JPH04213398A - Transparent soap composition - Google Patents
Transparent soap compositionInfo
- Publication number
- JPH04213398A JPH04213398A JP3953791A JP3953791A JPH04213398A JP H04213398 A JPH04213398 A JP H04213398A JP 3953791 A JP3953791 A JP 3953791A JP 3953791 A JP3953791 A JP 3953791A JP H04213398 A JPH04213398 A JP H04213398A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- transparent soap
- transparent
- soap composition
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000344 soap Substances 0.000 title claims abstract description 54
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- -1 alkyl glucoside Chemical class 0.000 claims abstract description 27
- 229930182478 glucoside Natural products 0.000 claims abstract description 20
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 238000004031 devitrification Methods 0.000 abstract description 7
- 150000008131 glucosides Chemical class 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- 239000003292 glue Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 235000011121 sodium hydroxide Nutrition 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- 235000015278 beef Nutrition 0.000 description 8
- 239000003240 coconut oil Substances 0.000 description 8
- 235000019864 coconut oil Nutrition 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000003760 tallow Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000003925 fat Substances 0.000 description 6
- 235000019197 fats Nutrition 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 238000007127 saponification reaction Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000008395 clarifying agent Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- WYUFTYLVLQZQNH-JAJWTYFOSA-N Ethyl beta-D-glucopyranoside Chemical compound CCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O WYUFTYLVLQZQNH-JAJWTYFOSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 206010050637 Skin tightness Diseases 0.000 description 1
- LGVFJHCENRNEOH-UHFFFAOYSA-N [O-]C(CC[N+]1(CCO)C=NCC1)=O Chemical compound [O-]C(CC[N+]1(CCO)C=NCC1)=O LGVFJHCENRNEOH-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 210000000245 forearm Anatomy 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical compound CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940057847 polyethylene glycol 600 Drugs 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、透明石鹸組成物に関す
るものであり、更に詳しくは、透明度が高く、しかも速
く透明化する為製造期間が短縮され、経日による失透が
防止され、かつ皮膚の美容，保護並びに水分付与効果に
優れた透明石鹸組成物に関する。[Industrial Application Field] The present invention relates to a transparent soap composition, and more specifically, it has high transparency, quickly becomes transparent, shortens the manufacturing period, prevents devitrification due to aging, and This invention relates to a transparent soap composition that has excellent skin beauty, protection, and hydration effects.
【０００２】0002
【従来の技術及び発明が解決しようとする課題】従来よ
り透明石鹸は、牛脂，ヤシ油等の混合油脂、あるいは牛
脂肪酸，ヤシ油脂肪酸等の混合脂肪酸を苛性ソーダ水溶
液でケン化あるいは中和して得られる石鹸生地を、低級
アルコールおよび水に溶解し、次いで透明化剤として砂
糖，グリセリン，ポリエチレングリコール等を加えて均
一透明に加熱溶解して調製した透明石鹸生地を、所定の
成型枠に流し込み、冷却固化した後、取り出して、切断
，面取り，乾燥を行い、そして■湯浸，■打型整型，■
艶出し，■乾燥等の■〜■の製造工程を繰り返すことに
よって製造されている。[Prior Art and Problems to be Solved by the Invention] Conventionally, transparent soaps have been made by saponifying or neutralizing mixed fats and oils such as beef tallow and coconut oil, or mixed fatty acids such as beef fatty acids and coconut oil fatty acids with an aqueous solution of caustic soda. The obtained soap dough is dissolved in lower alcohol and water, and then sugar, glycerin, polyethylene glycol, etc. are added as a clarifying agent, and the transparent soap dough prepared by heating and melting to make it uniformly transparent is poured into a predetermined molding frame. After cooling and solidifying, it is taken out, cut, chamfered, dried, and ■ soaked in hot water, ■ hammered into shape, and ■
It is manufactured by repeating the manufacturing steps (1) to (2), such as polishing and (2) drying.
【０００３】しかし、この透明石鹸は、製造に長期間を
要する，経日によって失透する，使用時に於ては、皮膚
のつっぱり感，皮膚に対する刺激等が発生するものもあ
る，等の欠点を有している。中でも特に問題となるのが
透明化に時間がかかるため、製造期間が長くなり、広大
なスペースを必要とすることである。[0003] However, these transparent soaps have drawbacks such as requiring a long period of time to manufacture, devitrification over time, and some causing skin tightness and irritation when used. have. Among these, the problem is that it takes time to make the film transparent, which lengthens the manufacturing period and requires a large amount of space.
【０００４】上記欠点を改善する方法として数多くの方
法が開示されているが、充分に満足する効果は得られて
いない。[0004] Many methods have been disclosed to improve the above-mentioned drawbacks, but no fully satisfactory effects have been obtained.
