JPH0429920A - Liquid cosmetic - Google Patents

Liquid cosmetic

Info

Publication number
JPH0429920A
JPH0429920A JP13646490A JP13646490A JPH0429920A JP H0429920 A JPH0429920 A JP H0429920A JP 13646490 A JP13646490 A JP 13646490A JP 13646490 A JP13646490 A JP 13646490A JP H0429920 A JPH0429920 A JP H0429920A
Authority
JP
Japan
Prior art keywords
cosmetic
parts
water
butanediol
liquid cosmetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13646490A
Other languages
Japanese (ja)
Inventor
Ikuo Takagishi
郁夫 高岸
Katsuhiko Kawabata
克彦 川端
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentel Co Ltd
Original Assignee
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pentel Co Ltd filed Critical Pentel Co Ltd
Priority to JP13646490A priority Critical patent/JPH0429920A/en
Publication of JPH0429920A publication Critical patent/JPH0429920A/en
Pending legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PURPOSE:To provide a liquid cosmetic containing a colorant, 3-methyl-1,3- butanediol and water, and having excellent drying resistance and dry-restoration property. CONSTITUTION:The objective cosmetic contains 1-20wt.% of a colorant, 2-30wt.% of 3-methyl-1,3-butanediol as a solvent and moisture-retaining agent and water as a main solvent. The cosmetic can be prepared by properly compounding a water-soluble organic solvent (e.g. propylene glycol), a moisture- retaining assistant (e.g. urea), a penetrant, a dispersing agent, an antiseptic, a viscosity conditioner, a pH modifier, etc., to the above essential components and stirring and dissolving the mixture. When the cosmetic is filled in a cosmetic-containing applicator, the applied skin becomes resistant to dry-up and the applied cosmetic can be quickly dried.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、化粧料内蔵タイプの塗布具に充填して用いた
場合塗布部がドライアップし難く、塗布したとき塗布跡
の乾燥が速い液状化粧料に関する。
Detailed Description of the Invention (Industrial Field of Application) The present invention is based on a liquid that is less likely to dry up when used in an applicator with built-in cosmetics, and which dries quickly after application. Regarding cosmetics.

(従来の技術及び発明が解決しようとする課題)従来、
液状化粧料には水溶性有機溶剤としてプロピレングリコ
ール、1,3−ブチレングリコール、グリセリンが用い
られている。
(Prior art and problems to be solved by the invention) Conventionally,
Propylene glycol, 1,3-butylene glycol, and glycerin are used as water-soluble organic solvents in liquid cosmetics.

しかしながら、プロピレングリコール、1,3−ブチレ
ングリコールを用いた場合はその保湿性が不十分であり
、塗布具のキャップを外して放置した場合、塗布部がド
ライアップして使用不能になり易く、また1、キャップ
をしておいても復元しにくい欠点があった。
However, when propylene glycol or 1,3-butylene glycol is used, its moisturizing properties are insufficient, and if the applicator is left with the cap removed, the applied area tends to dry up and become unusable. 1. It had the disadvantage that it was difficult to restore even if it was capped.

また、グリセリンを用いた場合は保湿性には優れるもの
の皮膚に塗布した場合の塗布跡の乾燥が遅く1例えばア
イライナーなどでは塗布跡の転写を起こす問題があった
。さらに、塗布部が乾燥した場合に、キャップをして復
元させようとしてもグリセリンの粘度が高すぎてインキ
の流動が阻害され、かえって復元が遅くなる問題があっ
た。
Furthermore, when glycerin is used, although it has excellent moisturizing properties, when it is applied to the skin, the application marks are slow to dry and there is a problem in that, for example, when using eyeliner, the application marks may be transferred. Furthermore, when the coated area dries, even if an attempt is made to restore it by capping it, the viscosity of the glycerin is too high and the flow of the ink is inhibited, causing the problem of slowing down the restoration.

本発明は化粧料内蔵タイプの塗布具に充填して塗布部が
ドライアップし難く、塗布跡の乾燥が速い液状化粧料を
得ることを課題とする。
An object of the present invention is to obtain a liquid cosmetic that can be filled into a cosmetic-containing applicator to prevent the application area from drying up easily and to quickly dry the application site.

