JPH04250856A - Metallic carrier for exhaust gas purifying catalyst of automobile - Google Patents

Metallic carrier for exhaust gas purifying catalyst of automobile

Info

Publication number
JPH04250856A
JPH04250856A JP3000924A JP92491A JPH04250856A JP H04250856 A JPH04250856 A JP H04250856A JP 3000924 A JP3000924 A JP 3000924A JP 92491 A JP92491 A JP 92491A JP H04250856 A JPH04250856 A JP H04250856A
Authority
JP
Japan
Prior art keywords
outside cylinder
outer cylinder
metallic
foil
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3000924A
Other languages
Japanese (ja)
Other versions
JP3083161B2 (en
Inventor
Mikio Yamanaka
幹雄 山中
Keiichi Omura
圭一 大村
Masuhiro Fukaya
益啓 深谷
Yoshimasa Zama
座間 芳正
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP03000924A priority Critical patent/JP3083161B2/en
Publication of JPH04250856A publication Critical patent/JPH04250856A/en
Application granted granted Critical
Publication of JP3083161B2 publication Critical patent/JP3083161B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

PURPOSE:To decrease the noises radiated from the above carrier which is superposed and joined with metallic flat foil and metallic corrugated foil and is inserted into a metallic outside cylinder and to decrease the uncomfortable noises of high frequencies by constituting the above-mentioned outside cylinder of double layers of metallic plates in contact with each other and specifying the thickness of the outside cylinder to a specific thickness or above. CONSTITUTION:The above-mentioned carrier 1 which is superposed and joined with the metallic flat foil 3 and the metallic corrugated foil 4 is inserted into the metallic outside cylinder 6. This outside cylinder 6 is constituted of the double layers of the metallic plates 7, 8 in contact with each other and the thickness of the outside cylinder 6 is specified to >=1.6mm in total. Namely, the outside cylinder 6 is formed as thick as >=1.6mm in total and, therefore, the transmission sounds are drastically attenuated at the time of passing the outside cylinder 6. In addition, the outside cylinder 6 is made into the plural layers, by which the natural frequencies of the outside cylinder are lowered and the frequencies of the resonance sounds are lowered. Consequently, the noises radiated from the metal carrier are decreased and the uncomfortable noises of the high frequencies are decreased as well.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】この発明は、自動車排ガスを浄化
する触媒メタル担体に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a catalyst metal carrier for purifying automobile exhaust gas.

【0002】0002

【従来の技術】自動車などの排ガスの浄化に触媒コンバ
ータが広く用いられている。自動車用触媒コンバータは
、排ガス中のCO,HC およびNOx の3成分を同
時に酸化・還元して浄化する3元系触媒が通常用いられ
ている。 触媒として、Pt/Rh やPd/Rh などが用いら
れ、またこれらを担持するγ−アルミナの基体としてメ
タル担体が採用され始めている。メタル担体は金属平箔
と金属波箔とを交互に重ね合せてハニカムを形成し、波
箔に触媒を担持させたものである。箔の材料として、2
0Cr−5Alステンレス鋼などの耐熱金属材料が用い
られる。また、箔の厚みは50μm 程度である。平箔
と波箔とはろう付などにより接合されている。ハニカム
は円筒形またはレーストラック形断面をなしており、C
r鋼またはNi−Cr 鋼などの耐熱鋼製の外筒に挿入
されている。上記触媒コンバータは、エキゾーストマニ
ホルドと消音器との間に取り付けられている。
BACKGROUND OF THE INVENTION Catalytic converters are widely used to purify exhaust gas from automobiles and the like. Automotive catalytic converters typically use a three-way catalyst that simultaneously oxidizes and reduces three components, CO, HC, and NOx in exhaust gas. Pt/Rh, Pd/Rh, etc. are used as catalysts, and metal carriers are beginning to be employed as substrates for γ-alumina supporting these catalysts. The metal carrier is formed by alternately stacking flat metal foils and corrugated metal foils to form a honeycomb, and the corrugated foils support the catalyst. As a foil material, 2
A heat-resistant metal material such as 0Cr-5Al stainless steel is used. Further, the thickness of the foil is about 50 μm. The flat foil and the corrugated foil are joined by brazing or the like. The honeycomb has a cylindrical or racetrack cross-section, C
It is inserted into an outer cylinder made of heat-resistant steel such as R steel or Ni-Cr steel. The catalytic converter is installed between the exhaust manifold and the muffler.

