JPH042880A - Fluorescent whitening treatment of polyamide web - Google Patents
Fluorescent whitening treatment of polyamide webInfo
- Publication number
- JPH042880A JPH042880A JP2102084A JP10208490A JPH042880A JP H042880 A JPH042880 A JP H042880A JP 2102084 A JP2102084 A JP 2102084A JP 10208490 A JP10208490 A JP 10208490A JP H042880 A JPH042880 A JP H042880A
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- polyamide fabric
- fluorescent whitening
- compound
- yellowing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004952 Polyamide Substances 0.000 title claims abstract description 51
- 229920002647 polyamide Polymers 0.000 title claims abstract description 51
- 230000002087 whitening effect Effects 0.000 title claims description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 42
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 239000004744 fabric Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 238000007654 immersion Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- -1 alkylphenyl phenyl ether Chemical compound 0.000 abstract description 14
- 238000005406 washing Methods 0.000 abstract description 4
- 239000006081 fluorescent whitening agent Substances 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000004383 yellowing Methods 0.000 description 12
- 239000004677 Nylon Substances 0.000 description 11
- 229920001778 nylon Polymers 0.000 description 11
- 239000000835 fiber Substances 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 7
- 125000000542 sulfonic acid group Chemical group 0.000 description 7
- 238000004043 dyeing Methods 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000004394 yellowing prevention Methods 0.000 description 5
- 241001584775 Tunga penetrans Species 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 3
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 3
- 235000012141 vanillin Nutrition 0.000 description 3
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 244000036905 Benincasa cerifera Species 0.000 description 1
- 235000011274 Benincasa cerifera Nutrition 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明はポリアミド布帛の蛍光増白処理方法に関するも
ので、さらに詳しくは、スポーツ衣料その他の衣料製昌
に使用するために、優れた耐光性および黄変防止性を有
する白炭の高い蛍光色をポリアミド布帛に付与する蛍光
増白処理方法に間するものである。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a fluorescent whitening treatment method for polyamide fabric, and more specifically, for use in the manufacturing of sports clothing and other clothing, it has excellent light resistance. and a fluorescent whitening treatment method for imparting the highly fluorescent color of white charcoal having anti-yellowing properties to polyamide fabrics.
(従来の技術)
ポリアミド繊維は強度、耐摩耗性なとの物性に優れてお
り、スポーツ衣料を初めとして各種の衣料製品に使用さ
れている。しかし、耐光性に優れた白瓜の高いポリアミ
ド繊維製品を得ることは困難であった。(Prior Art) Polyamide fibers have excellent physical properties such as strength and abrasion resistance, and are used in various clothing products including sports clothing. However, it has been difficult to obtain polyamide fiber products with excellent light resistance and high white color.
すなわち、ポリアミド繊維に白味を付与する方法として
、従来から各種の蛍光増白剤例えばスチルベン系、クマ
リン系、ピラゾリン系、イミダゾール系、オキサゾール
系蛍光増白剤などを用いて処理する蛍光増白法が知られ
ているが、白瓜は向上するものの耐光性の点で不充分で
あった。That is, as a method of imparting whiteness to polyamide fibers, conventional optical brightening methods have been used to treat polyamide fibers using various optical brighteners, such as stilbene-based, coumarin-based, pyrazoline-based, imidazole-based, and oxazole-based optical brighteners. is known, but although it improved white melon, it was insufficient in terms of light resistance.
また、これらの蛍光増白処理されたポリアミド繊維製品
は流通、使用の段階で各種の包装紙、包装フィルムなど
に接触して汚染されて黄変したり、あるいは大気中の窒
素酸化物(NOx)などにより変色したりすることが多
発し、その改善が望まれていた。In addition, these fluorescent whitened polyamide fiber products come into contact with various wrapping papers and films during distribution and use, becoming contaminated and yellowing, or exposed to nitrogen oxides (NOx) in the atmosphere. Discoloration frequently occurs due to such factors, and an improvement has been desired.
