JPH04231057A - Deodorizing bead agent - Google Patents
Deodorizing bead agentInfo
- Publication number
- JPH04231057A JPH04231057A JP2419089A JP41908990A JPH04231057A JP H04231057 A JPH04231057 A JP H04231057A JP 2419089 A JP2419089 A JP 2419089A JP 41908990 A JP41908990 A JP 41908990A JP H04231057 A JPH04231057 A JP H04231057A
- Authority
- JP
- Japan
- Prior art keywords
- deodorizing
- agent
- microorganisms
- bead
- microorganism
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 36
- 239000011324 bead Substances 0.000 title claims abstract description 28
- 244000005700 microbiome Species 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000001110 calcium chloride Substances 0.000 claims abstract description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 4
- 235000011148 calcium chloride Nutrition 0.000 claims abstract description 4
- 239000001103 potassium chloride Substances 0.000 claims abstract 2
- 239000002781 deodorant agent Substances 0.000 claims description 16
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 15
- 230000000813 microbial effect Effects 0.000 claims description 12
- 235000015097 nutrients Nutrition 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 8
- 241000588914 Enterobacter Species 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 241000235527 Rhizopus Species 0.000 claims description 6
- 235000010413 sodium alginate Nutrition 0.000 claims description 6
- 239000000661 sodium alginate Substances 0.000 claims description 6
- 229940005550 sodium alginate Drugs 0.000 claims description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- 241000228212 Aspergillus Species 0.000 claims description 5
- 241000194017 Streptococcus Species 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 235000010410 calcium alginate Nutrition 0.000 abstract description 3
- 239000000648 calcium alginate Substances 0.000 abstract description 3
- 229960002681 calcium alginate Drugs 0.000 abstract description 3
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 235000008935 nutritious Nutrition 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- 239000008103 glucose Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 235000014469 Bacillus subtilis Nutrition 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 4
- 230000004151 fermentation Effects 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 241001135265 Cronobacter sakazakii Species 0.000 description 3
- 240000005384 Rhizopus oryzae Species 0.000 description 3
- 235000013752 Rhizopus oryzae Nutrition 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 241001112078 Aspergillus usamii Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000194034 Lactococcus lactis subsp. cremoris Species 0.000 description 2
- 244000057717 Streptococcus lactis Species 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000193749 Bacillus coagulans Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000194032 Enterococcus faecalis Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000178960 Paenibacillus macerans Species 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 241001552694 Rhizobacter Species 0.000 description 1
- 235000014962 Streptococcus cremoris Nutrition 0.000 description 1
- 235000014897 Streptococcus lactis Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、微生物を利用する効率
よい消臭剤に関する。特に、常に、水分を抱えているこ
とができ、消臭活性の保持した微生物による消臭ビ−ズ
剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an efficient deodorant that utilizes microorganisms. In particular, it relates to deodorizing beads made of microorganisms that can always retain moisture and retain deodorizing activity.
【０００２】0002
【従来の技術】従来、アンモニア、硫化水素などの悪臭
を抑制し、汚物や生ゴミ等の悪臭を処理する消臭剤は、
液体のものが普通で、次いで固形のものもあるが、もと
もと消臭性の強い薬品は液体であるものが多いために、
それらを利用した消臭剤は液状の製品が主であった。[Prior Art] Conventionally, deodorants that suppress bad odors such as ammonia and hydrogen sulfide and treat bad odors such as filth and garbage have been used.
Usually, they are liquid, followed by solid ones, but since many chemicals with strong deodorizing properties are liquid,
Deodorants using these substances were mainly liquid products.
