JPH04168163A - Design coating composition - Google Patents
Design coating compositionInfo
- Publication number
- JPH04168163A JPH04168163A JP29671090A JP29671090A JPH04168163A JP H04168163 A JPH04168163 A JP H04168163A JP 29671090 A JP29671090 A JP 29671090A JP 29671090 A JP29671090 A JP 29671090A JP H04168163 A JPH04168163 A JP H04168163A
- Authority
- JP
- Japan
- Prior art keywords
- mica
- metal
- pigment
- mica pigment
- plated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008199 coating composition Substances 0.000 title description 10
- 239000010445 mica Substances 0.000 claims abstract description 53
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 53
- 239000000049 pigment Substances 0.000 claims abstract description 38
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 238000007747 plating Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000010409 thin film Substances 0.000 claims description 9
- 239000003973 paint Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 239000004408 titanium dioxide Substances 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- 230000001427 coherent effect Effects 0.000 abstract 4
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 description 13
- 235000019646 color tone Nutrition 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920000877 Melamine resin Polymers 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 239000004640 Melamine resin Substances 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は意匠性に優れた塗装仕上げが得られる意匠塗料
組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a decorative coating composition that provides a paint finish with excellent design.
［従来の技術］
近年自動車の上塗り塗料として、干渉パールマイカ顔料
を含む意匠塗装仕上げが多く用いられている。この干渉
バールマイカ顔料は、マイカを基材とし、そのマイカ表
面に二酸化チタンなどの無機質薄膜層が被覆されたもの
であり、光路長の異なる複数の反射面をもつことから青
色、赤色などの淡い独特の干渉色を発し、特有の意匠塗
装仕上げが得られる。[Prior Art] In recent years, decorative paint finishes containing interference pearl mica pigments have been widely used as top coats for automobiles. This interference burl mica pigment uses mica as its base material, and the mica surface is coated with an inorganic thin film layer such as titanium dioxide.Since it has multiple reflective surfaces with different optical path lengths, it produces unique pale colors such as blue and red. It emits an interference color and produces a unique design finish.
ところで、特開平２−３２１７０号、特開平２−５８５
７８号などの公報に、干渉パールマイカ顔料表面にさら
に金属メッキを施した金属メッキマイカ顔料が発表され
ている。これらの金属メッキマイカ顔料は、複数の反射
面における反射に加えて金属メッキ層表面での反射も加
わるため、極めて強い干渉光を発し、濃色も可能である
ため今後の自動車意匠塗装の主流となるものとして期待
されている。By the way, JP-A-2-32170, JP-A-2-585
No. 78 and other publications disclose metal-plated mica pigments in which the surface of interference pearl mica pigments is further plated with metal. These metal-plated mica pigments emit extremely strong interference light due to the reflection from the surface of the metal plating layer in addition to the reflection from multiple reflective surfaces, and are also capable of producing deep colors, so they will become the mainstream for future automotive design coatings. It is expected that this will become a reality.
［発明が解決しようとする課題］
しかしながら上記した金属メッキマイカ顔料は、半隠蔽
性であり、この顔料を含む塗膜は正面から見た場合は隠
蔽性が高いが、斜め方向から見た場合は隠蔽性が低いと
いう特性を有している。そのため例えば調色の必要性か
ら有機顔料を併用した場合には、正面から見た場合は隠
蔽性が高いため有機顔料による発色は大きくないが、斜
め方向から見ると隠蔽性が低いため光路が長くなり、そ
の間に含まれる顔料の量が多くなるため、有機顔料によ
る発色が大きい。したがって見る角度によって色調が極
端に異なることとなり、意匠性を損なう場合もある。[Problems to be Solved by the Invention] However, the metal-plated mica pigment described above has semi-hidden properties, and a coating film containing this pigment has high hiding properties when viewed from the front, but when viewed from an oblique direction. It has the characteristic of low concealment. Therefore, for example, when organic pigments are used in combination due to the need for color toning, when viewed from the front, the color development by the organic pigments is not large due to the high hiding power, but when viewed from an angle, the light path is long due to the low hiding power. Since the amount of pigment contained between them increases, the color development due to the organic pigment is large. Therefore, the color tone will vary drastically depending on the viewing angle, which may impair the design.