これらの黄変現象を改善する方法として、従来からポリ
アミドの末端アミノ基を封鎖する黄変防止処理方法が多
数知られており、例えば、ポリアミド繊維を該ポリアミ
ド繊維の末端アミノ基と共有結合する化合物で封鎖する
方法、あるいは末端アミノ基と共有結合する反応基を有
せず、かつスルホン酸基あるいは硫酸エステル基からな
るアニオン活性基を含有する無色の化合物で処理する方
法などが挙げられる。As a method for improving these yellowing phenomena, many anti-yellowing treatment methods have been known that block the terminal amino groups of polyamide. For example, a compound that covalently bonds polyamide fibers with the terminal amino groups of the polyamide fibers or a method of treating with a colorless compound that does not have a reactive group covalently bonded to the terminal amino group and contains an anionic active group consisting of a sulfonic acid group or a sulfuric acid ester group.
しかしながら、これらの黄変防止処理方法はポリアミド
繊維自体の黄変防止効果は認められるものの白瓜は得ら
れず、特に、ナイロン繊維に後次加工として撥水加工ま
たは撥水・防水加工を施して防水布帛を製造した場合に
撥水・防水性能を著しく低下させる欠点を有するもので
あった。However, although these anti-yellowing treatment methods are effective in preventing the yellowing of polyamide fibers themselves, they do not produce white melon. This has the disadvantage that when fabric is manufactured, water repellency and waterproof performance are significantly reduced.
(発明の目的)
本発明は上記の問題点を解消し、優れた耐光性と黄変防
止性を有し、かつ白瓜の高い蛍光色をポリアミド布帛に
付与することを目的に鋭意検討を重ねた結果、ポリアミ
ド布帛に特定の蛍光増白剤と特定の化合物との両化合物
を吸着させることによって本発明を完成するに至ったも
のである。(Purpose of the Invention) The present invention has been made through intensive studies aimed at solving the above-mentioned problems and providing a polyamide fabric with excellent light resistance and anti-yellowing properties, as well as a highly fluorescent color similar to that of white gourd. As a result, the present invention was completed by adsorbing both a specific fluorescent whitening agent and a specific compound onto a polyamide fabric.
(発明の構成)
本発明は、ポリアミド布帛を、一般式(1)[式中、R
′およびR”は同種または異種のものであって、水素原
子または1ルキル基を示す。(Structure of the Invention) The present invention provides a polyamide fabric having the general formula (1) [wherein R
' and R'' are the same or different and represent a hydrogen atom or a monoalkyl group.
Xは酸素原子またはNR(Rは水素原子または低級フル
キル基)を示す。X represents an oxygen atom or NR (R is a hydrogen atom or a lower furkyl group).
■は酸素または硫黄原子あるいはNR(Rは水素原子ま
たは低級1ルキル基)を示し、x、■が同時にいずれも
NR基を示す場合を除く。(2) represents an oxygen or sulfur atom or NR (R is a hydrogen atom or a lower monoalkyl group), except when both x and (2) simultaneously represent an NR group.
また、門は水素原子またはNa、Kを示す。]で表わさ
れる化合物をポリアミド布帛に対して0.3ないし5重
量%、
および一般式(2)
[式中、R9はアルキル基を、門は水素原子またはNa
、にを示す。]
で表わされる化合物をポリアミド布帛に対して0.3な
いし10重量%
を含有する水溶液で、50ないし98℃の温度で浸漬処
理を施して、ポリアミド布帛にこれらの化合物を吸着せ
しめることを特徴とするポリアミド布帛の蛍光増白処理
方法である。Furthermore, the gate represents a hydrogen atom, Na, or K. ] 0.3 to 5% by weight of the compound represented by the polyamide fabric, and general formula (2) [wherein R9 is an alkyl group, and the gate is a hydrogen atom or Na
, is shown. ] A polyamide fabric is subjected to an immersion treatment at a temperature of 50 to 98°C in an aqueous solution containing 0.3 to 10% by weight of the compound represented by the above to adsorb these compounds to the polyamide fabric. This is a fluorescent whitening treatment method for polyamide fabric.
本発明に適用されるポリアミド布帛としてはナイロン6
、ナイロン66などのポリアミド基を有するポリアミド
繊維からなる織物、編物および不織布などが使用できる
。The polyamide fabric applicable to the present invention is nylon 6.
Woven fabrics, knitted fabrics, and nonwoven fabrics made of polyamide fibers having polyamide groups, such as nylon 66, can be used.