【０００３】一方、消臭剤の性能を評価する場合、一般
には、散布して数時間から２４時間程度までの消臭効果
の持続性を有するものが通常で、それ以上の長時間にわ
たり、消臭効果を示すものは、ほとんどない。この原因
として、活性成分の液体が、流れ出てしまうか、活性成
分が蒸散してしまうか等で、活性成分が継続的に働くこ
とが困難であることが考えられる。また、液体の消臭剤
は、悪臭を発する物質、ゴミを積層又は積み上げた上部
から作用させることが多いが、薬剤が液体であるので、
悪臭物質の隙間を通って、流れ、下部にたまり、上部か
ら中間層にわたって、消臭剤が供給される量が不足し、
このために、消臭剤自体が活性の高いものであっても、
消臭効果を発揮できないことがあった。特に、長時間に
渡って、消臭効果を発揮し、実現することは、困難であ
った。On the other hand, when evaluating the performance of deodorants, it is common to find deodorizing effects that last from several hours to 24 hours after being sprayed; Very few exhibit odor effects. A possible cause of this is that it is difficult for the active ingredient to work continuously because the liquid of the active ingredient flows out or the active ingredient evaporates. In addition, liquid deodorants are often applied from the top of laminated or piled up substances and dirt that emit bad odors, but since the agent is a liquid,
The odor substances flow through the gaps, accumulate at the bottom, and the amount of deodorizing agent supplied from the top to the middle layer is insufficient.
For this reason, even if the deodorant itself is highly active,
In some cases, the deodorizing effect could not be achieved. In particular, it has been difficult to exhibit and realize a deodorizing effect over a long period of time.
【０００４】また、微生物を利用した消臭剤も提案され
ているが、微生物は、その生育条件下になければ、活性
がなくなり、消臭効果も落ちることが多い。これは、微
生物の周囲に水分がなくなることにより、生じることが
最も多いものである。それは、微生物含有の消臭剤は、
空気に触れるような状態に置かれることが多いが、その
ような消臭剤からは、水分が蒸発し易く、直ぐに、微生
物の周囲から水分が除かれ易くなるためである。[0004] Deodorants that utilize microorganisms have also been proposed, but microorganisms often lose their activity and deodorizing effect unless conditions are met for their growth. This most often occurs due to a lack of moisture around the microorganism. It is a deodorant containing microorganisms.
This is because deodorants are often left in contact with the air, and moisture from such deodorants tends to evaporate, making it easy for the moisture to be quickly removed from the vicinity of microorganisms.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、上記の問題
点を解決するためになされたもので、消臭効果を長期に
わたり、継続させることのできる実用的な消臭ビ−ズ剤
を提供することを目的とする。また、水流中又は気流中
においた場合にも、流されず、また、気体中に拡散する
ことがなく、長期間にわたり、継続する消臭効果を有す
る消臭ビ−ズ剤を提供することを目的とする。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and provides a practical deodorizing bead agent that can maintain the deodorizing effect for a long period of time. The purpose is to Furthermore, it is an object of the present invention to provide a deodorizing bead agent that is not washed away or diffused into gas even when placed in a water stream or an air stream, and has a continuous deodorizing effect for a long period of time. purpose.
【０００６】[0006]
【課題を解決するための手段】本発明は、上記の技術的
な課題の解決のために、成されたもので、微生物成分と
そのための栄養源及びアルギン酸ナトリウムよりなる微
生物含有剤を、ＫＣｌ或いはＣａＣｌ２ と水とよりな
る塩含有剤の中に滴下することにより作成した微生物成
分含有ビ−ズを用いた消臭ビ−ズ剤を提供する。その微
生物部分は、バチルス（Ｂａｃｉｌｌｕｓ）属、ストレ
プトコッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ）属、エン
テロバクタ−（Ｅｎｔｅｒｏｂａｃｔｅｒ）属、リゾ−
プス（Ｒｈｉｚｏｐｕｓ）属、アスペルギルス（Ａｓｐ
ｅｒｇｉｌｌｕｓ）属のいずれ或いはその２つ以上を組
合わせで構成され、また、そのための前記栄養源として
は、炭素系栄養源が、グルコ−ス、糖類であり、窒素系
栄養源が、塩化アンモニウム、硫安であるものが好適で
ある。[Means for Solving the Problems] The present invention was made to solve the above-mentioned technical problems, and includes a microbial component, a nutrient source therefor, and a microbial-containing agent consisting of sodium alginate. To provide a deodorizing bead preparation using microbial component-containing beads prepared by dropping them into a salt-containing agent consisting of CaCl2 and water. The microbial part includes the genus Bacillus, Streptococcus, Enterobacter, and Rhizobacter.
