JPH0426160Y2 - - Google Patents
Info
- Publication number
- JPH0426160Y2 JPH0426160Y2 JP1988019593U JP1959388U JPH0426160Y2 JP H0426160 Y2 JPH0426160 Y2 JP H0426160Y2 JP 1988019593 U JP1988019593 U JP 1988019593U JP 1959388 U JP1959388 U JP 1959388U JP H0426160 Y2 JPH0426160 Y2 JP H0426160Y2
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- color
- hue
- semi
- reversible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 7
- 238000004040 coloring Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 claims 1
- 239000000975 dye Substances 0.000 description 26
- 239000003973 paint Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- -1 aromatic carboxylic acids Chemical class 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 210000001508 eye Anatomy 0.000 description 5
- 239000000976 ink Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 210000000744 eyelid Anatomy 0.000 description 4
- 210000004209 hair Anatomy 0.000 description 4
- KKIJZWOPMWEAIV-UHFFFAOYSA-N 2,2-dimethylpropyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)(C)C KKIJZWOPMWEAIV-UHFFFAOYSA-N 0.000 description 3
- 210000005252 bulbus oculi Anatomy 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 210000004709 eyebrow Anatomy 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 230000001337 psychedelic effect Effects 0.000 description 3
- RCVMSMLWRJESQC-UHFFFAOYSA-N 7-[4-(diethylamino)-2-ethoxyphenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=NC=CC=C2C(=O)O1 RCVMSMLWRJESQC-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- VMPHSYLJUKZBJJ-UHFFFAOYSA-N trilaurin Chemical compound CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- JADYBWICRJWGBW-UHFFFAOYSA-N 2-hydroxy-3-(tetradecanoyloxy)propyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCC JADYBWICRJWGBW-UHFFFAOYSA-N 0.000 description 1
- 241000086550 Dinosauria Species 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 208000025174 PANDAS Diseases 0.000 description 1
- 208000021155 Paediatric autoimmune neuropsychiatric disorders associated with streptococcal infection Diseases 0.000 description 1
- 240000000220 Panda oleosa Species 0.000 description 1
- 235000016496 Panda oleosa Nutrition 0.000 description 1
- 241001147416 Ursus maritimus Species 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000001518 benzyl (E)-3-phenylprop-2-enoate Substances 0.000 description 1
- NGHOLYJTSCBCGC-QXMHVHEDSA-N benzyl cinnamate Chemical compound C=1C=CC=CC=1\C=C/C(=O)OCC1=CC=CC=C1 NGHOLYJTSCBCGC-QXMHVHEDSA-N 0.000 description 1
- 230000037237 body shape Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- NGHOLYJTSCBCGC-UHFFFAOYSA-N cis-cinnamic acid benzyl ester Natural products C=1C=CC=CC=1C=CC(=O)OCC1=CC=CC=C1 NGHOLYJTSCBCGC-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 1
- GHKVUVOPHDYRJC-UHFFFAOYSA-N didodecyl hexanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCC GHKVUVOPHDYRJC-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- RQIKFACUZHNEDV-UHFFFAOYSA-N dihexadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCC RQIKFACUZHNEDV-UHFFFAOYSA-N 0.000 description 1
- GYFBKUFUJKHFLZ-UHFFFAOYSA-N dioctadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCCCC GYFBKUFUJKHFLZ-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- QZQPCVVMCYMSFX-UHFFFAOYSA-N ditetradecyl hexanedioate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCC QZQPCVVMCYMSFX-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- UHUSDOQQWJGJQS-UHFFFAOYSA-N glycerol 1,2-dioctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCCCC UHUSDOQQWJGJQS-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- HIKYVKDNGAULJV-UHFFFAOYSA-N heptyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCC HIKYVKDNGAULJV-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 210000001747 pupil Anatomy 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940113164 trimyristin Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Toys (AREA)
Description
【考案の詳細な説明】
産業上の利用分野
本考案は色彩記憶玩具に関し、詳細には使用者
が適宜の加温または冷却手段を用いて一つの様相
から別の様相に変えることができ、しかも前記両
様相のいずれかを選択して常温域において保持で
きる、二面性を有する玩具に関する。[Detailed Description of the Invention] Industrial Application Field The present invention relates to a color memory toy, in particular, which can be changed from one aspect to another by the user using appropriate heating or cooling means, and which The present invention relates to a toy with dual characteristics that can select one of the above aspects and maintain it at room temperature.
