JPH04247213A - Dehumidifying deodorant - Google Patents
Dehumidifying deodorantInfo
- Publication number
- JPH04247213A JPH04247213A JP3013257A JP1325791A JPH04247213A JP H04247213 A JPH04247213 A JP H04247213A JP 3013257 A JP3013257 A JP 3013257A JP 1325791 A JP1325791 A JP 1325791A JP H04247213 A JPH04247213 A JP H04247213A
- Authority
- JP
- Japan
- Prior art keywords
- particles
- deodorant
- dehumidifying
- moisture absorbent
- deodorizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 55
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 43
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002250 absorbent Substances 0.000 claims abstract description 21
- 230000002745 absorbent Effects 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 15
- 150000002367 halogens Chemical class 0.000 claims abstract description 15
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 13
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000741 silica gel Substances 0.000 abstract description 8
- 229910002027 silica gel Inorganic materials 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 2
- 239000004745 nonwoven fabric Substances 0.000 abstract description 2
- 239000000969 carrier Substances 0.000 abstract 1
- 239000000499 gel Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treating Waste Gases (AREA)
- Drying Of Gases (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は脱湿脱臭剤、特に、長期
に渡って優れた脱湿および脱臭効果を維持することので
きる脱湿脱臭剤に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a dehumidifying and deodorizing agent, and more particularly to a dehumidifying and deodorizing agent that can maintain excellent dehumidifying and deodorizing effects over a long period of time.
【０００２】0002
【従来の技術とその課題】従来、脱湿脱臭剤としては、
シリカゲルと活性炭を混合したものが知られている。こ
の種の脱湿脱臭剤は、例えば、実公昭５０─４０６６０
号公報に開示されるように、袋状カバー体に収納され、
靴を保管する際にカビ，腐食，悪臭等が発生するのを防
止するために使用される。[Prior art and its problems] Conventionally, as a dehumidifying and deodorizing agent,
A mixture of silica gel and activated carbon is known. This type of dehumidifying and deodorizing agent is, for example,
As disclosed in the publication, it is housed in a bag-like cover body,
It is used to prevent mold, corrosion, bad odors, etc. from forming when storing shoes.
【０００３】しかしながら、前記脱湿脱臭剤では、脱臭
剤として活性炭を使用しているため、脱臭速度が遅く、
例えば、一晩靴内に挿入しておくだけでは十分な脱臭効
果を期待できなかった。However, since the dehumidifying and deodorizing agent uses activated carbon as a deodorizing agent, the deodorizing speed is slow;
For example, it was not possible to expect a sufficient deodorizing effect just by inserting it into shoes overnight.
【０００４】そこで、脱臭剤として、前記活性炭に代え
て、例えば、安定化二酸化塩素を使用することが考えら
れる。しかし、担体に安定化二酸化塩素を含浸させたも
のでは、脱臭効果を向上させることはできるが、脱臭期
間が短いという欠点があることが明らかになった。[0004] Therefore, it is conceivable to use, for example, stabilized chlorine dioxide as a deodorizing agent instead of the activated carbon. However, it has become clear that when a carrier is impregnated with stabilized chlorine dioxide, the deodorizing effect can be improved, but the deodorizing period is short.
【０００５】したがって、本発明は脱湿作用は勿論のこ
と、優れた脱臭作用を長期に渡って維持することのでき
る脱湿脱臭剤を提供することを目的とする。[0005] Accordingly, an object of the present invention is to provide a dehumidifying and deodorizing agent that can maintain not only a dehumidifying effect but also an excellent deodorizing effect over a long period of time.
【０００６】[0006]
【課題を解決するための手段】本発明は、前記目的を達
成するため、脱湿脱臭剤を、吸湿剤粒子と、二酸化ハロ
ゲンを含浸させるとともに、外表面を樹脂でコーティン
グした脱臭剤粒子との混合物から構成したものである。
そして、形成される樹脂皮膜は、前記二酸化ハロゲンが
徐々に放出されるような厚さ（通常、０．１ｍｍ以下）
にする。[Means for Solving the Problems] In order to achieve the above object, the present invention provides a dehumidifying and deodorizing agent comprising moisture absorbent particles and deodorizing particles impregnated with halogen dioxide and coated on the outer surface with a resin. It is composed of a mixture. The resin film formed has a thickness such that the halogen dioxide is gradually released (usually 0.1 mm or less).
Make it.
