JPH04212891A - Thermal stencil paper - Google Patents

Thermal stencil paper

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Publication number
JPH04212891A
JPH04212891A JP40628690A JP40628690A JPH04212891A JP H04212891 A JPH04212891 A JP H04212891A JP 40628690 A JP40628690 A JP 40628690A JP 40628690 A JP40628690 A JP 40628690A JP H04212891 A JPH04212891 A JP H04212891A
Authority
JP
Japan
Prior art keywords
fiber
film
thermoplastic resin
resin film
synthetic fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP40628690A
Other languages
Japanese (ja)
Other versions
JP2964016B2 (en
Inventor
Fukashi Hashimoto
橋本 不可止
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daito Chemical Co Ltd
Original Assignee
Daito Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daito Chemical Co Ltd filed Critical Daito Chemical Co Ltd
Priority to JP40628690A priority Critical patent/JP2964016B2/en
Publication of JPH04212891A publication Critical patent/JPH04212891A/en
Application granted granted Critical
Publication of JP2964016B2 publication Critical patent/JP2964016B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To reduce a fiber wt. basis and to improve ink permeability and image sharpness by forming thermal stencil paper by scattering a synthetic fiber such as a polyester fiber on the single surface of a thermoplastic resin film and bonding the same to said film under heating and pressure to provide a fiber layer. CONSTITUTION:Synthetic fibers cut into predetermined length are mixed and loosened to be scattered on the single surface of a thermoplastic resin film by wind force or electrostatic force. Subsequently, the thermoplastic resin film having the synthetic fibers scattered thereon is passed through a press plate of light applied pressure and a press roll and the synthetic fibers are bonded to the film under heating and pressure by a hot roll to form a fiber layer. As the thermoplastic resin film, a biaxially stretched polyester film is pref. As the synthetic fiber constituting the fiber layer, a polyester, polyamide or polyimide type monofilament, a rayon monofilament or a carbon fiber is pref.

