JPH0425444A - Moisture-permeable nonwoven fabric composite sheet - Google Patents

Moisture-permeable nonwoven fabric composite sheet

Info

Publication number
JPH0425444A
JPH0425444A JP13221290A JP13221290A JPH0425444A JP H0425444 A JPH0425444 A JP H0425444A JP 13221290 A JP13221290 A JP 13221290A JP 13221290 A JP13221290 A JP 13221290A JP H0425444 A JPH0425444 A JP H0425444A
Authority
JP
Japan
Prior art keywords
nonwoven fabric
water resistance
less
composite sheet
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13221290A
Other languages
Japanese (ja)
Other versions
JP2905558B2 (en
Inventor
Takeshi Konishi
武四 小西
Toshiaki Iwamoto
岩本 俊昭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP13221290A priority Critical patent/JP2905558B2/en
Publication of JPH0425444A publication Critical patent/JPH0425444A/en
Application granted granted Critical
Publication of JP2905558B2 publication Critical patent/JP2905558B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE:To obtain a nonwoven fabric composite sheet, a surface of which has a hydrophilic nature and which has high water resistance though it has moisture permeability, by bonding a nonwoven-fabric having water repellency of a specific value or less and a web having water resistance of a specific value or more. CONSTITUTION:At least one surface is coated with a hydrophilic nonwoven fabric having the surface of water repellency of 70 points or less, and the nonwoven fabric layer and a layer including a wab having water resistance of 50cm or more are bonded and unified in a discontinuous manner with a bonding resin having an equilibrium moisture rate of 3% or less. The nonwoven fabric having the water repellency of 70 points or less of a surface can be acquired through a wet type method, a dry type method such as a card method, a random web method, etc., and a span bonding method, etc., from fibers having the equilibrium moisture rate of approximately 4% or more or fibers, into which these fibers are mixed. The nonwoven fabric having water resistance of 50cm or more is represented by polypropylene. A polyolefin resin, etc., having moisture content of approximately 0% can be obtained by the nonwoven fabric through an MB method.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明の製品は表面が親木、吸水性であり、透湿性を有
し、しかも水を通しにくい高い耐水度を有しているため
、紙おむつなど衛生材料のカバー材料、作業衣、病院な
どで用いられる覆布(ドレープ)、ベツドシーツ、おね
しょマット、あるいは鮮度保持用包装材料など巾広い分
野で利用できる。
[Detailed Description of the Invention] <Industrial Application Field> The product of the present invention has a parent wood surface, water absorbency, moisture permeability, and high water resistance that makes it difficult for water to pass through. It can be used in a wide range of fields, including cover materials for sanitary materials such as disposable diapers, work clothes, drapes used in hospitals, bed sheets, bedwetting mats, and packaging materials for preserving freshness.

〈従来の技術〉 メルトブローン(以下MBと記す)法によって得られる
不織布は、不織布を構成する単繊維の繊度(直径)が小
さい。したがって不織布の繊維間空隙が数ミクロン以下
にもなり得る。ポリプロピレンなど疎水性の樹脂からM
B不織布を作れば、通気性を有し乍ら、ある程度の防水
性、すなわち本発明で言う耐水度を有する不織布が得ら
れる。
<Prior Art> In a nonwoven fabric obtained by the melt blown (hereinafter referred to as MB) method, the fineness (diameter) of the single fibers constituting the nonwoven fabric is small. Therefore, the interfiber voids of the nonwoven fabric can be several microns or less. M from hydrophobic resins such as polypropylene
If B nonwoven fabric is made, a nonwoven fabric that has breathability and a certain degree of waterproofness, that is, water resistance as referred to in the present invention, can be obtained.

一方MB不織布は構成繊維の分子配向が、汎用繊維に比
較して、進んでいないため強力が小さい。
On the other hand, MB nonwoven fabric has less strength because the molecular orientation of its constituent fibers is not as advanced as that of general-purpose fibers.