本発明に使用する前記一般式(1)で表わされる化合物
は、ポリオレフィン製の材料の蛍光漂白剤として公知の
複素環式スチリル化合物を、常法によりスルホン化する
ことにより得られるもので、該スルホン酸基は遊離のも
のであフてもNaまたはKなどのアルカリ金属塩であっ
ても良い。なお、該化合物中にはスルホン酸基をill
のみ含むものが少量含有されていても差し支えない。The compound represented by the general formula (1) used in the present invention is obtained by sulfonating a heterocyclic styryl compound, which is known as a fluorescent bleaching agent for polyolefin materials, by a conventional method. The acid group may be free or may be an alkali metal salt such as Na or K. Note that the compound contains a sulfonic acid group.
There is no problem even if it contains a small amount of something that only contains
この化合物の使用量はポリアミド布帛に対して0.3な
いし5重量%の範囲が好ましく、水溶液として処理する
。使用量が0.3重量%より少ないと8度が向上せず、
一方、使用量が5重量%を超えても特に8度の向上は朋
待てきない。The amount of this compound used is preferably in the range of 0.3 to 5% by weight based on the polyamide fabric, and the compound is treated as an aqueous solution. If the amount used is less than 0.3% by weight, 8 degrees will not improve,
On the other hand, even if the amount used exceeds 5% by weight, an improvement of 8 degrees cannot be expected.
本発明に使用する前記一般式(2)で表わされる化合物
は、アルキルフェニル・フェニルエーテルをスルホン化
することにより得られるもので、該スルホン酸基は遊離
のものであっても、NaまたはKなどのアルカリ金属塩
であっても良い。なお、該化合物中にはスルホン酸基を
1個のみ含むものが少量含有されていても差し支えない
。The compound represented by the general formula (2) used in the present invention is obtained by sulfonating alkylphenyl phenyl ether, and even if the sulfonic acid group is free, Na or K etc. It may be an alkali metal salt of Note that there is no problem even if the compound contains a small amount of one containing only one sulfonic acid group.
この化合物の使用量はポリアミド布帛に対して0.3な
いし1帽1%の範囲が好ましく、水溶液として処理する
。使用量が0.3重量%より少ないと耐光性および黄変
防止性が向上せず、一方、使用量が10重量%より多い
と耐光性および黄変防止性は向上するが、後次加工にお
ける撥水性を著しく低下させる。The amount of this compound used is preferably in the range of 0.3 to 1% based on the polyamide fabric, and the compound is treated as an aqueous solution. If the amount used is less than 0.3% by weight, the light fastness and yellowing prevention properties will not be improved, while if the amount used is more than 10% by weight, the light resistance and yellowing prevention properties will be improved, but the Significantly reduces water repellency.
上記2種類の化合物による処理条件は、それぞれの化合
物を規定範囲内で含有する水溶液とし、中性または酸性
の条件下で50ないし98℃の温度で処理して吸着させ
る。The conditions for treatment with the above two types of compounds are such that an aqueous solution containing each compound within a specified range is used, and the treatment is performed at a temperature of 50 to 98° C. under neutral or acidic conditions to cause adsorption.
処理液温度を50ないし98℃の温度に昇温することに
よってこれらの化合物の吸着速度を促進し、使用した化
合物の殆んど全量をポリアミド布帛に吸着させることが
出来る。なお、酸性下で処理する場合には酢酸などを添
加してpi(を3ないし5の範囲に調整するのが好まし
い。By raising the temperature of the treatment solution to a temperature of 50 to 98°C, the rate of adsorption of these compounds can be accelerated and almost all of the compounds used can be adsorbed onto the polyamide fabric. In addition, when processing under acidic conditions, it is preferable to add acetic acid or the like to adjust pi to a range of 3 to 5.
処理方法としては任意の方法によって吸着させることが
できるが、通常の染色加工に適用される浸染法により容
易に処理できる。なお、該処理にあたっては柔軟剤、帯
電防止剤などを併用しても差し支えない。Adsorption can be carried out by any method, but it can be easily treated by a dip dyeing method that is commonly applied to dyeing processes. In this treatment, a softener, an antistatic agent, etc. may be used in combination.
