen flame retardants include tetrabromobisphenol A (TBA), 2,2-bis(4-hydroxy-3,5-dibromophenyl)propane, hexabromobenzene (HBB), and tris(2-dibromobenzene). ,
3-dibromopropyl) isocyanurate (TAIC-
6B), 2,2-bis(4-hydroxyethoxy-3,
5-dibromophenyl)propane (TBA-EO),
Examples include decabromodiphenyl oxide (DBDPO) and halogen-containing polyphosphate.
【0042】また上記無機系難燃剤としては、赤リン、
酸化スズ、三酸化アンチモン、水酸化ジルコニウム、メ
タホウ酸バリウム、水酸化アルミニウム、及び水酸化マ
グネシウム等をあげることができる。[0042] The inorganic flame retardants include red phosphorus,
Examples include tin oxide, antimony trioxide, zirconium hydroxide, barium metaborate, aluminum hydroxide, and magnesium hydroxide.
【0043】またリン系難燃剤を使用することも可能で
あり、この種の難燃剤としては、例えばリン酸アンモニ
ウム、トリクレジルホスフェート(TPC)等をあげる
ことができる。
[燃焼試験]フィルタA、Jについて燃焼試験を行った
。燃焼試験は、金網上に水平に保持したフィルタ試料に
60秒間火を当て、離した時のフィルタ試料の燃焼時間
を測定した。繰返し回数は5回とした。試験結果を表6
に示す。It is also possible to use a phosphorus-based flame retardant, and examples of this type of flame retardant include ammonium phosphate and tricresyl phosphate (TPC). [Combustion test] A combustion test was conducted on filters A and J. In the combustion test, a filter sample held horizontally on a wire mesh was exposed to fire for 60 seconds, and the burning time of the filter sample when released was measured. The number of repetitions was 5. Table 6 shows the test results.
Shown below.
【0044】[0044]
【表6】
表6に示すように、粘着剤にハロゲン系及び無機系の2
種の難燃剤を添加して作製したフィルタJは、市販のま
まの粘着剤で作製したフィルタAに比べて優れた難燃性
を示した。[Table 6] As shown in Table 6, halogen-based and inorganic adhesives are used.
Filter J, which was made with the addition of certain flame retardants, showed superior flame retardancy compared to Filter A, which was made with the commercially available adhesive.
【0045】[0045]
【発明の効果】本発明によれば、脱臭フィルタとしての
一般的な脱臭効果と、エアコンディショナに対して使用
されるフィルタとしての低圧力損失及び脱臭効果の継続
性とを適当に備えたエアコンディショナ用の脱臭フィル
タを提供することが可能となる。しかも、フィルタの発
黴の防止、難燃性の向上が達成される。Effects of the Invention According to the present invention, an air conditioner is provided that has the general deodorizing effect as a deodorizing filter, and the low pressure loss and continuity of the deodorizing effect as a filter used for air conditioners. It becomes possible to provide a deodorizing filter for a dishwasher. Moreover, prevention of mold generation and improvement of flame retardancy of the filter can be achieved.
【図1】本発明に係る脱臭フィルタの一実施例を示す平
面図。FIG. 1 is a plan view showing an embodiment of a deodorizing filter according to the present invention.
【図2】本発明に係るフィルタをエアコンディショナの
室内機の筐体内に組込んだ状態を示す側面図。FIG. 2 is a side view showing a state in which a filter according to the present invention is incorporated into a housing of an indoor unit of an air conditioner.
【図3】本発明に係るフィルタの製造工程の一例を示す
図。FIG. 3 is a diagram showing an example of the manufacturing process of a filter according to the present invention.
【図4】ハニカム状格子の構造を示す斜視図。FIG. 4 is a perspective view showing the structure of a honeycomb lattice.
【図5】格子のセルサイズの変化に基づく活性炭担持量
と圧力損失との関係を示すグラフ。FIG. 5 is a graph showing the relationship between the amount of supported activated carbon and pressure loss based on changes in the cell size of the lattice.
【図6】活性炭の粒子寸法の変化に基づく活性炭担持量
と圧力損失との関係を示すグラフ。FIG. 6 is a graph showing the relationship between the amount of supported activated carbon and pressure loss based on changes in particle size of activated carbon.