そのため特公昭60−11148に示されるごと<MB
不織布と強力を有するスパンポンド不織布とを融着一体
化し、作業衣や病院で用いられる手術衣、覆布(ドレー
プ)あるいは滅菌ラップなどに用いられている。このよ
うにMB不織布とスパンポンドとのはり合わせによって
、十分な強力を有し、通気性を持ち、しかも耐水度の大
きい複合シートを得ることはできる。しかし大きな耐水
度が要求される場合、シート表面は撥水性にならざるを
得ないのが現状である。たとえば耐水度65crrlを
有するポリプロピレンからなるMB不織布を親水油剤が
付与すれたナイロンスパンポンドでサンドインチ状には
さみ、三ツの層を融着一体した場合、確かに表面は親水
性となり吸液もあるが、耐水度は3cm程度にまで低下
してしまう。すなわち表面を親水性とすれば耐水度は低
下してしまうのが現状である。
Therefore, as shown in Special Publication No. 60-11148 <MB
Non-woven fabrics and strong spunpond non-woven fabrics are fused together and used in work clothes, surgical gowns used in hospitals, drapes, sterilization wraps, etc. In this way, by laminating the MB nonwoven fabric and the spunpond, it is possible to obtain a composite sheet that has sufficient strength, air permeability, and high water resistance. However, if high water resistance is required, the current situation is that the sheet surface must be water repellent. For example, if a MB nonwoven fabric made of polypropylene with a water resistance of 65 crrl is sandwiched between nylon spunpons coated with a hydrophilic oil agent, and the three layers are fused together, the surface will certainly be hydrophilic and absorb liquid. However, the water resistance drops to about 3 cm. In other words, the current situation is that if the surface is made hydrophilic, the water resistance will decrease.

〈問題を解決するだめの手段、作用〉 本発明者らは上述の問題を解決するため、鋭意検討を重
ねた結果、本発明を完成するにいたったものである。す
なわち、少なくとも一表面に表面の撥水度が70点以下
である親水性不織布で覆われており、該不織布層と耐水
度が50cm以上であるウェブを含む層とが平衝水分率
3%以下の接着性樹脂で不連続状に接着一体化されてい
ることを特徴とする親水性表面を有しかつ耐水度50c
m以上である透湿性不織布複合シートを提供しようとす
るものである。
<Means and effects for solving the problem> The present inventors have conducted intensive studies to solve the above-mentioned problem, and as a result, have completed the present invention. That is, at least one surface is covered with a hydrophilic nonwoven fabric having a surface water repellency of 70 points or less, and the nonwoven fabric layer and a layer containing a web having a water resistance of 50 cm or more have an average moisture content of 3% or less. It has a hydrophilic surface characterized by being integrally bonded discontinuously with an adhesive resin and has a water resistance of 50c.
It is an object of the present invention to provide a moisture permeable nonwoven fabric composite sheet having a moisture permeability of at least m.

ここで撥水度はJIS L−1092(スプレー法)、
耐水度はJIS L−1092A法(低水圧法)、平衝
水分率はJIS L−1096でそれぞれ測定されるも
のである。
Here, the water repellency is JIS L-1092 (spray method),
Water resistance is measured by JIS L-1092A method (low water pressure method), and equilibrium moisture content is measured by JIS L-1096.

表面の撥水度が70点以下である不織布は各種の方法に
よって得ることができるが、木綿、レーヨン、ビニロン
あるいはナイロンなど平衝水分率が4%程度以上を有す
る繊維、あるいは、これらの繊維が混合された繊維から
湿式法やカード法、ランダムウェブ法なとの乾式法、さ
らにはスパンポンド法などによって容易に得ることかで
きる。また表面の繊維が疎水性のものであっても親水性
界面活性剤を付与するとか、親水性成分を練り込むこと
によっても撥水度70点以下の表面材を得ることができ
る。本発明において撥水度は少なくとも70点以下が好
ましいが、親水性、吸液性がとくに望まれる場合、撥水
度は30点より低いことがさらに望ましい。
Nonwoven fabrics with a surface water repellency of 70 points or less can be obtained by various methods, but fibers such as cotton, rayon, vinylon, or nylon having an average water content of about 4% or more, or those fibers It can be easily obtained from the mixed fibers by a wet method, a card method, a dry method such as a random web method, or a spun-pond method. Even if the fibers on the surface are hydrophobic, a surface material with a water repellency of 70 points or less can be obtained by adding a hydrophilic surfactant or incorporating a hydrophilic component. In the present invention, the water repellency is preferably at least 70 points or less, but if hydrophilicity and liquid absorption are particularly desired, the water repellency is more preferably lower than 30 points.