従来の技術
この種の温度変化により二面性を示す玩具につ
いては、所定の温度を境としてその前後で表面の
色が異なるよう色彩されたものが提案されている
(例えば実開昭60−102090、特開昭60−228141、
同61−188481、同61−196988号)が、それらは変
化前後の両状態のうち常温域では特定の一方の状
態しか存在しえない。即ちもう一方の状態はその
状態が現出するのに要する熱または冷熱の適用さ
れている間は維持されるが、前記熱または冷熱の
適用がなくなれば常温域で呈する状態に戻つてし
まうと言うものである。BACKGROUND ART Regarding this kind of toy that exhibits duality due to temperature changes, it has been proposed that the surface color changes before and after a predetermined temperature (for example, Utility Model No. 60-102090). , Japanese Patent Publication No. 60-228141,
61-188481, 61-196988), but of the two states before and after the change, only one specific state can exist in the normal temperature range. In other words, the other state is maintained as long as the heat or cold required to bring it about is applied, but when the heat or cold is no longer applied, it returns to the state it exhibits at room temperature. It is something.
考案が解決しようとする問題点
本考案は表面の色彩が温度変化により変化する
だけでなく、変化前後の両様相のいずれかを自由
に選択して常温でその様相を維持させることので
きる二面性を示す玩具を提供しようとするもので
ある。Problems that the invention aims to solve This invention has two aspects: it not only changes the color of the surface due to temperature changes, but also allows you to freely select either the appearance before or after the change and maintain that appearance at room temperature. The idea is to provide toys that show sexuality.
問題点を解決するための手段
本考案の色彩記憶玩具は、自体一つの様相を有
する玩具の少なくとも一部の表面に、更に、温度
変化によりヒステリシス特性を示して着色状態と
無色状態または有色1と有色2間の互変性を呈す
る準可逆感温色素を含むインキ、絵具、塗料等の
形態の色材で色彩を施した構成である。Means for Solving the Problems The color memory toy of the present invention further exhibits a hysteresis characteristic depending on temperature changes on the surface of at least a portion of the toy, which itself has one aspect, so as to change the color between a colored state and a colorless state or a colored state. It is a composition in which colors are applied using a coloring material in the form of ink, paint, paint, etc. containing a quasi-reversible temperature-sensitive dye that exhibits chromatism between two colored colors.
前記準可逆感温色素としては本出願人が先に提
案(特願昭59−121267号、特願昭60−264285号)
した可逆感熱記録組成物が好適に用いられる。 The semi-reversible temperature-sensitive dye was previously proposed by the present applicant (Japanese Patent Application No. 121267/1982, Japanese Patent Application No. 264285/1983).
A reversible thermosensitive recording composition that has been prepared is preferably used.
前記組成物は、(イ)電子供与性呈色性有機化合
物、(ロ)フエノール性水酸基を有する化合物、芳香
族カルボン酸等から選ばれる前記成分(イ)を呈色さ
せる電子受容性有機化合物、(ハ)下記(1)乃至(7)に示
される化合物群から選ばれるカルボン酸エステル
化合物の3成分を必須成分とする均質相溶体から
なる組成物である。 The composition comprises: (a) an electron-donating color-forming organic compound, (b) an electron-accepting organic compound that causes the component (a) to develop color, selected from compounds having a phenolic hydroxyl group, aromatic carboxylic acids, etc. (c) A composition consisting of a homogeneous compatible solution containing three essential components of carboxylic acid ester compounds selected from the compound groups shown in (1) to (7) below.
(1) 分子中に置換芳香族環を含むカルボン酸エス
テル、
(2) 無置換芳香族環を含むカルボン酸と炭素数10
以上の脂肪族アルコールのエステル、
(3) 分子中にシクロアルキル基を含むカルボン酸
エステル、
(4) 炭素数6以上の脂肪酸と無置酸芳香族アルコ
ール又はフエノールのエステル、
(5) 炭素数8以上の脂肪族と分枝脂肪族アルコー
ルのエステル、
(6) ジカルボン酸と芳香族アルコール又は分枝脂
肪族アルコールのエステル、
(7) 桂皮酸ベンジル、ステアリン酸ヘプチル、ア
ジピン酸ジデシル、アジピン酸ジラウリル、ア
ジピン酸ジミリスチル、アジピン酸ジセチル、
アジピン酸ジステアリル、トリラウリン、トリ
ミリスチン、トリステアリン、ジミリスチン、
ジステアリン。(1) Carboxylic acid ester containing a substituted aromatic ring in the molecule, (2) Carboxylic acid containing an unsubstituted aromatic ring and 10 carbon atoms
(3) Carboxylic acid esters containing a cycloalkyl group in the molecule; (4) Esters of fatty acids with 6 or more carbon atoms and unsubstituted aromatic alcohols or phenols; (5) 8 carbon atoms. (6) Esters of dicarboxylic acids and aromatic alcohols or branched aliphatic alcohols, (7) Benzyl cinnamate, heptyl stearate, didecyl adipate, dilauryl adipate, dimyristyl adipate, dicetyl adipate,
Distearyl adipate, trilaurin, trimyristin, tristearin, dimyristin,
Distearin.