【０００７】前記吸湿剤粒子はシリカゲル，ゼオライト
等、公知の吸湿剤からなる粒子を使用でき、その粒径は
任意であるが、通常１〜５ｍｍ程度に設定される。また
、前記脱臭剤粒子の担体は二酸化ハロゲン溶液を担持で
きるものであれば任意のものを使用できるが、経済的観
点からは前記吸湿剤粒子と同じものを使用するのが好適
である。さらに、前記二酸化ハロゲンとしては安定化二
酸化塩素が好適である。[0007] As the moisture absorbent particles, particles made of a known moisture absorbent such as silica gel or zeolite can be used, and the particle size is arbitrary, but is usually set to about 1 to 5 mm. Further, as the carrier for the deodorizing agent particles, any carrier can be used as long as it can support the halogen dioxide solution, but from an economical point of view, it is preferable to use the same carrier as the moisture absorbent particles. Furthermore, stabilized chlorine dioxide is suitable as the halogen dioxide.
【０００８】前記安定化二酸化塩素は、前記脱臭剤粒子
中の濃度が１００〜３０００ｐｐｍとなるように担体に
含浸させるのが望ましい。前記吸湿剤粒子と脱臭剤粒子
とは、重量比で１：９〜９：１となるように混合し、前
記吸湿剤粒子と脱臭剤粒子との混合物中の濃度が５０〜
１０００ｐｐｍとなるように混合するのが好適である。[0008] The stabilized chlorine dioxide is preferably impregnated into the carrier so that the concentration in the deodorant particles is 100 to 3000 ppm. The moisture absorbent particles and deodorant particles are mixed in a weight ratio of 1:9 to 9:1, and the concentration of the moisture absorbent particles and deodorant particles in the mixture is 50 to 9:1.
It is suitable to mix so that it becomes 1000 ppm.
【０００９】前記コーティング樹脂としては、任意の合
成樹脂を使用できるが、アクリル酸メトキシエチル・ア
クリル酸ヒドロキシエチル・アクリル酸ブチル共重合体
，アクリル酸メトキシエチル・アクリル酸ヒドロキシエ
チル共重合体等のアクリル系樹脂が好ましい。As the coating resin, any synthetic resin can be used, but acrylic resins such as methoxyethyl acrylate/hydroxyethyl acrylate/butyl acrylate copolymer, methoxyethyl acrylate/hydroxyethyl acrylate copolymer, etc. type resins are preferred.
【００１０】前記脱臭剤粒子のコーティング樹脂は、顔
料およびカーボンブラックのうちの少なくとも１種を混
合したものでもよく、前記顔料としては、公知の無機顔
料を使用するのが好ましい。The coating resin for the deodorant particles may be a mixture of at least one of a pigment and carbon black, and it is preferable to use a known inorganic pigment as the pigment.
【００１１】[0011]
【作用】本発明によれば、吸湿剤粒子は従来のものと同
様、湿気を吸収するが、脱臭剤粒子は外表面を樹脂によ
りコーティングされているため、その内部に含浸させた
二酸化ハロゲンを徐々に放出し、そのガスが臭気成分と
反応して脱臭する。[Operation] According to the present invention, the moisture absorbent particles absorb moisture in the same way as conventional ones, but since the outer surface of the deodorant particles is coated with resin, the halogen dioxide impregnated inside the particles gradually absorbs moisture. The gas reacts with odor components and deodorizes them.
【００１２】0012
【実施例】次に、本発明に係る脱湿脱臭剤を靴の脱湿脱
臭具に適用した場合について添付図面を参照して説明す
る。この脱湿脱臭具は、布，不織布，その他通気性およ
び可撓性を有する材料からなる袋状カバー体１に吸湿剤
粒子２および脱臭剤粒子３を収納したものである。[Embodiment] Next, a case in which the dehumidifying and deodorizing agent according to the present invention is applied to a dehumidifying and deodorizing device for shoes will be described with reference to the accompanying drawings. This dehumidifying and deodorizing tool has moisture absorbent particles 2 and deodorizing particles 3 housed in a bag-like cover body 1 made of cloth, nonwoven fabric, or other breathable and flexible material.
【００１３】前記吸湿剤粒子２には、市販の粒状シリカ
ゲルを使用する。一方、前記脱臭剤粒子３は、図２に示
すように、担体４となるシリカゲル粒子に安定化二酸化
塩素溶液を含浸させ、その表面に樹脂皮膜５を形成した
ものである。この脱臭剤粒子３は、例えば、次のように
して製造することができる。For the moisture absorbent particles 2, commercially available granular silica gel is used. On the other hand, as shown in FIG. 2, the deodorant particles 3 are obtained by impregnating silica gel particles serving as a carrier 4 with a stabilized chlorine dioxide solution and forming a resin film 5 on the surface thereof. The deodorizer particles 3 can be manufactured, for example, as follows.