【０００５】従って本発明の目的は、透明化が速く（製
造期間の短縮）しかも透明度が高く、経日による失透が
少なく、更に肌に対して良好なしっとり感やなめらかさ
を付与し得る透明石鹸組成物を提供することにある。[0005] Therefore, the object of the present invention is to provide a transparent material that can be quickly transparentized (reduced production period), has high transparency, has little devitrification due to aging, and can impart good moisturizing and smoothness to the skin. An object of the present invention is to provide a soap composition.
【０００６】[0006]
【課題を解決するための手段】本発明は、一般式（Ｉ）
[Means for Solving the Problems] The present invention provides general formula (I)
【化２】
（式中、Ｒは炭素数２〜２０の直鎖又は分岐鎖状のアル
キル基、ｎは１〜５の整数を示す。）で表わされる、ア
ルキルグルコシドを含有することを特徴とする、透明石
鹸組成物である。It is characterized by containing an alkyl glucoside represented by the following formula: (wherein, R is a linear or branched alkyl group having 2 to 20 carbon atoms, and n is an integer of 1 to 5.) It is a transparent soap composition.
【０００７】本発明において用いられるアルキルグルコ
シドのアルキル基の例としては、エチル基，プロピル基
，ブチル基，イソブチル基，ペンチル基，３−メチルブ
チル基，ヘキシル基，メチルペンチル基，ヘプチル基，
４−メチルヘキシル基，５−メチルヘキシル基，４−エ
チルペンチル基，オクチル基，６−メチルヘプチル基，
５−メチルヘプチル基，５，５−ジメチルヘキシル基，
ヤシ油アルキル基（炭素数８〜２０），ドデシル基，テ
トラデシル基，ヘキサデシル基，オクタデシル基，エイ
コシル基などが挙げられるがこれらに限定されるもので
はない。Examples of the alkyl group of the alkyl glucoside used in the present invention include ethyl group, propyl group, butyl group, isobutyl group, pentyl group, 3-methylbutyl group, hexyl group, methylpentyl group, heptyl group,
4-methylhexyl group, 5-methylhexyl group, 4-ethylpentyl group, octyl group, 6-methylheptyl group,
5-methylheptyl group, 5,5-dimethylhexyl group,
Examples include, but are not limited to, a coconut oil alkyl group (having 8 to 20 carbon atoms), a dodecyl group, a tetradecyl group, a hexadecyl group, an octadecyl group, and an eicosyl group.
【０００８】その含有量は、透明石鹸組成物全体を１０
０重量％として０．０１〜１０．０重量％が好ましく、
更に好ましくは０．１〜５重量％である。あまり少ない
と透明性，保湿性等に顕著な効果を認めにくく、又多す
ぎた場合、透明性が低下する傾向が見られる。[0008] The content of the entire transparent soap composition is 10
0.01 to 10.0% by weight is preferable as 0% by weight,
More preferably, it is 0.1 to 5% by weight. If the amount is too small, it is difficult to notice any noticeable effects on transparency, moisture retention, etc. If the amount is too large, the transparency tends to decrease.
【０００９】本発明には、透明石鹸膠として牛脂，ヤシ
油，パーム油，パーム核油，オリーブ油，ヒマシ油等の
動植物油脂，又はその油脂酸，もしくは単体脂肪酸とア
ルカリ水溶液の反応物に多価アルコール，砂糖等を添加
溶解したもの等の、一般的な透明石鹸膠を使用すること
ができる。[0009] In the present invention, the transparent soap glue is made of animal or vegetable fats and oils such as beef tallow, coconut oil, palm oil, palm kernel oil, olive oil, or castor oil, or their fatty acid, or a reaction product of a simple fatty acid and an aqueous alkali solution with a polyvalent content. General transparent soap glue, such as one in which alcohol, sugar, etc. are added and dissolved, can be used.
【００１０】本発明の透明石鹸組成物は、本発明の目的
を達成する範囲でさらに他の成分を配合することができ
る。The transparent soap composition of the present invention may further contain other components within the range that achieves the object of the present invention.
【００１１】即ち、一般の石鹸に使用されている、保湿
剤，過脂肪剤，増泡剤，酸化防止剤，香料，染料，ｐＨ
調整剤，金属イオン封鎖剤，殺菌剤，アニオン界面活性
剤（炭素数１２〜２８の直鎖状アルファオレフィンスル
ホン酸塩等），両性界面活性剤（イミダゾリン型，ベタ
イン型，置換アミノ酸型），高級脂肪酸アルカノールア
ミド（高級脂肪酸モノエタノールアミド，高級脂肪酸ジ
エタノールアミド等），その他の油性物質（ラノリン，
流動パラフィン，固形パラフィン等）を併用配合するこ
とができる。[0011] That is, moisturizing agents, superfatting agents, foaming agents, antioxidants, fragrances, dyes, and pH values used in general soaps.