前記準可逆性感温色素は好ましくは微小カプセ
ル化されて粒子状形態で用いられる。 The semi-reversible thermosensitive dye is preferably microencapsulated and used in particulate form.
前記ヒステリシス特性とは温度変化による着色
温度の変化をプロツトした曲線の形状が、温度を
変色温度域より低温側から高温へと変化させる場
合と逆に高温側から低温へ変化させる場合とで異
なり、両曲線を合体するとループ状となる(第9
図参照)。該ループの両端における両曲線の合致
点のうち、低温側の合致点の温度をA、高温側の
合致点をBとすれば、本考案に用いられる準可逆
感温色素はAが氷や冷水から得られる温度、即ち
0℃乃至15℃程度の温度であり、Bは体温、風呂
の湯温またはヘアドライヤー等身近なものから得
られる温度、即ち凡そ27℃乃至90℃の温度を示す
ものであり、そして着色状態と無色状態の両相ま
たは有色1と有色2の両相が共存できる温度域
(以後2色保持温度域と称する)が常温域にある
ものが用いられ、特に約10℃乃至35℃の範囲の常
温域にあるものが好適に選択される。 The hysteresis characteristic is that the shape of the curve plotting the change in coloring temperature due to temperature change is different depending on whether the temperature is changed from a lower temperature to a higher temperature than the discoloration temperature range or vice versa. Combining both curves creates a loop (9th
(see figure). Among the matching points of both curves at both ends of the loop, if the temperature of the matching point on the low temperature side is A, and the matching point on the high temperature side is B, then in the semi-reversible temperature-sensitive dye used in the present invention, A is ice or cold water. B indicates the temperature obtained from familiar objects such as body temperature, bath water temperature, or hair dryer, that is, approximately 27 to 90 degrees Celsius. The temperature range (hereinafter referred to as the two-color retention temperature range) in which both the colored and colorless phases or the colored 1 and colored 2 phases can coexist is within the room temperature range, and in particular, from about 10°C to Those in the normal temperature range of 35°C are preferably selected.
更に準可逆感温色素について、色の異なるも
の、前記2色保持温度域が常温域内であるが互い
に異なるもの、前記の特殊な例として一方の準可
逆感温色素の2色保持温度域が他方の準可逆感温
色素のそれより広く且つそれを包含している関係
にある組合わ等、異種の組合せが、同一表面部分
に適用されたり、異なる表面部分にそれぞれ適用
されることにより多種多様の模様、デザインの様
相間の互変性を玩具に付与する。 Furthermore, regarding the semi-reversible temperature-sensitive dyes, there are those with different colors, those whose two-color retention temperature range is within the room temperature range but different from each other, and special examples of the above, such as those where one semi-reversible temperature-sensitive dye has a two-color retention temperature range of the other. Combinations of different types, such as combinations that are broader than and include those of quasi-reversible temperature-sensitive dyes, can be applied to the same surface area or applied to different surface areas, resulting in a wide variety of effects. To impart compatibility between patterns and design aspects to toys.
この準可逆感温色素は適宜のビヒクル中に分散
されてインキ、絵具または塗料などの形態の色材
として形象玩具の表面の所望個所を彩色する。勿
論、玩具に組み込まれる前の部材の表面に前記処
理が行われてもよい。 This semi-reversible temperature-sensitive dye is dispersed in a suitable vehicle and used as a colorant in the form of ink, paint or paint to color a desired location on the surface of a figurative toy. Of course, the above treatment may be performed on the surface of the member before it is incorporated into the toy.
作 用
前記準可逆感温色素が塗布された部分が無色の
状態(下地の彩色が現れている様相)にある形象
玩具は該表面を一旦前記A温度以下に冷却して着
色状態にし、常温に戻せば、前記着色状態の様相
は常温域で保持される。Function: If the part of the figurative toy to which the semi-reversible temperature-sensitive dye is coated is colorless (the underlying coloring appears), the surface is once cooled to below temperature A to make it colored, and then allowed to cool to room temperature. If returned, the aspect of the colored state is maintained at room temperature.
また着色状態にある前記表面部分を一旦前記B
温度以上に加温して無色状態にしてから常温域に
戻せば前記無色状態の様相は常温域で保持され
る。有色1と有色2の互変性の様相についても同
様である。 In addition, once the surface portion in the colored state is
If the material is heated above the temperature to make it colorless and then returned to room temperature, the colorless state will be maintained at room temperature. The same holds true for the aspect of tautism between colored 1 and colored 2.
このように本考案の形象玩具は2種の様相から
使用者が所望に応じて一つの様相を選択して、そ
の様相を保持でき、更に別の様相へ変化させてそ
れを保持できる機能を発揮する。この場合、前記
塗布部の一部だけに熱または冷熱を適用すれば、
その部分のみが変化した様相となる。 In this way, the figurative toy of the present invention has the function of allowing the user to select one aspect from two types as desired, retain that aspect, and then change to another aspect and retain it. do. In this case, if heat or cold is applied only to a part of the application area,
Only that part will appear to have changed.
