JPH0413434A - Isothermal forging method and lubricating sheet for isothermal forging - Google Patents
Isothermal forging method and lubricating sheet for isothermal forgingInfo
- Publication number
- JPH0413434A JPH0413434A JP2113118A JP11311890A JPH0413434A JP H0413434 A JPH0413434 A JP H0413434A JP 2113118 A JP2113118 A JP 2113118A JP 11311890 A JP11311890 A JP 11311890A JP H0413434 A JPH0413434 A JP H0413434A
- Authority
- JP
- Japan
- Prior art keywords
- lubricant
- isothermal forging
- forging
- workpiece
- die
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010275 isothermal forging Methods 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims description 23
- 230000001050 lubricating effect Effects 0.000 title claims description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 45
- 239000011888 foil Substances 0.000 claims abstract description 43
- 239000004327 boric acid Substances 0.000 claims abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 38
- 238000005242 forging Methods 0.000 claims description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 abstract description 12
- 238000010438 heat treatment Methods 0.000 abstract description 5
- -1 boric acid compound Chemical class 0.000 abstract 1
- 238000009792 diffusion process Methods 0.000 description 7
- 239000005368 silicate glass Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 239000006082 mold release agent Substances 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
- B21K29/00—Arrangements for heating or cooling during processing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Forging (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、従来よりも低い鍛造力で成形することので
きる恒温鍛造法およびその恒温鍛造法で用いる潤滑シー
トに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a constant temperature forging method that allows forming with a lower forging force than conventional methods, and a lubricating sheet used in the constant temperature forging method.
一般に、Ti基合金、Ni基合金等の難加工材を成形す
る方法として金型を被加工材と等温に保持して鍛造する
恒温鍛造法があることは良く知られているところである
。この恒温鍛造法は予備成形から最終成形まで同じ金型
で一工程で成形することかできる可能性かあるところか
ら盛んに研究がなされているか、金型の温度を難加工性
被加工材と同等の温度に保持して高温で鍛造するために
、金型にとっては非常に苛酷な条件での使用となり、か
かる苛酷な条件て使用てきる金型の価格は非常に高価な
ものであるにもかかわらず使用寿命が短いので恒温鍛造
製品は一般に高価なものとなり、特殊な部品の製造にの
み使用されている。Generally, it is well known that as a method for forming difficult-to-process materials such as Ti-based alloys and Ni-based alloys, there is an isothermal forging method in which a die is held at the same temperature as the workpiece. This isothermal forging method has been actively researched because it has the possibility of forming everything from preforming to final forming in the same mold in one step. The molds are used under very harsh conditions because they are held at a temperature of Because of their short service life, isothermal forged products are generally expensive and are only used to make special parts.
さらに、上記恒温鍛造は高温で低ひずみ速度で鍛造され
るために(例えば、Ni基超塑性合金を被加工材として
恒温鍛造するには、1000℃以上の温度でIQ’s−
’程度の低ひずみ速度で鍛造する)、被加工材と金型と
の間に拡散接合が極めて起こりやすく、かかる拡散接合
が起こると恒温鍛造力の大幅な増加をもたらし、好まし
くない。Furthermore, since the above-mentioned isothermal forging is forged at a high temperature and a low strain rate (for example, in order to isothermal forge a Ni-based superplastic alloy as a workpiece material, IQ's -
When forging is carried out at a low strain rate of about 100 lbs.), diffusion bonding is extremely likely to occur between the workpiece and the die, and when such diffusion bonding occurs, it results in a significant increase in isothermal forging force, which is undesirable.
