JPH04286948A - Constituent concentration measuring device - Google Patents

Constituent concentration measuring device

Info

Publication number
JPH04286948A
JPH04286948A JP7441291A JP7441291A JPH04286948A JP H04286948 A JPH04286948 A JP H04286948A JP 7441291 A JP7441291 A JP 7441291A JP 7441291 A JP7441291 A JP 7441291A JP H04286948 A JPH04286948 A JP H04286948A
Authority
JP
Japan
Prior art keywords
measured
concentration
measuring device
admittance
high frequency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7441291A
Other languages
Japanese (ja)
Inventor
Masuo Yamaguchi
山口 益男
Masayuki Ito
正行 伊藤
Akira Takai
皓 高井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHOKUHIN SANGYO ONLINE SENSOR GIJUTSU KENKYU KUMIAI
Original Assignee
SHOKUHIN SANGYO ONLINE SENSOR GIJUTSU KENKYU KUMIAI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHOKUHIN SANGYO ONLINE SENSOR GIJUTSU KENKYU KUMIAI filed Critical SHOKUHIN SANGYO ONLINE SENSOR GIJUTSU KENKYU KUMIAI
Priority to JP7441291A priority Critical patent/JPH04286948A/en
Publication of JPH04286948A publication Critical patent/JPH04286948A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To enable a concentration of water contents and constituents of a substance to be measured highly accurately by reducing influence of temperature. CONSTITUTION:High-frequency and low-frequency constant voltage signals are supplied to an object to be measured. Current which flows to the object to be measured is measured along with this voltage signal, admittance at the high frequency and low frequency is calculated from the measured current value and then the difference is calculated. A signal corresponding to the concentration of water contents and constituents is output based on the difference.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、オンライン用の水分や
成分濃度計として用いられ、被測定物中に含まれる成分
、例えば水分等の濃度の測定を行なう成分濃度測定装置
に関し、特に電気的測定方法における導電率を含むアド
ミッタンス測定による成分濃度測定装置に関するもので
ある。
[Field of Industrial Application] The present invention relates to a component concentration measuring device that is used as an online moisture or component concentration meter to measure the concentration of components, such as moisture, contained in an object to be measured. The present invention relates to a component concentration measuring device that uses admittance measurement including conductivity in a measuring method.

【0002】0002

【従来の技術】被測定物中に含まれる水分や成分の濃度
を測定する装置として成分濃度測定装置があり、特にこ
の装置を用いた電気的方法による水分や成分の濃度の測
定方法としては、誘電率測定による方法あるいは導電率
を含むアドミッタンス測定による方法等が知られている
BACKGROUND OF THE INVENTION There is a component concentration measuring device as a device for measuring the concentration of moisture or components contained in an object to be measured. A method based on permittivity measurement, a method based on admittance measurement including conductivity, etc. are known.

【0003】ここで、上述した方法のうちアドミッタン
ス測定による成分濃度測定について説明する。被測定物
をアドミッタンスとして考える場合、一般に図4に示す
等価回路で表わすことができる。さらに、これをベクト
ル表示すると図5のようになる。そして、今、被測定物
の水分または成分の濃度が変化した場合、コンダクタン
スGおよびサセプタンスBの大きさが変化し、総合的に
アドミッタンスの絶対値|Y|=(G2 +B2 )1
/2 が変化する。これより、アドミッタンスの絶対値
|Y|を測定することで被測定物の水分や成分の濃度を
求めることができる。
[0003] Among the above-mentioned methods, component concentration measurement by admittance measurement will now be explained. When considering the object to be measured as an admittance, it can generally be represented by an equivalent circuit shown in FIG. Furthermore, when this is expressed as a vector, it becomes as shown in FIG. Now, if the concentration of water or components in the object to be measured changes, the magnitudes of conductance G and susceptance B will change, and the overall absolute value of admittance |Y|=(G2 +B2)1
/2 changes. From this, by measuring the absolute value of admittance |Y|, the concentration of moisture or components in the object to be measured can be determined.

