JPH0429737B2 - - Google Patents
Info
- Publication number
- JPH0429737B2 JPH0429737B2 JP59155988A JP15598884A JPH0429737B2 JP H0429737 B2 JPH0429737 B2 JP H0429737B2 JP 59155988 A JP59155988 A JP 59155988A JP 15598884 A JP15598884 A JP 15598884A JP H0429737 B2 JPH0429737 B2 JP H0429737B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- aluminum
- metal aluminum
- coating layer
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 30
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000007751 thermal spraying Methods 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 239000011247 coating layer Substances 0.000 description 12
- 210000003298 dental enamel Anatomy 0.000 description 10
- 230000007797 corrosion Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- LNSPFAOULBTYBI-UHFFFAOYSA-N [O].C#C Chemical group [O].C#C LNSPFAOULBTYBI-UHFFFAOYSA-N 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 238000004534 enameling Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は金属アルミニウム被覆用溶射材、特に
金属アルミニウムの素地金属の表面を溶射被覆し
て保護する溶射材に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a thermal spraying material for coating metal aluminum, and particularly to a thermal spraying material for coating and protecting the surface of a base metal of metal aluminum.
（従来技術）
近年、金属アルミニウムは航空機、船舶、車
両、建材および厨房用器具の素材として広範囲な
用途に、多量に使用されている。金属アルミニウ
ムは軽量という特長がある反面、融点が660℃と
低く、耐食性が劣り、表面硬度が低いという欠点
を有している。そこで、金属アルミニウムの表面
を保護するため、金属アルミニウムの表面が塗装
されたり、または、アルマイトのように表面に酸
化皮膜を形成させることが行われている。しかし
ながら、金属アルミニウムの表面が塗装された
り、酸化皮膜が形成されても、この表面にキズが
つきやすいという欠点は有している。(Prior Art) In recent years, metallic aluminum has been used in large quantities in a wide range of applications as a material for aircraft, ships, vehicles, building materials, and kitchen appliances. Although metal aluminum has the advantage of being lightweight, it has the disadvantages of a low melting point of 660°C, poor corrosion resistance, and low surface hardness. Therefore, in order to protect the surface of metal aluminum, the surface of metal aluminum is painted or an oxide film is formed on the surface like alumite. However, even if the surface of metal aluminum is painted or an oxide film is formed, it has the disadvantage that the surface is easily scratched.
このため、金属アルミニウムの表面にほうろう
を掛けることが行われているが、この場合、ほう
ろうの溶融成分であるフリツトは素地金属より低
融点のものでなければならないので、普通550℃
以下の温度で電気炉またはトンネル炉等の加熱炉
に入れて焼付けられる。低融点のフリツトとして
は鉛系または燐酸系の２グループがあるが、普通
耐食性に優れた鉛系フリツトが用いられている。
しかしながら、鉛系のフリツトはホウ砂、石英、
螢石、長石などを原料とし、これにアルカリ金
属、アルカリ土類金属などの金属の硝酸塩および
炭酸塩、鉛、錫、亜鉛、ニツケルおよびコバルト
の酸化物を配合して作つたものである。したがつ
て、これらの原料を用いて造つた金属アルミニウ
ムのほうろうは耐食性を若干改善することができ
るが、アルカリ、フツ素、ホウ素、鉛がかなり量
を含有しているので完全な耐食性の被覆層はでき
ず、ほうろうの強度、硬度が十分でないという欠
点はある。 For this reason, enameling is applied to the surface of metal aluminum, but in this case, the frit, which is the molten component of the enamel, must have a lower melting point than the base metal, so it is usually heated to 550°C.
It is baked in a heating furnace such as an electric furnace or tunnel furnace at the following temperatures. There are two groups of low-melting point frits: lead-based and phosphoric acid-based, and lead-based frits, which have excellent corrosion resistance, are usually used.
However, lead-based frits are made of borax, quartz,
It is made from fluorite, feldspar, etc. as raw materials, mixed with nitrates and carbonates of metals such as alkali metals and alkaline earth metals, and oxides of lead, tin, zinc, nickel, and cobalt. Therefore, although metallic aluminum enamel made from these raw materials can have slightly improved corrosion resistance, it cannot be completely corrosion-resistant because it contains significant amounts of alkali, fluorine, boron, and lead. The disadvantage is that the strength and hardness of the enamel is not sufficient.