【0003】0003

【発明が解決しようとする課題】メタル担体では平箔と
波箔とが上述のように接合され、かく形成されたハニカ
ムが直接外筒に接合されている。一方、ここを流れる排
気ガスはエンジンの爆発音や排気音振動をまだ保有して
いるため、上記接合部分を通して外筒を振動させ、メタ
ル担体は大きな騒音を放射する。特に、レーストラック
型メタル担体では、外筒の平行部分が排気ガスによって
振動し易い構造となっている。このために、メタル担体
は従来のセラミック (コーディエライト) 担体に比
べて騒音が大きかった。また、メタル担体からの放射音
には、外筒壁を通過する透過音と外筒自体の共振音の2
成分がある。透過音に対しては外筒の厚さを増して面密
度を大きくすればよい。しかし、外筒を厚くすれば外筒
の剛性が増して、共振音は周波数が高くなり、かえって
不快感を与えるという問題があった。そこで、この発明
はメタル担体から放射される騒音を低くし、不快な高周
波数の騒音を少なくすることができる自動車排気ガス浄
化触媒用メタル担体を提供しようとするのものである。
[Problems to be Solved by the Invention] In the metal carrier, the flat foil and the corrugated foil are joined as described above, and the honeycomb thus formed is directly joined to the outer cylinder. On the other hand, the exhaust gas flowing through this still contains the engine's explosion sound and exhaust sound vibrations, so it vibrates the outer cylinder through the joint, and the metal carrier emits loud noise. In particular, the racetrack type metal carrier has a structure in which the parallel portions of the outer cylinder are likely to vibrate due to exhaust gas. For this reason, metal carriers were noisier than traditional ceramic (cordierite) carriers. In addition, there are two types of sound radiated from the metal carrier: transmitted sound passing through the outer cylinder wall and resonance sound of the outer cylinder itself.
There are ingredients. To deal with transmitted sound, it is sufficient to increase the surface density by increasing the thickness of the outer cylinder. However, if the outer cylinder is made thicker, the rigidity of the outer cylinder increases, and the frequency of the resonant sound becomes higher, which causes a problem of causing discomfort. Therefore, the present invention aims to provide a metal carrier for an automobile exhaust gas purification catalyst that can reduce noise emitted from the metal carrier and reduce unpleasant high-frequency noise.

【0004】0004

【課題を解決するための手段】この発明の自動車排気ガ
ス浄化触媒用メタル担体は、金属平箔と金属波箔とが重
ね合されて接合され、金属製外筒に挿入されたメタル担
体において、上記外筒が互いに接する金属板の複層から
なっている。そして、上記外筒の厚みは合計で1.6 
mm以上である。
[Means for Solving the Problems] The metal carrier for an automobile exhaust gas purification catalyst of the present invention has a metal carrier in which a metal flat foil and a metal corrugated foil are overlapped and bonded and inserted into a metal outer cylinder. The outer cylinder is made of multiple layers of metal plates that are in contact with each other. The total thickness of the outer cylinder is 1.6
mm or more.

【0005】外筒は、複数枚の金属板を重ね合せて複層
に形成する。また、一枚の金属板を渦状に巻き重ねても
よい。隣り合う金属板は、互いに接している。層数は2
〜3が実用的である。3層の場合、2枚の板の間に金属
箔を挟み込んでもよい。挟み込む金属箔は、耐熱性を考
慮してステンレス箔を用いる。外筒の厚みが1.6 m
m未満であると、十分な遮音効果を得ることができず、
また高温排気ガスの圧力により外筒が変形する。
[0005] The outer cylinder is formed into a multilayer structure by overlapping a plurality of metal plates. Alternatively, one metal plate may be spirally wound and overlapped. Adjacent metal plates are in contact with each other. The number of layers is 2
~3 is practical. In the case of three layers, a metal foil may be sandwiched between two plates. As the metal foil to be sandwiched, stainless steel foil is used in consideration of heat resistance. The thickness of the outer cylinder is 1.6 m
If it is less than m, sufficient sound insulation effect cannot be obtained,
Moreover, the outer cylinder is deformed by the pressure of the high-temperature exhaust gas.