つぎに耐水度50cm以上を有する不織布はポリプロピ
レンに代表される、水分率が約0%であるポリオレフィ
ン系樹脂などをMB法によって不織布にすることによっ
て容易に得られる。この時、平均繊維直径を10ミクロ
ン以下、さらには数ミクロン以下にすれば高い耐水度を
有するMB不織布が得られる。またフラット熱カレンダ
ー処理することによって、透湿性や通気性を維持したま
ま、耐水度を向上させることも可能である。本発明に必
要な耐水度を有するMB不織布を得るためには、不織布
の目付は15g/m2以上が必要である。MB不織布を
構成する繊維の直径、熱カレンダーによる処理、目付な
どの要因を調整することによって透湿性や通気性を保持
したまま、耐水度を向上させることが可能であり、本発
明の効果は一層大きいものになる。
Next, a nonwoven fabric having a water resistance of 50 cm or more can be easily obtained by making a polyolefin resin, typified by polypropylene, with a moisture content of about 0% into a nonwoven fabric by the MB method. At this time, if the average fiber diameter is set to 10 microns or less, or even several microns or less, an MB nonwoven fabric with high water resistance can be obtained. Further, by flat heat calendering, it is possible to improve water resistance while maintaining moisture permeability and air permeability. In order to obtain an MB nonwoven fabric having the water resistance required for the present invention, the basis weight of the nonwoven fabric must be 15 g/m2 or more. By adjusting factors such as the diameter of the fibers constituting the MB nonwoven fabric, thermal calendar treatment, and basis weight, it is possible to improve water resistance while maintaining moisture permeability and air permeability, and the effects of the present invention are further enhanced. It becomes something big.

本発明においてMBウェブはそのまま用いられてもよい
が、MBウェブとポリプロピレンスパンポンド、あるい
はポリプロピレン編織布など平衝水分率が0%に近い疎
水性材料などとの積層、またはMBウェブをこれら疎水
性材料でサンドインチ状にはさみ、融着一体化した積層
物を用いてもよい。
In the present invention, the MB web may be used as it is, but the MB web may be laminated with a hydrophobic material with an average water content close to 0%, such as polypropylene spunpond or polypropylene knitted fabric, or the MB web may be laminated with a hydrophobic material such as polypropylene spunpond or polypropylene knitted fabric, or the MB web may be laminated with a hydrophobic material such as polypropylene spunpond or polypropylene knitted fabric. A laminate in which materials are sandwiched in a sandwich-like manner and fused together may be used.

親水性の表面材とMBウェブを含む層とを一体化するに
は平衝水分率が3%以下、好ましくは1%以下である接
着性樹脂を、フィルム状にならない様、すなわち不連続
状に、表面材とMBウェブを含む層との間に介在させ加
圧、必要に応じて加熱加圧し、表面材とMBウェブを含
む層とを接着する。接着性樹脂には機能性官能基が導入
されているオレフィン系あるいはアクリル系樹脂などが
用いられる。接着は融着、粘着などを含め化学的あるい
は物理的方法、さらにはこれらの組合わせ機構によって
達成される。接着性樹脂に融点を有する熱可塑性樹脂を
用いる場合、その融点はMB樹脂の軟化点(示差熱分析
において変更が始まる温度)よりも低いことが好ましく
、また表面材の組成に熱可塑性繊維が含まれる場合、そ
の繊維の融点よりも低いことがさらに好ましい。
In order to integrate the hydrophilic surface material and the layer containing the MB web, an adhesive resin having an average moisture content of 3% or less, preferably 1% or less, is applied in a discontinuous manner so as not to form a film. , the surface material and the layer containing the MB web are interposed between the surface material and the layer containing the MB web, pressure is applied, and if necessary, heating and pressure is applied to bond the surface material and the layer containing the MB web. As the adhesive resin, an olefin resin or acrylic resin into which a functional group is introduced is used. Adhesion can be achieved by chemical or physical methods, including fusion, adhesion, etc., or by a combination of these mechanisms. When a thermoplastic resin having a melting point is used as the adhesive resin, the melting point is preferably lower than the softening point of the MB resin (the temperature at which changes begin in differential thermal analysis), and the composition of the surface material contains thermoplastic fibers. If the melting point is lower than the melting point of the fiber, it is more preferable.

接着性樹脂は本発明の複合シートが透湿性を失うことの
ないよう、連続的、すなわちフィルム状にならないよう
不連続的に表面材とMBウェブを含む層の間に介在させ
ることが必要である。また接着性樹脂の平衝水分率が3
%より大きい場合、得られる不織布複合シートの耐水度
が低下するので好ましくない。
In order to prevent the composite sheet of the present invention from losing its moisture permeability, the adhesive resin needs to be interposed continuously between the surface material and the layer containing the MB web, i.e. discontinuously so as not to form a film. . In addition, the equilibrium moisture content of the adhesive resin is 3
%, it is not preferable because the water resistance of the obtained nonwoven fabric composite sheet decreases.

以下に本発明の内容を理解しやすくするために、実施例
を挙げて説明するが本発明はこれらの実施例のみに限定
されるものではない。
EXAMPLES In order to make the content of the present invention easier to understand, examples will be described below, but the present invention is not limited to these examples.