（発明の目的）
本発明は、被覆層の強度、硬度、定着性、耐食
性、耐熱性、耐衝撃性がアルミニウムほうろうよ
りも格段と優れ、かつ金属アルミニウム表面に酸
素−アセチレン炎またはプラズマジエツト炎で溶
射被覆した場合、均一な被覆層が効率よく得られ
る金属アルミニウム被覆用溶射材を提供すること
を目的とする。(Purpose of the Invention) The present invention provides a coating layer that has strength, hardness, fixing properties, corrosion resistance, heat resistance, and impact resistance that are significantly superior to aluminum enamel, and that coats the metal aluminum surface with oxygen-acetylene flame or plasma jet flame. An object of the present invention is to provide a thermal spray material for coating metal aluminum that can efficiently form a uniform coating layer when thermally sprayed.
（発明の構成）
本発明に係る金属アルミニウム被覆用溶射材は
組成がSiO250〜54重量％、MgO30〜40重量％、
CaO0.5〜６重量％、Al2O31.5〜５重量％、およ
びFe2O35〜８重量％であるフリツトよりなるこ
とを特徴とするものである。この金属アルミニウ
ム被覆用溶射材を金属アルミニウム表面に酸素−
アセチレン炎またはプラズマジエツト炎により溶
射すると、耐熱性、硬度、耐食性、密着性がアル
ミニウムほうろうよりも著しく優れた被覆層が効
率よく均一に形成されるのである。(Structure of the Invention) The thermal spray material for coating metal aluminum according to the present invention has a composition of 50 to 54% by weight of SiO 2 , 30 to 40% by weight of MgO,
The frit is characterized by comprising 0.5-6% by weight of CaO, 1.5-5% by weight of Al 2 O 3 and 5-8% by weight of Fe 2 O 3 . This thermal spraying material for coating aluminum metal is applied to the surface of metal aluminum with oxygen.
When sprayed with an acetylene flame or a plasma jet flame, a coating layer with heat resistance, hardness, corrosion resistance, and adhesion significantly superior to that of aluminum enamel can be efficiently and uniformly formed.
ここで、SiO2が50重量％未満では良好なガラ
ス状態とならず、また54重量％を超えると粘性が
急速に上昇するので溶射されたものに繊維状物が
混在し均一な被覆面を形成しないので不適当であ
る。 Here, if SiO 2 is less than 50% by weight, a good glass state will not be obtained, and if it exceeds 54% by weight, the viscosity will increase rapidly, so fibrous substances will be mixed in the sprayed material and a uniform coated surface will be formed. It is inappropriate because it does not.
MgOは溶射被覆されるフリツトの膨張係数を
金属アルミニウムの膨張係数に近似させるために
30重量％以上必要であるが、40重量％を超えると
溶融温度を上昇せしめるので好ましくない。 MgO is used to make the expansion coefficient of the frit to be thermally sprayed close to that of metallic aluminum.
It is necessary to use 30% by weight or more, but if it exceeds 40% by weight, it is not preferable because it increases the melting temperature.
CaOはフリツトの溶融温度を下げるのに用いら
れるが、0.5重量％未満では効果が少なく、６重
量％を超えると粘性が急激に降下するので好まし
くない。 CaO is used to lower the melting temperature of the frit, but if it is less than 0.5% by weight it has little effect, and if it exceeds 6% by weight the viscosity drops rapidly, which is not preferred.
Al2O3は溶射初期に金属アルミニウムの表面に
生成するアルミニウムの酸化物薄膜と融合して密
着層を完成させる成分として作用するが、1.5重
量％未満では融合、密着効果が乏しく、５重量％
を超えると溶融温度が上昇せしめるので好ましく
ない。 Al 2 O 3 acts as a component that fuses with the thin aluminum oxide film that forms on the surface of metal aluminum during thermal spraying to complete an adhesion layer, but if it is less than 1.5% by weight, the fusion and adhesion effects are poor;
Exceeding this is not preferable because it increases the melting temperature.
Fe2O3は溶射した際、広範囲に、かつ急速に均
一な被覆層を生成させる。すなわち、加熱温度に
おける流動性を向上させる成分であるが、５重量
％未満では効果が乏しく、８重量％を超えると被
覆層の耐熱性、耐食性を低下させる。 When sprayed, Fe 2 O 3 quickly forms a uniform coating over a wide area. That is, it is a component that improves fluidity at heating temperatures, but if it is less than 5% by weight, the effect is poor, and if it exceeds 8% by weight, it reduces the heat resistance and corrosion resistance of the coating layer.
なお、SiO2、MgO、CaO、Al2O3、Fe2O3の外
に、NiO、MnO2、Cr2O3が１重量％以下であつ
ても本発明の溶射材の効果は殆ど変らない。 Furthermore, even if NiO, MnO 2 and Cr 2 O 3 in addition to SiO 2 , MgO, CaO, Al 2 O 3 and Fe 2 O 3 are contained in amounts of 1% by weight or less, the effect of the thermal spray material of the present invention hardly changes. do not have.