【0006】[0006]

【作用】外筒を1.6 mm以上と厚くすることにより
透過音に対する面密度が大きくなり、透過音は外筒を通
過する際にそれだけ大きく減衰される。また、外筒を複
数層にすることにより、境界面の摩擦により外筒のダン
ピング特性が向上して共振音を減らし、外筒の剛性のア
ップが少ないので外筒の固有振動数は上がらず、共振音
の周波数は高くならない。
[Operation] By increasing the thickness of the outer cylinder to 1.6 mm or more, the areal density for transmitted sound increases, and the transmitted sound is attenuated to a greater extent when passing through the outer cylinder. In addition, by making the outer cylinder into multiple layers, the damping characteristics of the outer cylinder are improved due to the friction at the interface, reducing resonance noise, and since the increase in rigidity of the outer cylinder is small, the natural frequency of the outer cylinder does not increase. The frequency of the resonant sound does not become high.

【0007】[0007]

【実施例】第1図はこの発明の実施例を示しており、メ
タル担体の縦断面図である。メタル担体1は、レースト
ラック形ハニカム2を備えている。レーストラック形ハ
ニカム2は、平箔3と波箔4とが重ね合わされ、渦状と
なっている。平箔3と波箔4とはろう付されている。レ
ーストラック形ハニカム2は、レーストラック形外筒6
に挿入されている。レーストラック形外筒6は、内部筒
7および外部筒8からなる2重筒である。レーストラッ
ク形ハニカム2の外周面と内部筒7の内周面とはろう付
により接合されている。
DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 shows an embodiment of the present invention, and is a longitudinal sectional view of a metal carrier. The metal carrier 1 is provided with a racetrack-shaped honeycomb 2. The racetrack-shaped honeycomb 2 has a spiral shape in which a flat foil 3 and a corrugated foil 4 are overlapped. The flat foil 3 and the corrugated foil 4 are brazed together. The racetrack-shaped honeycomb 2 has a racetrack-shaped outer cylinder 6
is inserted into. The racetrack-shaped outer cylinder 6 is a double cylinder consisting of an inner cylinder 7 and an outer cylinder 8. The outer circumferential surface of the racetrack-shaped honeycomb 2 and the inner circumferential surface of the inner cylinder 7 are joined by brazing.

【0008】ここで、上記メタル担体からの放射音の測
定例について説明する。厚さ50 mの20Cr−5A
lステンレス鋼箔よりなる平箔および波箔を重ね合わせ
て円筒状に巻いた。ついで、これを径方向に押圧してレ
ーストラック形ハニカム (短径:80 mm 、長径
:160 mm、長さ:105mm)  を製作した。 一方、板厚1 mmの19Crステンレス鋼板にあらか
じめリブ加工した後、レーストラック形に成形し、縁部
を溶接して内部筒とした。また、板厚1.2 mmの1
9Crステンレス鋼板をリブ加工したうえ、レーストラ
ック形に成形して外部筒とした。この外部筒を上記内部
筒に重ね合せ、外部筒の縁部を溶接して2層のステンレ
ス鋼板よりなる外筒を準備した。そして、外筒に上記ハ
ニカムを挿入し、波箔・平箔・内部筒を相互にろう付し
たのち、波箔に触媒Pt/Rh を担持させた。また別
に、板厚1.5 mmの19Crステンレス鋼板を用い
て、上記実施例のものと同一外形寸法の1層レーストラ
ック形外筒を製作した。このレーストラック形外筒に同
様のハニカムを挿入して前者と同様にろう付を行ってメ
タル担体とし、これを比較例 (従来例) として用い
た。
[0008] Here, an example of measuring the sound radiated from the metal carrier will be explained. 20Cr-5A with a thickness of 50 m
A flat foil and a corrugated stainless steel foil were overlapped and rolled into a cylindrical shape. Then, this was pressed in the radial direction to produce a racetrack-shaped honeycomb (shorter diameter: 80 mm, longer diameter: 160 mm, length: 105 mm). On the other hand, a 1 mm thick 19Cr stainless steel plate was processed with ribs in advance, then formed into a racetrack shape, and the edges were welded to form an internal cylinder. In addition, 1 with a plate thickness of 1.2 mm
A 9Cr stainless steel plate was processed with ribs and formed into a racetrack shape to form an external cylinder. This outer tube was superimposed on the inner tube, and the edges of the outer tube were welded to prepare an outer tube made of two layers of stainless steel plates. Then, the honeycomb was inserted into the outer tube, and the corrugated foil, flat foil, and inner tube were brazed to each other, and then the catalyst Pt/Rh was supported on the corrugated foil. Separately, a single-layer racetrack-shaped outer cylinder having the same external dimensions as that of the above example was manufactured using a 19Cr stainless steel plate with a thickness of 1.5 mm. A similar honeycomb was inserted into this racetrack-shaped outer cylinder and brazed in the same manner as the former to form a metal carrier, which was used as a comparative example (conventional example).