Rhizopus spp., Aspergillus spp.
ergillus) or a combination of two or more thereof, and the carbon-based nutrients are glucose and sugars, and the nitrogen-based nutrients are ammonium chloride, ammonium chloride, Ammonium sulfate is preferred.
【０００７】[0007]
【作用】本発明の消臭ビ−ズ剤は、硬化したアルギン酸
ナトリウム或いはカルシウムからなる膜の中に、常に、
水分をためており、微生物成分は常に濡れているために
、微生物の活性が失われることなく、微生物は保護、保
存され、そのために、本発明の消臭ビ−ズ剤では、長期
間にわたり、消臭効果を失うことがない。更に、その消
臭ビ−ズ剤は、球体或いは球体に近い形状であるので、
その集合体にすると、ビ−ズの間に隙間ができ、空気が
流通し易く、微生物にとり必要な好気性雰囲気が容易に
、得られる。[Operation] The deodorizing bead agent of the present invention always has
Since moisture is stored and the microbial components are always wet, the microorganisms are protected and preserved without losing their activity. It does not lose its deodorizing effect. Furthermore, since the deodorant beads are spherical or nearly spherical in shape,
When made into an aggregate, gaps are created between the beads, allowing air to circulate easily, and an aerobic atmosphere necessary for microorganisms can be easily obtained.
【０００８】本発明の消臭ビ−ズ剤は、微生物成分を含
有せしめるために、その育成に必要な栄養を含有せしめ
る。そのために、炭素系栄養素としてグルコ−スを、及
び窒素系栄養素として塩化アンモニウムを含有せしめた
ものである。The deodorant beads of the present invention contain nutrients necessary for the growth of microorganisms in order to contain them. For this purpose, it contains glucose as a carbon-based nutrient and ammonium chloride as a nitrogen-based nutrient.
【０００９】その微生物部分は、バチルス（Ｂａｃｉｌ
ｌｕｓ）属、ストレプトコッカス（Ｓｔｒｅｐｔｏｃｏ
ｃｃｕｓ）属、エンテロバクタ−（Ｅｎｔｅｒｏｂａｃ
ｔｅｒ）属、リゾ−プス（Ｒｈｉｚｏｐｕｓ）属、アス
ペ ルギルス（Ａｓｐｅｒｇｉｌｌｕｓ）属のいずれ或
いはその２つ以上を組合わせで構成される 。更に、具
体的な微生物としては、■バチルス（Ｂａｃｉｌｌｕｓ
）属は、特に、バチルス・ズブチルス（Ｂ．ｓｕｂｔｉ
ｌｉｓ）［ＩＡＭ（Ｉｎｓｔｉｔｕｔｅ ｏｆ Ａｐｐ
ｌｉｅｄ Ｍｉｃｒｏｂｉｏｌｏｇｙ；東京大学応用微
生物研究所 有用菌株保存施設の略称；以下同様にこの
略称で示す）１１６８］が好適であるが、この他に、バ
チルス ・ナットウ（Ｂ．ｎａｔｔｏ）［ＩＦＯ（Ｉｎ
ｓｔｉｔｕｔｅ ｆｏｒ Ｆｅｒｍｅｎｔａｔｉｏｎ
Ｏｓａｋａ：財団法人発酵研究所：の略称；以下同様に
この略称で示す） ３００９］、バチルス・コアギュラ
ス（Ｂ．ｃｏａｇｕｌａｎｓ）［ＩＡＭ １１１５］、
バチルス・マセランス（Ｂ．ｍａｃｅｒａｎｓ）［ＩＡ
Ｍ １２４３］も利用で きる。■ストレプトコッカス
（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ）属の微生物としては、
ストレプトコッ カス・ファカリス（Ｓ．ｆａｅｃａｌ
ｉｓ）［ＩＡＭ １１１９］、ストレプトコッカス・ク
レモリス（Ｓ．ｃｒｅｍｏｒｉｓ）［ＩＡＭ １１５０