また表面の各部分毎に異種の準可逆感温色素が
塗布されていると、各部分が変化するごとに全体
の模様またはデザインが変わるという機能も示さ
れる。 Furthermore, if different types of quasi-reversible temperature-sensitive dyes are applied to different parts of the surface, the overall pattern or design changes as each part changes.
前記機能の応用としては、人形において素顔の
様相と化粧した顔、普通の化粧をした顔と濃厚な
化粧をした顔の各2相間の変化、また全般的には
単一色と迷彩色、デザイン1とデザイン2、無地
と任意のデザイン、有色1と有色2、有色1と有
色1/有色2の模様間の互変性を呈する表面をも
つ玩具(乗物、動物、怪獣、恐龍などの形象玩具
及び人形衣服等)、特定の例として動物玩具にお
いて馬と縞馬、白熊とパンダ等の各両相間の互変
性を呈し、それぞれの様相が常温域で保持される
ものである。 Applications of the above functions include changes between two phases in dolls: a face with a bare face and a face with makeup, a face with normal makeup and a face with heavy makeup, and generally a single color and a camouflage color, and design 1. and design 2, toys with surfaces exhibiting tautism between plain color and arbitrary design, colored 1 and colored 2, colored 1 and colored 1/colored 2 patterns (figurative toys and dolls such as vehicles, animals, monsters, dinosaurs, etc.) Clothes, etc.), specific examples include animal toys that exhibit tautotropism between each phase, such as a horse and a striped horse, a polar bear and a panda, and each aspect is maintained at room temperature.
実施例
実施例 1
ポリ塩化ビニル樹脂製で、顔面が通常の化粧を
した様相、即ち唇が淡いピンク色、頬が淡い朱
色、瞼が淡い紫色に着色されている人形につい
て、温度変化により青色無色(A点10℃、B点
32℃)、紫色無色(A点10℃、B点32℃)、およ
びピンク色無色(A点10℃、B点32℃)にそれ
ぞれ変化する準可逆感温色素L,M,Nをそれぞ
れ含む塗料L′,M′,未′をそれぞれ唇、頬及び瞼
にスプレー塗装し、乾燥して顔面が二面性を示す
色彩記憶人形を得た。Examples Example 1 A doll made of polyvinyl chloride resin with a normal face makeup, that is, lips colored pale pink, cheeks pale vermilion, and eyelids pale purple, changes to blue and colorless due to temperature changes. (A point 10℃, B point
32℃), purple colorless (A point 10℃, B point 32℃), and pink colorless (A point 10℃, B point 32℃) Contains semi-reversible temperature-sensitive dyes L, M, and N, respectively. Paints L', M', and M' were spray-painted on the lips, cheeks, and eyelids, respectively, and after drying, a color memory doll with a dual-faced face was obtained.
前記準可逆感温色素L,M,Nは、各々以下の
組成からなつており、各3成分を混合、融解して
均質相溶体としたものである。 The quasi-reversible temperature-sensitive dyes L, M, and N each have the following compositions, and each of the three components is mixed and melted to form a homogeneous compatible solution.
尚、塗料化に当たつては、前記感温色素を公知
の界面重合法によりエポキシ樹脂膜で内包された
微小カプセルの形態として用いた。 In producing the paint, the temperature-sensitive dye was used in the form of microcapsules encapsulated in an epoxy resin film by a known interfacial polymerization method.