なお、本発明の処理方法においては、ポリアミド布帛に
前記の一般式(1)で表わされる化合物の水溶液を用い
て吸着処理を施した後、次いで前記の一般式(2)で表
わされる化合物の水溶液を用いて吸着処理を施すことも
できるが、両化合物を含有する水溶液を用いて同時に吸
着処理を施すのが経済的である。In addition, in the treatment method of the present invention, after adsorption treatment is performed on the polyamide fabric using an aqueous solution of the compound represented by the above general formula (1), then an aqueous solution of the compound represented by the above general formula (2) is applied. Although the adsorption treatment can be performed using an aqueous solution containing both compounds, it is more economical to perform the adsorption treatment at the same time using an aqueous solution containing both compounds.
(作用)
本発明の蛍光増白方法は、ポリアミド布帛に2種類の特
定の化合物すなわちスルホン酸基を含有する複素環式ス
チリル化合物(1)とスルホン酸基を含有するアルキル
フェニル・フェニルエーテル化合物(2)とを処理、吸
着させるが、これによって優れた耐光性および黄変防止
性を有する8度の高い蛍光色のポリアミド布帛を得るこ
とできる。(Function) The fluorescent whitening method of the present invention involves adding two specific compounds to a polyamide fabric, namely, a heterocyclic styryl compound (1) containing a sulfonic acid group and an alkylphenyl phenyl ether compound (1) containing a sulfonic acid group. 2) is treated and adsorbed, thereby making it possible to obtain a highly fluorescent polyamide fabric of 8 degrees Celsius, which has excellent light resistance and anti-yellowing properties.
この作用機構は不詳であるが、これらの化合物の化学構
造に起因すると推定され、化合物中のスルホン酸基がポ
リアミド布帛の末端アミノ基に対してイオン結合により
吸着し、かつ両化合物の相乗作用により著効を示すもの
と見なされる。The mechanism of this action is unknown, but it is presumed to be due to the chemical structure of these compounds, in which the sulfonic acid groups in the compounds adsorb to the terminal amino groups of the polyamide fabric through ionic bonds, and due to the synergistic action of both compounds. It is considered to be an indication of effectiveness.
すなわち、ポリアミド布帛に前記化合物(1)を単独で
処理、吸着させた場合は従来の蛍光増白剤で処理、吸着
させた場合よりも耐光性の良好な8度を付与できるが不
充分であり、かつ黄変防止性に乏しく、一方、前記化合
物(2)を単独で処理、吸着させた場合は黄変防止性は
良好であるが8度が乏しい。That is, when a polyamide fabric is treated and adsorbed with the compound (1) alone, it is possible to impart better light resistance of 8 degrees than when treated with a conventional fluorescent brightener, but it is insufficient. , and the yellowing prevention property is poor. On the other hand, when the compound (2) is treated and adsorbed alone, the yellowing prevention property is good but the 8 degree is poor.
また、本発明に使用する化合物(1)の代わりに通常用
いられる蛍光増白剤を使用し、本発明に使用する化合物
(2)と併用して処理を施した場合は黄変防止性は向上
するが、8度および耐光性が不充分であり、一方、前記
化合物(2)の代わりに通常用いられる黄変防止処理剤
を使用し、前記化合物(1)と併用して処理を施した場
合は8度および耐光性は若干向上するが不充分であり、
かつ、後次加工として撥水処理を施した場合に撥水性を
著しく低下させる。Furthermore, when a commonly used fluorescent brightener is used instead of compound (1) used in the present invention and treated in combination with compound (2) used in the present invention, the yellowing prevention property is improved. However, when the 8 degree and light resistance are insufficient, and on the other hand, a commonly used anti-yellowing treatment agent is used instead of the compound (2) and treated in combination with the compound (1). is 8 degrees and the light resistance is slightly improved, but it is insufficient.
Moreover, when a water repellent treatment is applied as a subsequent processing, the water repellency is significantly reduced.
以上のことから、本発明の蛍光増白処理方法はポリアミ
ド布帛にイオン的に結合した2種類の特定の化合物が機
構は詳らかでないが相互に補助作用して顕著な効果を示
すものと判断する。From the above, it is concluded that the fluorescent whitening treatment method of the present invention exhibits a remarkable effect due to the two types of specific compounds ionically bonded to the polyamide fabric acting as mutual aids, although the mechanism is not clear.
以下、本発明を実施例により説明する。The present invention will be explained below using examples.
(実施例1)
70dナイロンタフタ(密度210本/インチ)をオー
ブンソーバーにより70℃で精練を行う。(Example 1) 70d nylon taffeta (density 210 pieces/inch) is scoured at 70°C using an oven soaker.