］及びストレプトコッカス・ラクチス（Ｓ．ｌａｃｔｉ
ｓ）［ＩＦＯ １２５４６］などを用いることができる
。また、カビの１種の■リゾ−プス（Ｒｈｉｚｏｐｕｓ
）属の微生物としては、リゾ−プス・フォルモサエンシ
ス（Ｒｈｉｚｏｐｕｓ ｆｏｒｍｏｓａｅｎｓｉｓ）［
ＩＡＭ ６２５０］、リゾ−プス・オリ ザエ（Ｒｈｉ
ｚｏｐｕｓ ｏｒｙｚａｅ）［ＩＡＭ ６００６］、リ
ゾ−プス・シュ−ドシネンシス（Ｒｈｉｚｏｐｕｓ ｐ
ｓｅｕｄｏｃｈｉｎｅｎｓｉｓ）［ＩＡＭ ６０４２］
などを用いることができる。■エンテロバクタ−（Ｅｎ
ｔｅｒｏｂａｃｔｅｒ）属の微生物としては、エンテロ
バクタ−・ サカザキ（Ｅ．ｓａｋａｚａｋｉｉ）［Ｉ
ＡＭ １２６６０］、エンテロバクタ−・アグロネラン
ス（Ｅ．ａｇｇｌｏｎｅｒａｎｓ［ＩＡＭ １２６５９
］などを用いることができる。そして■アスペルギルス
（Ａｓｐｅｒｇｉｌｌｕｓ）属の微生物としては、アス
ペルギルス ・ニガ−（Ａ．ｎｉｇｅｒ）［ＩＦＯ ４
０６６］、アスペルギルス・ウサミイ（Ａ．ｕｓａｍｉ
ｉ）［ＩＦＯ ６０８２］などを用いることができる。[0009] The microorganism part is Bacillus (Bacillus).
Streptococcus spp.
ccus), Enterobacter (Enterobacter)
ter), Rhizopus, and Aspergillus, or a combination of two or more thereof. Furthermore, as a specific microorganism, ■Bacillus (Bacillus)
) genus, in particular Bacillus subtilis (B. subti
lis) [IAM(Institute of App
Lied Microbiology; Abbreviation for Useful Bacterial Strain Preservation Facility, Institute of Applied Microbiology, The University of Tokyo; hereinafter referred to by this abbreviation) 1168] is suitable, but in addition to this, B. natto [IFO (In
institute for fermentation
Osaka: Abbreviation for Fermentation Research Institute; hereinafter referred to by this abbreviation) 3009], B. coagulans [IAM 1115],
Bacillus macerans [IA
M 1243] is also available. ■As a microorganism of the Streptococcus genus,
Streptococcus faecalis (S.faecal)
is) [IAM 1119], Streptococcus cremoris (S. cremoris) [IAM 1150
] and Streptococcus lactis (S. lactis
s) [IFO 12546] etc. can be used. In addition, a type of mold called Rhizopus (Rhizopus)
) microorganisms of the genus Rhizopus formosaensis [
IAM 6250], Rhizopus oryzae (Rhi
zopus oryzae) [IAM 6006], Rhizopus p.
seudochinensis) [IAM 6042]
etc. can be used. ■Enterobacter (En
Microorganisms of the genus terobacter include Enterobacter sakazakii [I
AM 12660], Enterobacter agglonerans (E. agglonerans [IAM 12659
] etc. can be used. ■ As a microorganism of the Aspergillus genus, Aspergillus niger [IFO 4
066], Aspergillus usami (A. usami
i) [IFO 6082] etc. can be used.
