JPH04139038A - Method and device for producing optical fiber - Google Patents

Method and device for producing optical fiber

Info

Publication number
JPH04139038A
JPH04139038A JP2257127A JP25712790A JPH04139038A JP H04139038 A JPH04139038 A JP H04139038A JP 2257127 A JP2257127 A JP 2257127A JP 25712790 A JP25712790 A JP 25712790A JP H04139038 A JPH04139038 A JP H04139038A
Authority
JP
Japan
Prior art keywords
optical fiber
coating material
coating
spray
orifice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2257127A
Other languages
Japanese (ja)
Inventor
Kohei Kobayashi
宏平 小林
Hiroo Matsuda
松田 裕男
Ichiro Yoshimura
一朗 吉村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP2257127A priority Critical patent/JPH04139038A/en
Publication of JPH04139038A publication Critical patent/JPH04139038A/en
Pending legal-status Critical Current

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  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

PURPOSE:To produce a coated optical fiber having a uniform-thickness coating by extruding a coating material-contg. soln. from an orifice by liq. pressure and spraying the fine-particle coating material on the drawn optical fiber. CONSTITUTION:An optical fiber glass preform 1 is heated, melted and drawn into an optical fiber 3 by a drawing furnace 2, and the optical fiber 3 leaving the furnace 2 is immediately introduced into a spray coating vessel 10. An airless spray gun 4 having an orifice 13 is set in the vessel 10 and communicated with a resin composition supplying and pressurizing tank 8. The resin composition soln. is pressurized to about 1-100kg/cm<2> by N2 gas, etc., in the tank 8, supplied to the spray gun 4 through a line 12, depressurized, sprayed as the fine particle 14 and uniformly applied on the optical fiber 3. The coated optical fiber 3 is introduced into a resin curing furnace 5 to cure the coating layer and wound on a winder 6. Meanwhile, the diameter of the orifice of the spray gun 4 is controlled to about 50mu to 1mm, and the size of the sprayed fine particle is uniformly adjusted to about 0.2mu.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は光ファイバの製造方法及び製造装置に関し、詳
しくは光ファイバを樹脂被覆する新規な方法とそのため
の装置に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method and apparatus for manufacturing an optical fiber, and more particularly to a novel method for coating an optical fiber with resin and an apparatus therefor.

[従来の技術] 光ファイバは大容量、低損失といった優れた伝送特性に
加え、無銹導、軽量という利点から新しい伝送方式とし
て実用化されようとしている。光ファイバはその素材が
ガラスであり、200μm以下の細径に加工されること
から、その機械的強度は最も重要な特性の一つである。
[Prior Art] Optical fibers are about to be put into practical use as a new transmission method because of their excellent transmission characteristics such as large capacity and low loss, as well as their non-rusting and lightweight properties. Optical fibers are made of glass and are processed to have a diameter of 200 μm or less, so mechanical strength is one of the most important properties.

この機械的強度の改善のためには、光ファイバ母材を溶
融線引きした直後に樹脂組成物を塗布、硬化させ、ガラ
スの処女強度を保持すると共に、その後の傷の発生を防
くいわゆるタンデムプライマリ−コート法が採られてい
る。
In order to improve this mechanical strength, a so-called tandem primary is applied and cured immediately after the optical fiber base material is molten and drawn to maintain the virgin strength of the glass and prevent subsequent scratches. -The coat method is used.

[発明が解決しようとする課題] この樹脂組成物塗布には、従来よりダイスディッピング
方式、フェルト方式、スプレ一方式等が行われてきたが
、各々一長一短があり、光ファイバに非接触で塗布でき
るという点でダイスティッピング方式とスプレ一方式が
優れており、最も多く採用されている。しかしダイスデ
ィッピング方式は2〜3μm以下の塗膜形成が不可能で
あり、スプレ一方式では薄膜を実現できるものの光ファ
イバに均一な被膜を得ること、すなわち、樹脂組成物の
塗膜厚の制御が難しいという欠点を有している。
[Problem to be solved by the invention] Conventionally, die dipping method, felt method, spray method, etc. have been used to apply this resin composition, but each method has advantages and disadvantages. In this respect, the die tipping method and the spray method are superior and are most commonly used. However, the die dipping method cannot form a coating film with a thickness of 2 to 3 μm or less, and although the spray method can achieve a thin film, it is difficult to obtain a uniform coating on the optical fiber, that is, to control the coating thickness of the resin composition. It has the disadvantage of being difficult.