Description

【発明の詳細な説明】 【0001】 【産業上の利用分野】本発明は、閃光照射、赤外線照射
、レーザー光線等のパルス的照射や、所謂サーマルヘッ
ドの接触により穿孔製版され、輪転印刷や平版印刷に供
される感熱性孔版原紙に関する。 【0002】 【従来技術及び考案が解決しようとする課題】従来、感
熱性孔版原紙(以下単に原紙という)としては、塩化ビ
ニリデン系フィルム、ポリエステル系フィルム等の熱可
塑性樹脂フィルムと、天然繊維、合成繊維又はこれらの
混抄からなる薄葉紙、不織布、紗などからなる多孔性支
持体とを接着剤で貼り合わせた構造のものが、特開昭5
1−2512号公報や特開昭57−182495号公報
において提案されている。 【0003】しかしながら、これらの原紙は印刷画像の
鮮明性の点で必ずしも満足のいくものではなかった。 【0004】その理由としては、原紙を構成するフィル
ムが熱エネルギーの印加により溶融穿孔されても、その
孔部分に支持体を構成する繊維やフィルムと支持体を接
着する接着剤があれば、その繊維や接着剤によって印刷
インキの透過性が阻害され、印刷用紙に画線を構成する
点を形成出来ず、所謂白ぬけ現像を起こし、画像鮮明度
の低下が起こっていたからである。 【0005】また、支持体の構成繊維として天然繊維を
用いた場合には、純繊維以外の原料夾雑物に起因する肉
眼で確認可能な塊が混在し、この塊がインキの透過性を
阻害し同様に画像鮮明性の低下が起こるといった不具合
を生じていた。 【0006】このように、支持体は、フィルムが極めて
薄く弱いことから補強のため、又、製版したときに、例
えば、○の中央部が欠落して●になることを防ぐため、
更には、耐印刷性の維持向上のため、原紙には不可欠の
ものであるにも拘らず、印刷インキの透過性を阻害する
等の不具合を生ぜしめていた。 【0007】これらの欠点を改良するため、従来から様
々な試みがなされている。 【0008】例えば支持体の繊維密度を下げた所謂嵩高
な支持体を用いることによって、フィルム上の繊維坪量
を低くして、インク透過性を向上させる方法もある。し
かしながら、この場合、画像鮮明性は向上するが、支持
体の紙力、例えば引張強度等が低下すると共に、原紙に
充分インクが行き渡らないために印刷開始時に数枚の印
刷不良物が出て好ましくない。 【0009】以上の如く、原紙の支持体を構成する繊維
は天然繊維、合成繊維を問わず、画像鮮明性を阻害する
ものであり、極力、細い繊維を少なく用いるのが好まし
い方向であるが、支持体を製造する際の操業の安定性、
それ以降の二次加工適性、機械的な強度などから自ら限
界があった。つまり、一般的には繊維坪量9〜12g/
m2、 繊度0.5デニール(合成繊維の場合、天然繊
維はもっと太い)が実用に供されているにすぎない。 【0010】本発明は、このような事情に鑑みなされた
ものであり、繊維坪量を少なくし、インキ透過性の良好
な画像鮮明性の優れた原紙を提供することを目的とする
ものである。 【0011】 【課題を解決するための手段及び作用】上記目的を達成
するため、請求項1記載の発明は、「熱可塑性樹脂フィ
ルムの片面にポリエステル等の合成繊維が散布され熱圧
着されて成る繊維層が形成されていることを特徴とする
感熱性孔版原紙」をその要旨とした。 【0012】また、請求項2記載の発明は、「合成繊維
の繊度が5デニール以下であることを特徴とする感熱性
孔版原紙」をその要旨とした。 【0013】また、請求項3記載の発明は、「合成繊維
の繊維長が50mm以下であることを特徴とする感熱性
孔版原紙」をその要旨とした。 【0014】本発明における熱可塑性フィルムとしては
、品質の均一性、安定性という点から、従来より原紙の
フィルムとして用いられている二軸延伸されたポリエス
テルフィルムが好ましいが、二軸延伸されたポリスチレ
ン、ポリ塩化ビニリデン、ポリカーボネートなども使用
可能である。例えばポリエステルフィルムを用いる場合
、その膜厚は製版時の印加エネルギーを考慮して、サー
マルヘッド用には0.5〜2μ、閃光照射用には2〜5
μが好ましい。この熱可塑性樹脂フィルムの片面にポリ
エステル等の合成繊維が散布され熱圧着されて繊維層が
形成されているのである。 【0015】繊維層を構成する合成繊維としては、ポリ
エステル系、ポリアミド系、或いはイミド系モノフィラ
メント、レーヨンモノフィラメント、カーボンファイバ
ーなどが好適である。その繊度としては、5デニール以
下がよく、好ましくは0.05〜3デニール、より好ま
しくは0.1〜2デニールである。繊度が5デニールを
越えると、印刷物のべた部に繊維目が出て、画像が悪化
することになる。また、維長としては50mm以下がよ
く、好ましくは2〜20mmである。繊維長が50mm
を越えると低坪量化及び均一散布が困難となる。繊維坪
量としては3〜12g/m2が好ましく、より好ましく
は3〜9g/m2である。繊維坪量が3g/m2より低
いと印刷鮮明性は良いが耐印刷性が低下し、12g/m
2を越えると印刷鮮明性が悪化することになる。 【0016】本発明に用いられるフィルム面への合成繊
維の散布方法としては、特に限定されるものではないが
、例えば定長切断された各種長さの1種若しくは2種以
上の合成繊維を混合し、結束をほぐし、これを風力及び
静電気力でフィルム面上に散布するとよい。尚、熱可塑
性樹脂フィルムとの一体化を完全なものにするため、前
記合成繊維にバインダー繊維を混入させてもよい。 尚、散布後の静電気反発力による飛散を防ぐために、フ
ィルム面に粘着剤を微量塗布し、弱い粘着性を付与して
も良い。 【0017】合成繊維の散布された熱可塑性樹脂フィル
ムは、軽度の印加圧のプレス板、プレスロールを経て、
熱ロールで熱圧着され、熱可塑性樹脂フィルム上に合成
繊維よりなる繊維層が形成されるのである。尚、ロール
の温度及び圧力は、フィルムや合成繊維の種類、繊維の
坪量等を考慮して適宜決定すると良い。また、繊維地合
の向上のため、散布、軽度プレスの工程を繰り返しても
よい。また、熱圧着後必要に応じて、帯電防止処理や繊
維面にサーマルヘッド或いは原稿の付着防止のための離
型剤のコートを行なってもよい。 【0018】尚、熱ロールを通すときの熱による熱収縮
を防ぐため、低融点樹脂をコートした複合モノフィラメ
ントを合成繊維として用いたり、感熱性樹脂接着剤層を
コートしたフィルムを用いたりしてロール温度を極力低
くすることも有効である。 【0019】このようにして形成された繊維層は熱可塑
性樹脂フィルムを補強し、耐印刷性を維持向上せしめる
よう作用する。一方、この繊維層は低坪量化されており
、インキ透過性を阻害することはなく、印刷鮮明性が悪
化することもない。 【0020】 【実施例】 【0021】 【実施例1】厚さ1.8μのポリエステルフィルム上に
繊維長5mm、0.5デニールのポリエステルモノフィ
ラメント、及び繊維長5mm、1.0デニールのポリエ
ステル系バインダーモノフィラメントの混合物を集束部
のないよう充分に混合撹拌後散布し、軽く金属板で圧着
後、熱ロールを通して、繊維坪量6g/m2 の原紙を
得た。 【0022】こうして、得られた原紙をセイキ工業製エ
スプリ21vx型のサーマルヘッド製版方式の製版輪転
印刷機にて、テストパターンを製版印刷した。 【0023】 【比較例1】比較のために実施例1と同じ厚さ1.8μ
のポリエステルフィルムと、マニラ麻100%で繊維坪
量9.5g/m2 の薄葉紙とを接着剤を用いて貼合し
て原紙を得た。これを実施例1と同様に製版印刷した。 【0024】 【比較例2】ポリエステルモノフィラメント(バインダ
ー繊維約50%)からなる繊維坪量11g/m2 の薄
葉紙と、実施例1と同じ厚さ1.8μのポリエステルフ
ィルムとを接着剤を用いて貼合して原紙を得た。これを
実施例1と同様に製版印刷した。 【0025】尚、各原紙には帯電防止剤及び離型剤を塗
布した。上述した実施例1、比較例1、2により得られ
た印刷物について、印刷物の黒べた部分の光学的濃度、
直型5.0mmの黒丸寸法の変化率及び良好に印刷され
た印刷物の枚数を表1に示した。 【0026】 【表1】 【0027】   【発明の効果】以上述べたように、請求項1記載の原紙
は、従来の抄紙法による支持体では限界とされていた9
g/m2 を下回る低坪量の繊維層によって熱可塑性樹
脂フィルムが支持されていることから、熱可塑性樹脂フ
ィルムが溶融穿孔されたとき、フィルムの孔部分に存在
する繊維に起因する印刷インキの透過性不良を改善し、
以って画像鮮明性の向上を計ることができる。 【0028】また、請求項1記載の原紙にあっては、フ