準可逆感温色素Lの組成(部数は重量部)
3−(4−ジエチルアミノ−2−エトキシフエ
ニル)−3−(1−エチル−2−メチルインドー
ル−3−イル)−4−アザフタリド 3部
ビスフエノールA 10部
ステアリン酸ネオペンチル 100部
準可逆感温色素Mの組成(部数は重量部)
3−(4−ジエチルアミノ−2−エトキシフエ
ニル)−3−(1−エチル−2−メチルインドー
ル−3−イル)−4−アザフタリド 1部
1,2−ベンツ−6−ジエチルアミノフルオラ
ン 2部
ビスフエノールA 12部
ステアリン酸ネオペンチル 100部
準可逆感温色素Nの組成(部数は重量部)
1,2−ベンツ−6−ジエチルアミノフルオラ
ン 3部
ビスフエノールA 12部
ステアリン酸ネオペンチル 100部
この人形の顔面を手で温めて普通の化粧をした
顔の様相にした後、約25℃の室温下、約10℃の冷
水で冷やしたところ唇が濃青色、頬が濃紫色、瞼
が濃ピンク色にそれぞれ変化してサイケデリツク
な化粧をした顔の様相を呈し、この様相は14℃乃
至29℃の温度域で安定に保持された。 Composition of semi-reversible thermosensitive dye L (parts by weight) 3-(4-diethylamino-2-ethoxyphenyl)-3-(1-ethyl-2-methylindol-3-yl)-4-azaphthalide 3 parts Bisphenol A 10 parts Neopentyl stearate 100 parts Composition of semi-reversible thermosensitive dye M (parts are parts by weight) 3-(4-diethylamino-2-ethoxyphenyl)-3-(1-ethyl-2-methylindole- 3-yl)-4-azaphthalide 1 part 1,2-benz-6-diethylaminofluorane 2 parts Bisphenol A 12 parts Neopentyl stearate 100 parts Composition of semi-reversible thermosensitive dye N (parts by weight) 1,2 -Benz-6-diethylaminofluorane 3 parts Bisphenol A 12 parts Neopentyl stearate 100 parts After warming the doll's face with your hands to make it look like a face with normal makeup, place it at room temperature of about 25℃ for about 10 minutes. When cooled with cold water at ℃, the lips changed to dark blue, the cheeks to dark purple, and the eyelids to dark pink, giving the appearance of a face with psychedelic makeup, and this appearance was observed in the temperature range of 14℃ to 29℃. was held stably.
次に再度顔面を手で温めたところ、サイケデリ
ツクな化粧が消え、普通の化粧をした顔の様相に
変化した。この操作の繰り返し毎にサイケデリツ
ク化粧相と普通の化粧相の互変性を示し、何回も
繰り返して遊ぶことができた。また唇、頬または
瞼の何れかの部分だけについても前記の変化をさ
せることができた。 Next, when she warmed her face with her hands again, the psychedelic makeup disappeared and her face changed to a face with normal makeup. Each time this operation was repeated, the psychedelic makeup phase and the normal makeup phase showed compatibility, allowing the player to play with it over and over again. Moreover, the above-mentioned changes could be made only in any part of the lips, cheeks, or eyelids.
実施例 2
淡青色無地のポリエステル布地に、温度変化に
より緑色無色(A点8℃、B点35℃)、赤色
無色(A点8℃、B点35℃)、橙色無色(A点
8℃、B点35℃)にそれぞれ変化する準可逆感温
色素P,Q,Rにそれぞれ含むスクリーン印刷イ
ンキP′,Q′,R′を用いて斑点模様をスクリーン
印刷し、この生地を衣装に仕立て、人形に装着さ
せて衣装が二面性を示す色彩記憶人形を得た。Example 2 A pale blue plain polyester fabric was colored green colorless (A point 8°C, B point 35°C), red colorless (A point 8°C, B point 35°C), orange colorless (A point 8°C, Using screen printing inks P', Q', and R' containing semi-reversible temperature-sensitive dyes P, Q, and R that change at point B (35°C), a spotted pattern is screen printed, and this fabric is made into costumes. By attaching it to a doll, we obtained a color memory doll whose costume shows duality.
この人形の衣装をヘアドライヤーで加温して、
約20℃の室温下で淡青色無地の衣装を着た様相に
した。次にこの人形を冷蔵庫に入れて冷却したと
ころ、無地の衣装が淡青色地に緑、赤、橙色の斑
点模様の様相に変化し、この様相は15℃乃至30℃
の温度域で安定に保持された。 Heat this doll's costume with a hair dryer,
It appeared to be wearing a plain light blue costume at a room temperature of approximately 20 degrees Celsius. Next, when this doll was placed in the refrigerator and cooled, the plain costume changed to a light blue background with green, red, and orange spots, and this appearance changed from 15℃ to 30℃.
It was maintained stably in the temperature range of .
次に再びヘアドライヤーで加温したところ、前
記斑点模様は消え、淡青色無地の衣装を着た様相
の人形に変化した。この操作の繰り返し毎に衣装
は無地と斑点模様の互変性を呈し、何回も繰り返
し遊ぶことができた。 Next, when the doll was heated again with a hair dryer, the spotted pattern disappeared and the doll appeared to be wearing a plain light blue costume. Each time this operation was repeated, the costume changed between a solid color and a spotted pattern, allowing the user to play with it over and over again.
実施例 3
ABS樹脂製ミニチユアカー表面に温度変化に
より赤色黄色(A点10℃、B点32℃)に変化す
る準可逆感温色素を含む塗料をスプレー塗装し、
乾燥してボデイが二面性を示す色彩記憶ミニチユ
アカーを得た。これを図面1,2図に示す。Example 3 A paint containing a semi-reversible temperature-sensitive dye that changes to red and yellow depending on temperature changes (A point 10℃, B point 32℃) was spray-painted on the surface of an ABS resin miniature car.
After drying, a color memory miniature car with a dual-sided body was obtained. This is shown in Figures 1 and 2.