次いで、下記の化合物(a)
をナイロンタフタの重量に対して2重量%、および下記
の化合物(b)
をナイロンタフタの重量に対して3重量%、酢酸2g/
Lを水に溶解して調製した処理液(浴比1 :30)に
ナイロンタフタを浸漬し、ジッガー染色機を用いて85
℃で30分間処理し、水洗、乾燥して蛍光増白されたポ
リアミド布帛を得た。Next, the following compound (a) was added at 2% by weight based on the weight of the nylon taffeta, the following compound (b) was added at 3% by weight based on the weight of the nylon taffeta, and acetic acid 2g/
Nylon taffeta was immersed in a treatment solution prepared by dissolving L in water (bath ratio 1:30), and dyed using a jigger dyeing machine.
C. for 30 minutes, washed with water, and dried to obtain a fluorescent whitened polyamide fabric.
この製品の物性を第1表に示す。The physical properties of this product are shown in Table 1.
(比較例1)
実施例1と同一のナイロンタフタを精練処理した後、L
E U COP HOR−P A F K (SAN
DOZ)をナイロンタフタの重量に対して21Effi
%、酢酸2g/Lを水に溶解して調製した処理液(浴比
1:30)に浸漬し、ジッガー染色機を用いて85℃で
30分間処理し、水洗、乾燥して蛍光増白されたポリア
ミド布帛を得た。(Comparative Example 1) After scouring the same nylon taffeta as in Example 1, L
E U COP HOR-P A F K (SAN
DOZ) to 21Effi for the weight of nylon taffeta.
%, acetic acid 2g/L dissolved in water (bath ratio 1:30), treated at 85℃ for 30 minutes using a jigger dyeing machine, washed with water, dried and fluorescent whitened. A polyamide fabric was obtained.
このものの物性を第1表に示す。The physical properties of this product are shown in Table 1.
(参考例1)
実施例1と同一のナイロンタフタを精練処理した後、実
施例1で使用した化合物(a)をナイロンタフタの重量
に対して2重量%、酢酸2g/Lを水に溶解して調製し
た処理液(浴比1:30)に浸漬し、ジッガー染色機を
用いて85℃で30分間処理し、水洗、乾燥して蛍光増
白されたポリアミド布帛を得た。このものの物性を第1
表に示す。(Reference Example 1) After scouring the same nylon taffeta as in Example 1, 2% by weight of the compound (a) used in Example 1 and 2 g/L of acetic acid were dissolved in water based on the weight of the nylon taffeta. The polyamide fabric was immersed in a treatment solution (bath ratio 1:30) prepared as described above, treated at 85°C for 30 minutes using a jigger dyeing machine, washed with water, and dried to obtain a fluorescent whitened polyamide fabric. The physical properties of this thing are
Shown in the table.
(参考例2)
実施例1と同一のナイロンタフタを精練処理した後、L
EUCOPHOR−PAFK (SANDOZ)をナイ
ロンタフタの重量に対して2!1Ef1%、および実施
例1で使用した化合物(b)をナイロンタフタの重量に
対して3重量%、酢*2g/Lを水に溶解して調製した
処理液(浴比1 :30)に浸漬し、ジッガー染色機を
用いて85℃で30分間処理し、水洗、乾燥して蛍光増
白されたポリアミド布帛を得た。(Reference Example 2) After scouring the same nylon taffeta as in Example 1, L
EUCOPHOR-PAFK (SANDOZ) at 2!1Ef1% based on the weight of nylon taffeta, compound (b) used in Example 1 at 3% by weight based on the weight of nylon taffeta, and vinegar*2 g/L in water. It was immersed in a treatment solution (bath ratio 1:30) prepared by dissolving it, treated at 85° C. for 30 minutes using a jigger dyeing machine, washed with water, and dried to obtain a fluorescent whitened polyamide fabric.
このものの物性を第1表に示す。The physical properties of this product are shown in Table 1.
第1表 但し、試験方法は下記に準じて実施した。Table 1 However, the test method was conducted according to the following.
耐光性: J l5L−0842
NOx変色: J I 5L−0855バニリン汚染度
:
(1)試料5gを採取し、これをバニリン0.3%水溶
液(バニリンは特級試薬を使用)に30℃で浸漬し、1
0分間を要して50℃まで昇温しで浸漬処理する。Light resistance: J I5L-0842 NOx discoloration: J I5L-0855 Vanillin contamination level: (1) Collect 5 g of sample and immerse it in a 0.3% vanillin aqueous solution (a special grade reagent is used for vanillin) at 30°C. ,1
The temperature was raised to 50° C. over a period of 0 minutes for immersion treatment.