かかる拡散接合の発生を防止するために、従来から金型
と被加工材の間にケイ酸ガラスなどの潤滑剤を介在させ
て鍛造しているが、特に高温高圧下に比較的長時間保持
される恒温鍛造下においては、上記公知のケイ酸ガラス
などの潤滑剤では潤滑剤切れによる拡散接合か起こりや
すいという問題点があった。In order to prevent the occurrence of such diffusion bonding, a lubricant such as silicate glass has traditionally been interposed between the die and the workpiece during forging, but this is especially true when the material is held at high temperature and pressure for a relatively long period of time. Under constant-temperature forging, there is a problem in that diffusion bonding is likely to occur due to the lubricant running out when using a lubricant such as the above-mentioned known silicate glass.
また、上記拡散接合が防止されても、被加工材と金型の
せん断摩擦係数か恒温鍛造圧力に大きな影響を与えるこ
とが知られており、恒温鍛造力の増加を防止するために
」二記せん断摩擦係数を小さくする必要があるが、従来
のケイ酸ガラスなどを潤滑剤として用いる程度では十分
な効果が得られていない。In addition, even if the diffusion bonding described above is prevented, it is known that the shear friction coefficient between the workpiece and the die has a large effect on the isothermal forging pressure. It is necessary to reduce the coefficient of shear friction, but the use of conventional silicate glass or the like as a lubricant does not provide sufficient effects.
そこで、本発明者等は、かかる問題点を解決すべく研究
を行った結果、
被加工材と金型の間に、ケイ酸ガラスなどの潤滑剤とと
もに金属箔を介在させて恒温鍛造すると、従来よりも被
加工材と金型とが拡散接合することが少なく、かつせん
断摩擦係数も小さくなるために従来よりも低い恒温鍛造
力で鍛造することができるという知見を得たのである。Therefore, the present inventors conducted research to solve these problems, and found that isothermal forging with a metal foil interposed between the workpiece and the mold together with a lubricant such as silicate glass has improved the conventional method. They found that there is less diffusion bonding between the workpiece and the die, and the shear friction coefficient is also smaller, making it possible to forge with a lower isothermal forging force than in the past.
この発明は、かかる知見にもとづいてなされたものであ
って、
被加工材を金型に装入して恒温鍛造する方法において、
上記液加り材と金型との間に、潤滑剤とともに金属箔を
介在せしめる恒温鍛造法に特徴を有するものである。This invention was made based on this knowledge, and includes a method for isothermal forging by charging a workpiece into a mold,
This method is characterized by a constant temperature forging method in which metal foil is interposed along with a lubricant between the liquid-added material and the mold.
上記被加工材と金型との間に潤滑剤とともに介在する金
属箔の枚数は、通常一枚であるか二枚以りであってもよ
く、二枚以上の場合は、金属箔と金属箔の間に粘性の低
いホウ酸系ガラスの潤滑剤を介在させることか一層好ま
しい。金属箔としては、Ti 、A、Q、Feおよびそ
の合金からなり、被加工材と同等またはそれ以下の強度
を有する金属箔がよく、温度、使用条件により選択する
必要かあり、その厚さは10〜100μmが好ましい。The number of metal foils interposed between the workpiece and the mold together with the lubricant is usually one or two or more, and in the case of two or more, the metal foil and the metal foil are It is more preferable to interpose a low viscosity boric acid glass lubricant between the two. Metal foils are preferably made of Ti, A, Q, Fe, and their alloys, and have a strength equal to or lower than that of the workpiece, and should be selected depending on the temperature and usage conditions. 10 to 100 μm is preferable.
被加工材と金型の間に潤滑剤および金属箔を介在させる
には、あらかじめ潤滑剤を両面に均一に塗布した金属箔
を鍛造用潤滑シートとして用意しておき、鍛造時にその
鍛造用潤滑シートを取出して被加工材と金属箔との間に
介在させて恒温鍛造すると鍛造作業か容易になり、スプ
レーで潤滑剤を塗布する手間も省けるので作業能率も一
層向上する。To interpose a lubricant and metal foil between the workpiece and the die, prepare a metal foil with lubricant uniformly applied on both sides as a forging lubricant sheet, and use the forging lubricant sheet during forging. By taking out the metal foil and interposing it between the workpiece and the metal foil and forging at a constant temperature, the forging process becomes easier, and the work efficiency is further improved because it eliminates the need to apply lubricant by spraying.