また、赤や黄などの有機顔料は耐候性が充分とはいえな
い。しかし従来の着色塗料のように有機顔料を多量に含
む場合には、僅かの変色はほとんど目立たず実用域にあ
る。ところが金属メッキマイカ顔料に僅かに混合するよ
うな場合には、有機顔料の変色は発色に大きく影響し、
耐候性に不具合が生じるようになる。Furthermore, organic pigments such as red and yellow do not have sufficient weather resistance. However, when conventional colored paints contain a large amount of organic pigment, slight discoloration is hardly noticeable and is within the practical range. However, when slightly mixed with metal-plated mica pigments, the discoloration of the organic pigments greatly affects color development.
Problems with weather resistance will occur.
さらに、干渉色による発色のみであれば、鮮やかな発色
であるのに対し、有機顔料を添加するとやや濁った感じ
の発色となる。Furthermore, if only interference color is used, the color will be bright, but if an organic pigment is added, the color will be slightly cloudy.
本発明はこのような事情に鑑みてなされたものであり、
金属メッキマイカ顔料を用いた塗料組成物において、正
面から見た場合と斜め方向から見た場合の色調の差を縮
小し、意匠性を向上させることを目的とする。The present invention was made in view of these circumstances, and
The purpose of the present invention is to reduce the difference in color tone when viewed from the front and from an oblique direction, and to improve the design of a paint composition using metal-plated mica pigments.
［課題を解決するための手段］
上記課題を解決する本発明の意匠塗料組成物は、マイカ
とマイカ表面に被覆された無機質薄膜層とからなり干渉
色を有する干渉パールマイカ顔料と、干渉パールマイカ
顔料に金属がメッキされて形成された光輝層をもつ金属
メッキマイカ顔料と、を含むことを特徴とする。[Means for Solving the Problems] The design coating composition of the present invention which solves the above problems comprises: an interference pearl mica pigment which is composed of mica and an inorganic thin film layer coated on the surface of the mica and has an interference color; A metal-plated mica pigment having a glitter layer formed by plating a pigment with a metal.
干渉パールマイカ顔料は、天然雲母、合成雲母などのマ
イカを基体とし、そのマイカ表面に無機質薄膜層が厚さ
２００μｍ以上形成されたものである。この無機質薄膜
層としては、二酸化チタンが主流であるが、他に酸化鉄
、水酸化アルミニウム、水酸化クロムなども用いること
ができる。無機質薄膜層の屈折率、厚さにより発色する
干渉色か異なる。この干渉パールマイカ顔料は、例えば
メルク社から「イリオジン」の商品名で市販されている
。The interference pearl mica pigment has a base of mica such as natural mica or synthetic mica, and has an inorganic thin film layer of 200 μm or more in thickness formed on the surface of the mica. This inorganic thin film layer is mainly made of titanium dioxide, but iron oxide, aluminum hydroxide, chromium hydroxide, etc. can also be used. The interference color produced differs depending on the refractive index and thickness of the inorganic thin film layer. This interference pearl mica pigment is commercially available, for example, from Merck & Co. under the trade name "Iriodin."
金属メッキマイカ顔料は、上記した干渉パールマイカ顔
料にさらに銀、金、ニッケル、コバルト、マンガンなど
の光輝性を有する金属または合金がメッキされた光輝層
をもつ。この光輝層は上記無機質薄膜層表面に設けても
よいし、無機質薄膜層とマイカとの間に設けることもで
きる。そして無機質薄膜層の屈折率、その厚さ、さらに
金属メッキ量によって異なる干渉色が生じる。この光輝
層を形成するには通常無電解メッキが利用される。The metal-plated mica pigment has a glitter layer in which the above-described interference pearl mica pigment is further plated with a metal or alloy having glitter, such as silver, gold, nickel, cobalt, or manganese. This glitter layer may be provided on the surface of the inorganic thin film layer, or may be provided between the inorganic thin film layer and mica. Different interference colors occur depending on the refractive index of the inorganic thin film layer, its thickness, and the amount of metal plating. Electroless plating is usually used to form this bright layer.