Adjustment agent, sequestering agent, bactericide, anionic surfactant (linear alpha olefin sulfonate with 12 to 28 carbon atoms, etc.), amphoteric surfactant (imidazoline type, betaine type, substituted amino acid type), high grade Fatty acid alkanolamide (higher fatty acid monoethanolamide, higher fatty acid diethanolamide, etc.), other oily substances (lanolin,
(liquid paraffin, solid paraffin, etc.) can be combined.
【００１２】なお、本発明においては、一般に透明石鹸
に用いられている他の透明化剤を必ずしも添加する必要
はないが、より優れた透明性を得るために、これら透明
化剤を配合してもよい。[0012] In the present invention, it is not necessarily necessary to add other clarifying agents that are generally used in transparent soaps, but in order to obtain better transparency, these clarifying agents may be added. Good too.
【００１３】この透明化剤としては、砂糖等の多糖類，
グリセリン，プロピレングリコール等の多価アルコール
類，もしくはアルコール類等が挙げられる。本発明の透
明石鹸組成物の製造方法としては例えば、透明石鹸膠と
アルキルグルコシドと必要に応じて前述の任意成分とを
、加温しながら混合し、枠に流し込み、冷却固化し、切
断，乾燥，成型する通常の枠練り製造法で良い。[0013] As the clarifying agent, polysaccharides such as sugar,
Examples include polyhydric alcohols such as glycerin and propylene glycol, and alcohols. The method for producing the transparent soap composition of the present invention includes, for example, mixing transparent soap glue, alkyl glucoside, and the above-mentioned optional components as necessary with heating, pouring into a frame, cooling and solidifying, cutting, and drying. , the usual frame kneading manufacturing method for molding may be used.
【００１４】[0014]
【実施例】次に実施例を挙げ本発明を説明するが、本発
明はこれら実施例に限定されるものではない。なお、本
実施例に記載した各試験方法は、下記の通りである。[Examples] Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples. In addition, each test method described in this example is as follows.
【００１５】（１）透明性評価試験
３０ｍｍの厚さの製品（試料）を通し、５〜４３ポイン
トの標準印刷活字見本の最小ポイント数を読み取る。そ
のポイント数が小さいもの程透明度が良いことを示して
いる。(1) Transparency evaluation test A product (sample) with a thickness of 30 mm is passed through and the minimum number of points of a standard printed type sample of 5 to 43 points is read. The smaller the number of points, the better the transparency.
【００１６】（２）保存安定性試験
包装しない状態にて、温度４５℃の恒温室に放置し、失
透する状態（日数）を観察した（肉眼にて判定した）。(2) Storage stability test The sample was left unpackaged in a thermostatic chamber at a temperature of 45° C., and the state (number of days) of devitrification was observed (determined with the naked eye).
【００１７】（３）実用試験
女子２０人（パネル）が、洗顔時に使用し、皮膚への刺
激改善性，使用感（しっとり感）の良否を判定してアン
ケートに答え、その評価を以下のように判定した。(3) Practical test 20 women (panel) used the product when washing their faces, judged the improvement in skin irritation and the quality of the feeling of use (moist feeling), answered a questionnaire, and gave their evaluations as follows: It was determined that
【００１８】
評 価 基 準
評価記号 良いと答えた人が１８人
以上の場合
… ◎ 〃
が１４人〜１７人の場合
… ○ 〃
が８人〜１３人の場合
… △
〃 が７人以下の場合
…
×Evaluation criteria
Evaluation symbol: If 18 or more people answered good
… ◎ 〃
If there are 14 to 17 people
… ○ 〃
If there are 8 to 13 people
… △
〃 is 7 or less people
…
×
【００１９】（４）皮膚水分含有量評価試験健康
成人の前腕屈側部４×４ｃｍ２ に、２０μｌの石鹸水
を塗布する。塗布３０分後に、Ｓｋｉｎ Ｓｕｒｆａ
ｃｅ Ｈｙｄｒｏｍｅｔｅｒ（ＩＢＳ社製）を用いて
、高周波に対する皮膚の伝導度（マイクロモー；μΩ−
１）を測定する。(4) Skin moisture content evaluation test 20 μl of soapy water is applied to a 4×4 cm 2 area on the flexor side of the forearm of a healthy adult. 30 minutes after application, Skin Surfa
CE Hydrometer (manufactured by IBS) was used to measure skin conductivity (micromo; μΩ-) to high frequencies.
1) Measure.
【００２０】この測定値が大きい程、皮膚の電気抵抗が
小さく、水分含有量が多いことを表している（日本香粧
品科学会誌４；２０１〜２０８，１９８０）。[0020] The larger the measured value, the lower the electrical resistance of the skin and the higher the water content (Journal of the Japanese Cosmetic Science Society 4: 201-208, 1980).