【００１４】まず、粒状シリカゲル４を図示しない回転
ドラム内に収容し、このドラムを回転させながら安定化
二酸化塩素溶液（助川化学製）を前記粒状シリカゲル４
に噴霧し、安定化二酸化塩素の濃度が１００〜３０００
ｐｐｍとなるように含浸させる。そして、安定化二酸化
塩素を含浸させた後、さらにアクリル酸メトキシエチル
・アクリル酸ヒドロキシエチル・アクリル酸ブチル共重
合体（互応化学工業製商品名 プラサイズＬ─３０１
）にカーボンブラックを混合した樹脂液を噴霧し、前記
シリカゲルの表面に樹脂皮膜を形成させる。First, the granular silica gel 4 is placed in a rotating drum (not shown), and while the drum is rotated, a stabilized chlorine dioxide solution (manufactured by Sukegawa Chemical Co., Ltd.) is applied to the granular silica gel 4.
The concentration of stabilized chlorine dioxide is 100-3000.
Impregnate it so that it becomes ppm. Then, after impregnating with stabilized chlorine dioxide, methoxyethyl acrylate, hydroxyethyl acrylate, and butyl acrylate copolymer (product name: Plastize L-301 manufactured by Gooo Kagaku Kogyo Co., Ltd.) is added.
) is sprayed with a resin liquid mixed with carbon black to form a resin film on the surface of the silica gel.
【００１５】このようにして形成した脱臭剤粒子３は外
観が銀黒色で、前記吸湿剤粒子２と判別可能となってお
り、混合する際の材料間違いを防止できる。そして、前
記吸湿剤粒子２と脱臭剤粒子３とを重量比が１：９〜９
：１となるように混合して袋状カバー体１に収納するが
、混合物の二酸化塩素濃度が５０〜１０００ｐｐｍ、好
ましくは、２００〜５００ｐｐｍとなるように混合すれ
ば、靴の脱湿脱臭具に適用する脱湿脱臭剤として最適で
ある。The deodorant particles 3 thus formed have a silver-black appearance and can be distinguished from the moisture absorbent particles 2, thereby preventing mistakes in materials during mixing. Then, the moisture absorbent particles 2 and the deodorant particles 3 are mixed in a weight ratio of 1:9 to 9.
:1 and stored in the bag-like cover body 1.If the mixture is mixed so that the chlorine dioxide concentration of the mixture is 50 to 1000 ppm, preferably 200 to 500 ppm, it can be used as a dehumidifying and deodorizing device for shoes. It is ideal as a dehumidifying and deodorizing agent.
【００１６】なお、脱湿脱臭具では、靴内に挿入してお
けば吸湿剤粒子２が周囲の水分を吸着して乾燥させる一
方、脱臭剤粒子３からはコーティングした樹脂のために
徐々にガス化した安定化二酸化塩素が放出され、所望の
脱臭効果を長期に渡って得られることにより悪臭を抑え
るとともに除菌を行うことができる。[0016] In the dehumidifying and deodorizing device, if inserted into the shoe, the moisture absorbent particles 2 will adsorb the surrounding moisture and dry it, while the deodorant particles 3 will gradually release gas due to the coated resin. The stabilized chlorine dioxide is released, and the desired deodorizing effect can be obtained over a long period of time, making it possible to suppress bad odors and sterilize bacteria.
【００１７】[0017]
【発明の効果】以上の説明から明らかなように、本発明
に係る脱湿脱臭剤によれば、吸湿剤粒子による脱湿作用
は勿論のこと、脱臭剤粒子に含浸させた二酸化ハロゲン
が外表面にコーティングした樹脂のために徐々にガス化
して周囲に放出されるので、長期に渡って、しかも、急
速に脱臭および除菌を行うことができる。[Effects of the Invention] As is clear from the above explanation, according to the dehumidifying and deodorizing agent of the present invention, not only the moisture absorbing agent particles have a dehumidifying effect, but also the halogen dioxide impregnated in the deodorant particles is Because of the resin coated on the surface, it gradually gasifies and is released into the surrounding environment, allowing for rapid deodorization and sterilization over a long period of time.