(課題を解決するための手段) 本発明は、着色材と3−メチル−1,3−ブタンジオー
ルと水とから少なくともなることを特徴とする液状化粧
料を要旨とする。
(Means for Solving the Problems) The gist of the present invention is a liquid cosmetic comprising at least a colorant, 3-methyl-1,3-butanediol, and water.

以下、本発明の詳細な説明する。The present invention will be explained in detail below.

着色材は染料、顔料どちらでも化粧品に使用できるもの
であれば使用できる。また、単独または複数混合して用
いても差し支えない。その使用量は、液状化粧料全体に
対して1〜20重量%が好ましい。
The colorant can be either dye or pigment as long as it can be used in cosmetics. Further, they may be used alone or in combination. The amount used is preferably 1 to 20% by weight based on the entire liquid cosmetic.

水は主溶剤として用いるものである。Water is used as the main solvent.

3−メチル−1,3−ブタンジオールは溶剤及び保湿材
として用いるものである。その使用量は2〜30重量%
が好ましい。
3-Methyl-1,3-butanediol is used as a solvent and a humectant. The amount used is 2-30% by weight
is preferred.

これらの他に、塗布部および塗布跡の乾燥調節剤として
プロピレングリコール、1.3−ブタンジオール、グリ
セリンといった従来用いられていた水溶性有機溶剤を少
量併用てきる。又、保湿助剤として尿素、浸透剤または
分散剤として界面活性剤、塗布跡の耐水性、定着性の向
上または分散剤として樹脂、防腐・防黴剤、粘度調節剤
として水溶性高分子、p、 H調整剤としてアルカリ化
剤などを適宜添加できる。
In addition to these, a small amount of conventionally used water-soluble organic solvents such as propylene glycol, 1,3-butanediol, and glycerin can be used as a drying agent for the coated area and coating trace. In addition, urea is used as a moisturizing aid, surfactant is used as a penetrating agent or dispersant, resin is used as a dispersing agent to improve the water resistance and fixing properties of the coated area, preservative and fungicide, and water-soluble polymer is used as a viscosity regulator. , An alkalizing agent or the like can be appropriately added as an H adjuster.

本液状化粧料は、着色材として染料を用いた場合は従来
知られている撹拌機などで各成分を撹拌混合し、均一に
溶解させる等の方法で得られ、着色材として顔料を用い
た場合は従来知られている分散機などで顔料を分散し、
他の各成分と撹拌混合し、分散液となす等の方法で得る
ことができる。
When using a dye as a coloring agent, this liquid cosmetic can be obtained by stirring and mixing each component with a conventionally known stirrer or the like and dissolving them uniformly; when using a pigment as a coloring agent, this liquid cosmetic can be obtained by The pigment is dispersed using a conventionally known dispersing machine,
It can be obtained by stirring and mixing with other components to form a dispersion.

(作用) 本発明の3−メチル−1,3−ブタンジオールはグリセ
リンよりやや劣るがプロピレングリコールや1,3−ブ
タンジオールよりも保湿性が良いので塗布部のドライア
ップがし難く、かつ、沸点はプロピレングリコールや1
,3−ブタンジオールとほぼ同様でグリセリンと比べて
格段に低いので塗布跡の乾燥も速い。この様に3−メチ
ル−1゜3−ブタンジオールは、保湿性と沸点のバラン
スが良好であるため、液状化粧料として優れた性能が得
られるものと推察される。
(Function) Although the 3-methyl-1,3-butanediol of the present invention is slightly inferior to glycerin, it has better moisturizing properties than propylene glycol or 1,3-butanediol, so it is difficult to dry up the applied area, and it has a boiling point is propylene glycol or 1
, 3-butanediol, and much lower than glycerin, so the application marks dry quickly. As described above, 3-methyl-1°3-butanediol has a good balance between moisturizing properties and boiling point, so it is presumed that it can provide excellent performance as a liquid cosmetic.

(実施例) 以下、本発明を実施例によりさらに詳細に説明するが、
実施例、比較例中に単に「部」とあるのは「重量部」を
示す。
(Example) Hereinafter, the present invention will be explained in more detail with reference to Examples.
In Examples and Comparative Examples, "parts" simply indicate "parts by weight."