【００２１】（５）皮膚水分保持能評価試験上記の水分
含有量測定後、試料塗布部位のうち直径６ｍｍの部分に
ボールペンでしるしをつけ、蒸留水を一滴置き、１０秒
間放置する。水滴をガーゼで十分ふきとった直後，及び
その３０，６０，９０，１２０秒後の水分含有量（μΩ
−１）を測定し、Ｗ０ ， Ｗ１ ， Ｗ２ ， Ｗ３
， Ｗ４ とする。(5) Skin Moisture Retention Ability Evaluation Test After measuring the moisture content as described above, mark a 6 mm diameter portion of the sample application site with a ballpoint pen, place a drop of distilled water on it, and leave it for 10 seconds. Moisture content (μΩ
-1) and measure W0, W1, W2, W3
, W4.
【００２２】次式により皮膚の水分保持能（％）を算出
する。The moisture retention capacity (%) of the skin is calculated using the following formula.
【００２３】実施例１，２
配合油脂（牛脂２８．０重量％，ヤシ油１２．０重量％
）４０．０重量％にエタノール２０重量％を鹸化釜中で
５０℃〜７０℃に混合加温し、これに、別途カセイソー
ダ６．１重量％を水１５．９重量％に溶解したカセイソ
ーダ水溶液を少しずつ滴下し、７０℃〜７５℃に保って
鹸化した。鹸化終了後、７０℃前後に保温したまま砂糖
１２．０重量％を加え、さらにグリセリン６．０重量％
を加えて混合溶解し、透明石鹸膠を得た。Examples 1 and 2 Compounded fats and oils (28.0% by weight of beef tallow, 12.0% by weight of coconut oil)
) 40.0% by weight and 20% by weight of ethanol were mixed and heated at 50°C to 70°C in a saponification pot, and to this was added a separate caustic soda aqueous solution in which 6.1% by weight of caustic soda was dissolved in 15.9% by weight of water. It was added dropwise little by little and saponified by keeping it at 70°C to 75°C. After saponification, 12.0% by weight of sugar was added while keeping the temperature at around 70°C, and 6.0% by weight of glycerin was added.
was added and mixed and dissolved to obtain a transparent soap glue.
【００２４】この透明石鹸膠９７．０重量％とｎ＝１の
エチルグルコシド（実施例１）、又はｎ＝２，Ｒの炭素
数１２のアルキルグルコシド（実施例２）を３．０重量
％混合して枠に流し込み、冷却固化した後切断し、乾燥
後成型して（通常の枠練り方式）、本発明の透明石鹸組
成物を得た。97.0% by weight of this transparent soap glue was mixed with 3.0% by weight of ethyl glucoside with n=1 (Example 1) or alkyl glucoside with n=2 and R having 12 carbon atoms (Example 2). The resultant mixture was poured into a frame, cooled and solidified, then cut, dried and then molded (normal frame kneading method) to obtain a transparent soap composition of the present invention.
【００２５】比較例１
次に比較のためにアルキルグルコシドは配合せず、透明
石鹸膠を１００．０重量％使用する他は、実施例１，２
と同様に行って、比較例１の透明石鹸組成物を得た。Comparative Example 1 Next, for comparison, Examples 1 and 2 were used, except that no alkyl glucoside was blended and 100.0% by weight of transparent soap glue was used.
In the same manner as above, a transparent soap composition of Comparative Example 1 was obtained.
【００２６】これらの透明石鹸組成物（実施例１，２，
比較例１）について、前述の（１）〜（５）の各試験を
行った結果を、表１に示した。These transparent soap compositions (Examples 1, 2,
Regarding Comparative Example 1), the results of each of the tests (1) to (5) described above are shown in Table 1.
【００２７】[0027]
【表１】[Table 1]
【００２８】表１から明らかなように、本発明の透明石
鹸組成物（実施例１，２）は、透明化するのが速く、か
つ５０日後の透明度も高く、失透日数（透明石鹸に白い
濁りが発生するまでの日数）も長く、実用試験（刺激性
，使用感）においても比較例１よりも優れていた。また
実施例２を適用した皮膚は、比較例１の場合に比べて、
皮膚水分含有量が多く、水分保持能にも優れていた。As is clear from Table 1, the transparent soap compositions of the present invention (Examples 1 and 2) become transparent quickly and have high transparency after 50 days. It took a longer time (number of days until turbidity appeared) and was superior to Comparative Example 1 in practical tests (irritancy, feeling of use). In addition, the skin to which Example 2 was applied, compared to Comparative Example 1,
The skin had a high water content and excellent water retention ability.
【００２９】実施例３〜８
表２，表３に示す組成に基づいて、実施例１と同様の方
法で、実施例３〜８の透明石鹸組成物を製造した。これ
らの透明石鹸組成物について前述の各試験を実施し、そ
の結果を表２，表３に示した。Examples 3 to 8 Transparent soap compositions of Examples 3 to 8 were produced in the same manner as in Example 1 based on the compositions shown in Tables 2 and 3. The above-mentioned tests were conducted on these transparent soap compositions, and the results are shown in Tables 2 and 3.