(2〉充分に水洗した後、乾燥する。(2> After thoroughly washing with water, dry it.
(3)上記の処理を施した試料の汚染度(黄変度)をグ
レースケールにより判定する。(3) Determine the degree of contamination (yellowing degree) of the sample subjected to the above treatment using a gray scale.
(発明の効果)
本発明は以上のようなものであり、ポリアミド布帛に2
種類の特定の化合物を吸着せしめたことにより、優れた
耐光性および黄変防止性を有する8度の高い蛍光色のポ
リアミド布帛を得ることできた。(Effects of the Invention) The present invention is as described above, and the polyamide fabric has two
By adsorbing certain kinds of compounds, it was possible to obtain a highly fluorescent polyamide fabric of 8 degrees Celsius, which has excellent light resistance and anti-yellowing properties.
この蛍光増白処理を施したポリアミド布帛は耐熱性およ
び耐洗濯性に優れ、洗濯3回後も8度および物性は変化
がなかった。The polyamide fabric subjected to this fluorescent whitening treatment had excellent heat resistance and washing resistance, and its physical properties remained unchanged at 8 degrees Celsius even after washing three times.
また、この蛍光増白処理を施したポリアミド布帛は後次
加工として撥水加工を施した場合に撥水性を殆ど阻害せ
ず、従って、優れた耐光性および黄変防止性を有する8
度の高い防水性のポリアミド布帛を得ることができる利
点がある。In addition, when this fluorescent whitening treated polyamide fabric is subjected to a water repellent treatment as a subsequent treatment, its water repellency is hardly inhibited, and therefore it has excellent light fastness and anti-yellowing properties.
There is an advantage that a highly waterproof polyamide fabric can be obtained.
以上that's all
Claims (1)
て、水素原子またはアルキル基を示す。 Xは酸素原子またはNR(Rは水素原子または低級アル
キル基)を示す。 Yは酸素または硫黄原子あるいはNR(Rは水素原子ま
たは低級アルキル基)を示し、X、Yが同時にいずれも
NR基を示す場合を除く。 また、Mは水素原子またはNa、Kを示す。]で表わさ
れる化合物をポリアミド布帛に対して0.3ないし5重
量%、 および一般式(2) ▲数式、化学式、表等があります▼(2) [式中、R_1はアルキル基を、Mは水素原子またはN
a、Kを示す。] で表わされる化合物をポリアミド布帛に対して0.3な
いし10重量% を含有する水溶液で、50ないし98℃の温度で浸漬処
理を施して、ポリアミド布帛にこれらの化合物を吸着せ
しめることを特徴とするポリアミド布帛の蛍光増白処理
方法。[Claims] A polyamide fabric is made of a polyamide fabric having the general formula (1) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(1) [In the formula, R' and R'' are the same or different types, and are hydrogen atoms or represents an alkyl group. 0.3 to 5% by weight of a compound represented by the formula (M represents a hydrogen atom or Na or K) based on the polyamide fabric, and general formula (2) ▲Math. , chemical formulas, tables, etc.▼(2) [In the formula, R_1 is an alkyl group, M is a hydrogen atom or N
a, K is shown. ] A polyamide fabric is subjected to an immersion treatment at a temperature of 50 to 98°C in an aqueous solution containing 0.3 to 10% by weight of the compound represented by the above to adsorb these compounds to the polyamide fabric. A fluorescent whitening treatment method for polyamide fabric.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2102084A JPH042880A (en) | 1990-04-18 | 1990-04-18 | Fluorescent whitening treatment of polyamide web |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2102084A JPH042880A (en) | 1990-04-18 | 1990-04-18 | Fluorescent whitening treatment of polyamide web |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH042880A true JPH042880A (en) | 1992-01-07 |
Family
ID=14317912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2102084A Pending JPH042880A (en) | 1990-04-18 | 1990-04-18 | Fluorescent whitening treatment of polyamide web |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH042880A (en) |
-
1990
- 1990-04-18 JP JP2102084A patent/JPH042880A/en active Pending
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