慄蓬−例」− 黄色4号             1.2部(C,1
,19140、東色ピグメンI−■製)青色1号   
          3.0部(C,1,42090、
東色ピグメント■製)ユカフ71−−マーAM−75−
R20510、0部(ベタイン型アクリル系両性樹脂の 30%ブルシン変性エタノール溶液、 定着性向上用樹脂、三菱油化■製) イソプレングリコール       8.0部(3−メ
チル−1,3−ブタンジオール、■クラレ製) ニューサイドSCQ、3部 (デヒドロ酢酸ナトリウム、防腐防黴剤、日本合成化学
■製) 精製水             77.5部上記成分
を撹拌、溶解して緑色の液状化粧料を得た。
Horror - Example" - Yellow No. 4 1.2 parts (C, 1
, 19140, Toshiki Pigmen I-■) Blue No. 1
3.0 parts (C, 1,42090,
Made by Toshiki Pigment■) Yukafu 71--Mar AM-75-
R20510, 0 parts (30% brucine-denatured ethanol solution of betaine type acrylic amphoteric resin, resin for improving fixing properties, manufactured by Mitsubishi Yuka ■) Isoprene glycol 8.0 parts (3-methyl-1,3-butanediol, ■ (manufactured by Kuraray) Newside SCQ, 3 parts (sodium dehydroacetate, preservative and fungicide, manufactured by Nippon Gosei Kagaku ■) Purified water 77.5 parts The above components were stirred and dissolved to obtain a green liquid cosmetic.

U−鐸A 赤色104号           1.0部(C,1
,454]−0、東色ピグメント曲製製)青色1号  
           1.0部ユカフォーマーAM−
75−1ll      25.0部(ベタイン型アク
リル系両性樹脂の30%水溶液、定着性向上用樹脂、三
菱油化■製)イソプレングリコール      12.
0部グリセリン           3.0部精製尿
素             2.0部メッキンスM 
           O,5部(パラオキシ安息香酸
メチル、防腐防黴剤、上野製薬■製) 精製水             55.5部」二記成
分を撹拌、溶解して紫色の液状化粧料を得た。
U-Taku A Red No. 104 1.0 part (C, 1
,454]-0, manufactured by Toshiki Pigment Kyusei) Blue No. 1
1.0 part Yukaformer AM-
75-1ll 25.0 parts (30% aqueous solution of betaine type acrylic amphoteric resin, resin for improving fixing properties, manufactured by Mitsubishi Yuka ■) Isoprene glycol 12.
0 parts Glycerin 3.0 parts Purified urea 2.0 parts Mechinsu M
O, 5 parts (methyl paraoxybenzoate, preservative and fungicide, manufactured by Ueno Pharmaceutical Co., Ltd.) Purified water 55.5 parts The two components were stirred and dissolved to obtain a purple liquid cosmetic.

失速側−4 赤色104号           0.2部青色1号
             1.8部ユカフォーマーA
M−75−WH7,0部(ベタイン型アクリル系両性樹
脂の20%水溶液、定着性向上用樹脂、三菱油化■製)
プロピレングリコール       1.0部イソプレ
ングリコール       9.0部メノキンスM  
         015部精製水         
    80.5部上記成分を撹拌、溶解して青色の液
状化粧料を得た。
Stall side-4 Red No. 104 0.2 parts Blue No. 1 1.8 parts Yukaformer A
M-75-WH 7.0 parts (20% aqueous solution of betaine type acrylic amphoteric resin, resin for improving fixing properties, manufactured by Mitsubishi Yuka ■)
Propylene glycol 1.0 parts Isoprene glycol 9.0 parts Menokins M
015 parts purified water
80.5 parts The above ingredients were stirred and dissolved to obtain a blue liquid cosmetic.