なお、金属メッキ量は、パールマイカに対する重量比で
０．５〜８０％程度が好ましい。The amount of metal plating is preferably about 0.5 to 80% by weight relative to pearl mica.
干渉パールマイカ顔料と金属メッキマイカ顔料との混合
比は特に制限されず、種々の比率で用いることができる
。そして干渉パールマイカ顔料の含有率が多くなる程、
正面から見た場合と斜め方向から見た場合の色調の差が
小さくなる。The mixing ratio of the interference pearl mica pigment and the metal-plated mica pigment is not particularly limited, and various ratios can be used. And the higher the content of interference pearl mica pigment,
The difference in color tone when viewed from the front and when viewed from an oblique direction is reduced.
なお上記干渉パールマイカ顔料及び金属メッキマイカ顔
料の他に、有機顔料、無機顔料などを併用することもで
きる。しかしながら有機顔料や無機顔料を用いると色調
に濁りや曇りが生じる場合が多く、耐候性も低下するの
で、上記２種類のマイカ系顔料のみで構成することが望
ましい。In addition to the above-mentioned interference pearl mica pigment and metal-plated mica pigment, organic pigments, inorganic pigments, etc. can also be used in combination. However, when organic pigments or inorganic pigments are used, the color tone often becomes cloudy or cloudy, and the weather resistance is also reduced, so it is desirable to use only the above two types of mica pigments.
本発明の塗料組成物の他の成分はバインダーとなる樹脂
成分であるが、この樹脂としては透明であれば特に制限
されず、従来と同様にアクリル−メラミン樹脂、ポリエ
ステル−メラミン樹脂、アルキド−メラミン樹脂、など
のメラミン硬化型樹脂、あるいはイソシアネート硬化型
ウレタン樹脂などから種々選択することができる。The other component of the coating composition of the present invention is a resin component serving as a binder, but this resin is not particularly limited as long as it is transparent, and as in the past, acrylic-melamine resin, polyester-melamine resin, alkyd-melamine resin, alkyd-melamine resin, etc. A variety of resins can be selected from melamine-curing resins such as resin, isocyanate-curing urethane resins, and the like.
［発明の作用および効果］
干渉パールマイカ顔料を含む塗膜は、正面から見た場合
と斜め方向から見た場合の発色の差が小さい。したかつ
て本発明の塗料組成物では、上記発色の差の大きな金属
メッキマイカ顔料に干渉パールマイカ顔料が混合されて
いるので、その会見る方向による発色の差を小さくする
ことができる。[Operations and Effects of the Invention] A coating film containing an interference pearl mica pigment has a small difference in color development when viewed from the front and when viewed from an oblique direction. However, in the coating composition of the present invention, since the interference pearl mica pigment is mixed with the metal-plated mica pigment, which has a large difference in color development, the difference in color development depending on the direction in which it is viewed can be reduced.
また両顔料とも干渉色により発色するので、有機顔料の
ような濁り、白ぼけが生じず鮮明な色調が得られる。Furthermore, since both pigments develop color using interference colors, clear color tones can be obtained without the turbidity and white blurring that occurs with organic pigments.
すなわち本発明の意匠塗料組成物によれば、光干渉によ
り鮮明に発色し、かつ見る方向による発色の差が小さく
意匠性に優れた塗膜を形成することができる。That is, according to the decorative coating composition of the present invention, it is possible to form a coating film that is clearly colored by light interference, has small differences in coloring depending on the viewing direction, and is excellent in design.
［実施例］ 以下実施例により具体的に説明する。[Example] This will be explained in detail below using examples.