【0009】つぎに、上記のようにして製作したメタル
担体の両端面にコーンを溶接し、エンジンの排気ガス管
の途中に接続した。また、メタル担体を800mm角の
遮音ボックスで囲み、エンジン音を直接検出しないよう
にした。測定用マイクロフォンをメタル担体上250 
mmの位置に配置し、各エンジン回転数によるメタル担
体からの放射音を測定した。エンジン回転数3000 
rpmにおける測定結果、外筒が板厚1.5 mmのス
テンレス鋼板で構成されたメタル担体 (従来例) に
比べて、外筒が板厚1.0 mmと1.2mm のステ
ンレス鋼板2枚で構成されたメタル担体 (本発明) 
では放射音が8 db低下することが明らかとなった。 また、周波数解析 (FFT) の結果、各共振点が比
較例に比べて低周波側にシフトしていた。さらに、外筒
の各層の厚みおよび層数が異なるいくつかの例について
測定した結果を表1に示す。表1は、エンジン回転数3
000 rpmにおける放射音レベルを相対比較で示し
ている。
[0009] Next, cones were welded to both end faces of the metal carrier produced as described above, and the cones were connected to the middle of an exhaust gas pipe of an engine. Additionally, the metal carrier was surrounded by an 800 mm square sound insulating box to prevent direct detection of engine noise. Measurement microphone on metal carrier 250
The metal carrier was placed at a position of mm, and the sound emitted from the metal carrier at each engine speed was measured. Engine speed 3000
The measurement results at rpm show that compared to the metal carrier (conventional example) in which the outer cylinder is made of stainless steel plates with a plate thickness of 1.5 mm, the outer cylinder is made of two stainless steel plates with plate thicknesses of 1.0 mm and 1.2 mm. Structured metal carrier (invention)
It was revealed that the radiated sound was reduced by 8 db. Furthermore, as a result of frequency analysis (FFT), each resonance point was shifted to the lower frequency side compared to the comparative example. Furthermore, Table 1 shows the results of measurements for several examples in which the thickness and number of layers of each layer of the outer cylinder were different. Table 1 shows engine speed 3
The radiation sound level at 000 rpm is shown in relative comparison.

【0010】0010

【表1】[Table 1]

【0011】表1に示す測定結果から次のことが明らか
である。0.8−0.8 (2枚) の例は外筒の厚み
が1.6 mmであり、従来例の外筒の厚みにほぼ等し
いが、外筒を2層にすることにより放射音が6 db低
下している。また、外筒の内部筒と外部筒との間に厚み
0.05 mm のステンレス鋼箔を挟み込むことによ
っても、放射音レベルは低くなる。さらに、外筒の平行
部にリブを付けることも、放射音レベル低下に効果があ
る。
From the measurement results shown in Table 1, the following is clear. In the case of 0.8-0.8 (2 pieces), the thickness of the outer cylinder is 1.6 mm, which is almost the same as the thickness of the conventional example, but the radiated sound is reduced by making the outer cylinder two layers. 6 db lower. The radiated sound level can also be lowered by inserting a stainless steel foil with a thickness of 0.05 mm between the inner and outer cylinders of the outer cylinder. Furthermore, adding ribs to the parallel portions of the outer cylinder is also effective in reducing the level of radiated sound.