従来の、スプレ一方式のスプレ一部分を第3図に示すが
、50 kg/as’〜100 kg/cm”というか
なり高圧の圧縮ガスを用いて被覆材(樹脂組成物)を霧
化しているため、被覆材微粒子の大きさが均一でなく、
ガラスファイバ表面に塗布された被覆膜にムラが生じて
均一厚さにすることは不可能であった。
Figure 3 shows a part of the conventional one-spray system, which uses compressed gas at a fairly high pressure of 50 kg/as' to 100 kg/cm'' to atomize the coating material (resin composition). , the size of the particles of the coating material is not uniform,
The coating film applied to the surface of the glass fiber was uneven, making it impossible to achieve a uniform thickness.

また、かなり高圧の圧縮ガスが被覆材を霧化すると、霧
は多量に発生し、被覆材粒子は高速度で吹き飛ばされ、
約50%の被覆材が周囲に飛散してしまい、被覆材微粒
子の付着効率が低くなるという欠点もあった。
Additionally, when compressed gas at a fairly high pressure atomizes the coating material, a large amount of fog is generated and the coating material particles are blown away at high velocity.
There was also a drawback that about 50% of the coating material was scattered to the surroundings, resulting in a low adhesion efficiency of the coating material fine particles.

そして、このように塗布状態が良くないため余分な回数
の塗布が必要となり工程の時間が長くなり、付着効率が
低いことから材料コストが高く、さらに周辺への飛散を
防止する設備を要するため設備コストもかかるため、品
質上の不利のみならず杼済上の不利にもつながっていた
In addition, because the coating condition is not good, it is necessary to apply an extra number of times, which increases the process time, and because the adhesion efficiency is low, material costs are high.Furthermore, equipment to prevent scattering to the surrounding area is required, which requires equipment. The high cost also led to disadvantages not only in terms of quality but also in terms of shipping costs.

本発明は、上記した従来各方式の諸欠点を改善して、均
一な被覆厚さの薄膜を実現できて、しかも従来よりコス
トを低減できる、光ファイバを樹脂被覆する新規な方法
とそのための装置を課題としてなされたものである。
The present invention provides a new method and apparatus for coating optical fibers with resin, which can improve the various drawbacks of the conventional methods described above, realize a thin film with a uniform coating thickness, and reduce the cost compared to the conventional methods. This was done as a challenge.

[課題を解決するための手段] 本発明者らは、スプレ一方式は均一塗布には問題がある
ものの、2〜3μm以下の厚さに塗布できる長所がある
ので、特に霧化における問題を解決すべ(研究努力の結
果、かなり高圧の圧縮空気の使用によらず、被覆材自身
の液圧を利用して小径のオリフィスから押出し噴霧する
方法(以下、エアレス・スプレー法と称する)及び装置
に到達し、本発明の完成を見た。
[Means for Solving the Problems] The present inventors have found that although the one-sided spray method has a problem with uniform application, it has the advantage of being able to apply to a thickness of 2 to 3 μm or less, so it solves the problem particularly in atomization. (As a result of our research efforts, we have developed a method and device that uses the hydraulic pressure of the coating material itself to extrude and spray it from a small-diameter orifice (hereinafter referred to as the airless spray method), without the use of fairly high-pressure compressed air. The present invention was completed.

本発明は線引きしたガラスファイバ外周に被覆材微粒子
を噴霧により付着させて被覆層を有する光ファイバを製
造する方法において、被覆材を含有する溶液を該溶液の
液圧によりオリフィスから押し出すことにより被覆材微
粒子として噴霧することを特徴とする方法により上記の
課題を解決する。
The present invention provides a method for producing an optical fiber having a coating layer by spraying coating material fine particles onto the outer periphery of a drawn glass fiber. The above problem is solved by a method characterized by spraying as fine particles.