二の発明を第1図および第2図を用いて、さらに具体的
に説明する。The second invention will be explained in more detail using FIGS. 1 and 2.
第1図および第2図は、この発明の側面説明図であり、
1は金型、2は離型剤、3は被加工材、4は潤滑剤、5
は金属箔、6はホウ酸系ガラス潤滑剤、7は高周波加熱
コイルである。FIG. 1 and FIG. 2 are side explanatory views of the present invention,
1 is a mold, 2 is a mold release agent, 3 is a workpiece material, 4 is a lubricant, 5
6 is a metal foil, 6 is a boric acid glass lubricant, and 7 is a high frequency heating coil.
第1図に示されるように、この発明では、離型剤2を塗
布l−た金型1と被加工材3の間に、両面に潤滑剤4を
塗布した金属箔5を介在させて恒温鍛造する。まt:、
第2図に示されるように、金属箔5を二枚使用する場合
には、二枚の金属箔55の間にホウ酸系ガラス潤滑剤6
を介在させると一層よい結果が得られる。As shown in FIG. 1, in this invention, a metal foil 5 coated with a lubricant 4 on both sides is interposed between a mold 1 coated with a mold release agent 2 and a workpiece 3 to keep the temperature constant. Forge. Mat:,
As shown in FIG. 2, when two metal foils 5 are used, a boric acid glass lubricant 6 is applied between the two metal foils 55.
Better results can be obtained by intervening.
潤滑剤4は、離型剤2を塗布した金型1の表面にスプレ
ー等で塗布してもよいか、不均一な塗布がなされて型抜
き性が悪くなることがあるので、あらかしめ潤滑剤4を
金属箔5の両面に塗布した鍛造用潤滑シートを作製して
巻取っておき、使用時に必要量巻戻して切り出し、金型
1に敷いて使用する方かよい。The lubricant 4 may be applied by spraying or the like to the surface of the mold 1 coated with the mold release agent 2, or the lubricant 4 may be applied with a pre-coated lubricant to avoid uneven application and poor mold removal properties. It is preferable to prepare a lubricating sheet for forging by coating 4 on both sides of metal foil 5, roll it up, unwind it by the required amount at the time of use, cut it out, and spread it on the mold 1 for use.
上記第1図および第2図に示されるようにセットされた
被加工材は、高周波加熱コイル7によって加熱され恒温
鍛造される。The workpiece set as shown in FIGS. 1 and 2 above is heated by the high-frequency heating coil 7 and subjected to isothermal forging.
つぎに、この発明を実施例にもとづいて詳細に説明する
。Next, the present invention will be explained in detail based on examples.
実施例]−4および従来例1
被加工材として、外径=12■、内径:6rnrs、高
さ:4mmの寸法を有し、リング面の表面粗さ:10即
Rを有するチタン合金(Ti −6%Agax
4%V)製リング、
金属箔として、厚さ=30虜の純Ti箔、離型剤として
、BN、
潤滑剤として、ケイ酸ガラス、
ホウ酸系ガラス潤滑剤として、B2O3,98%B2O
3−29ciB 1203.98%B 20 a 2
%PbO1
をそれぞれ用意し、これらを第1図および第2図に示す
ように、表面粗さ:]0囮Rの二・ノケmaχ
ル合金(I N +00)製金型の間にセットし、上記
被加工材であるリングを900°Cに加熱恒温保持し、
歪速度 I X 10’/ sで圧縮し、せん断摩擦係
数値を求めて、それらの値を第1表に示した。Example]-4 and Conventional Example 1 The workpiece was a titanium alloy (Ti -6%Agax 4%V) ring, as a metal foil, pure Ti foil with a thickness of 30 mm, as a mold release agent, BN, as a lubricant, silicate glass, as a boric acid glass lubricant, B2O3, 98% B2O
3-29ciB 1203.98%B 20 a 2
%PbO1, and as shown in FIGS. 1 and 2, these were set between molds made of a two-dimensional alloy (IN +00) with a surface roughness of 0 decoy R. The ring, which is the workpiece material mentioned above, is heated and kept at a constant temperature of 900°C.