このミニチユアカーのボデイを手で温めて約24
℃の室温下で黄色のボデイの様相にした(第1図
に図示の様相)。次にコールドスプレーで10℃以
下に冷却したところ、赤色のボデイに変化し、こ
の様相は15℃乃至30℃の温度域で安定に保持され
た。 Warm the body of this miniature car by hand for about 24 hours.
It was made to have a yellow body shape at room temperature (the shape shown in FIG. 1). Next, when the body was cooled to below 10°C using cold spray, it changed to a red body, and this appearance remained stable in the temperature range of 15°C to 30°C.
次にボデイの屋根の部分だけを手で温めたとこ
ろ、屋根の部分のみが赤色から黄色に変化し、黄
色と赤色のツートーンカラーボデイの様相を呈し
た(第2図に図示の様相)。更に手でボデイ全体
を温めたところ、黄色/赤色ツートーンカラーか
ら黄色のボデイに変化した。この操作の繰り返し
毎に赤色、黄色、任意のデザインの黄色/赤色ツ
ートーンカラー間の互変性を呈し、何回も繰り返
し遊ぶことができた。 Next, when we heated only the roof part of the body with our hands, only the roof part changed from red to yellow, giving the appearance of a two-tone yellow and red body (as shown in Figure 2). When I further warmed the entire body with my hands, it changed from a yellow/red two-tone color to a yellow body. Each time this operation was repeated, the game exhibited compatibility between red, yellow, and a yellow/red two-tone color of an arbitrary design, allowing the player to play the game over and over again.
実施例 4
ポリ塩化ビニル樹脂製で、第3図示の様相の顔
面をもつ人形に、第4図示のとおり目玉の瞳部分
3′に緑色無色(A点10℃、B点30℃)、目玉の
他の部分3にこげ茶色無色(A点10℃、B点30
℃)及び眉毛の部分3″に茶色無色(A点10℃、
B点30℃)の変化を示す準可逆感温色素をそれぞ
れ含む塗料を塗布して顔面が二面性を呈する色彩
記憶人形を得た。Example 4 A doll made of polyvinyl chloride resin and having a face as shown in Figure 3 was given a green and colorless pupil portion 3' of the eyeball (point A: 10°C, point B: 30°C) as shown in Figure 4. Other parts 3 are dark brown and colorless (point A 10℃, point B 30℃)
°C) and the eyebrow part 3″ is brown and colorless (A point 10 °C,
A color memory doll with a dual-faced face was obtained by applying paint containing semi-reversible temperature-sensitive dyes that exhibit changes in temperature (B point 30°C).
第5図に前記目玉部分の拡大断面図、第6図に
前記眉毛部分の拡大断面図を示した。図中の符号
は1が顔面基材、2,2′が非変色像、3,3′,
3″が準可逆感温色素層である。 FIG. 5 shows an enlarged sectional view of the eyeball part, and FIG. 6 shows an enlarged sectional view of the eyebrow part. In the figure, 1 is the facial base material, 2, 2' is the non-discolored image, 3, 3',
3'' is a semi-reversible temperature-sensitive dye layer.
この人形の顔面を10℃以下の温度に冷やすと、
第4図示の両目を開いた様相となり、30℃以上の
湯を含むタオルを片目に押し当てると、片目だけ
が閉じたウインクした様相となり、更に顔全体に
前記タオルを押し当てると第3図示の両目の閉じ
た眠つている様相となる。いずれの様相も常温域
で保持され、各様相間の変化は繰り返し再現され
た。 If you cool this doll's face to a temperature below 10℃,
If you press a towel containing hot water of 30°C or higher over one eye, the appearance will appear with both eyes open as shown in the fourth figure, and if you press the towel containing hot water over one eye, only one eye will become closed and winking, and if you further press the towel over the entire face, the appearance shown in the third figure It appears to be asleep with both eyes closed. All aspects were maintained at room temperature, and changes between each aspect were repeatedly reproduced.
実施例 5
ミニチユアカー(トラツク)の側面に多色の塗
料を用い、刷毛でマークを描き、該マークの
全面上にピンク色無色(A点10℃、B点35℃)
の変化を示す準可逆感温色素を含む塗料1を塗布
し、更にその表面に濃緑色〓無色(A点10℃、B
点35℃)の準可逆感温色素を含む塗料2で前記塗
布面と部分的に重なるよう塗布して二面性のマー
クを付けたミニカーを得た。Example 5 A mark was drawn with a brush using multi-colored paint on the side of a miniature car (truck), and a pink colorless (point A: 10°C, point B: 35°C) was painted on the entire surface of the mark.