【0004】すなわち、被測定物への印加電圧をE、被
測定物のアドミッタンスをYとすると、被測定物を流れ
る電流値IはI=Y・Eとなり、各要素の絶対値は|I
|=|Y|・|E|と表わされ、一定振幅の電圧を被測
定物に印加すれば、流れる電流値からアドミッタンスの
絶対値を知ることができる。
That is, if the voltage applied to the object to be measured is E and the admittance of the object to be measured is Y, then the current value I flowing through the object to be measured is I=Y・E, and the absolute value of each element is |I
It is expressed as |=|Y|·|E|, and by applying a voltage with a constant amplitude to the object to be measured, the absolute value of admittance can be determined from the flowing current value.

【0005】[0005]

【発明が解決しようとする課題】ところで、上述した測
定方法を適用した装置において、コンダクタンスGは被
測定物の温度によって大きく変化することが知られてお
り、そのため温度補正を行なう必要が生ずるという問題
があった。また、前述した誘電率測定による方法を適用
した装置では、絶縁物中の低水分測定等には適している
が、高水分域や導電性物質中の水分等の成分測定が困難
であるという問題があった。そこで、本発明は上述した
問題点に鑑みてなされたものであって、その目的は、物
質の水分や成分の濃度の測定を温度による影響を小さく
して高精度に行なえる成分濃度測定装置を提供すること
にある。
[Problems to be Solved by the Invention] However, in a device to which the above-mentioned measurement method is applied, it is known that the conductance G changes greatly depending on the temperature of the object to be measured, and therefore there is a problem in that it is necessary to perform temperature correction. was there. In addition, although the device applying the above-mentioned dielectric constant measurement method is suitable for measuring low moisture content in insulating materials, it is difficult to measure components such as moisture in high moisture areas or conductive materials. was there. SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and an object of the present invention is to provide a component concentration measuring device that can measure the moisture content of a substance and the concentration of components with high precision while minimizing the influence of temperature. It is about providing.

【0006】[0006]

【課題を解決するための手段】上記目的を達成するため
、本発明による成分濃度測定装置は、被測定物中に含ま
れる水分や成分の濃度を測定する成分濃度測定装置にお
いて、前記被測定物に対して高周波数および低周波数に
よる一定の電圧信号を供給する信号供給部と、前記電圧
信号の供給に基づいて前記被測定物に流れる電流値を測
定する測定部と、測定した電流値に基づき前記高周波数
および低周波数におけるアドミッタンスを算出してその
差分を演算し、この差分に基づいて前記水分や成分の濃
度に対応する信号を出力する演算部とを備えたことを特
徴としている。
[Means for Solving the Problems] In order to achieve the above object, the component concentration measuring device according to the present invention is a component concentration measuring device for measuring the concentration of water or components contained in a measured object. a signal supply unit that supplies a constant voltage signal at a high frequency and a low frequency to The present invention is characterized by comprising a calculation unit that calculates the admittance at the high frequency and the low frequency, calculates the difference between the admittances, and outputs a signal corresponding to the concentration of the water or component based on this difference.

【0007】[0007]

【作用】信号供給部は高周波数および低周波数による一
定の電圧信号を被測定物に供給する。信号供給部により
被測定物に電圧信号が供給されると、測定部がこの電圧
信号の供給に基づいて被測定物に流れる電流値を測定す
る。そして、演算部では測定部が測定した電流値に基づ
いて高周波数および低周波数におけるアドミッタンスを
算出し、さらに算出したアドミッタンスの差分を演算し
て水分や成分の濃度に対応する信号を出力する。
[Operation] The signal supply section supplies a constant voltage signal of high frequency and low frequency to the object to be measured. When a voltage signal is supplied to the object to be measured by the signal supply section, the measuring section measures the value of the current flowing through the object to be measured based on the supply of this voltage signal. Then, the calculation section calculates the admittance at high frequency and low frequency based on the current value measured by the measurement section, further calculates the difference between the calculated admittances, and outputs a signal corresponding to the concentration of water or components.