実施例4 赤色102号           1.5部(東色ピ
グメント■製) 黄色5号             1.0部(東色ピ
グメント■製) 青色1号             1.5部ニッコー
ルTO−304,,0部 (ポリオキシエチレン(20)ソルビタントリオレエー
ト、非イオン系界面活性剤、日光ケミカルズ■製) ニラコールNP−103,0部 (ポリオキシエチレン(10)ノニルフェニルエーテル
、非イオン系界面活性剤、 日光ケミカルズ■製) イソプレングリコール      10.0部ハイソル
ブDM           O,8部(フェノキシエ
タノール、防腐防黴剤、東邦化学工業■製) ポバールPVA−1051,5部 (ポリビニルアルコール、粘度調節剤、■クラレ製) 精製水             76.7部上記成分
のうち、先ずポバールPVA−105全量を精製水15
部に加え、加熱、撹拌して溶解し、これを残りの成分と
共に撹拌、溶解して黒色の液状化粧料を得た。
Example 4 Red No. 102 1.5 parts (manufactured by Toshiki Pigment ■) Yellow No. 5 1.0 parts (manufactured by Toshiki Pigment ■) Blue No. 1 1.5 parts Nikkor TO-304, 0 parts (polyoxyethylene (20) Sorbitan trioleate, nonionic surfactant, manufactured by Nikko Chemicals ■) Nilacol NP-10 3,0 parts (polyoxyethylene (10) nonylphenyl ether, nonionic surfactant, manufactured by Nikko Chemicals ■) Isoprene Glycol 10.0 parts Hysolve DM O, 8 parts (phenoxyethanol, antiseptic, antifungal agent, manufactured by Toho Chemical Industries, Ltd.) Poval PVA-1051, 5 parts (polyvinyl alcohol, viscosity modifier, manufactured by ■Kuraray) Purified water 76.7 parts Of the above ingredients, first add the entire amount of Poval PVA-105 to 15 ml of purified water.
This was stirred and dissolved together with the remaining ingredients to obtain a black liquid cosmetic.

尖庭孤旦 紺青               5.0部(コンジ
ヨウ、大東化成工業■製) ニラコール To−103,0部 (ポリオキシエチレン(20)ソルビタンモノオレエー
ト、分散剤、 日光ケミカルズ■製) メッキンスM            O,5部イソプ
レングリコール       8.0部ニッコール N
P−100,2部 ペプタイドPA−1003,0部 (ポリペブタイド、分散助剤、■製ニッピ製)精製水 
            80.3部上記成分のうち紺
青、ニラコールTo−10の全量を精製水15部に加え
均一に撹拌した後、3本ロールミルにて5回通しを行っ
た。これに、残りの成分を混合、均一に溶解したものを
徐々に加え、1時間撹拌して青色の液状化粧料を得た。
Sentei Kodan Konsei 5.0 parts (Konjiyo, manufactured by Daito Kasei Kogyo ■) Nilacol To-10 3,0 parts (polyoxyethylene (20) sorbitan monooleate, dispersant, manufactured by Nikko Chemicals ■) Meccinsu M O,5 Part Isoprene Glycol 8.0 parts Nikkor N
P-100, 2 parts Peptide PA-100 3, 0 parts (polypeptide, dispersion aid, manufactured by Nippi) Purified water
80.3 parts of the above components, including Prussian blue and Niracol To-10, were added to 15 parts of purified water, stirred uniformly, and then passed through a three-roll mill five times. To this, the remaining ingredients were mixed and uniformly dissolved and gradually added, and the mixture was stirred for 1 hour to obtain a blue liquid cosmetic.

ル較桝よ 実施例1のイソプレングリコールの代わりにグリセリン
を加えた以外は同様になして緑色の液状化粧料を得た。
A green liquid cosmetic was obtained in the same manner as in Example 1 except that glycerin was added instead of isoprene glycol.

ル較孤I 実施例2のイソプレングリコールの代わりにグリセリン
を加えた以外は同様になして紫色の液状化粧料を得た。
Comparison I A purple liquid cosmetic was obtained in the same manner as in Example 2, except that glycerin was added instead of isoprene glycol.

ル較孤菱 実施例3のイソプレングリコールの代わりにプロピレン
グリコールを加えた以外は同様になして青色の液状化粧
料を得た。
A blue liquid cosmetic was obtained in the same manner as in Example 3 except that propylene glycol was added instead of isoprene glycol.

え較孤↓ 実施例4のイソプレングリコールの代わりに1゜3−ブ
タンジオールを加えた以外は同様になして黒色の液状化
粧料を得た。
Comparison ↓ A black liquid cosmetic was obtained in the same manner as in Example 4, except that 1°3-butanediol was added instead of isoprene glycol.