【００３０】[0030]
【表２】[Table 2]
【００３１】[0031]
【表３】[Table 3]
【００３２】表２，表３から明らかなように、実施例３
〜８に示す本発明の透明石鹸組成物は、透明化するのが
速く、かつ５０日後の透明度も高く、保存安定性も良好
であり、刺激性及び使用感も優れていた。又、これらの
透明石鹸を使用した皮膚は、水分含有量が多く、水分保
持能にも優れていた。As is clear from Tables 2 and 3, Example 3
The transparent soap compositions of the present invention shown in items 1 to 8 became transparent quickly, had high transparency after 50 days, had good storage stability, and had excellent irritation and feel when used. Furthermore, the skin treated with these transparent soaps had a high water content and excellent water retention ability.
【００３３】実施例９，１０，比較例２〜４表４，表５
の組成に基づいて、実施例１と同様にして、実施例９，
１０及び比較例２〜４の各透明石鹸組成物を製造した。
これらの透明石鹸組成物について前述の各試験を行い、
結果を表４，表５に示した。Examples 9 and 10, Comparative Examples 2 to 4 Table 4, Table 5
Based on the composition of Example 9, in the same manner as Example 1,
Transparent soap compositions No. 10 and Comparative Examples 2 to 4 were manufactured. The above-mentioned tests were conducted on these transparent soap compositions, and
The results are shown in Tables 4 and 5.
【００３４】[0034]
【表４】[Table 4]
【００３５】[0035]
【表５】[Table 5]
【００３６】表４，表５から明らかなように、実施例９
，１０に示す本発明の透明石鹸組成物は、透明化するの
が速く、かつ５０日後の透明度も高く、保存安定性も良
好であり、低刺激性で、使用感にも優れていた。又、こ
れらの透明石鹸組成物を適用した後の皮膚は、水分含有
量，水分保持能に優れていた。As is clear from Tables 4 and 5, Example 9
The transparent soap composition of the present invention shown in ., 10 became transparent quickly, had high transparency after 50 days, had good storage stability, was hypoallergenic, and had an excellent feel when used. Furthermore, the skin after applying these transparent soap compositions had excellent moisture content and moisture retention ability.
【００３７】これに対して、本発明の必須成分であるア
ルキルグルコシドを配合せずに、その他の透明化剤とし
てグリセリンを配合した比較例２，ポリエチレングリコ
ール６００（平均分子量６００）を配合した比較例３，
およびプロピレングリコールを配合した比較例４の透明
石鹸組成物は、透明度及び保存安定性，刺激改善性，使
用感，水分含有量，水分保持能が劣り、本発明の透明石
鹸組成物に及ばず、本発明の必須成分であるアルキルグ
ルコシドの作用効果が顕著であることを示している。On the other hand, Comparative Example 2 in which glycerin was blended as another clarifying agent without blending alkyl glucoside, which is an essential component of the present invention, and Comparative Example in which polyethylene glycol 600 (average molecular weight 600) was blended. 3,
The transparent soap composition of Comparative Example 4 containing propylene glycol was inferior to the transparent soap composition of the present invention in terms of transparency, storage stability, irritation improvement properties, feeling of use, moisture content, and moisture retention ability. This shows that the effect of alkyl glucoside, which is an essential component of the present invention, is remarkable.
【００３８】実施例１１，１２
配合油脂（牛脂２６．０重量％，ヒマシ油２．０重量％
，パーム核油１２．０重量％）４０．０重量％にエタノ
ール１８．０重量％を鹸化釜中で５０℃〜７０℃にて混
合加温し、これに、別途カセイソーダ６．１重量％を水
１７．９重量％に溶解したカセイソーダ水溶液を少しず
つ滴下し、７０℃〜７５℃に保って鹸化する。終了後、
７０℃前後に保温したまま、砂糖１２．０重量％を加え
、さらにグリセリン６．０重量％を加え混合溶解して透
明石鹸膠を得た。Examples 11 and 12 Compounded fats and oils (26.0% by weight of beef tallow, 2.0% by weight of castor oil)
, 40.0% by weight of palm kernel oil (12.0% by weight) and 18.0% by weight of ethanol were mixed and heated at 50°C to 70°C in a saponification pot, and to this was added 6.1% by weight of caustic soda. An aqueous solution of caustic soda dissolved in 17.9% by weight of water is added dropwise little by little and saponified while being maintained at 70°C to 75°C. After the end,
While keeping the temperature at around 70° C., 12.0% by weight of sugar was added, and further 6.0% by weight of glycerin was added and mixed and dissolved to obtain a transparent soap glue.
【００３９】この透明石鹸膠９４．４重量％に、ｎ＝１
のイソブチルグルコシド（実施例１１）、又はｎ＝５，
Ｒの炭素数１６のアルキルグルコシド（実施例１２）を
５．０重量％，香料０．５重量％，エデト酸四ナトリウ
ム四水塩０．１重量％を配合し実施例１と同様にして本
発明の透明石鹸組成物を得た。[0039] In this transparent soap glue 94.4% by weight, n=1
isobutyl glucoside (Example 11), or n=5,
This product was prepared in the same manner as in Example 1 by blending 5.0% by weight of alkyl glucoside with R having 16 carbon atoms (Example 12), 0.5% by weight of fragrance, and 0.1% by weight of edetate tetrasodium tetrahydrate. A transparent soap composition of the invention was obtained.