【0008】[0008]

【実施例】図1は本発明による成分濃度測定装置の一実
施例を示す概略構成図である。この実施例による成分濃
度測定装置は、アドミッタンス測定による方法を適用し
たもので、信号供給部1、測定部2、演算部3を備えて
概略構成され、2つの周波数によりアドミッタンス差を
もって被測定物中に含まれる水分や成分の濃度の測定を
行なっている。すなわち、一定振幅の電圧信号を被測定
物に印加し、この印加された電圧信号によって被測定物
に流れる電流値から2つの周波数fH ,fL による
被測定物のアドミッタンスを求め、これらアドミッタン
スの差分演算を行なっている。
DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a schematic diagram showing an embodiment of a component concentration measuring device according to the present invention. The component concentration measuring device according to this embodiment applies a method based on admittance measurement, and is roughly configured with a signal supply section 1, a measurement section 2, and a calculation section 3. We measure the concentration of moisture and components contained in That is, a voltage signal with a constant amplitude is applied to the measured object, the admittance of the measured object at two frequencies fH and fL is calculated from the value of the current flowing through the measured object due to the applied voltage signal, and the difference between these admittances is calculated. is being carried out.

【0009】信号供給部1は高周波数側発振回路4、低
周波数側発振回路5、加算器6、電流バッファ7、電圧
印加電極8を備えて構成されている。高周波数側発振回
路4は100kHz〜数10MHzの発振周波数fH 
を有する信号を、また、低周波数側発振回路5はDC〜
数100kHzの発振周波数fL を有する信号を加算
器6に出力している。加算器6は高周波数側発振回路4
および低周波数側発振回路5からの信号をミキシングし
て電流バッファ7に供給し、電流バッファ7では供給さ
れた電圧信号Eに基づいて所定の電圧を電圧印加電極8
を通じて被測定物に印加している。
The signal supply section 1 includes a high frequency oscillation circuit 4, a low frequency oscillation circuit 5, an adder 6, a current buffer 7, and a voltage application electrode 8. The high frequency side oscillation circuit 4 has an oscillation frequency fH of 100 kHz to several tens of MHz.
In addition, the low frequency side oscillation circuit 5 receives a signal having DC to
A signal having an oscillation frequency fL of several 100 kHz is output to the adder 6. Adder 6 is high frequency side oscillation circuit 4
and the signals from the low frequency side oscillation circuit 5 are mixed and supplied to the current buffer 7, and the current buffer 7 applies a predetermined voltage to the voltage application electrode 8 based on the supplied voltage signal E.
The voltage is applied to the object to be measured through the

【0010】測定部2は電流測定電極9、電流測定回路
10、高周波数側通過フィルタ11、低周波数側通過フ
ィルタ12、高周波数側変換回路13、低周波数側変換
回路14を備えて構成されている。電流測定電極9は印
加された電圧に基づいて被測定物に流れる電流を取り出
すもので、この電極9によって取り出された電流は電流
測定回路10に検出される。電流測定回路10は検出し
た電流を所定レベルの電圧信号に変換して後段の各フィ
ルタ11,12側に出力している。高周波数側通過フィ
ルタ11は電流測定回路10から供給された電圧信号の
うち高周波数、例えば100kHz〜数10MHzの信
号を高周波数側変換回路13に出力している。また、低
周波数側通過フィルタ12は電流測定回路10から供給
された電圧信号のうち低周波数、例えばDC〜数100
kHzの信号を低周波数側変換回路14に出力している
。高周波数側変換回路13および低周波数側変換回路1
4は各フィルタ11,12からの電圧信号を直流信号に
変換して演算部3に出力している。
The measuring section 2 includes a current measuring electrode 9, a current measuring circuit 10, a high frequency side pass filter 11, a low frequency side pass filter 12, a high frequency side conversion circuit 13, and a low frequency side conversion circuit 14. There is. The current measuring electrode 9 extracts the current flowing through the object to be measured based on the applied voltage, and the current extracted by the electrode 9 is detected by the current measuring circuit 10. The current measuring circuit 10 converts the detected current into a voltage signal of a predetermined level and outputs the voltage signal to the filters 11 and 12 at the subsequent stage. The high frequency side pass filter 11 outputs a high frequency signal of the voltage signal supplied from the current measurement circuit 10, for example, a signal of 100 kHz to several tens of MHz to the high frequency side conversion circuit 13. Further, the low frequency side pass filter 12 selects a low frequency signal from among the voltage signals supplied from the current measuring circuit 10, for example, from DC to several hundred.
A kHz signal is output to the low frequency side conversion circuit 14. High frequency side conversion circuit 13 and low frequency side conversion circuit 1
4 converts the voltage signal from each filter 11, 12 into a DC signal and outputs it to the calculation section 3.