また、本発明は上記方法を実現する装置として、(イ)
線引炉、(11)線引きガラスファイバ通過用貫通孔を
有する噴霧塗布装置容器と、該容器内において通過ガラ
スファイバの外周に設けた1以上の噴霧器とを有してな
る噴霧塗布装置、(/I)被覆材硬化手段、を(イ)〜
(八)の順に設けてなる光ファイバ製造装置において、
上記噴霧器が被覆材含有溶液供給装置に連通しており、
当該被覆材含有溶液の液圧により該溶液をオリフィスか
ら押し出し噴霧するものであることを特徴とする光ファ
イバ製造装置を提供する。
Further, the present invention provides an apparatus for realizing the above method (a)
A drawing furnace, (11) a spray coating device comprising a spray coating device container having a through hole for passing the drawn glass fiber, and one or more sprayers provided around the outer periphery of the passing glass fiber in the container; I) Covering material curing means, (A) ~
In an optical fiber manufacturing apparatus provided in the order of (8),
The sprayer communicates with a coating material-containing solution supply device,
An optical fiber manufacturing apparatus is provided, characterized in that the coating material-containing solution is forced out of an orifice and sprayed by the hydraulic pressure of the solution.

本発明装置は、上記噴霧塗布装置容器において光ファイ
バに対して噴霧器とは反対の位置に、付着しなかった被
覆材微粒子の回収用排気孔を設けることにより、被覆材
のリサイクル使用を可能とできる。
The apparatus of the present invention enables recycling of the coating material by providing an exhaust hole for collecting unattached particles of the coating material at a position opposite to the atomizer relative to the optical fiber in the spray applicator container. .

図面を参照して本発明を具体的に説明すると、第1図は
本発明の実施態様を示す概略図であり、光ファイバ用ガ
ラス母材(プリフォーム)■を線引炉2で加熱溶融して
光ファイバ3に線引きし、線引き炉2を出た該光ファイ
バ3を直ちに噴霧塗布容器内に導入する。噴霧塗布容器
lO内部には第2図に断面図を示すオリフィス12を有
する構造の噴霧器(エアレス・スプレーがン)4を1以
上備えており、また、該エアレス・スプレーガンは被覆
材(例えば樹脂組成物)供給加圧タンク8に連通してい
る。該樹脂組成物供給加圧タンク8てN、ガス又は空気
等により] kg/am!〜100 kg7cm’程度
に加圧した樹脂組成物溶液をライン12によりエアレス
・スプレーガン4に供給すると、液圧によりすりフィス
13から樹脂組成物微粒子14となって噴霧され、光フ
ァイバ3の外周に均一に塗布される。続いて、塗布層を
形成されたファイバを樹脂硬化炉5内に導入して塗布層
を加熱又は紫外線照射等により硬化させて被覆層とし、
巻取装置6で巻き取る。また、噴霧塗布容器10内でフ
ァイバに付着しなかった樹脂組成物を、容器下部の回収
孔7を経て収納タンク9に回収し、樹脂組成物供給・リ
サイクル・ライン11を経て樹脂組成物供給加圧タンク
8に戻し、繰り返し使用する。回収はポンプ等の排気に
よってもよい。
To explain the present invention in detail with reference to the drawings, FIG. 1 is a schematic diagram showing an embodiment of the present invention, in which a glass preform (preform) for an optical fiber is heated and melted in a drawing furnace 2. The optical fiber 3 is drawn into an optical fiber 3, and the optical fiber 3 exiting the drawing furnace 2 is immediately introduced into a spray coating container. The interior of the spray application container IO is equipped with one or more sprayers (airless spray guns) 4 having an orifice 12 whose cross-sectional view is shown in FIG. composition) is connected to the supply pressurized tank 8. The resin composition supply pressurized tank 8 is supplied with N, gas, air, etc.] kg/am! When a resin composition solution pressurized to about 100 kg 7 cm' is supplied to the airless spray gun 4 through the line 12, the resin composition fine particles 14 are sprayed from the grating 13 due to the liquid pressure and are applied to the outer periphery of the optical fiber 3. Applied evenly. Subsequently, the fiber on which the coating layer has been formed is introduced into the resin curing furnace 5, and the coating layer is cured by heating or ultraviolet irradiation to form a coating layer,
It is wound up with a winding device 6. Further, the resin composition that did not adhere to the fiber in the spray coating container 10 is collected into the storage tank 9 through the collection hole 7 at the bottom of the container, and the resin composition is supplied and added via the resin composition supply/recycle line 11. Return it to the pressure tank 8 and use it repeatedly. Recovery may be done by exhausting with a pump or the like.

本発明のエアレス・スプレーガン4のオリフィス径は5
0μm〜1mm程度であり、図では簡略化してオリフィ
ス1個が示しであるが、多数のオリフィスを有するもの
であってもよい。
The orifice diameter of the airless spray gun 4 of the present invention is 5
The diameter is approximately 0 μm to 1 mm, and although one orifice is shown for simplicity in the figure, it may have a large number of orifices.