Paint 1 containing a semi-reversible temperature-sensitive dye that exhibits a change in temperature is applied, and the surface is further coated with colors ranging from dark green to colorless (A point 10℃, B point
Paint 2 containing a semi-reversible temperature-sensitive dye with a temperature of 35° C.) was applied so as to partially overlap the coated surface to obtain a miniature car with a two-sided mark.
第7図に前記マーク部の拡大断面図を示す。図
中の符号は1がミニカー基材、2,2′はマーク
を構成している塗料、3は前記塗料1,3′は
前記塗料2をそれぞれ表す。 FIG. 7 shows an enlarged sectional view of the mark portion. In the figure, 1 represents the base material of the minicar, 2 and 2' represent the paint forming the mark, and 3 represents the paint 1 and 3' the paint 2, respectively.
このミニチユアカーは35℃以上の温度にさらす
とマークが表示され、このマークは常温域に戻
しても保持された。次に10℃以下の温度に冷やす
とマークとは別のマークが表示され、このマ
ークも常温域において保持され、この変化を繰
り返して遊ぶことができた。 This miniature car displayed a mark when exposed to temperatures above 35 degrees Celsius, and this mark remained even when the car was returned to room temperature. Next, when it was cooled to a temperature below 10 degrees Celsius, a different mark was displayed, and this mark also remained in the room temperature range, allowing the player to play by repeating this change.
実施例 6
アート紙表面にカラフルな絵柄をオフセツト印
刷し、前記絵柄全面上に黒色無色(A点10℃、
B点30℃)の変化を示す準可逆感温色素を含むイ
ンキにてスクリーン印刷して二面性を有する模擬
インスタント写真を得た。Example 6 A colorful pattern was offset printed on the surface of art paper, and a colorless black (A point 10℃,
A simulated instant photograph having duality was obtained by screen printing with an ink containing a semi-reversible temperature-sensitive dye exhibiting a change in point B (30° C.).
第8図に模擬インスタント写真の拡大断面図を
示す。図中の符号は1が基材、2,2′,2″は絵
柄を構成しているインキ、3は準可逆感温色素層
をそれぞれ表す。 FIG. 8 shows an enlarged cross-sectional view of the simulated instant photograph. In the figure, 1 represents the base material, 2, 2', and 2'' represent the ink constituting the pattern, and 3 represents the semi-reversible temperature-sensitive dye layer, respectively.
この模擬インスタント写真は10℃以下に冷やす
と全面黒色を呈し、常温域(15℃〜28℃)に戻し
ても黒色は維持され、30℃以上の温度にさらすと
黒色が消え、カラフルな絵柄の様相となる。この
絵柄は常温域において維持され、前記変化を繰り
返して遊ぶことができた。 This simulated instant photo becomes entirely black when cooled to below 10℃, remains black even when returned to room temperature (15℃ to 28℃), and disappears when exposed to temperatures above 30℃, creating a colorful pattern. It becomes the appearance. This pattern was maintained at room temperature and could be played by repeating the changes described above.
考案の効果
前記のとおり本考案は日常の生活範囲の熱源ま
たは冷熱源で玩具の表面の一部または全部の様相
を変化させることができると同時に、常温域で所
望の様相を保持でき、更に玩具の各部分、例えば
人形の顔、毛髪、爪(マニキユア)、衣装、アク
セサリー、靴、帽子等にそれぞれ二面性を付与す
れば、それらの部材を取り替えることなく1個の
玩具で幾通りかの様相を呈する玩具として活用で
きる。このように本考案は1個の玩具で使用者に
種々の遊び方を提供し、玩具に高い付加価値を付
与するものである。Effects of the invention As mentioned above, the present invention is capable of changing the appearance of part or all of the surface of a toy using heat or cold sources found in daily life, and at the same time retaining the desired appearance at room temperature. By giving each part of the doll, such as the doll's face, hair, nails (manicure), costumes, accessories, shoes, hats, etc., a dual nature, you can create several different versions of the toy without having to replace those parts. It can be used as a toy that exhibits various aspects. In this way, the present invention provides users with a variety of ways to play with a single toy, and adds high added value to the toy.
第1図及び第2図は実施例3のミニチユアカー
の斜視図であり、第1図はボデイ全体が黄色の様
相を呈しており、第2図はボデイの屋根の部分が
黄色、他の部分は赤色のツートーンカラーの様相
を呈している状態を示しており、第3図及び第4
図は実施例4の人形の互変性の模様をそれぞれ表
しており、第5図は前記顔面の目玉部分、第6図
は眉毛部分の各拡大断面図である。第7図は実施
例5のミニチユアカーのマーク部の拡大断面図で
あり、第8図は実施例6のインスタント写真の拡
大断面図である。第9図は本考案に用いられる準
可逆感温色素の温度変化による変色のヒステリシ
ス特性を示すグラフである。
1……基材、2,2′……非変色像、3,3′,
3″……準可逆感温色素層。
Figures 1 and 2 are perspective views of the miniature car of Example 3. In Figure 1, the entire body is yellow, and in Figure 2, the roof part of the body is yellow, and the other parts are yellow. It shows a state in which it has a red two-tone color appearance, and Figures 3 and 4.