【0011】演算部3は測定部2における各変換回路1
3,14からの信号に基づいて高周波数fH および低
周波数fL におけるアドミッタンスの絶対値|YH 
|,|YL |を算出してそのアドミッタンス差Δ|Y
|=|YH |−|YL |を演算している。そして、
この差分Δ|Y|に基づいて図3に示すような水分や成
分の濃度に対応する信号を出力している。なお、図3は
上述した成分濃度測定装置を魚肉すり身用の水分センサ
として応用した場合における水分値と出力値の関係の一
例を示している。
[0011] The calculation unit 3 includes each conversion circuit 1 in the measurement unit 2.
Based on the signals from 3 and 14, the absolute value of admittance at high frequency fH and low frequency fL |YH
|, |YL | and their admittance difference Δ|Y
|=|YH |−|YL | is being calculated. and,
Based on this difference Δ|Y|, a signal corresponding to the concentration of water and components as shown in FIG. 3 is output. Note that FIG. 3 shows an example of the relationship between the moisture value and the output value when the above-described component concentration measuring device is applied as a moisture sensor for minced fish meat.

【0012】ここで、誘電分散域を避けての高周波数f
H と低周波数fL に対する被測定物のアドミッタン
スの絶対値|YH |,|YL |は次式で表わされる
。 |YH |=(G2 +BH 2)1/2|YL |=
(G2 +BL 2)1/2なお、Gは周波数に依存し
ないコンダクタンスで、BH ,BL はfH ,fL
 のそれぞれにおけるサセプタンス分であり、BH >
BL 、すなわち|YH |>|YL |とする。
Here, the high frequency f avoiding the dielectric dispersion region
The absolute values of the admittance of the object to be measured with respect to H and the low frequency fL are expressed by the following equations. |YH |=(G2 +BH 2)1/2 |YL |=
(G2 + BL 2) 1/2 Note that G is the frequency-independent conductance, and BH and BL are fH and fL
is the susceptance component in each of BH >
BL, that is, |YH |>|YL |.

【0013】従って、|YH |と|YL |との差分
Δ|Y|は次式のように表わせる。 Δ|Y|=|YH |−|YL |=(G2 +BH 
2)1/2 −(G2 +BL 2)1/2   ここ
で、周波数fH ,fL の大きさによりBH ,BL
 の温度係数は異なる大きさを持たせることができる。 周波数fH ,fL を適当な大きさに選定することに
より、|YH |と|YL |の温度係数をほぼ等しい
大きさにすると、両者の差分Δ|Y|を求めることによ
り、温度係数を消去することができる。また、水分や成
分の濃度の変化に対しては、コンダクタンスあるいはキ
ャパシタンスCが変化するが、BH >BL なので|
YH|,|YL |の変化の大きさは異なりΔ|Y|が
変化することになる。従って、Δ|Y|を測定すること
により被測定物の水分や成分の濃度の測定を行なうこと
ができる。
Therefore, the difference Δ|Y| between |YH| and |YL| can be expressed as follows. Δ|Y|=|YH |−|YL |=(G2 +BH
2) 1/2 - (G2 + BL 2) 1/2 Here, depending on the magnitude of frequencies fH and fL, BH and BL
The temperature coefficient of can have different magnitudes. By selecting appropriate frequencies fH and fL, the temperature coefficients of |YH| and |YL| can be made approximately equal, and the temperature coefficients can be eliminated by finding the difference Δ|Y| between the two. be able to. Also, conductance or capacitance C changes in response to changes in the concentration of water or components, but since BH > BL |
The magnitude of change in YH| and |YL| is different, and Δ|Y| changes. Therefore, by measuring Δ|Y|, it is possible to measure the concentration of moisture and components in the object to be measured.