比較例5 実施例5のイソプレングリコールの代わりにグリセリン
を加えた以外は同様になして青色の液状化粧料を得た。
Comparative Example 5 A blue liquid cosmetic was obtained in the same manner as in Example 5 except that glycerin was added instead of isoprene glycol.

(発明の効果) 以上の実施例、比較例で得られた液状化粧料について試
験を行った。
(Effects of the Invention) Tests were conducted on the liquid cosmetics obtained in the above Examples and Comparative Examples.

結果を表1に示す。The results are shown in Table 1.

表1.試験結果 塗布部耐乾燥性:実施例1〜5、比較例1〜5で得た液
状化粧料を連通多孔を有するウレタン製ペン先を塗布部
として取り付けた塗布具に充填して試験用サンプルとし
、キャップを外して横向きに放置し一定時間毎に塗布し
て塗布不能となるまでの時間を測定した。
Table 1. Test results Drying resistance of applied part: The liquid cosmetics obtained in Examples 1 to 5 and Comparative Examples 1 to 5 were filled into an applicator equipped with a urethane nib having continuous pores as an application part to prepare test samples. The cap was removed, the product was left horizontally, and the product was applied at regular intervals, and the time until application became impossible was measured.

O:4時間基」二塗布可能 △:2から4時間位まで塗布可能 ×:2時間以内で塗布不能 塗布部乾燥復元性:塗布部耐乾燥性と同様に試験サンプ
ルを作成し、キャップを外して6時間横向きに放置した
後キャップをして一定時間毎に塗布して塗布可能となる
時間を測定した。
O: Possible to apply 2 coats for 4 hours △: Possible to coat from 2 to 4 hours After leaving the solution on its side for 6 hours, the solution was capped and applied at regular intervals to measure the time required for application.

022時間以内に塗布可能となる 6210時間以内に塗布可能となる X:塗布可能となるのに10時間を超える塗布跡の乾燥
性:塗布部耐乾燥性と同様に試験サンプルを作成し、皮
膚に塗布して乾燥するまでの時間を測定した。
0 Can be applied within 22 hours 62 Can be applied within 10 hours The time taken from application to drying was measured.

O:20秒以内に乾燥する △:40秒以内に乾燥する ×:40秒以内に乾燥しない 以上詳細に説明した様に本発明に係る液状化粧料は、塗
布部の耐乾燥性及び塗布部の乾燥復元性に対して優れた
性能を有し、皮膚に塗布したときも良好な乾燥性を示し
、液状化粧料内蔵タイプの塗布具に非常に好適に用い得
るものである。
O: Drys within 20 seconds △: Drys within 40 seconds ×: Does not dry within 40 seconds As explained in detail above, the liquid cosmetic according to the present invention has excellent drying resistance of the applied area and It has excellent performance in terms of dry recovery properties, shows good drying properties when applied to the skin, and can be very suitably used in applicators containing liquid cosmetics.

Claims (1)

【特許請求の範囲】[Claims] 着色材と3−メチル−1,3−ブタンジオールと水とか
ら少なくともなることを特徴とする液状化粧料。
A liquid cosmetic comprising at least a colorant, 3-methyl-1,3-butanediol, and water.
JP13646490A 1990-05-25 1990-05-25 Liquid cosmetic Pending JPH0429920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13646490A JPH0429920A (en) 1990-05-25 1990-05-25 Liquid cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13646490A JPH0429920A (en) 1990-05-25 1990-05-25 Liquid cosmetic

Publications (1)

Publication Number Publication Date
JPH0429920A true JPH0429920A (en) 1992-01-31

Family

ID=15175723

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13646490A Pending JPH0429920A (en) 1990-05-25 1990-05-25 Liquid cosmetic

Country Status (1)

Country Link
JP (1) JPH0429920A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9625429B2 (en) 2010-10-29 2017-04-18 Cohesive Technologies Inc. LC-MS configuration for purification and detection of analytes having a broad range of hydrophobicites

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9625429B2 (en) 2010-10-29 2017-04-18 Cohesive Technologies Inc. LC-MS configuration for purification and detection of analytes having a broad range of hydrophobicites

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