The figures show the tautomy patterns of the doll of Example 4, with FIG. 5 being an enlarged cross-sectional view of the eyeball portion of the face, and FIG. 6 being an enlarged cross-sectional view of the eyebrow portion. FIG. 7 is an enlarged sectional view of the mark portion of the miniature car of Example 5, and FIG. 8 is an enlarged sectional view of the instant photograph of Example 6. FIG. 9 is a graph showing the hysteresis characteristic of color change due to temperature change of the semi-reversible thermosensitive dye used in the present invention. 1...Base material, 2,2'...Non-color image, 3,3',
3″...Semi-reversible temperature-sensitive dye layer.
Claims (1)
一部が準可逆感温色素を含む色材で彩色された色
彩記憶玩具であつて、前記準可逆感温色素は、該
感温色素が第1色相状態にあつて温度が上昇する
過程では、第2の温度に達すると第1色相は変色
し始め、第2の温度より高い温度TB以上の温度
域で完全に第2色相となり、前記感温色素が第2
色相状態にあつて温度が下降する過程では、前記
第2の温度より低い第1の温度に達すると第2色
相は変色し始め、第1の温度より低い温度TA以
下の温度域で完全に第1色相となり、前記第1の
温度と第2の温度の間の温度域内で第1色相と第
2色相の両相が共存可能であるヒステリシス特性
を示す感温色素であり、ここで温度TAは0℃乃
至15℃の間の温度であり、温度TBは27℃乃至90
℃の間の温度であり、第1の温度と第2の温度の
間の温度域は10℃乃至35℃の範囲内の温度域であ
ることを特徴とする色彩記憶玩具。 A color memory toy which itself has one appearance and further has at least a portion of its surface colored with a coloring material containing a semi-reversible temperature-sensitive dye, wherein the semi-reversible temperature-sensitive dye is In the process where the temperature rises in the hue state, the first hue begins to change color when it reaches the second temperature, and completely becomes the second hue in the temperature range higher than the second temperature T B , and the aforementioned sensitivity Warm pigment is the second
In the process of decreasing temperature in the hue state, the second hue begins to change color when it reaches the first temperature lower than the second temperature, and completely changes color in the temperature range below the temperature T A lower than the first temperature. It is a temperature-sensitive dye that exhibits a hysteresis characteristic in which both the first hue and the second hue can coexist within a temperature range between the first temperature and the second temperature, and where the temperature T A is a temperature between 0°C and 15°C, and temperature T B is between 27°C and 90°C.
A color memory toy characterized in that the temperature is between 10°C and 35°C, and the temperature range between the first temperature and the second temperature is within the range of 10°C to 35°C.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1988019593U JPH0426160Y2 (en) | 1987-04-29 | 1988-02-17 | |
GB8809915A GB2205255B (en) | 1987-04-29 | 1988-04-27 | Color changing toy |
AU15248/88A AU608834B2 (en) | 1987-04-29 | 1988-04-28 | Color memory toy |
ES8900547A ES2012266A6 (en) | 1987-04-29 | 1988-04-28 | Color changing toy |
CA000565417A CA1340198C (en) | 1987-04-29 | 1988-04-28 | Color memory toy |
FR888805821A FR2614549B1 (en) | 1987-04-29 | 1988-04-29 | COLORED MEMORY TOY |
DE8805700U DE8805700U1 (en) | 1987-04-29 | 1988-04-29 | Color memory toy |
KR2019880006138U KR950007440Y1 (en) | 1987-04-29 | 1988-04-29 | Color memory toys |
US08/208,912 US20030087580A1 (en) | 1987-04-29 | 1994-03-11 | Color memory toy |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6456487 | 1987-04-29 | ||
JP1988019593U JPH0426160Y2 (en) | 1987-04-29 | 1988-02-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6442100U JPS6442100U (en) | 1989-03-14 |
JPH0426160Y2 true JPH0426160Y2 (en) | 1992-06-23 |
Family
ID=31717423
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1988019593U Expired JPH0426160Y2 (en) | 1987-04-29 | 1988-02-17 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0426160Y2 (en) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60124997U (en) * | 1984-01-31 | 1985-08-23 | 株式会社 タカラ | perspective toy |
JPS60141897U (en) * | 1984-02-29 | 1985-09-19 | 株式会社タカラ | pattern play toys |
JPS61111499U (en) * | 1984-12-26 | 1986-07-15 |
-
1988
- 1988-02-17 JP JP1988019593U patent/JPH0426160Y2/ja not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6442100U (en) | 1989-03-14 |
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