JPH04129551A - Glasses having water absorptive porous body - Google Patents
Glasses having water absorptive porous bodyInfo
- Publication number
- JPH04129551A JPH04129551A JP24879090A JP24879090A JPH04129551A JP H04129551 A JPH04129551 A JP H04129551A JP 24879090 A JP24879090 A JP 24879090A JP 24879090 A JP24879090 A JP 24879090A JP H04129551 A JPH04129551 A JP H04129551A
- Authority
- JP
- Japan
- Prior art keywords
- porous body
- water
- glasses
- air holes
- dry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 16
- 239000011521 glass Substances 0.000 title abstract description 5
- 239000011148 porous material Substances 0.000 claims description 18
- 230000003287 optical effect Effects 0.000 claims description 4
- 208000003556 Dry Eye Syndromes Diseases 0.000 abstract description 8
- 206010013774 Dry eye Diseases 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 6
- 208000024891 symptom Diseases 0.000 abstract description 4
- 238000001704 evaporation Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 2
- 229920002554 vinyl polymer Polymers 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract 1
- 230000002093 peripheral effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000607 artificial tear Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000005336 safety glass Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 206010010741 Conjunctivitis Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006059 cover glass Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 210000000744 eyelid Anatomy 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 206010023332 keratitis Diseases 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000004488 tear evaporation Effects 0.000 description 1
- 230000004489 tear production Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Materials For Medical Uses (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、目かねに関する。さらに詳しくは、ドライア
イ(涙液減少症)患者の不快感を軽減させる機能を有す
る目かねに関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to eyelids. More specifically, the present invention relates to an eye mask that has the function of alleviating the discomfort of patients with dry eyes (lacrimalia).
人間の日常生活において涙の役割は重要である。 Tears play an important role in human daily life.
目の乾燥を防ぎ、目に入ったゴミ等の異物を洗い流すほ
か、殺菌作用も持っており、涙が減るとこれらの働きが
低下して角膜炎や結膜炎等の病気にかかりやすくなるこ
とは周知の事実である。In addition to preventing dryness of the eyes and washing away foreign substances such as dust that have entered the eyes, it also has a bactericidal effect, and it is well known that when tear production decreases, these functions decrease, making you more susceptible to diseases such as keratitis and conjunctivitis. This is a fact.
また、近年の傾向として、テレビ画面を長時間見つめる
コンピューター作業従事者にドライアイ患者が増えてい
るとも言われている。It is also said that, as a recent trend, the number of dry eye patients is increasing among computer workers who stare at television screens for long periods of time.
この様なドライアイ患者に対しては、従来より、人工涙
液の添加が行われていたが、いかに人工涙液の組成を変
えても軽症の患者以外には効果が乏しい。そこで、患者
の少ない涙をいかに有効に活用するかが重要であるとの
観点から涙道閉鎖を行なう方法があり、この方法には、
手術による方法、プラグやロッドをそう人する方法等が
考案されているが、苦痛を伴う、涙点拡大等の副作用を
伴う、効果が継続しない、高い頻度で医師の手をわずら
れせる等何らかの欠点を伴なうものである。また、涙液
蒸散防止を目的として水泳用間がねを装用する方法があ
り、簡単で、かつある程度の効果は期待できるものの充
分満足できるものではない。Conventionally, artificial tears have been added to such dry eye patients, but no matter how much the composition of the artificial tears is changed, the effects are poor for patients other than those with mild symptoms. Therefore, there is a method of closing the lacrimal duct from the perspective of how effectively the patient's tears can be used.
Surgical methods and methods of inserting plugs or rods have been devised, but these methods are painful, have side effects such as enlarged lacrimal puncta, do not continue to be effective, and require the intervention of doctors frequently. It comes with some drawbacks. There is also a method of wearing swimming glasses for the purpose of preventing tear evaporation, which is simple and can be expected to be effective to some extent, but is not fully satisfactory.
本発明は、上述の課題を解決し、ドライアイ患者の不快
感、症状を軽減させるべき機能を有する目がねを提供す
ることを目的とする。An object of the present invention is to solve the above-mentioned problems and provide an eyeglass having a function to alleviate the discomfort and symptoms of dry eye patients.
本発明者等はこの様な課題を解決するために鋭意検討の
結果、目かねの非光学部品の内側の一部又は全てを連続
気孔を有する吸水性多孔質体で構成させ、その吸水性多
孔質体を吸水させた状態にして装用することによりドラ
イアイ患者の不快感、症状を軽減させうる効果があるこ
とを見出し本発明に至った。In order to solve these problems, the inventors of the present invention have made extensive studies and found that a part or all of the inside of the non-optical parts of the eye can be made of a water-absorbing porous material having continuous pores. The present invention was based on the discovery that wearing the material after it absorbs water has the effect of alleviating the discomfort and symptoms of dry eye patients.
すなわち、本発明は目がねの非光学部品において、該部
品の少なくとも内側の、一部又は全部が、連続気孔を有
する吸水性多孔質体によって構成されることを特徴とす
る吸水性多孔質体付き目がねである。That is, the present invention provides a water-absorbing porous body for non-optical parts for eyeglasses, characterized in that at least part or all of the inside of the part is constituted by a water-absorbing porous body having continuous pores. It has a side effect.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
まず本発明で言う目かねには、通常の視力補正層目がね
以外に、安全目がね、サイドカバー何口がね、サングラ
ス、ゴーグル、水泳用目がね、おおい何回がね等あらゆ
る目がわが含まれる。First of all, the eyewear referred to in the present invention includes, in addition to normal vision correction layer glasses, safety glasses, side cover glasses, sunglasses, goggles, swimming glasses, canopies, etc. Eyes include me.