【0014】次に、上述した構成による成分濃度測定装
置の動作について説明する。まず、被測定物の水分や成
分の濃度の状態に応じて高周波数および低周波数を設定
し、信号供給部1において設定した周波数に基づく一定
の電圧信号を電圧印加電極8を介して被測定物に印加す
る。被測定物に対して電圧信号が印加されると、これに
よって被測定物に電流が流れ、この電流は測定部2によ
って測定される。すなわち、電流は電流測定電極9を介
して電流測定回路10により測定された後、所定レベル
の電圧信号に変換され、高周波数通過フィルタ11ある
いは低周波数通過フィルタ12を通して高周波数側変換
回路13あるいは低周波数側変換回路14に出力される
。そして、各変換回路13,14では供給された電圧信
号を直流信号に変換して演算部3に出力している。演算
部3では各変換回路13,14からの信号に基づいて高
周波数fH および低周波数fL のそれぞれにおける
アドミッタンスの絶対値|YH |,|YL |を算出
してこれらのアドミッタンス差Δ|Y|を演算し、水分
や成分の濃度に対応する電圧信号を出力する。
Next, the operation of the component concentration measuring device having the above-described configuration will be explained. First, a high frequency and a low frequency are set according to the concentration of water and components of the object to be measured, and a constant voltage signal based on the set frequency is applied to the object to be measured via the voltage application electrode 8 in the signal supply section 1. to be applied. When a voltage signal is applied to the object to be measured, a current flows through the object to be measured, and this current is measured by the measuring section 2. That is, the current is measured by the current measuring circuit 10 via the current measuring electrode 9, and then converted into a voltage signal of a predetermined level, passed through the high frequency pass filter 11 or the low frequency pass filter 12, and then sent to the high frequency side conversion circuit 13 or the low frequency side conversion circuit 13. It is output to the frequency side conversion circuit 14. Each of the conversion circuits 13 and 14 converts the supplied voltage signal into a DC signal and outputs it to the calculation section 3. The calculation unit 3 calculates the absolute values of admittance |YH |, |YL | at each of the high frequency fH and low frequency fL based on the signals from each conversion circuit 13 and 14, and calculates the admittance difference Δ |Y| It calculates and outputs a voltage signal corresponding to the concentration of water and components.

【0015】従って、上述した装置では高周波数および
低周波数における被測定物のアドミッタンス差Δ|Y|
を測定することにより被測定物の水分や成分の濃度を温
度の影響を十分小さくして測定することができる。
Therefore, in the above-mentioned apparatus, the admittance difference Δ|Y|
By measuring this, it is possible to measure the concentration of moisture and components in the object to be measured while sufficiently minimizing the influence of temperature.

【0016】次に、図2は上述した成分濃度測定装置を
パイプライン構造の検出装置に組込んで構成した例を示
している。この装置はステンレスパイプ15の両端に他
のパイプと接続される接続用のフランジ16が形成され
、ステンレスパイプ15の略中央の内壁面に電圧印加電
極8および電流測定電極9を表出させた状態で絶縁物1
7に挾持されて上述した成分濃度測定装置がパイプ連結
されたものである。そして、ステンレスパイプ15内を
流れてくる魚肉のすり身等の被測定物中に含まれる水分
や成分の濃度の測定を上述した方法により行なっている
。以上説明した成分濃度測定装置は、特に液状およびス
ラリー状物質中の水分や成分の濃度の測定に応用でき、
例えば魚肉すり身および練り製品の製造工程用水分計等
を含む広範囲に使用することができる。
Next, FIG. 2 shows an example in which the above-described component concentration measuring device is incorporated into a detection device having a pipeline structure. In this device, connecting flanges 16 for connecting to other pipes are formed at both ends of a stainless steel pipe 15, and a voltage applying electrode 8 and a current measuring electrode 9 are exposed on the inner wall surface at approximately the center of the stainless steel pipe 15. Insulator 1
The above-mentioned component concentration measuring device is held between the tubes 7 and connected by a pipe. The concentration of moisture and components contained in the object to be measured, such as minced fish, flowing through the stainless steel pipe 15 is measured by the method described above. The component concentration measuring device described above can be applied particularly to measuring the concentration of moisture and components in liquid and slurry materials.
For example, it can be used in a wide range of applications, including moisture meters for the manufacturing process of fish paste and paste products.