実施例1 水分率が0%であるポリプロピレン樹脂からMB法によ
って、目付30g/m”、平均繊維直径が4ミクロンで
あるMBウェブを得た。このウェブを100℃で7ラツ
ト熱カレンダー処理し、厚み0.1mm。
Example 1 An MB web having a basis weight of 30 g/m'' and an average fiber diameter of 4 microns was obtained by the MB method from a polypropylene resin with a moisture content of 0%. Thickness: 0.1mm.

耐水度90c+n、軟化点115℃を有するMB不織布
を作った。
An MB nonwoven fabric having a water resistance of 90c+n and a softening point of 115°C was produced.

一方親水性界面活性剤が付与されt;撥水度0点、目付
25g/m”を有するナイロンスパンホンドラ表面材と
して用意した。このナイロンスパンポンドの片側面に融
点91℃、平衝水分率0.01%であるエチレン酢ビ系
樹脂を約5mm間隔で、ドツト(水玉)状、すなわち不
連続状に、8g/m”の割合で塗布し tこ 。
On the other hand, a hydrophilic surfactant was applied to a nylon spun surface material having a water repellency of 0 points and a basis weight of 25 g/m. 0.01% ethylene-vinyl acetate resin was applied at a rate of 8 g/m'' in dots (polka dots), ie, discontinuously, at intervals of about 5 mm.

つぎに樹脂が塗布された面を内側として、上記MB不織
布をナイロンスパンポンドでサンドイッチ状にはさみ、
100°Cに加熱された熱ロールで加圧し乍ら連続的に
処理した。その結果、中心にMB不織布、両側表面にナ
イロンスパンポンドが配置されている三層積層の不織布
複合シートが得られI;。
Next, sandwich the MB nonwoven fabric with nylon spun pads with the resin-coated side facing inside.
The treatment was carried out continuously while being pressurized with a hot roll heated to 100°C. As a result, a three-layer laminated nonwoven fabric composite sheet was obtained in which a MB nonwoven fabric was placed in the center and nylon spunponds were placed on both sides.

この不織布複合シートは両側表面ともに撥水度0点で、
吸水性があり、JIS L−1099A−1法による透
湿度は300g/m”・hrを示し、耐水度は88cm
を示した。
This non-woven composite sheet has a water repellency of 0 points on both surfaces,
It has water absorption properties, and has a moisture permeability of 300 g/m"・hr according to the JIS L-1099A-1 method, and a water resistance of 88 cm.
showed that.

かくして得られた不織布複合シートを病院用ベツドのマ
ットカバーとして用いたところ、むれ感もなく、ベツド
上にこぼれた液体を表面で吸収する一方、マットまでの
液体の通過を防止し、マットを汚すことはなかった。
When the nonwoven composite sheet obtained in this way was used as a mat cover for a hospital bed, it did not feel stuffy, and while the surface absorbed liquid spilled on the bed, it also prevented the liquid from passing through to the mat, causing it to become dirty. That never happened.

比較例1 実施例1において用いたMB不織布とナイロンスパンポ
ンドを実施例1と同様、MB不織布を中心とし、ナイロ
ンスパンポンドを両側に配置し、熱エムポスによって三
層を部分的、不連続的に融着一体化した。かくして得ら
れた不織布複合、シートは両側表面ともに親水性であり
、透湿性も有していたか、耐水度は5cmにまで低下し
ていた。
Comparative Example 1 The MB nonwoven fabric and nylon spunpond used in Example 1 were used in the same way as in Example 1, with the MB nonwoven fabric in the center and nylon spunponds placed on both sides, and the three layers were partially and discontinuously formed by heat embossing. Integrated by fusion. The nonwoven composite sheet thus obtained was hydrophilic on both surfaces and had moisture permeability, or its water resistance was reduced to 5 cm.

このシートを実施例1と同様ベツドマットのカバーに用
いても、ベツド上でこぼれた液体はマットまで浸透し、
マットの汚れを防止することはできなかった。
Even if this sheet is used as a cover for a bed mat as in Example 1, liquid spilled on the bed will penetrate into the mat.
It was not possible to prevent the mat from becoming dirty.

実施例2 ポリプロピレン樹脂から、目付20g/m2、平均繊維
直径3.5ミクロン、軟化点105℃を有するMBウェ
ブを得た。このウェブを界面活性剤などが付与されてい
ない目付15g/m”を有するポリプロピレンスパンポ
ンドではさみ、エムポン面積が全面積の16%である不
連続パターンによって融着一体化した。得られたMBウ
ェブを含む層(三層積層品)は耐水度77cmを示した
Example 2 An MB web having a basis weight of 20 g/m 2 , an average fiber diameter of 3.5 microns, and a softening point of 105° C. was obtained from a polypropylene resin. This web was sandwiched between polypropylene spunpons having a basis weight of 15 g/m'' to which no surfactant was added, and fused and integrated using a discontinuous pattern in which the Empon area was 16% of the total area.The obtained MB web (three-layer laminate) had a water resistance of 77 cm.