本発明に用いられる被覆材についてはこの種の光ファイ
バ被覆に使用される材料、例えばウレタンアクリル系、
シリコン系、エポキシ系、フッ素系等の各種樹脂組成物
等を含有する液体であれば特に制限はないが、樹脂組成
物そのものでも、高粘度の樹脂組成物を溶媒に溶解して
低粘度化したもの又は分散媒中に分散したものでもよい
。樹脂組成物としては熱、紫外線、電子線等によって反
応硬化するものが好ましく、例えばウレタンアクリル系
、シリコン系、エポキシ系、フッ素系等の樹脂組成物が
挙げられる。また液圧で噴霧できるためには、オリフィ
スに供給される被覆材の粘度は500cps以下程度で
あることが好ましい。
Regarding the coating material used in the present invention, materials used for coating this type of optical fiber, such as urethane acrylic,
There is no particular restriction as long as the liquid contains various resin compositions such as silicone-based, epoxy-based, fluorine-based, etc., but even the resin composition itself can be prepared by dissolving a high-viscosity resin composition in a solvent to lower the viscosity. It may be a substance or a substance dispersed in a dispersion medium. The resin composition is preferably one that can be cured by reaction with heat, ultraviolet rays, electron beams, etc., and includes, for example, urethane-acrylic, silicone-based, epoxy-based, and fluorine-based resin compositions. Further, in order to be able to spray using hydraulic pressure, the viscosity of the coating material supplied to the orifice is preferably about 500 cps or less.

本発明において、ガラスファイバ表面に形成される被覆
層をムラがなく、均一厚みで平滑な薄膜とするためには
、 ■溶剤に溶かして粘度を500cps程麿以下に低くし
た被覆材を用いる、 ■溶液中に溶けない被覆材の微粒子を分散混合したエマ
ルジョンをオリフィスより分散させてスプレー塗装する
、 ■溶媒に溶解したり分散させたりしなくても、そのまま
で使用できる液体状の被覆材を使用する、等、種々の手
段によることができる。
In the present invention, in order to make the coating layer formed on the surface of the glass fiber a smooth thin film with no unevenness and uniform thickness, (1) use a coating material whose viscosity is lowered to about 500 cps or less by dissolving it in a solvent; (2) Spray painting by dispersing an emulsion containing fine particles of a coating material that does not dissolve in a solution through an orifice.■Use a liquid coating material that can be used as is without dissolving or dispersing it in a solvent. , etc., by various means.

[作用] 本発明によれば、線引きしたガラス光ファイバにエアレ
ス・スプレー法により被覆材微粒子を付着させて被覆光
ファイバとする。圧縮空気を用いずに被覆材の液圧のみ
で噴霧することにより、被覆材微粒子の大きさを 0.
2μm程度の均一なものにできるので、ガラスファイバ
表面に形成される被覆層はムラがなく、均一厚みで平滑
な薄膜となり、本発明者らの実験によれば 〜5μm5
μm程一な薄膜が実現できた。
[Operation] According to the present invention, coating material fine particles are attached to a drawn glass optical fiber by an airless spray method to form a coated optical fiber. By spraying only with the hydraulic pressure of the coating material without using compressed air, the size of the coating material particles can be reduced to 0.
Since it can be made into a uniform layer of about 2 μm, the coating layer formed on the surface of the glass fiber is a smooth thin film with a uniform thickness, and according to experiments by the present inventors, it is ~5 μm5.
We were able to create a thin film with a thickness of approximately μm.

また、液圧のみの噴霧であるため、従来法のような飛散
の問題はなく、付着効率も高く、塗布時間や設備コスト
も低減できる。更に、被覆材の回収・繰り返し使用も簡
単であり、この点でも製造コストの低減が可能である。
In addition, since the spray is performed using only hydraulic pressure, there is no problem of scattering as in conventional methods, and the adhesion efficiency is high, reducing coating time and equipment costs. Furthermore, recovery and repeated use of the covering material are easy, and manufacturing costs can be reduced in this respect as well.

[実施例] 以下、実施例を挙げて本発明を説明するが、本発明はこ
れに限定されるところはない。
[Example] The present invention will be described below with reference to Examples, but the present invention is not limited thereto.