（実施例１）
干渉パールマイカとしてのホワイトパールマイカ（「イ
リオジン１０３ＷＩＩＪに無電解メッキにより銀が５重
量％付着されて形成された銀メッキマイカ２．０重量部
と、アクリル樹脂（「アクリディックＡ−３２２Ｊ大日
本インキ化学社製）２８．８重量部、メラミン樹脂（［
スーパーベッカミンＬ−１１７−６０Ｊ大日本インキ化
学社製）６．０重量部及びシンナー６３．２重量部をデ
イスパー、でよく混合し、実施例１のベースコート塗料
組成物を調整した。(Example 1) White pearl mica as interference pearl mica (2.0 parts by weight of silver-plated mica formed by attaching 5% by weight of silver to Iriodin 103WIIJ by electroless plating) and acrylic resin (acrylic A -322J Dainippon Ink Chemical Co., Ltd.) 28.8 parts by weight, melamine resin ([
6.0 parts by weight of Super Beckamine L-117-60J (manufactured by Dainippon Ink & Chemicals Co., Ltd.) and 63.2 parts by weight of thinner were thoroughly mixed in a disper to prepare the base coat coating composition of Example 1.
このベースコートに赤味を付与するために、赤色干渉パ
ールマイカ（［イリオジン２１５ＷＩ［Ｊヌル９社製）
２．０重量％を含み上記ベースコートと同一樹脂組成の
調整用原色Ａを調整した。そしてベースコート１００重
量部に対して調整用原色Ａを１０重量部混合し、電着塗
膜及び中塗り塗膜をもつ綱板表面に塗装し、さらに別に
製造されたアクリル−メラミン系クリア塗料をウェット
−オン−ウェットで塗布して、１４０℃で３０分焼付け
て硬化させた。In order to give this base coat a reddish tint, red interference pearl mica ([Iriodin 215WI [manufactured by J Null 9]) was used.
Adjustment primary color A containing 2.0% by weight and having the same resin composition as the above base coat was prepared. Then, 10 parts by weight of primary color A for adjustment was mixed with 100 parts by weight of the base coat, and the mixture was applied to the surface of the steel plate having the electrodeposited coating film and the intermediate coating film, and then a separately manufactured acrylic-melamine clear paint was wetted. -On-wet application and baking at 140°C for 30 minutes to cure.
得られた塗板について正面及び斜め方向からみた場合の
意匠を目視で判定した。また屋外暴露に２年間供し、そ
の変色度合を目視で判定して耐候性を調査した。結果を
第１表に示す。The design of the obtained coated board when viewed from the front and diagonally was visually judged. The material was also exposed outdoors for 2 years, and its degree of discoloration was visually determined to investigate its weather resistance. The results are shown in Table 1.
（実施例２）
調整用原色Ａの代りに、青色干渉パールマイカ顔料（「
イリオジン２２５ＷＩＩｊメルク社製）を２重量部含み
、ベースコートと同一の樹脂組成からなる調整用原色Ｂ
を用意し、ベースコート１００重量部に対して調整用原
色Ｂを１５重量部を配合して実施例２の塗料組成物を調
整した。そして実施例１と同様に試験し結果を第１表に
示す。(Example 2) Instead of the primary color A for adjustment, a blue interference pearl mica pigment ("
Adjustment primary color B containing 2 parts by weight of Iriodin 225WIIj (manufactured by Merck & Co.) and having the same resin composition as the base coat.
A coating composition of Example 2 was prepared by blending 15 parts by weight of adjusting primary color B with 100 parts by weight of the base coat. The test was carried out in the same manner as in Example 1, and the results are shown in Table 1.