【0017】[0017]

【発明の効果】以上説明したように、本発明の成分濃度
測定装置によれば、高周波数と低周波数とのアドミッタ
ンス差を測定することで温度係数による影響を小さくし
て水分や成分の濃度の測定を高精度に行なうことができ
る。
Effects of the Invention As explained above, according to the component concentration measuring device of the present invention, by measuring the admittance difference between high and low frequencies, the influence of the temperature coefficient can be reduced and the concentration of water and components can be measured. Measurements can be made with high precision.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明による成分濃度測定装置の一実施例を示
す概略構成図
[FIG. 1] A schematic configuration diagram showing an embodiment of a component concentration measuring device according to the present invention.

【図2】同成分濃度測定装置をパイプライン構造の検出
装置に組込んで構成した例を示す図
[Figure 2] A diagram showing an example of a configuration in which the same component concentration measuring device is incorporated into a detection device with a pipeline structure.

【図3】同成分濃度測定装置を魚肉すり身用の水分セン
サとして応用した場合における水分値と出力値の関係の
一例を示す図
[Figure 3] A diagram showing an example of the relationship between moisture value and output value when the same component concentration measuring device is applied as a moisture sensor for minced fish meat.

【図4】被測定物をアドミッタンスとして考えた場合の
等価回路を示す図
[Figure 4] Diagram showing an equivalent circuit when the object to be measured is considered as an admittance.

【図5】図4に示した等価回路をベクトル表示によって
表現した図
[Figure 5] A diagram representing the equivalent circuit shown in Figure 4 using vector representation.

【符号の説明】[Explanation of symbols]

1  信号供給部,                
  2  測定部3  演算部,          
            4  高周波数側発振回路 5  低周波数側発振回路,        10  
電流測定回路13  高周波数側変換回路,     
   14  低周波数側変換回路
1 signal supply section,
2 measurement section 3 calculation section,
4 High frequency side oscillation circuit 5 Low frequency side oscillation circuit, 10
Current measurement circuit 13 High frequency side conversion circuit,
14 Low frequency side conversion circuit

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  被測定物中に含まれる水分や成分の濃
度を測定する成分濃度測定装置において、前記被測定物
に対して高周波数および低周波数による一定の電圧信号
を供給する信号供給部と、前記電圧信号の供給に基づい
て前記被測定物に流れる電流値を測定する測定部と、測
定した電流値に基づき前記高周波数および低周波数にお
けるアドミッタンスを算出してその差分を演算し、この
差分に基づいて前記水分や成分の濃度に対応する信号を
出力する演算部とを備えたことを特徴とする成分濃度測
定装置。
1. A component concentration measuring device for measuring the concentration of water or components contained in an object to be measured, comprising: a signal supply section that supplies a constant voltage signal at a high frequency and a low frequency to the object to be measured; , a measurement unit that measures the value of current flowing through the object to be measured based on the supply of the voltage signal; and a measurement unit that calculates the admittance at the high frequency and the low frequency based on the measured current value and calculates the difference between the admittances. A component concentration measuring device comprising: a calculation section that outputs a signal corresponding to the concentration of the moisture or component based on the concentration of the moisture or component.
JP7441291A 1991-03-15 1991-03-15 Constituent concentration measuring device Pending JPH04286948A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7441291A JPH04286948A (en) 1991-03-15 1991-03-15 Constituent concentration measuring device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7441291A JPH04286948A (en) 1991-03-15 1991-03-15 Constituent concentration measuring device

Publications (1)

Publication Number Publication Date
JPH04286948A true JPH04286948A (en) 1992-10-12

Family

ID=13546457

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7441291A Pending JPH04286948A (en) 1991-03-15 1991-03-15 Constituent concentration measuring device

Country Status (1)

Country Link
JP (1) JPH04286948A (en)

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