ィルムと支持体とを張り合わせるものではないため、接
着剤によって印刷インキの透過性が阻害されることもな
い。 【0029】また、請求項1記載の原紙にあっては、繊
維層の構成繊維として合成繊維を用いたため、純繊維以
外の原料夾雑物が該繊維層に混入することがなく、原料
夾雑物に起因してインキ透過性が阻害されることもない
。 【0030】また、請求項2記載の原紙は、繊維層を構
成する合成繊維の繊度が5デニール以下であることから
、印刷物のベタ部に繊維目が出て画像が悪化することも
ない。 【0031】また、請求項3記載の原紙は、繊維層を構
成する合成繊維の繊維長が50mm以下であることから
、低坪量化及び均一散布を実現することができる。
Detailed Description of the Invention [0001] [Industrial Application Field] The present invention is applicable to perforation plate making by flash irradiation, infrared ray irradiation, pulsed irradiation such as laser beam irradiation, or contact with a so-called thermal head, and is used in rotary printing and planographic printing. The present invention relates to heat-sensitive stencil paper used for. [Prior art and problems to be solved by the invention] Conventionally, heat-sensitive stencil paper (hereinafter simply referred to as base paper) has been made of thermoplastic resin films such as vinylidene chloride films and polyester films, natural fibers, and synthetic fibers. A structure in which fibers or a porous support made of thin paper, non-woven fabric, gauze, etc. made of fibers or a mixture thereof are bonded together with an adhesive was disclosed in Japanese Patent Application Laid-open No. 5
This method has been proposed in Japanese Patent Application Laid-open No. 1-2512 and Japanese Patent Application Laid-open No. 182495/1982. However, these base papers have not always been satisfactory in terms of the clarity of printed images. [0004] The reason for this is that even if the film constituting the base paper is melted and perforated by the application of thermal energy, if there are fibers constituting the support or an adhesive that adheres the film and the support in the perforations, the This is because the permeability of the printing ink is obstructed by the fibers and adhesives, making it impossible to form dots that make up the image lines on the printing paper, resulting in so-called whiteout development and a decrease in image clarity. [0005] Furthermore, when natural fibers are used as constituent fibers of the support, visible lumps caused by raw material impurities other than pure fibers are mixed in, and these lumps inhibit ink permeability. Similarly, problems such as a decrease in image clarity have occurred. [0006] As described above, the support is used to reinforce the film since it is extremely thin and weak, and also to prevent the center part of a circle from being missing and becoming a black mark when making a plate.
Furthermore, although it is essential for base paper in order to maintain and improve printing durability, it has caused problems such as inhibiting the permeability of printing ink. [0007] Various attempts have been made in the past to improve these drawbacks. For example, there is a method of improving the ink permeability by lowering the basis weight of the fibers on the film by using a so-called bulky support with a lower fiber density. However, in this case, although the image clarity improves, the paper strength of the support, such as tensile strength, etc., decreases, and since the ink is not sufficiently spread over the base paper, several sheets of defective prints appear at the start of printing, which is undesirable. do not have. As described above, the fibers constituting the base paper support, regardless of whether they are natural fibers or synthetic fibers, impede image clarity, and it is preferable to use as few thin fibers as possible. operational stability when manufacturing supports;
After that, there were limits due to suitability for secondary processing, mechanical strength, etc. In other words, generally the fiber basis weight is 9 to 12 g/