【図7】活性炭の寸法とセルサイズとの関係による脱臭
フィルタの機能評価を示す図。FIG. 7 is a diagram showing functional evaluation of a deodorizing filter based on the relationship between activated carbon dimensions and cell size.
【図8】フィルタのCO濃度低減に関する実験結果を示
すグラフ。FIG. 8 is a graph showing experimental results regarding CO concentration reduction in filters.
10…脱臭フィルタ、12…基板、14…ガス吸着剤、
16…セル、30…エアコンディショナの室内機、34
…除塵フィルタ、36…熱交換器。10... Deodorizing filter, 12... Substrate, 14... Gas adsorbent,
16...Cell, 30...Indoor unit of air conditioner, 34
...Dust filter, 36...Heat exchanger.
Claims (3)
りフィルタ基体に接着されたガス吸着剤粒子とからなる
フィルタであって、上記粘着剤に難燃剤が添加されてい
ることを特徴とするエアコンディショナ用脱臭フィルタ
。1. An air conditioner comprising a lattice-shaped filter base and gas adsorbent particles adhered to the filter base with an adhesive, wherein a flame retardant is added to the adhesive. Deodorizing filter for dishwashers.
系難燃剤とを含む請求項1記載のフィルタ。2. The filter according to claim 1, wherein the flame retardant includes a halogen flame retardant and an inorganic flame retardant.
記基体の格子の1セルの平面積=約0.20−約0.3
5cm2 、上記ガス吸着剤粒子の寸法=約20−約6
0メッシュ、上記基体平面単位面積当りのガス吸着剤粒
子の使用量=約400 −約2000g/m2 、本フ
ィルタの開口率=約50−約80%、の上記各条件を全
て満たす請求項1または2記載のフィルタ。3. Thickness of the base body = about 15 mm or less, flat area of one cell of the lattice of the base body = about 0.20 to about 0.3.
5cm2, size of the above gas adsorbent particles = about 20 - about 6
0 mesh, the amount of gas adsorbent particles used per unit area of the substrate plane = about 400 to about 2000 g/m2, and the aperture ratio of the filter = about 50 to about 80%. 2. The filter described in 2.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3091673A JPH0783814B2 (en) | 1991-03-29 | 1991-03-29 | Deodorizing filter for air conditioner |
KR1019920000275A KR950006511B1 (en) | 1991-03-29 | 1992-01-10 | Deodorization filter for aircondition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3091673A JPH0783814B2 (en) | 1991-03-29 | 1991-03-29 | Deodorizing filter for air conditioner |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04300616A true JPH04300616A (en) | 1992-10-23 |
JPH0783814B2 JPH0783814B2 (en) | 1995-09-13 |
Family
ID=14033007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3091673A Expired - Fee Related JPH0783814B2 (en) | 1991-03-29 | 1991-03-29 | Deodorizing filter for air conditioner |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0783814B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08299720A (en) * | 1995-05-10 | 1996-11-19 | Bridgestone Corp | Deodorizing filter |
JPH11319460A (en) * | 1998-05-08 | 1999-11-24 | Toyobo Co Ltd | Laminated gas adsorbing sheet and air cleaning filter using the sheet |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0248015A (en) * | 1988-08-08 | 1990-02-16 | Tokyo Roki Kk | Honeycomb structure supporting activated carbon and production thereof |
-
1991
- 1991-03-29 JP JP3091673A patent/JPH0783814B2/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0248015A (en) * | 1988-08-08 | 1990-02-16 | Tokyo Roki Kk | Honeycomb structure supporting activated carbon and production thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08299720A (en) * | 1995-05-10 | 1996-11-19 | Bridgestone Corp | Deodorizing filter |
JPH11319460A (en) * | 1998-05-08 | 1999-11-24 | Toyobo Co Ltd | Laminated gas adsorbing sheet and air cleaning filter using the sheet |
JP4670118B2 (en) * | 1998-05-08 | 2011-04-13 | 東洋紡績株式会社 | Laminated gas adsorbing sheet and air cleaning filter using the same |
Also Published As
Publication number | Publication date |
---|---|
JPH0783814B2 (en) | 1995-09-13 |
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