【００１０】以上の微生物は、その増殖により、酵素や
有機酸を生成する。即ち、悪臭源を中和する有機酸を生
成したり、悪臭源を分解する酵素を生成する。この消臭
有効成分を生成する作用は、長期的に継続し、悪臭源の
量が増して、消臭有効成分を消費してもかなりの期間、
補充生成させることができる。また、以上の微生物によ
り生産されたアミラ−ゼ、プロテア−ゼなどの酵素は短
時間で有機物や悪臭源を分解できる。本発明の消臭ビ−
ズ剤は、前記の微生物成分１〜５重量部、グルコ−ス１
〜５重量部、塩化アンモニウム２〜１０重量部、アルギ
ン酸ナトリウム或いはカルシウム５０〜１５０重量部、
水２０〜２００重量部から構成されるものが好適である
。含有するグルコ−スは、微生物の培地、栄養源となり
、有機酸に変換されるものであり、１重量部未満では、
微生物の生育を効果的に促進しない、また、５重量部を
超えると、アスペルギルス属やバチルス属などの特定の
微生物が増え過ぎて、他の属の微生物との共存が不可能
になるものである。また、塩化アンモニウムは、微生物
の生育、増殖の際に、窒素系栄養源となり、２重量部未
満では、微生物の生育を効果的に促進しなく、また、１
０重量部を超えると、複数の微生物の共存が不可能とな
るものである。[0010] The above microorganisms produce enzymes and organic acids through their multiplication. That is, it produces an organic acid that neutralizes the source of the malodor or an enzyme that decomposes the source of the malodor. The action of producing this deodorizing active ingredient continues over a long period of time, and even if the amount of the source of bad odor increases and the deodorizing active ingredient is consumed, it will continue for a considerable period of time.
Replenishment can be generated. Furthermore, enzymes such as amylase and protease produced by the above-mentioned microorganisms can decompose organic matter and sources of bad odors in a short time. Deodorizing beer of the present invention
The anti-aging agent contains 1 to 5 parts by weight of the above-mentioned microbial component and 1 part of glucose.
~5 parts by weight, 2 to 10 parts by weight of ammonium chloride, 50 to 150 parts by weight of sodium or calcium alginate,
Preferably, it is composed of 20 to 200 parts by weight of water. The glucose contained serves as a medium and nutrient source for microorganisms, and is converted into organic acids, and if it is less than 1 part by weight,
It does not effectively promote the growth of microorganisms, and if it exceeds 5 parts by weight, certain microorganisms such as Aspergillus and Bacillus will increase too much, making coexistence with microorganisms of other genera impossible. . In addition, ammonium chloride serves as a nitrogen nutrient source during the growth and multiplication of microorganisms, and if it is less than 2 parts by weight, it will not effectively promote the growth of microorganisms, and if it is less than 2 parts by weight, it will not effectively promote the growth of microorganisms.
If the amount exceeds 0 parts by weight, the coexistence of multiple microorganisms becomes impossible.
【００１２】アルギン酸ナトリウム或いはカルシウムは
、ビ−ズ剤に形成するために必要な樹脂であり、塩類の
水溶液に接触して、固化するものである。その含有量は
、５０〜１５０重量部必要である。使用する水としては
、脱イオン水や蒸留水が好適である。消臭ビ−ズ剤に中
に含有され、微生物の生育に必要なものである。Sodium alginate or calcium alginate is a resin necessary for forming beads, and solidifies when it comes into contact with an aqueous solution of salts. Its content is required to be 50 to 150 parts by weight. The water used is preferably deionized water or distilled water. It is contained in deodorant beads and is necessary for the growth of microorganisms.
【００１３】本発明の消臭ビ−ズ剤の大きさは、塩類の
水溶液中に微生物成分水溶液を滴下する速度を調整する
こと、或いは、塩類水溶液を攪拌しながら滴下すること
により、また、その攪拌速度を調整することにより、調
整することができる。好適には、消臭ビ−ズ剤の大きさ
は、０．５ｍｍ〜２ｍｍである。このビ−ズの大きさは
、球体の表面積を決めるために、微生物の消臭効果を決
めることになる。The size of the deodorizing beads of the present invention can be determined by adjusting the speed at which the aqueous microbial component solution is dropped into the aqueous salt solution, or by dropping the aqueous salt solution while stirring. This can be adjusted by adjusting the stirring speed. Preferably, the size of the deodorant beads is 0.5 mm to 2 mm. The size of the beads determines the surface area of the sphere, which in turn determines the deodorizing effect on microorganisms.