m2 and a fineness of 0.5 denier (synthetic fibers are thicker, natural fibers are thicker). The present invention was made in view of the above circumstances, and it is an object of the present invention to provide a base paper with a reduced fiber basis weight, good ink permeability, and excellent image clarity. . Means and Effects for Solving the Problems In order to achieve the above object, the invention according to claim 1 provides a film comprising a thermoplastic resin film having synthetic fibers such as polyester dispersed on one side and bonded by thermocompression. The gist of the paper was "a heat-sensitive stencil paper characterized by the formation of a fibrous layer." [0012] The gist of the invention as claimed in claim 2 is ``a heat-sensitive stencil paper characterized in that the fineness of synthetic fibers is 5 deniers or less.'' [0013] The gist of the invention as set forth in claim 3 is ``a heat-sensitive stencil paper characterized in that the fiber length of synthetic fibers is 50 mm or less.'' The thermoplastic film used in the present invention is preferably a biaxially stretched polyester film, which has been conventionally used as a base paper film, from the viewpoint of quality uniformity and stability. , polyvinylidene chloride, polycarbonate, etc. can also be used. For example, when using a polyester film, the film thickness should be 0.5 to 2 μm for a thermal head, and 2 to 5 μm for a flash irradiation, taking into account the energy applied during plate making.
μ is preferred. Synthetic fibers such as polyester are sprinkled on one side of this thermoplastic resin film and bonded under heat to form a fiber layer. Suitable synthetic fibers constituting the fiber layer include polyester, polyamide, or imide monofilaments, rayon monofilaments, and carbon fibers. The fineness is preferably 5 deniers or less, preferably 0.05 to 3 deniers, more preferably 0.1 to 2 deniers. If the fineness exceeds 5 denier, fiber grains will appear in the solid areas of the printed matter and the image will deteriorate. Further, the fiber length is preferably 50 mm or less, preferably 2 to 20 mm. Fiber length is 50mm
If the amount exceeds 100%, it becomes difficult to reduce the basis weight and uniformly spread the powder. The fiber basis weight is preferably 3 to 12 g/m2, more preferably 3 to 9 g/m2. When the fiber basis weight is lower than 3 g/m2, printing clarity is good, but printing resistance decreases, and 12 g/m
If it exceeds 2, printing clarity will deteriorate. The method of dispersing the synthetic fibers onto the film surface used in the present invention is not particularly limited, but for example, one or more synthetic fibers of various lengths cut to a fixed length may be mixed. It is recommended to loosen the bundle and spread it over the film surface using wind and electrostatic force. Incidentally, in order to complete the integration with the thermoplastic resin film, binder fibers may be mixed into the synthetic fibers. In addition, in order to prevent scattering due to electrostatic repulsion after dispersion, a small amount of adhesive may be applied to the film surface to impart weak adhesiveness. The thermoplastic resin film sprinkled with synthetic fibers is passed through a press plate and a press roll under mild pressure.