（比較例１〜比較例４）
それぞれの比較例では、赤色有機顔料（「シンカシャレ
ットＹ、ＲＴ−７５９ＤＪチバカイギー社製」２重量部
をベースコートと同一の樹脂組成の樹脂中にペイントシ
ェーカーで分散した調整用第１表
（以下余白）
原色Ｃ１および青色有機顔料（［ヘリオゲンブル−Ｌ−
６９００Ｊ ＢＡＳＦ社製」２重量部をベースコートと
同一の樹脂組成の樹脂中にペイントシェーカーで分散し
た調整用原色りを用いた。比較例１および比較例２では
、実施例１と同様のベースコート１００重量部に調整用
原色Ｃを３重量部および１重量部それぞれ混合した。比
較例３および比較例４では、実施例１と同様のベースコ
ート１００重量部に調整用原色りを１．５重量部および
０．５重量部それぞれ混合した。そして実施例１と同様
に試験して結果を第１表に示す。(Comparative Examples 1 to 4) In each comparative example, 2 parts by weight of a red organic pigment ("Shinka Charette Y, RT-759DJ manufactured by Ciba Kaigyi Co., Ltd.") was dispersed in a resin having the same resin composition as the base coat using a paint shaker. Adjustment Table 1 (blank below) Primary color C1 and blue organic pigment ([Heliogen Blue-L-
6900J (manufactured by BASF) was dispersed in a resin having the same resin composition as the base coat using a paint shaker to adjust the primary color. In Comparative Examples 1 and 2, 100 parts by weight of the same base coat as in Example 1 was mixed with 3 parts by weight and 1 part by weight of adjusting primary color C, respectively. In Comparative Examples 3 and 4, 1.5 parts by weight and 0.5 parts by weight of adjusting primary colors were mixed with 100 parts by weight of the same base coat as in Example 1, respectively. The test was carried out in the same manner as in Example 1, and the results are shown in Table 1.
（評価）
第１表より、実施例の塗料組成物から得られた塗板では
、正面から見た場合と斜め方向から見た場合の色調の差
が適度であり、意匠性に優れている。また屋外（愛知県
西加茂郡藤岡町）で２年間暴露しても色調の変化はみら
れなかった。(Evaluation) From Table 1, the coated plates obtained from the coating compositions of Examples have a moderate difference in color tone when viewed from the front and when viewed from an oblique direction, and are excellent in design. No change in color tone was observed even after two years of exposure outdoors (Fujioka Town, Nishikamo District, Aichi Prefecture).
一方、比較例１及び比較例３では、それぞれ正面から見
た場合の意匠には優れているが、斜め方向から見た場合
にそれぞれ赤味及び青味が強く発色し、正面との差が大
きくなって意匠性に優れているとはいいがたい、そして
比較例２及び比較例４では、有機顔料の量が少なく斜め
方向から見た場合には丁度良い色調となるが、正面から
見た場合に色調が薄くなるという不具合がある。On the other hand, Comparative Examples 1 and 3 have excellent designs when viewed from the front, but when viewed from an oblique direction, the colors are strongly reddish and bluish, and the difference from the front is large. However, in Comparative Examples 2 and 4, the amount of organic pigment is small and the color tone is just right when viewed from an angle, but when viewed from the front. There is a problem that the color tone becomes lighter.
ざらに比較例の塗料組成物では、すべて耐候性に問題が
あり、赤色顔料を用いた場合にその程度が大きい。Generally speaking, all of the comparative coating compositions had problems in weather resistance, and the problem was more severe when red pigments were used.