It was compressed at a strain rate of I x 10'/s, and the shear friction coefficient values were determined, and these values are shown in Table 1.
一方、従来例〕として、第3図に示されるように、ケイ
酸ガラス潤滑剤4をBNM型剤2が塗布されている金型
1の上に塗布し、被加工材3をBN離型剤2およびケイ
酸ガラス潤滑剤4の塗布された金型1.1の間に置き、
金属箔を用いることなく、ケイ酸ガラスのみを潤滑剤と
して用い、全く同様にして圧縮してせん断摩擦係数値を
求めて、それらの値を第1表に示した。On the other hand, as a conventional example], as shown in FIG. 2 and a mold 1.1 coated with silicate glass lubricant 4,
Using only silicate glass as a lubricant without using metal foil, the samples were compressed in exactly the same manner to determine the shear friction coefficient values, and the values are shown in Table 1.
実施例5〜8および従来例2
直径:200mm、高さ: 20+n+eの寸法を有し
、実施例1〜4および従来例1て用いた合金と同一の組
成のチタン合金(Ti −6%A、Q−4%V)製置板
を用意し、この円板を第2表に示される潤滑剤を用いて
第1図〜第3図のいずれかの方法でセットし、上記実施
例1〜4および従来例1と同一条件(炉温加熱温度・9
00℃、歪速度、1刈0’/ s )で宴さ:l0mm
になるまで圧縮して実施例5〜8および従来例2の恒温
鍛造を実施し、この時圧縮に要する恒温鍛造力を測定し
、その結果を第2表に示した。Examples 5 to 8 and Conventional Example 2 A titanium alloy (Ti-6%A, Q-4%V) A preparation plate was prepared, and this disk was set using the lubricant shown in Table 2 by any of the methods shown in FIGS. and the same conditions as conventional example 1 (furnace temperature heating temperature 9
00℃, strain rate, 1 cut 0'/s): 10mm
The isothermal forging of Examples 5 to 8 and Conventional Example 2 was carried out by compressing the specimens until the temperature was 2. The isothermal forging force required for compression was measured, and the results are shown in Table 2.
第1表および第2表の結果から、この発明の恒温鍛造法
によると、従来よりもせん断摩擦係数が小さく、かつ恒
温鍛造力を小さくすることができ、さらに金属箔を一枚
用いる場合よりも、金属箔を二枚用いる方が一層せん断
摩擦係数および恒温鍛造力を小さくすることができるこ
ともわかる。From the results in Tables 1 and 2, it is clear that according to the isothermal forging method of the present invention, the shear friction coefficient is smaller than that of the conventional method, and the isothermal forging force can be reduced, and furthermore, it is better than when using a single sheet of metal foil. It can also be seen that the shear friction coefficient and constant temperature forging force can be further reduced by using two metal foils.
なお、この実施例では、単純な圧縮加工を伴う恒温鍛造
について述べているが、この発明の恒温鍛造法は、これ
に限定されるものではなく、押出例えば静水圧押出に準
する押出加工などにも適用することができるものである
。Although this example describes isothermal forging accompanied by simple compression processing, the isothermal forging method of the present invention is not limited to this, and can be applied to extrusion processing, for example, extrusion processing similar to isostatic pressure extrusion. can also be applied.