【００１４】次に、本発明の消臭ビ−ズ剤を具体的に実
施例により説明するが、本発明はそれらによって限定さ
れるものではない。Next, the deodorizing beads of the present invention will be specifically explained with reference to Examples, but the present invention is not limited thereto.
【００１５】[0015]
【実施例】微生物として、バチルス・ズブチルス（Ｂ．
ｓｕｂｔｉｌｉｓ）［ＩＡＭ １１６８］１．０ｇとエ
ンテロバクタ−・サカザキイ（Ｅ．ｓａｋａｚａｋｉｉ
）［ＩＡＭ １２６６０］を添加した微生物製剤１．
５ｇにグルコ−ス２ｇ、塩化アンモニウム４ｇ並びにア
ルギン酸ナトリウム５５ｇを水３０ｇに溶解させた水溶
液Ａを作成する。次に、ＣａＣｌ２ の５％水溶液Ｂを
用意する。前記の微生物成分を含有する水溶液Ａを、水
溶液Ｂの中に滴下すると、アルギン酸ナトリウムが硬化
して、径０．５〜５ｍｍの範囲のビ−ズが生成する。こ
のビ−ズ径は、水溶液Ｂを攪拌しながら、或いはその濃
度を調整することにより、調整できる。[Example] As a microorganism, Bacillus subtilis (B.
subtilis) [IAM 1168] 1.0 g and Enterobacter sakazakii (E. sakazakii).
) [IAM 12660] microbial preparation 1.
An aqueous solution A is prepared by dissolving 2 g of glucose, 4 g of ammonium chloride, and 55 g of sodium alginate in 30 g of water. Next, a 5% aqueous solution B of CaCl2 is prepared. When the above-mentioned aqueous solution A containing the microbial component is dropped into the aqueous solution B, the sodium alginate hardens to produce beads having a diameter in the range of 0.5 to 5 mm. The bead diameter can be adjusted by stirring the aqueous solution B or by adjusting its concentration.
【００１６】次に、調製したビ−ズ剤４０ｇ、孔を開い
た円筒に入れ、次の性能試験に用いた。
［消臭の性能試験］以上の試験対象の消臭ビ−ズ剤を、
３５℃で放置し、発酵臭の発生を経日的に、官能試験で
確認すると共に、濃度２０ｐｐｍ及び１０ｐｐｍのアン
モニア水溶液を調整して、該アンモニア溶液２ｃｃに対
して、前記の各消臭ビ−ズ剤含有円筒を入れて、５０ｃ
ｃの密閉容器中で、北川式検知管で測定して、気相中の
アンモニア濃度を測定した。消臭ビ−ズ剤は製造直後を
０日として、それを３５℃で保存して、２０日毎にアン
モニア濃度の経日的変化をヒト官能及び検知管で測定調
査した。Next, 40 g of the prepared beads were placed in a cylinder with holes and used in the next performance test. [Deodorizing performance test] The deodorizing bead preparations tested above were tested.
After being left at 35°C, the generation of fermentation odor was confirmed by a sensory test over time, and ammonia aqueous solutions with concentrations of 20 ppm and 10 ppm were prepared, and each of the above-mentioned deodorizing bottles was added to 2 cc of the ammonia solution. Insert the cylinder containing the zinc agent and make 50c.
The ammonia concentration in the gas phase was measured using a Kitagawa detection tube in the sealed container of c. The deodorizing bead preparation was stored at 35° C., with the day immediately after production taken as day 0, and the daily change in ammonia concentration was measured every 20 days using human senses and a detection tube.