A fibrous layer made of synthetic fibers is formed on the thermoplastic resin film by thermocompression bonding with a hot roll. Note that the temperature and pressure of the roll may be appropriately determined in consideration of the type of film or synthetic fiber, the basis weight of the fiber, etc. Further, in order to improve the fiber texture, the steps of scattering and light pressing may be repeated. Further, after thermocompression bonding, if necessary, antistatic treatment or coating of a release agent to prevent adhesion of a thermal head or a document to the fiber surface may be performed. [0018] In order to prevent thermal shrinkage due to heat when passing through a hot roll, composite monofilaments coated with a low melting point resin are used as synthetic fibers, or a film coated with a heat-sensitive resin adhesive layer is used. It is also effective to keep the temperature as low as possible. The fibrous layer thus formed serves to reinforce the thermoplastic resin film and maintain and improve printing resistance. On the other hand, this fiber layer has a low basis weight and does not impede ink permeability and does not deteriorate print clarity. [Example] [Example 1] A polyester monofilament with a fiber length of 5 mm and a 0.5 denier and a polyester binder with a fiber length of 5 mm and a 1.0 denier on a polyester film with a thickness of 1.8 μm. The monofilament mixture was thoroughly mixed and stirred so as not to form any bundles, then dispersed, lightly pressed with a metal plate, and then passed through a hot roll to obtain a base paper with a fiber basis weight of 6 g/m2. A test pattern was printed on the base paper thus obtained using a Seiki Kogyo Esprit 21vx thermal head plate making type rotary printing press. [Comparative Example 1] For comparison, the same thickness as Example 1, 1.8μ
A base paper was obtained by laminating a polyester film of 100% and a thin paper made of 100% Manila hemp with a fiber basis weight of 9.5 g/m2 using an adhesive. This was printed in the same manner as in Example 1. [Comparative Example 2] A thin paper with a fiber basis weight of 11 g/m2 made of polyester monofilament (approximately 50% binder fiber) and a polyester film with a thickness of 1.8 μm, which is the same as in Example 1, were attached using an adhesive. A base paper was obtained. This was printed in the same manner as in Example 1. Incidentally, each base paper was coated with an antistatic agent and a mold release agent. Regarding the printed matter obtained in Example 1 and Comparative Examples 1 and 2 described above, the optical density of the solid black part of the printed matter,
Table 1 shows the rate of change in the dimension of the straight 5.0 mm black circle and the number of well-printed prints. [Table 1] [Effects of the Invention] As described above, the base paper according to claim 1 has the ability to achieve 9
Since the thermoplastic resin film is supported by a fiber layer with a low basis weight of less than g/m2, when the thermoplastic resin film is melt perforated, printing ink permeation due to the fibers present in the perforations of the film is reduced. improve sexual defects,
Accordingly, it is possible to improve image clarity. Furthermore, in the base paper according to claim 1, since the film and the support are not pasted together, the permeability of printing ink is not inhibited by the adhesive. In addition, in the base paper according to claim 1, since synthetic fibers are used as the constituent fibers of the fiber layer, raw material impurities other than pure fibers do not mix into the fiber layer, and raw material foreign materials do not mix with the fiber layer. As a result, ink permeability is not inhibited. Further, in the base paper according to the second aspect, since the fineness of the synthetic fibers constituting the fiber layer is 5 deniers or less, the appearance of fiber grains in solid areas of printed matter does not deteriorate the image. Further, in the base paper according to claim 3, since the fiber length of the synthetic fibers constituting the fiber layer is 50 mm or less, it is possible to realize a low basis weight and uniform dispersion.