特許出願人 アイシン化工株式会社 同 トヨタ自動車株式会社 代理人 弁理士 大川 宏 手続補正書（自発） 平成 ３年 ７月２シ日Patent applicant: Aisin Kako Co., Ltd. Same Toyota Motor Corporation Agent: Patent Attorney Hiroshi Okawa Procedural amendment (voluntary) July 2nd, 1991
Claims (1)
とからなり干渉色を有する干渉パールマイカ顔料と、 該干渉パールマイカ顔料に金属がメッキされて形成され
た光輝層をもつ金属メッキマイカ顔料と、を含むことを
特徴とする意匠塗料組成物。(1) An interference pearl mica pigment that is composed of mica and an inorganic thin film layer coated on the surface of the mica and has an interference color, and a metal-plated mica pigment that has a glitter layer formed by plating the interference pearl mica pigment with a metal. A design paint composition comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29671090A JPH04168163A (en) | 1990-10-31 | 1990-10-31 | Design coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29671090A JPH04168163A (en) | 1990-10-31 | 1990-10-31 | Design coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04168163A true JPH04168163A (en) | 1992-06-16 |
Family
ID=17837084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29671090A Pending JPH04168163A (en) | 1990-10-31 | 1990-10-31 | Design coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04168163A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997047693A1 (en) | 1996-06-10 | 1997-12-18 | Nittetsu Mining Co., Ltd. | Multilayer coated powder |
| JP2002275424A (en) * | 2001-03-21 | 2002-09-25 | Nippon Paint Co Ltd | Bright coating composition, method for forming coating film and multilayered coating film |
| CN100381214C (en) * | 2003-12-31 | 2008-04-16 | 重庆宗申技术开发研究有限公司 | Powder injection process for machining metal parts |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5378236A (en) * | 1976-12-22 | 1978-07-11 | Nippon Paint Co Ltd | Glittering powder coating composition |
| JPS6426684A (en) * | 1987-07-22 | 1989-01-27 | Aisin Chem | Metallic pattern topcoating |
-
1990
- 1990-10-31 JP JP29671090A patent/JPH04168163A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5378236A (en) * | 1976-12-22 | 1978-07-11 | Nippon Paint Co Ltd | Glittering powder coating composition |
| JPS6426684A (en) * | 1987-07-22 | 1989-01-27 | Aisin Chem | Metallic pattern topcoating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997047693A1 (en) | 1996-06-10 | 1997-12-18 | Nittetsu Mining Co., Ltd. | Multilayer coated powder |
| EA001505B1 (en) * | 1996-06-10 | 2001-04-23 | Ниттецу Майнинг Ко., Лтд. | Multilayer coated powder |
| JP2002275424A (en) * | 2001-03-21 | 2002-09-25 | Nippon Paint Co Ltd | Bright coating composition, method for forming coating film and multilayered coating film |
| CN100381214C (en) * | 2003-12-31 | 2008-04-16 | 重庆宗申技术开发研究有限公司 | Powder injection process for machining metal parts |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR960014754B1 (en) | Coating composition | |
| JPS63232882A (en) | Finish coating method | |
| CN101553526B (en) | Color foundation coat and color top coat paint system | |
| US20050244584A1 (en) | Methods and compositions for forming a specular coating film | |
| JPH09508172A (en) | High chroma paint containing multilayer interference platelets | |
| CA2221078A1 (en) | Process for formation of multilayer film | |
| JPH06228456A (en) | Pigment mixture | |
| US5194336A (en) | Chromatically colored fluororesin-coated material | |
| JP4756443B2 (en) | Method for forming metallic glitter coating film and coated article | |
| CZ300777B6 (en) | Ink composition, blend for its preparation and security document | |
| KR920002986B1 (en) | Pigment | |
| JPH0676566B2 (en) | Coating composition and coated product | |
| KR910006720B1 (en) | Metallic paint film | |
| JPH04168163A (en) | Design coating composition | |
| US5049442A (en) | Opalescent coatings containing foamed metal oxides | |
| JPH11189734A (en) | Colored mica titanium-based pigment, and coating body using the same | |
| JPH0232170A (en) | Pigment | |
| JPH09323064A (en) | Formation of bright coating film and coated material | |
| JP2023544125A (en) | Metallic effect pigment-free radar-ready coatings on substrates | |
| JPS59215857A (en) | Laminated coated material having excellent decorative designability | |
| JPH0258582A (en) | Coating compound composition | |
| JPH0245578A (en) | Paint composition | |
| JPH07292294A (en) | Metallic coating material having color flip-flop characteristic | |
| JPH05132635A (en) | Metallic coating material of delicate luster containing guanine | |
| JPH0788490B2 (en) | Metallic pattern finish paint |