一方、レーヨンステープルより目付30g/m2、撥水
度0点である乾式不織布を得た。
On the other hand, a dry nonwoven fabric having a basis weight of 30 g/m2 and a water repellency of 0 points was obtained from rayon staples.

つぎに上記MBを含む層の上に融点85°C1平衝水分
率0.1%を有するエチレン・エチルアクリレート・無
水マレイン酸三元共重合体粉末を15g/m2の割合で
分散し、この上に乾式不織布を重合し90°C熱ロール
で両者を圧着した。
Next, ethylene/ethyl acrylate/maleic anhydride terpolymer powder having a melting point of 85°C and an average water content of 0.1% is dispersed on the layer containing MB at a rate of 15 g/m2, and then A dry nonwoven fabric was polymerized and the two were pressed together using a 90°C heated roll.

得られた不織布複合シートのレーヨン乾式不織布側は優
れた吸水性を示し、透湿度320g/m”・hrを示し
、しかも耐水度75cmを示すものであった。
The rayon dry nonwoven fabric side of the obtained nonwoven fabric composite sheet exhibited excellent water absorption, with a water vapor permeability of 320 g/m''·hr and a water resistance of 75 cm.

〈発明の効果〉 本発明によれば表面が親水性であり、かつ透湿性であり
乍ら、高い耐水度を有する不織布複合シートを得ること
が可能であり、その利用価値は極めて大きい。
<Effects of the Invention> According to the present invention, it is possible to obtain a nonwoven fabric composite sheet that has a hydrophilic surface, moisture permeability, and high water resistance, and its utility value is extremely high.

特詐出願人 株式会社 り ラ し 代 理 人 弁理士 水掻 堅Special fraud applicant RiRashi Co., Ltd. Representative Patent Attorney Ken Mizuki

Claims (1)

【特許請求の範囲】[Claims] 少なくとも一表面に表面の撥水度が70点以下である親
水性不織布で覆われており、該不織布層と耐水度が50
cm以上であるウェブを含む層とが平衝水分率3%以下
の接着性樹脂で不連続状に接着一体化されていることを
特徴とする親水性表面を有しかつ耐水度50cm以上で
ある透湿性不織布複合シート。
At least one surface is covered with a hydrophilic nonwoven fabric having a surface water repellency of 70 points or less, and the nonwoven fabric layer has a water resistance of 50 points or less.
It has a hydrophilic surface characterized by being integrally bonded with a layer containing a web having an average moisture content of 3% or less in a discontinuous manner, and has a water resistance of 50cm or more. Moisture-permeable nonwoven composite sheet.
JP13221290A 1990-05-21 1990-05-21 Moisture permeable nonwoven composite sheet Expired - Fee Related JP2905558B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13221290A JP2905558B2 (en) 1990-05-21 1990-05-21 Moisture permeable nonwoven composite sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13221290A JP2905558B2 (en) 1990-05-21 1990-05-21 Moisture permeable nonwoven composite sheet

Publications (2)

Publication Number Publication Date
JPH0425444A true JPH0425444A (en) 1992-01-29
JP2905558B2 JP2905558B2 (en) 1999-06-14

Family

ID=15076018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13221290A Expired - Fee Related JP2905558B2 (en) 1990-05-21 1990-05-21 Moisture permeable nonwoven composite sheet

Country Status (1)

Country Link
JP (1) JP2905558B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002128545A (en) * 2000-10-18 2002-05-09 Sekisui Chem Co Ltd Intermediate film for laminated glass and laminated glass
JP2014502928A (en) * 2011-01-19 2014-02-06 ザ プロクター アンド ギャンブル カンパニー Process for producing an adhesive joint between a hydrophilic nonwoven fabric and a hydrophobic nonwoven fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002128545A (en) * 2000-10-18 2002-05-09 Sekisui Chem Co Ltd Intermediate film for laminated glass and laminated glass
JP2014502928A (en) * 2011-01-19 2014-02-06 ザ プロクター アンド ギャンブル カンパニー Process for producing an adhesive joint between a hydrophilic nonwoven fabric and a hydrophobic nonwoven fabric
US8841505B2 (en) 2011-01-19 2014-09-23 The Procter & Gamble Company Process for making a bond between a hydrophilic and a hydrophobic nonwoven

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