Claims (1)

【特許請求の範囲】 【請求項の1】  熱可塑性樹脂フィルムの片面にポリ
エステル等の合成繊維が散布され熱圧着されて成る繊維
層が形成されていることを特徴とする感熱性孔版原紙。 【請求項2】  合成繊維の繊度が5デニール以下であ
ることを特徴とする請求項1記載の感熱性孔版原紙。 【請求項3】  合成繊維の繊維長が50mm以下であ
ることを特徴とする請求項1または2記載の感熱性孔版
原紙。
[Scope of Claims] [Claim 1] A heat-sensitive stencil paper, characterized in that a fiber layer is formed by sprinkling synthetic fibers such as polyester on one side of a thermoplastic resin film and bonding them under heat. 2. The heat-sensitive stencil paper according to claim 1, wherein the synthetic fiber has a fineness of 5 deniers or less. 3. The heat-sensitive stencil paper according to claim 1, wherein the synthetic fiber has a fiber length of 50 mm or less.
JP40628690A 1990-12-05 1990-12-05 Heat-sensitive stencil paper Expired - Fee Related JP2964016B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP40628690A JP2964016B2 (en) 1990-12-05 1990-12-05 Heat-sensitive stencil paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP40628690A JP2964016B2 (en) 1990-12-05 1990-12-05 Heat-sensitive stencil paper

Publications (2)

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JPH04212891A true JPH04212891A (en) 1992-08-04
JP2964016B2 JP2964016B2 (en) 1999-10-18

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Family Applications (1)

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JP40628690A Expired - Fee Related JP2964016B2 (en) 1990-12-05 1990-12-05 Heat-sensitive stencil paper

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0583959A2 (en) * 1992-08-19 1994-02-23 Riso Kagaku Corporation Process for producing heat-sensitive stencil sheet
WO1994025285A1 (en) * 1993-04-23 1994-11-10 Toray Industries, Inc. Heat-sensitive stencil paper
US6025286A (en) * 1996-05-09 2000-02-15 Kawatsu; Yukio Heat-sensitive stencil sheet

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0583959A2 (en) * 1992-08-19 1994-02-23 Riso Kagaku Corporation Process for producing heat-sensitive stencil sheet
EP0583959A3 (en) * 1992-08-19 1995-09-06 Riso Kagaku Corp Process for producing heat-sensitive stencil sheet
WO1994025285A1 (en) * 1993-04-23 1994-11-10 Toray Industries, Inc. Heat-sensitive stencil paper
US6025286A (en) * 1996-05-09 2000-02-15 Kawatsu; Yukio Heat-sensitive stencil sheet

Also Published As

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