【００４０】実施例１３，１４
配合油脂（牛脂２０．０重量％，パーム油４．０重量％
，ヤシ油８．０重量％，パーム核油８．０重量％）４０
．０重量％にエタノール１８．０重量％を鹸化釜中で５
０℃〜７０℃にて混合加温し、これに、別途カセイソー
ダ６．１重量％を水１７．９重量％に溶解したカセイソ
ーダ水溶液を少しずつ滴下し、７０℃〜７５℃に保って
鹸化する。終了後、７０℃前後に保温したまま、砂糖１
２．０重量％を加え、さらにグリセリン６．０重量％を
加え混合溶解して透明石鹸膠を得た。Examples 13 and 14 Compounded fats and oils (20.0% by weight of beef tallow, 4.0% by weight of palm oil)
, coconut oil 8.0% by weight, palm kernel oil 8.0% by weight) 40
．． 0% by weight and 18.0% by weight of ethanol in a saponification pot.
Mix and heat at 0°C to 70°C, add aqueous caustic soda solution prepared by dissolving 6.1% by weight of caustic soda in 17.9% by weight of water little by little, and saponify by keeping at 70°C to 75°C. . After finishing, add 1 cup of sugar while keeping warm at around 70℃.
2.0% by weight was added, and further 6.0% by weight of glycerin was added and mixed and dissolved to obtain a transparent soap glue.
【００４１】この透明石鹸膠９２．３重量％に、ｎ＝１
のペンチルグルコシド（実施例１３）、又はｎ＝５，Ｒ
の炭素数１８のアルキルグルコシド（実施例１４）を５
．０重量％，ソルビトール２．０重量％，ヤシ油アルキ
ルＮ−カルボキシエチルＮ−ヒドロキシエチルイミダゾ
リニウムベタインナトリウム０．５重量％，染料０．１
重量％，香料０．１重量％を配合し、実施例１と同様に
して本発明の透明石鹸組成物を得た。[0041] In this transparent soap glue 92.3% by weight, n=1
pentyl glucoside (Example 13), or n=5, R
5 of the 18 carbon alkyl glucoside (Example 14)
．． 0% by weight, sorbitol 2.0% by weight, coconut oil alkyl N-carboxyethyl N-hydroxyethylimidazolinium betaine sodium 0.5% by weight, dye 0.1
A transparent soap composition of the present invention was obtained in the same manner as in Example 1 except that 0.1% by weight of perfume was added.
【００４２】実施例１５，１６
配合油脂（牛脂２０．０重量％，オリーブ油４．０重量
％，ヤシ油１６．０重量％）４０．０重量％にエタノー
ル１８．０重量％を鹸化釜中で５０℃〜７０℃にて混合
加温し、これに、別途カセイソーダ６．１重量％を水１
７．９重量％に溶解したカセイソーダ水溶液を少しずつ
滴下し、７０℃〜７５℃に保って鹸化する。終了後、７
０℃前後に保温したまま、砂糖１２．０重量％を加え、
さらにグリセリン６．０重量％を加え混合溶解して透明
石鹸膠を得た。Examples 15 and 16 40.0% by weight of blended fats and oils (20.0% by weight of beef tallow, 4.0% by weight of olive oil, 16.0% by weight of coconut oil) and 18.0% by weight of ethanol were added in a saponification pot. Mix and heat at 50°C to 70°C, and add 6.1% by weight of caustic soda to 1% of water.
An aqueous solution of caustic soda dissolved at 7.9% by weight is added dropwise little by little and saponified while being maintained at 70°C to 75°C. After finishing, 7
While keeping the temperature around 0℃, add 12.0% by weight of sugar,
Furthermore, 6.0% by weight of glycerin was added and mixed and dissolved to obtain a transparent soap glue.
【００４３】この透明石鹸膠９３．８重量％に、ｎ＝１
のオクチルグルコシド（実施例１５）、又はｎ＝１，Ｒ
の炭素数２０のアルキルグルコシド（実施例１６）を５
．０重量％，Ｎ−混合脂肪酸−Ｌ・グルタミン酸ナトリ
ウム０．５重量％，３，４，４−トリクロロカルバニリ
ド０．１重量％，香料０．５重量％，エデト酸四ナトリ
ウム四水塩０．１重量％を配合し、実施例１と同様にし
て本発明の透明石鹸組成物を得た。[0043] In this transparent soap glue 93.8% by weight, n=1
octyl glucoside (Example 15), or n=1, R
of alkyl glucoside having 20 carbon atoms (Example 16)
．． 0% by weight, N-mixed fatty acid-L sodium glutamate 0.5% by weight, 3,4,4-trichlorocarbanilide 0.1% by weight, fragrance 0.5% by weight, edetate tetrasodium tetrahydrate 0 A transparent soap composition of the present invention was obtained in the same manner as in Example 1 by adding .1% by weight.