【0012】0012

【発明の効果】この発明の自動車排気ガス浄化触媒用メ
タル担体によれば、外筒を合計で1.6 mm以上と厚
くしているので、透過音は外筒を通過する際に大きく減
衰される。また、外筒を複数層にすることにより、外筒
の固有振動数が下がり、共振音の周波数は低くなる。こ
の結果、メタル担体から放射される騒音は低くなり、不
快な高周波数の騒音も少なくなる。
[Effects of the Invention] According to the metal carrier for an automobile exhaust gas purification catalyst of the present invention, since the outer cylinder is thickened to a total thickness of 1.6 mm or more, transmitted sound is greatly attenuated when passing through the outer cylinder. Ru. Furthermore, by forming the outer cylinder into multiple layers, the natural frequency of the outer cylinder is lowered, and the frequency of the resonant sound is lowered. As a result, the metal carrier emits less noise and less unpleasant high frequency noise.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】この発明の実施例を示すメタル担体の縦断面図
である。
FIG. 1 is a longitudinal sectional view of a metal carrier showing an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1  メタル担体 2  レーストラック形ハニカム 3  平箔 4  波箔 6  外筒 7  内部筒 8  外部筒 1 Metal carrier 2 Racetrack shaped honeycomb 3 Flat foil 4 Wave foil 6 Outer cylinder 7 Internal cylinder 8 External tube

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  金属平箔と金属波箔とが重ね合されて
接合され、金属製外筒に挿入されたメタル担体において
、前記外筒が互いに接する金属板の複層からなり、外筒
の厚みが合計で1.6 mm以上であることを特徴とす
る自動車排気ガス浄化触媒用メタル担体。
Claim 1: In a metal carrier in which a flat metal foil and a corrugated metal foil are overlapped and bonded and inserted into a metal outer cylinder, the outer cylinder is composed of multiple layers of metal plates in contact with each other, A metal carrier for an automobile exhaust gas purification catalyst, characterized in that the total thickness is 1.6 mm or more.
JP03000924A 1991-01-09 1991-01-09 Metal carrier for automobile exhaust gas purification catalyst Expired - Lifetime JP3083161B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03000924A JP3083161B2 (en) 1991-01-09 1991-01-09 Metal carrier for automobile exhaust gas purification catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03000924A JP3083161B2 (en) 1991-01-09 1991-01-09 Metal carrier for automobile exhaust gas purification catalyst

Publications (2)

Publication Number Publication Date
JPH04250856A true JPH04250856A (en) 1992-09-07
JP3083161B2 JP3083161B2 (en) 2000-09-04

Family

ID=11487239

Family Applications (1)

Application Number Title Priority Date Filing Date
JP03000924A Expired - Lifetime JP3083161B2 (en) 1991-01-09 1991-01-09 Metal carrier for automobile exhaust gas purification catalyst

Country Status (1)

Country Link
JP (1) JP3083161B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001501705A (en) * 1996-10-04 2001-02-06 エミテツク ゲゼルシヤフト フユア エミツシオンステクノロギー ミツト ベシユレンクテル ハフツング Honeycomb body with heat insulator especially for exhaust gas catalyst
WO2006092169A1 (en) * 2005-03-03 2006-09-08 Arvinmeritor Emissions Technologies Gmbh Housing for a component of an exhaust system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001501705A (en) * 1996-10-04 2001-02-06 エミテツク ゲゼルシヤフト フユア エミツシオンステクノロギー ミツト ベシユレンクテル ハフツング Honeycomb body with heat insulator especially for exhaust gas catalyst
WO2006092169A1 (en) * 2005-03-03 2006-09-08 Arvinmeritor Emissions Technologies Gmbh Housing for a component of an exhaust system

Also Published As

Publication number Publication date
JP3083161B2 (en) 2000-09-04

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