（作用）
本発明の溶射材は、各種原料をSiO250〜54重
量％、MgO30〜40重量％、CaO0.5〜６重量％、
Al2O31.5〜５重量％およびFe2O35〜８重量％に
なるように配合した配合物を、ガス炉または電気
炉で溶融し、次いで、この溶融された溶湯を水冷
して得たガラスをボールミル等で粉砕して造つた
フリツトよりなる。(Function) The thermal spray material of the present invention contains various raw materials such as 50 to 54% by weight of SiO 2 , 30 to 40% by weight of MgO, 0.5 to 6% by weight of CaO,
A mixture containing 1.5 to 5% by weight of Al 2 O 3 and 5 to 8% by weight of Fe 2 O 3 is melted in a gas furnace or electric furnace, and then the molten metal is cooled with water to obtain a mixture. It consists of a frit made by crushing glass with a ball mill, etc.
フリツトの粒度は溶射機により異なるが、例え
ば、プラズマジエツトで溶射する場合10〜40μm
程度になるように粉砕、分級したものを用いる。
このフリツトよりなる溶射材はプラズマジエツト
によつて、常温の大気圧の雰囲気中にて金属アル
ミニウム板表面から50mm〜150mmの距離より溶射
される。 The particle size of the frit varies depending on the thermal spraying machine, but for example, when spraying with a plasma jet, it is 10 to 40 μm.
Use products that have been crushed and classified to a certain degree.
This thermal spray material made of frit is sprayed by a plasma jet from a distance of 50 mm to 150 mm from the surface of the metal aluminum plate in an atmosphere at room temperature and atmospheric pressure.
（発明の効果）
本発明の溶射材を用いて金属アルミニウム表面
に酸素−アセチレン炎またはプラズマジエツトで
溶射被覆すると、均一な被覆層が効率よく得られ
ると共に、被覆層の強度、硬度定着性、耐食性、
耐熱性、耐衝撃性がアルミニウムほうろうよりも
格段と優れたものとなり、金属アルミニウムの利
用はより広範なものにすることができる。(Effects of the Invention) When the thermal spraying material of the present invention is thermally sprayed onto a metal aluminum surface with oxygen-acetylene flame or plasma jet, a uniform coating layer can be efficiently obtained, and the strength, hardness and fixing properties of the coating layer can be improved. Corrosion resistance,
The heat resistance and impact resistance are far superior to that of aluminum enamel, and metal aluminum can be used more widely.
（実施例）
原料として珪石、マグネサイト、石灰石の天然
鉱石と、Fe2O3、Al2O3の工業用酸化物を用い、
原料配合物を電気炉で溶融した溶湯を水冷し、得
られたガラスをボールミルで湿式粉砕、乾燥、分
級して粒度10〜30μm、組成がSiO251.5重量％、
MgO30.8重量％、CaO5.6重量％、Al2O34.9重量
％、Fe2O37.2重量％のフリツトを造つた。(Example) Using natural ores of silica stone, magnesite, and limestone and industrial oxides of Fe 2 O 3 and Al 2 O 3 as raw materials,
The raw material mixture is melted in an electric furnace, the molten metal is cooled with water, and the resulting glass is wet-pulverized in a ball mill, dried, and classified to have a particle size of 10 to 30 μm and a composition of 51.5% by weight of SiO 2 .
A frit containing 0.8% by weight of MgO3, 5.6% by weight of CaO, 4.9% by weight of Al 2 O 3 and 7.2% by weight of Fe 2 O 3 was prepared.
このフリツトを厚さ３mmの金属アルミニウム板
の表面上にプラズマジエツトにより常温の大気圧
の雰囲気中で、約100mmの距離から被覆厚さ0.1mm
になるように溶射したところ、強固な耐熱性、耐
食性の被覆層を金属アルミニウム板上に形成する
ことができた。 This frit is coated on the surface of a 3 mm thick metal aluminum plate with a coating thickness of 0.1 mm from a distance of about 100 mm using a plasma jet in an atmosphere at room temperature and atmospheric pressure.
When sprayed to the desired temperature, a strong heat-resistant and corrosion-resistant coating layer could be formed on the metal aluminum plate.
（比較例）
比較のため、SiO228.4重量％、PbO42.9重量
％、Na2O10.0重量％、K2O6.3重量％、Li2O2.5重
量％およびTiO29.9重量％の組成のアルミニウム
ほうろうを上記と同じ厚さの金属アルミニウム板
に掛け、電気炉で530℃で５分間焼付けて被覆層
の厚さ0.1mmのものを得た。(Comparative example) For comparison, 28.4% by weight of SiO2, 2.9% by weight of PbO, 10.0% by weight of Na2O, 6.3 % by weight of K2O, 2.5 % by weight of Li2O, and 9.9% by weight of TiO2. Aluminum enamel having the composition was applied to a metal aluminum plate having the same thickness as above and baked in an electric furnace at 530°C for 5 minutes to obtain a coating layer with a thickness of 0.1 mm.