【００４４】実施例１７，１８
配合油脂（牛脂２８．０重量％，ヤシ油１２．０重量％
）４０．０重量％にエタノール１８．０重量％を鹸化釜
中で５０℃〜７０℃にて混合加温し、これに、別途カセ
イソーダ６．１重量％を水１７．９重量％に溶解したカ
セイソーダ水溶液を少しずつ滴下し、７０℃〜７５℃に
保って鹸化する。終了後、７０℃前後に保温したまま、
砂糖１２．０重量％を加え、さらにグリセリン６．０重
量％を加え混合溶解して透明石鹸膠を得た。Examples 17 and 18 Compounded fats and oils (28.0% by weight of beef tallow, 12.0% by weight of coconut oil)
) 40.0% by weight and 18.0% by weight of ethanol were mixed and heated at 50°C to 70°C in a saponification pot, and 6.1% by weight of caustic soda was separately dissolved in 17.9% by weight of water. Add the caustic soda aqueous solution dropwise little by little and saponify it by keeping it at 70°C to 75°C. After finishing, keep it warm at around 70℃,
12.0% by weight of sugar was added and further 6.0% by weight of glycerin was added and mixed and dissolved to obtain a transparent soap glue.
【００４５】この透明石鹸膠９４．０９重量％に、ｎ＝
１の３−メチルブチルグルコシド（実施例１７）、又は
ｎ＝２，Ｒの炭素数１２のアルキルグルコシド（実施例
１８）を５．０重量％，ドデシル酸０．１重量％，ドデ
シル酸ジエタノールアミド０．１重量％，１，３−ブチ
レングリコール０．１重量％，香料０．５重量％，染料
０．０１重量％，エデト酸四ナトリウム四水塩０．１重
量％を配合し、実施例１と同様にして本発明の透明石鹸
組成物を得た。[0045] In this transparent soap glue 94.09% by weight, n=
5.0% by weight of 3-methylbutyl glucoside (Example 17) of 1 (Example 17), or 12-carbon alkyl glucoside of n=2, R (Example 18), 0.1% by weight of dodecylic acid, dodecylic acid diethanolamide Examples A transparent soap composition of the present invention was obtained in the same manner as in Example 1.
【００４６】実施例１１〜１８は、透明度が高く、透明
化するのが速く（製造期間の短縮）、経日による失透が
少なく、かつ皮膚の美容，保護及び水分付与効果に優れ
た透明石鹸組成物であった。[0046] Examples 11 to 18 are transparent soaps that have high transparency, become transparent quickly (reduced manufacturing period), have little devitrification over time, and have excellent skin beauty, protection, and hydration effects. It was a composition.
【００４７】[0047]
【発明の効果】以上記載のごとく、本発明の透明石鹸組
成物が、透明になるのが速く（製造期間の短縮）、しか
も透明度が高く、失透が遅く、更に肌に対してしっとり
感を与える等、いずれの点においても優れていることは
明らかである。又、本発明の透明石鹸組成物を適用した
後の皮膚は、水分含有量が多く、高い水分保持能を有す
る。Effects of the Invention As described above, the transparent soap composition of the present invention becomes transparent quickly (reducing manufacturing period), has high transparency, slows devitrification, and provides a moist feeling to the skin. It is clear that it is superior in all respects, such as giving. Furthermore, the skin after applying the transparent soap composition of the present invention has a high water content and a high water retention ability.
Claims (2)
キル基、ｎは１〜５の整数を示す。）で表わされる、ア
ルキルグルコシドを含有することを特徴とする透明石鹸
組成物。Claim 1: General formula (I) represented by the following formula (wherein, R is a linear or branched alkyl group having 2 to 20 carbon atoms, and n is an integer of 1 to 5) A transparent soap composition characterized by containing an alkyl glucoside.