この発明の請求項1および2に係わる恒温鍛造法では、
潤滑剤とともに被加工材と金型の間にこれらより表面の
滑らかな金属箔を挿入することにより、流体潤滑の寄与
か大きくなり、被加工材と金属箔、金型と金属箔の金属
接触面積か減少するのでせん断摩擦係数か減少し、さら
に金属箔自体か柔軟性を有する場合においては固体潤滑
剤として作用するので被加工材と金型の摩擦抵抗を大幅
に低減することかできる。In the constant temperature forging method according to claims 1 and 2 of this invention,
By inserting a metal foil with a smoother surface than these between the workpiece and the mold together with a lubricant, the contribution of fluid lubrication increases, and the metal contact area between the workpiece and the metal foil, and the mold and the metal foil. This decreases the shear friction coefficient, and if the metal foil itself is flexible, it acts as a solid lubricant, which can significantly reduce the frictional resistance between the workpiece and the mold.
また、この発明の請求項3に係る恒温鍛造法では、被加
工材と金型の間に潤滑剤とともに複数の金属箔を挿入し
、この金属箔の間にホウ酸系ガラスの潤滑剤を配するこ
とにより流体潤滑の寄与か大きくなり、せん断摩擦係数
がさらに減少するとともに、これら金属箔同士が擬似的
な平行面を形成し、その間の潤滑剤層かより完全な流体
潤滑条件に近ずくために摩擦抵抗を大きく低減すること
ができる。Further, in the constant temperature forging method according to claim 3 of the present invention, a plurality of metal foils are inserted together with a lubricant between the workpiece and the mold, and a boric acid glass lubricant is arranged between the metal foils. By doing so, the contribution of fluid lubrication increases, the shear friction coefficient further decreases, and these metal foils form pseudo-parallel surfaces, and the lubricant layer between them approaches perfect fluid lubrication conditions. Frictional resistance can be greatly reduced.
さらに、この発明の請求項4および5に係る潤滑シート
では、上記この発明の効果を与えるものを簡便に提供す
ることかでき、また使用が容易になる。Furthermore, the lubricating sheets according to claims 4 and 5 of the present invention can easily provide the effects of the present invention and are easy to use.
かかる作用を有するこの発明の恒温鍛造方法を用いると
、
上記被加工材と金型との間に拡散接合を生ずることなく
せん断摩擦係数を小さくすることができるので恒温鍛造
圧力を大幅に小さくすることかでき、したがって金型へ
の負荷を低減して金型寿命を延長することが可能となり
、さらに型抜性も向上させることができるので恒温鍛造
コストを従来よりも大幅に減少させることができるなど
産業上すぐれた効果をもたらすものである。When the isothermal forging method of the present invention having such an effect is used, the shear friction coefficient can be reduced without causing diffusion bonding between the workpiece and the die, so the isothermal forging pressure can be significantly reduced. Therefore, it is possible to reduce the load on the die and extend the life of the die, and it also improves the ease of removing the die, which makes it possible to significantly reduce isothermal forging costs compared to conventional methods. It brings about excellent industrial effects.
第1図および第2図は、この発明の恒温鍛造法を示す側
面説明図、
第3図は、従来の恒温鍛造法を示す側面説明図である。
1・・・金 型、 2・・・離型剤、3・・
・被加工材、 4・・潤滑剤、5・・・金属箔
、
6・・・ホウ酸系ガラス潤滑剤、
7・・高周波加熱コイル。1 and 2 are side explanatory views showing the isothermal forging method of the present invention, and FIG. 3 is a side explanatory view showing the conventional isothermal forging method. 1... Mold, 2... Mold release agent, 3...
- Workpiece material, 4... Lubricant, 5... Metal foil, 6... Boric acid glass lubricant, 7... High frequency heating coil.
Claims (5)
工材と恒温鍛造用金型の間に潤滑剤とともに金属箔を存
在せしめることを特徴とする恒温鍛造法。(1) A method for isothermal forging a workpiece, characterized in that a metal foil is present together with a lubricant between the workpiece and a die for isothermal forging.