実施例1 第1図に示す本発明の装置構成により被覆光ファイバを
製造した。ガラスプリフォームを200m/■inの線
速で線引きして外径125μmのガラスファイバ3とし
、噴霧塗布容器10内でスブL/−tiン4から、直径
約1μm以下のウレタンアクリレート系紫外線硬化型樹
脂組成物の微粒子を噴霧して、その後紫外線硬化炉を通
すことにより、厚さ約5μmの被覆層を有する被覆光フ
ァイバを得た。なお、被覆材の液圧は40 kg/cs
’であった。
Example 1 A coated optical fiber was manufactured using the apparatus configuration of the present invention shown in FIG. A glass preform is drawn at a linear speed of 200 m/inch to obtain a glass fiber 3 with an outer diameter of 125 μm, and a urethane acrylate ultraviolet curing type fiber having a diameter of about 1 μm or less is drawn from a sub-L/-tin 4 in a spray coating container 10. A coated optical fiber having a coating layer with a thickness of about 5 μm was obtained by spraying fine particles of the resin composition and then passing it through an ultraviolet curing oven. In addition, the hydraulic pressure of the coating material is 40 kg/cs
'Met.

得られた被覆光ファイバ30kmについて、樹脂被覆は
長手方向全長にわたり均一厚みに形成されていることが
確認できた。
Regarding the obtained coated optical fiber of 30 km, it was confirmed that the resin coating was formed to have a uniform thickness over the entire length in the longitudinal direction.

比較例1 第1図の装置において、スプレーガン4と樹脂供給加圧
タンク系に代えて従来の圧縮空気を用いるスプレー装置
を用いた以外は、実施例1と同条件として、被覆光ファ
イバを製造した。得られた被覆光ファイバ3Qkmにつ
いて調べたところ、樹脂被覆は長さ方向全長にわたり、
不均一な塗布であり、表面には凹凸が多く、局部的に樹
脂が付着していない部分も確認された。
Comparative Example 1 A coated optical fiber was manufactured under the same conditions as in Example 1, except that in the apparatus shown in FIG. 1, a conventional spray device using compressed air was used in place of the spray gun 4 and the resin supply pressurized tank system. did. When we investigated the obtained coated optical fiber 3Qkm, we found that the resin coating covers the entire length,
The coating was uneven, with many irregularities on the surface, and there were some areas where the resin did not adhere.

[発明の効果] 以上説明したように、本発明によれば線引きしたガラス
ファイバ表面にエアレス・スプレー法により大きさが均
一に安定した被覆材微粒子を付着できるため、均一厚み
で平滑な被覆をムラなく形成された被覆光ファイバを製
造できる。そして、本発明の装置は簡単な設備で、被覆
材の付着効率及び回収率よく、コスト低減して被覆光フ
ァイバを製造できる有利なものである。
[Effects of the Invention] As explained above, according to the present invention, fine particles of coating material having a uniform and stable size can be attached to the surface of a drawn glass fiber by an airless spray method, so that a smooth coating with a uniform thickness can be applied unevenly. It is possible to produce a coated optical fiber formed without the need for a coated optical fiber. The apparatus of the present invention is advantageous in that it can produce coated optical fibers with simple equipment, with good adhesion efficiency and recovery rate of the coating material, and at reduced costs.

【図面の簡単な説明】[Brief explanation of the drawing]

第1rI!Jは本発明の実施態様を示す概略図、第2図
は本発明のエアレス・スプレー装置のスプレーガン部分
を模式的に示す断面図、第3図は従来のスプレー法を示
す断面図である。 図中、1ニブリフオーム、2:線引炉、3:光ファイバ
、4:エアレス・スプレーガン、5:If脂硬化炉、6
:巻取機、7 樹脂組成物回収装置、8・##脂組成物
供給加圧タンク、9:樹脂組成物収納タンク、lO:噴
霧塗布容器、11:樹脂組成物供給・リサイクルライン
、12:加圧樹脂組成物供給ライン、13ニオリフイス
、14:41脂組成物微粒子、15:従来法の噴霧器、
を示す。
1st rI! J is a schematic diagram showing an embodiment of the present invention, FIG. 2 is a cross-sectional view schematically showing the spray gun portion of the airless spray device of the present invention, and FIG. 3 is a cross-sectional view showing a conventional spray method. In the figure, 1 nib form, 2: drawing furnace, 3: optical fiber, 4: airless spray gun, 5: If oil curing furnace, 6
: Winder, 7 Resin composition recovery device, 8/## Fat composition supply pressurized tank, 9: Resin composition storage tank, IO: Spray coating container, 11: Resin composition supply/recycle line, 12: Pressurized resin composition supply line, 13: Niorifice, 14:41 Fat composition fine particles, 15: Conventional method sprayer,
shows.