両者の性質を調べたところ下記のとおりであつ
た。なお、以下の試料はいずれも５×10cmの大き
さで５枚造つたものであり、下記の数値はその平
均値である。 When the properties of both were investigated, they were as follows. In addition, each of the following samples was made in five pieces with a size of 5 x 10 cm, and the numerical value below is the average value.
１ 本発明に係る溶射材の被覆層の表面硬度は旧
モース硬度で６であつたが、一方アルミニウム
ほうろうの場合は４であつた。1 The surface hardness of the coating layer of the thermal sprayed material according to the present invention was 6 on the old Mohs hardness scale, whereas it was 4 in the case of aluminum enamel.
２ 耐衝激性と同時に被覆層の密着性をみるため
直径36.5mm、重量200ｇの鋼球を試料上に落と
し、被覆層が剥離したときの落差を求めたとこ
ろ、本発明の溶射材で被覆したものは落差が38
cmであり、アルミニウムほうろうで被覆したも
のの落差は23cmであつた。2. In order to check the adhesion of the coating layer as well as the impact resistance, a steel ball with a diameter of 36.5 mm and a weight of 200 g was dropped onto the sample, and the drop when the coating layer peeled off was determined. The head of the one that did was 38
cm, and the height of the one coated with aluminum enamel was 23 cm.
３ 耐熱衝撃性を調べるため、熱板上に試料を乗
せ、所定温度になつたところで冷水を注ぎ被覆
層が剥離したときの温度差を求めたところ、本
発明の溶射材を被覆したものの温度差は400℃
であり、一方アルミニウムほうろうを被覆した
ものの温度差は240℃であつた。3. In order to investigate thermal shock resistance, a sample was placed on a hot plate, and when it reached a predetermined temperature, cold water was poured in and the temperature difference when the coating layer peeled off was determined. is 400℃
On the other hand, the temperature difference in the case covered with aluminum enamel was 240°C.
Claims (1)
％、CaO0.5〜６重量％、Al2O31.5〜５重量％お
よびFe2O35〜８重量％であるフリツトよりなる
金属アルミニウム被覆用溶射材。1. A metal consisting of a frit whose composition is 50-54% by weight of SiO 2 , 30-40% by weight of MgO, 0.5-6% by weight of CaO, 1.5-5% by weight of Al 2 O 3 and 5-8% by weight of Fe 2 O 3 Thermal spraying material for aluminum coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59155988A JPS6134169A (en) | 1984-07-25 | 1984-07-25 | Spraying material for coating metallic aluminum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59155988A JPS6134169A (en) | 1984-07-25 | 1984-07-25 | Spraying material for coating metallic aluminum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6134169A JPS6134169A (en) | 1986-02-18 |
| JPH0429737B2 true JPH0429737B2 (en) | 1992-05-19 |
Family
ID=15617893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59155988A Granted JPS6134169A (en) | 1984-07-25 | 1984-07-25 | Spraying material for coating metallic aluminum |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6134169A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4427264C2 (en) * | 1994-07-30 | 1996-09-26 | Mtu Muenchen Gmbh | Brushing surface for engine components and method for its production |
| US6875528B1 (en) | 1999-10-25 | 2005-04-05 | Nippon Steel Corporation | Ceramic composition, composite material, composite material production method, porous body, oxygen separator, and chemical reactor |
| JP4478499B2 (en) * | 2004-04-26 | 2010-06-09 | 独立行政法人海上技術安全研究所 | Marking method |
| JP6125318B2 (en) * | 2013-05-14 | 2017-05-10 | 大阪ガスケミカル株式会社 | Thermal spray composition and thermal spray coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5446144A (en) * | 1977-09-20 | 1979-04-11 | Matsushita Electric Ind Co Ltd | Hot plate |
| JPS5916976A (en) * | 1982-06-11 | 1984-01-28 | チエスコスロベンスカ・アカデミ−・ベド | Plasma spray coating material |
-
1984
- 1984-07-25 JP JP59155988A patent/JPS6134169A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5446144A (en) * | 1977-09-20 | 1979-04-11 | Matsushita Electric Ind Co Ltd | Hot plate |
| JPS5916976A (en) * | 1982-06-11 | 1984-01-28 | チエスコスロベンスカ・アカデミ−・ベド | Plasma spray coating material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6134169A (en) | 1986-02-18 |
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