金属箔の両面に潤滑剤を存在せしめることを特徴とする
請求項1記載の恒温鍛造法。(2) The constant-temperature forging method according to claim 1, characterized in that, when a sheet of metal foil is made to exist, a lubricant is made to be present on both sides of the sheet of metal foil.
と恒温鍛造用金型の間に潤滑剤とともに金属箔を二枚以
上介在せしめ、さらに上記金属箔と金属箔の間にはホウ
酸系ガラスを潤滑剤として介在せしめることを特徴とす
る恒温鍛造法。(3) In a method for isothermal forging a workpiece, two or more metal foils are interposed with a lubricant between the workpiece and the isothermal forging die, and boric acid is added between the metal foils. A constant temperature forging method characterized by the use of glass as a lubricant.
とする恒温鍛造用潤滑シート。(4) A lubricating sheet for constant temperature forging, characterized in that it is made by applying a lubricant to both sides of metal foil.
属箔の間にはホウ酸系ガラス潤滑剤が介在し、上記二枚
以上の金属箔のうち最外層の金属箔の外面には通常の潤
滑剤が塗布されていることを特徴とする恒温鍛造用潤滑
シート。(5) Consists of two or more metal foils and a lubricant, with a boric acid glass lubricant interposed between the two or more metal foils, and the outer surface of the outermost metal foil of the two or more metal foils. A lubricating sheet for constant temperature forging, which is characterized by having a regular lubricant applied to it.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2113118A JP2725438B2 (en) | 1990-05-07 | 1990-05-07 | Constant temperature forging method and lubricating sheet for constant temperature forging |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2113118A JP2725438B2 (en) | 1990-05-07 | 1990-05-07 | Constant temperature forging method and lubricating sheet for constant temperature forging |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0413434A true JPH0413434A (en) | 1992-01-17 |
JP2725438B2 JP2725438B2 (en) | 1998-03-11 |
Family
ID=14603974
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2113118A Expired - Lifetime JP2725438B2 (en) | 1990-05-07 | 1990-05-07 | Constant temperature forging method and lubricating sheet for constant temperature forging |
Country Status (1)
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JP (1) | JP2725438B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6372117B1 (en) | 1999-12-22 | 2002-04-16 | Nippon Macdermid Co., Ltd. | Bright tin-copper alloy electroplating solution |
JP2013530047A (en) * | 2010-06-14 | 2013-07-25 | エイティーアイ・プロパティーズ・インコーポレーテッド | Lubrication method for improved forgeability |
US9533346B2 (en) | 2010-02-05 | 2017-01-03 | Ati Properties Llc | Systems and methods for forming and processing alloy ingots |
US11059088B2 (en) | 2010-02-05 | 2021-07-13 | Ati Properties Llc | Systems and methods for processing alloy ingots |
-
1990
- 1990-05-07 JP JP2113118A patent/JP2725438B2/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6372117B1 (en) | 1999-12-22 | 2002-04-16 | Nippon Macdermid Co., Ltd. | Bright tin-copper alloy electroplating solution |
US9533346B2 (en) | 2010-02-05 | 2017-01-03 | Ati Properties Llc | Systems and methods for forming and processing alloy ingots |
US11059088B2 (en) | 2010-02-05 | 2021-07-13 | Ati Properties Llc | Systems and methods for processing alloy ingots |
US11059089B2 (en) | 2010-02-05 | 2021-07-13 | Ati Properties Llc | Systems and methods for processing alloy ingots |
JP2013530047A (en) * | 2010-06-14 | 2013-07-25 | エイティーアイ・プロパティーズ・インコーポレーテッド | Lubrication method for improved forgeability |
US10207312B2 (en) | 2010-06-14 | 2019-02-19 | Ati Properties Llc | Lubrication processes for enhanced forgeability |
Also Published As
Publication number | Publication date |
---|---|
JP2725438B2 (en) | 1998-03-11 |
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