【００１７】[0017]
【発明の効果】以上説明したように、本発明の消臭ビ−
ズ剤により、前記のような効果が得られた。それらをま
とめると、次のような顕著な技術的効果となる。即ち、
第１に、本発明の消臭ビ−ズ剤中の微生物は、常に濡れ
ている状態にあり、各種栄養源により活性化され、消臭
効果を有する有効成分としての酵素や有機酸を生成させ
、長期間にわたり、高い活性を継続することができ、長
期間に渡り、微生物の生育、増殖は極めてゆるやかに継
続するために、微生物特有の発酵臭は発生せず、当初予
測しなかった消臭効果をも長期的に略完全に持続させる
ことができた。Effects of the Invention As explained above, the deodorizing beer of the present invention
The effects described above were obtained by using the anti-oxidizing agent. Putting these together, we get the following remarkable technical effects. That is,
First, the microorganisms in the deodorant beads of the present invention are always in a wet state and are activated by various nutritional sources to produce enzymes and organic acids as active ingredients that have a deodorizing effect. , it is possible to maintain high activity for a long period of time, and the growth and proliferation of microorganisms continues extremely slowly over a long period of time, so the fermentation odor peculiar to microorganisms does not occur, resulting in an unexpected deodorizing effect. The effect was also able to be maintained almost completely over a long period of time.
【００１９】第２に、水流中又は気流中においた場合に
も、流れされず、また、気体中に拡散することがなく、
長期間にわたり、継続する消臭効果を有する消臭ビ−ズ
剤を提供できた。Second, even when placed in a water stream or an air stream, it will not be washed away or diffused into the gas.
It was possible to provide a deodorizing bead agent that has a continuous deodorizing effect over a long period of time.
Claims (2)
ン酸ナトリウムよりなる微生物含有剤を、ＫＣｌ或いは
ＣａＣｌ２ と水とよりなる塩含有剤の中に滴下するこ
とにより作成した微生物成分含有ビ−ズを用いた消臭ビ
−ズ剤。Claim 1: Using microbial component-containing beads prepared by dropping a microbial component, a nutrient source therefor, and a microbial agent containing sodium alginate into a salt-containing agent consisting of KCl or CaCl2 and water. Deodorant beads.
ｌｕｓ）属、ストレプトコッカス（Ｓｔｒｅｐｔｏｃｏ
ｃｃｕｓ）属、エンテロバクタ−（Ｅｎｔｅｒｏｂａｃ
ｔｅｒ）属、リゾ−プス（Ｒｈｉｚｏｐｕｓ）属、アス
ペ ルギルス（Ａｓｐｅｒｇｉｌｌｕｓ）属のいずれ或
いはその２つ以上を組合わせで構成され、 また、その
ための前記栄養源としては、炭素系栄養源が、グルコ−
ス、糖類であり、窒素系栄養源が、塩化アンモニウム、
硫安である請求項１に記載の消臭ビ−ズ剤。2. The microorganism part is Bacillus (Bacillus).
Streptococcus spp.
ccus), Enterobacter (Enterobacter)
ter), Rhizopus, and Aspergillus, or a combination of two or more thereof;
Nitrogen nutrients include ammonium chloride,
The deodorizing bead agent according to claim 1, which is ammonium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2419089A JPH04231057A (en) | 1990-12-27 | 1990-12-27 | Deodorizing bead agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2419089A JPH04231057A (en) | 1990-12-27 | 1990-12-27 | Deodorizing bead agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04231057A true JPH04231057A (en) | 1992-08-19 |
Family
ID=18526795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2419089A Withdrawn JPH04231057A (en) | 1990-12-27 | 1990-12-27 | Deodorizing bead agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04231057A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6297033B1 (en) * | 1996-04-02 | 2001-10-02 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Means and process for nitrate removal |
-
1990
- 1990-12-27 JP JP2419089A patent/JPH04231057A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6297033B1 (en) * | 1996-04-02 | 2001-10-02 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Means and process for nitrate removal |
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