【００１８】そして、前記脱臭剤粒子に二酸化ハロゲン
を１００〜３０００ｐｐｍの濃度となるように含浸させ
、前記吸湿剤粒子と脱臭剤粒子とを重量比が１：９〜９
：１となるように混合すれば、二酸化ハロゲンの放出を
長期間行うのに適しており、特に、全体の濃度が５０〜
１０００ｐｐｍ、好ましくは、２００〜５００ｐｐｍと
なるように混合すれば、靴の脱湿脱臭に最適である。[0018] Then, the deodorizing agent particles are impregnated with halogen dioxide to a concentration of 100 to 3000 ppm, and the weight ratio of the moisture absorbing agent particles and deodorizing agent particles is 1:9 to 9.
:1, it is suitable for releasing halogen dioxide for a long period of time, especially when the total concentration is 50~1.
When mixed at a concentration of 1000 ppm, preferably 200 to 500 ppm, it is optimal for dehumidifying and deodorizing shoes.
【００１９】また、脱臭剤として二酸化ハロゲンを使用
しているため、より脱臭効果が向上するとともに、脱臭
期間が長くなる。Furthermore, since halogen dioxide is used as a deodorizing agent, the deodorizing effect is further improved and the deodorizing period becomes longer.
【００２０】さらに、コーティング樹脂に原料およびカ
ーボンブラックのいずれか一方を混合するようにすれば
、吸湿剤粒子と材料間違いで混合されるのを防止できる
。Furthermore, by mixing either the raw material or carbon black with the coating resin, it is possible to prevent the moisture absorbent particles from being mixed with the wrong material.
【図１】 脱湿脱臭具の斜視図である。FIG. 1 is a perspective view of a dehumidifying and deodorizing tool.
【図２】 脱臭剤粒子の断面図である。FIG. 2 is a cross-sectional view of deodorant particles.
１…カバー体、２…吸湿剤粒子、３…脱臭剤粒子、４…
担体、５…樹脂皮膜。DESCRIPTION OF SYMBOLS 1...Cover body, 2...Moisture absorbent particles, 3...Deodorant particles, 4...
Carrier, 5...resin film.
Claims (6)
させるとともに、外表面を樹脂でコーティングした脱臭
剤粒子との混合物からなることを特徴とする脱湿脱臭剤
。1. A dehumidifying and deodorizing agent comprising a mixture of moisture absorbent particles and deodorizing particles impregnated with halogen dioxide and whose outer surface is coated with a resin.
度が１００〜３０００ｐｐｍであることを特徴とする請
求項１に記載の脱湿脱臭剤。2. The dehumidifying and deodorizing agent according to claim 1, wherein the halogen dioxide concentration in the deodorant particles is 100 to 3000 ppm.
が重量比で１：９〜９：１であることを特徴とする請求
項２に記載の脱湿脱臭剤。3. The dehumidifying and deodorizing agent according to claim 2, wherein the mixing ratio of the moisture absorbent particles and the deodorizing agent particles is 1:9 to 9:1 by weight.
中、二酸化ハロゲン濃度が５０〜１０００ｐｐｍである
ことを特徴とする請求項３に記載の脱湿脱臭剤。4. The dehumidifying and deodorizing agent according to claim 3, wherein the mixture of the moisture absorbent particles and the deodorizing agent particles has a halogen dioxide concentration of 50 to 1000 ppm.
およびカーボンブラックの少なくとも１種を含有するこ
とを特徴とする請求項１ないし請求項４のいずれかに記
載の脱湿脱臭剤。5. The dehumidifying and deodorizing agent according to claim 1, wherein the coating resin of the deodorant particles contains at least one of a pigment and carbon black.
素であることを特徴とする請求項１ないし請求項５のい
ずれかに記載の脱湿脱臭剤。6. The dehumidifying and deodorizing agent according to claim 1, wherein the halogen dioxide is stabilized chlorine dioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3013257A JPH04247213A (en) | 1991-02-04 | 1991-02-04 | Dehumidifying deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3013257A JPH04247213A (en) | 1991-02-04 | 1991-02-04 | Dehumidifying deodorant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04247213A true JPH04247213A (en) | 1992-09-03 |
Family
ID=11828166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3013257A Pending JPH04247213A (en) | 1991-02-04 | 1991-02-04 | Dehumidifying deodorant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04247213A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108124916A (en) * | 2017-12-04 | 2018-06-08 | 石永明 | A kind of composite type mouldproof agent |
| US10500566B2 (en) | 2018-03-07 | 2019-12-10 | Faz Too, Llc | Desiccant and deodorizing device |
-
1991
- 1991-02-04 JP JP3013257A patent/JPH04247213A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108124916A (en) * | 2017-12-04 | 2018-06-08 | 石永明 | A kind of composite type mouldproof agent |
| US10500566B2 (en) | 2018-03-07 | 2019-12-10 | Faz Too, Llc | Desiccant and deodorizing device |
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