Claims (3)

【特許請求の範囲】[Claims] (1)線引きしたガラスファイバ外周に被覆材微粒子を
噴霧により付着させて被覆層を有する光ファイバを製造
する方法において、被覆材を含有する溶液を該溶液の液
圧によりオリフィスから押し出すことにより被覆材微粒
子として噴霧することを特徴とする光ファイバの製造方
法。
(1) In a method of manufacturing an optical fiber having a coating layer by spraying coating material fine particles onto the outer periphery of a drawn glass fiber, the coating material is formed by extruding a solution containing the coating material from an orifice using the liquid pressure of the solution. A method for manufacturing an optical fiber, characterized by spraying it as fine particles.
(2)(イ)線引炉、(ロ)線引きガラスファイバ通過
用貫通孔を有する噴霧塗布装置容器と、該容器内におい
て通過ガラスファイバの外周に設けた1以上の噴霧器と
を有してなる噴霧塗布装置、(ハ)被覆材硬化手段、を
(イ)〜(ハ)の順に設けてなる光ファイバ製造装置に
おいて、上記噴霧器が被覆材含有溶液供給装置に連通し
ており、当該被覆材含有溶液の液圧により該溶液をオリ
フィスから押し出し噴霧するものであることを特徴とす
る光ファイバ製造装置。
(2) (a) a drawing furnace; (b) a spray applicator container having a through hole for passing the drawn glass fiber; and one or more sprayers provided in the container around the outer periphery of the passing glass fiber. In an optical fiber manufacturing apparatus comprising a spray coating device and (c) a coating material curing means in the order of (a) to (c), the sprayer communicates with a coating material-containing solution supply device, and the coating material-containing solution supply device An optical fiber manufacturing apparatus characterized in that the solution is forced out of an orifice and sprayed by the hydraulic pressure of the solution.
(3)上記噴霧塗布装置容器が光ファイバに対して噴霧
器とは反対の位置に、付着しなかった被覆材微粒子の回
収用排気孔を有することを特徴とする請求項(2)に記
載の光ファイバ製造装置。
(3) The optical fiber according to claim (2), wherein the spray coating device container has an exhaust hole for collecting coating material fine particles that have not adhered to the optical fiber at a position opposite to the sprayer. Fiber manufacturing equipment.
JP2257127A 1990-09-28 1990-09-28 Method and device for producing optical fiber Pending JPH04139038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2257127A JPH04139038A (en) 1990-09-28 1990-09-28 Method and device for producing optical fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2257127A JPH04139038A (en) 1990-09-28 1990-09-28 Method and device for producing optical fiber

Publications (1)

Publication Number Publication Date
JPH04139038A true JPH04139038A (en) 1992-05-13

Family

ID=17302106

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2257127A Pending JPH04139038A (en) 1990-09-28 1990-09-28 Method and device for producing optical fiber

Country Status (1)

Country Link
JP (1) JPH04139038A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2767724A1 (en) * 1997-09-01 1999-03-05 France Telecom METHOD AND DEVICE FOR COATING A WIRED ELEMENT WITH A THIN LAYER OF LIQUID AND OPTICAL FIBER AGENT THUS COATED
JP2006171288A (en) * 2004-12-15 2006-06-29 Ricoh Co Ltd Development device, process cartridge and image forming apparatus

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2767724A1 (en) * 1997-09-01 1999-03-05 France Telecom METHOD AND DEVICE FOR COATING A WIRED ELEMENT WITH A THIN LAYER OF LIQUID AND OPTICAL FIBER AGENT THUS COATED
WO1999011391A1 (en) * 1997-09-01 1999-03-11 France Telecom Method and device for coating a wireframe element with a fine liquid agent deposit and coated optical fibre
US6258404B1 (en) 1997-09-01 2001-07-10 France Telecom Method and device for coating a wireframe element with a fine liquid deposit and coated optical fiber
JP2006171288A (en) * 2004-12-15 2006-06-29 Ricoh Co Ltd Development device, process cartridge and image forming apparatus
JP4587801B2 (en) * 2004-12-15 2010-11-24 株式会社リコー Developing device, process cartridge, and image forming apparatus

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