ルコシドが、ｎ＝１，Ｒの炭素数２〜８のアルキルグル
コシドである、請求項１記載の透明石鹸組成物。2. The transparent soap composition according to claim 1, wherein the alkyl glucoside represented by the general formula (I) is an alkyl glucoside with n=1, R and having 2 to 8 carbon atoms.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16330090 | 1990-06-21 | ||
| JP20025990 | 1990-07-26 | ||
| JP2-200259 | 1990-07-26 | ||
| JP2-163300 | 1990-07-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04213398A true JPH04213398A (en) | 1992-08-04 |
| JP2728791B2 JP2728791B2 (en) | 1998-03-18 |
Family
ID=26488783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3953791A Expired - Fee Related JP2728791B2 (en) | 1990-06-21 | 1991-02-08 | Transparent soap composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2728791B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04372696A (en) * | 1991-06-20 | 1992-12-25 | Kao Corp | Detergent composition |
| JPH0762388A (en) * | 1993-08-25 | 1995-03-07 | P & P F:Kk | Transparent solid detergent composition |
| WO1995011959A1 (en) * | 1993-10-29 | 1995-05-04 | Henkel Kommanditgesellschaft Auf Aktien | Soap tablets |
| WO1999013041A1 (en) * | 1996-05-22 | 1999-03-18 | Pola Chemical Industries Inc. | Transparent solid soap and transparent soap stock |
| WO2006079856A1 (en) * | 2005-01-31 | 2006-08-03 | Marin Santic | Procedure of making of transparent soap from olive oil with essential-oil admixtures |
| JP2009144069A (en) * | 2007-12-14 | 2009-07-02 | Nof Corp | Transparent solid soap |
| WO2015047188A1 (en) * | 2013-09-30 | 2015-04-02 | Enza Biotech Ab | Surfactant composition |
| JP2020524597A (en) * | 2017-06-22 | 2020-08-20 | ソシエテ・デクスプロワタシオン・デ・プロデュイ・プール・レ・アンデュストリー・シミック・セピックＳｏｃｉｅｔｅ Ｄ’Ｅｘｐｌｏｉｔａｔｉｏｎ Ｄｅ Ｐｒｏｄｕｉｔｓ Ｐｏｕｒ Ｌｅｓ Ｉｎｄｕｓｔｒｉｅｓ Ｃｈｉｍｉｑｕｅｓ Ｓｅｐｐｉｃ | Novel surfactant mixtures, novel compositions containing them and their use in fire fighting foam concentrates |
-
1991
- 1991-02-08 JP JP3953791A patent/JP2728791B2/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04372696A (en) * | 1991-06-20 | 1992-12-25 | Kao Corp | Detergent composition |
| JPH0762388A (en) * | 1993-08-25 | 1995-03-07 | P & P F:Kk | Transparent solid detergent composition |
| WO1995011959A1 (en) * | 1993-10-29 | 1995-05-04 | Henkel Kommanditgesellschaft Auf Aktien | Soap tablets |
| JPH09504316A (en) * | 1993-10-29 | 1997-04-28 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Bar soap |
| US5705462A (en) * | 1993-10-29 | 1998-01-06 | Henkel Kommanditgesellschaft Auf Aktien | Bar soaps containing ether sulfates and oligoglycosides |
| WO1999013041A1 (en) * | 1996-05-22 | 1999-03-18 | Pola Chemical Industries Inc. | Transparent solid soap and transparent soap stock |
| WO2006079856A1 (en) * | 2005-01-31 | 2006-08-03 | Marin Santic | Procedure of making of transparent soap from olive oil with essential-oil admixtures |
| JP2009144069A (en) * | 2007-12-14 | 2009-07-02 | Nof Corp | Transparent solid soap |
| WO2015047188A1 (en) * | 2013-09-30 | 2015-04-02 | Enza Biotech Ab | Surfactant composition |
| CN105705623A (en) * | 2013-09-30 | 2016-06-22 | 安莎生物技术有限公司 | Surfactant composition |
| JP2016535811A (en) * | 2013-09-30 | 2016-11-17 | エンサ バイオテック アクチエボラグＥｎｚａ Ｂｉｏｔｅｃｈ Ａｂ | Surfactant composition |
| US10188736B2 (en) | 2013-09-30 | 2019-01-29 | Enza Biotech Ab | Surfactant composition |
| CN105705623B (en) * | 2013-09-30 | 2020-02-21 | 安莎生物技术有限公司 | Surfactant composition |
| JP2020041146A (en) * | 2013-09-30 | 2020-03-19 | エンサ バイオテック アクチエボラグＥｎｚａ Ｂｉｏｔｅｃｈ Ａｂ | Surfactant composition |
| US10857232B2 (en) | 2013-09-30 | 2020-12-08 | Enza Biotech Ab | Surfactant composition |
| JP2022060263A (en) * | 2013-09-30 | 2022-04-14 | エンサ バイオテック アクチエボラグ | Surfactant composition |
| JP2020524597A (en) * | 2017-06-22 | 2020-08-20 | ソシエテ・デクスプロワタシオン・デ・プロデュイ・プール・レ・アンデュストリー・シミック・セピックＳｏｃｉｅｔｅ Ｄ’Ｅｘｐｌｏｉｔａｔｉｏｎ Ｄｅ Ｐｒｏｄｕｉｔｓ Ｐｏｕｒ Ｌｅｓ Ｉｎｄｕｓｔｒｉｅｓ Ｃｈｉｍｉｑｕｅｓ Ｓｅｐｐｉｃ | Novel surfactant mixtures, novel compositions containing them and their use in fire fighting foam concentrates |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2728791B2 (en) | 1998-03-18 |
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