本発明において、目がねの非光学的部品とは、そのつる
、フレーム又はサイドカバー等であり、これらの少なく
とも内側の、一部又は全部が連続気孔を有する吸水性多
孔質体で構成される。In the present invention, the non-optical parts of the eyeglass are its temples, frames, side covers, etc., and at least the inner parts thereof are partially or entirely made of a water-absorbing porous material having continuous pores. .
すなわち、これら部品の1部又は全部が吸水性多孔質体
のみで構成されていてもよく、またこれら部品の内側の
、1部又は全部が吸水性多孔質体で構成されてもよい。That is, a part or all of these parts may be composed only of a water-absorbing porous material, or a part or all of the inside of these parts may be composed of a water-absorbing porous material.
さらにこのつる、フレーム、サイドカバー等の部位の内
側に接着剤やネジ等で連続気孔を有する吸水性多孔質体
を添着させてもよい。Further, a water-absorbing porous material having continuous pores may be attached to the inside of the temple, frame, side cover, etc., using an adhesive, screws, or the like.
本発明における連続気孔を有する吸水性多孔質体とは、
親水化処理したポリマーの粉末を焼結成形したもの、強
化繊維と硬化したバインダーを複合化させた多孔性複合
シート、ポリビニルホルマールの立体的樹枝網目状連続
組織体等で例示されるような連続気孔を有する多孔質体
である。The water-absorbing porous material having continuous pores in the present invention is
Continuous pores, such as those sintered from hydrophilized polymer powder, porous composite sheets made by combining reinforcing fibers and hardened binders, and three-dimensional dendritic network continuous structures of polyvinyl formal. It is a porous body with
この様な多孔質体の気孔率(%)は10%以上のものが
好ましく、さらに好ましくは30%以上である。気孔率
が小さいと吸水量が少なく、目がねとした場合吸水させ
る頻度が高くなってしまう。The porosity (%) of such a porous body is preferably 10% or more, more preferably 30% or more. If the porosity is small, the amount of water absorbed will be small, and if your eyes become wet, you will have to absorb water more frequently.
逆に、気孔率が95%を上回ると、形状保持性が充分で
ない、もろくなる等の問題が生ずる。On the other hand, if the porosity exceeds 95%, problems such as insufficient shape retention and brittleness will occur.
なお、本発明において気孔率は以下の様に定義される。Note that in the present invention, porosity is defined as follows.
気孔率(%)=(ρ。−ρ1)/ρ。×100ρ、=W
/V
ただし、上式において
ρ0− 原料の密度(g/c/)
ρ、 −多孔質体の見掛は密度(g/cnf)W −多
孔質体の重量(g)
■ = 多孔質体の体積(cnr)である。Porosity (%) = (ρ.-ρ1)/ρ. ×100ρ,=W
/V However, in the above formula, ρ0 - density of raw material (g/c/) ρ, - apparent density of porous body (g/cnf) W - weight of porous body (g) ■ = of porous body volume (cnr).
前記した連続気孔を有する吸水性多孔質体の中では、形
状保持性、形状付与性、の観点から、親水化処理したポ
リマーの焼結成形品が、好ましい。Among the water-absorbing porous bodies having continuous pores described above, sintered molded articles of polymers that have been subjected to hydrophilic treatment are preferred from the viewpoint of shape retention and shape imparting properties.
その場合、ポリマーとしては、ポリエチレン、ポリプロ
ピレン、エチレン・ブテン−1共重合体、エチレン・4
−メチルペンテン−1共重合体、エチレン・酢酸ビニル
共重合体等のポリオレフィン、ポリスチレン、アクリロ
ニトリル・スチレン共重合体、アクリロニトリル・ブタ
ジェン・スチレン共重合体、ポリカーボネート、ポリメ
チルメタアクリレート、ポリアミド、ポリエステル、ポ
リフェニレンオキサイド、ポリアクリロニトリル、ポリ
塩化ビニル、ポリ塩化ビニリデン及びこれらのアロイ化
物などを用いることが出来るが、なかでも、耐薬品性に
優れ、吸水による寸法変化を起こさないこと、吸水によ
る強度低下を起こさないこと、多量を安価に安定的に入
手可能なこと、焼結成形体として充分に強度を有するこ
と等よりポリオレフエン樹脂が好ましく用いられる。In that case, the polymers include polyethylene, polypropylene, ethylene/butene-1 copolymer, ethylene/4-butene copolymer,
-Methylpentene-1 copolymer, polyolefin such as ethylene/vinyl acetate copolymer, polystyrene, acrylonitrile/styrene copolymer, acrylonitrile/butadiene/styrene copolymer, polycarbonate, polymethyl methacrylate, polyamide, polyester, polyphenylene Oxide, polyacrylonitrile, polyvinyl chloride, polyvinylidene chloride, and their alloys can be used, but among them, it has excellent chemical resistance, does not cause dimensional changes due to water absorption, and does not cause strength loss due to water absorption. Polyolefin resins are preferably used because they can be stably obtained in large quantities at low cost, and have sufficient strength as sintered bodies.
また、これらのポリマーを、親水化するには、特開昭5
7−167330号公報に例示されるようなスルフォン
化による方法、特開昭63−061981号公報に例示
されるような特定の界面活性剤を配合する方法、表面に
親水性のモノマーをグラフトする方法、表面に親水性の
層を設ける方法等の種々の公知の親水化方法が挙げられ
る。In addition, in order to make these polymers hydrophilic, Japanese Patent Application Laid-open No. 5
A method by sulfonation as exemplified in JP 7-167330, a method of blending a specific surfactant as exemplified in JP-A-63-061981, a method of grafting a hydrophilic monomer onto the surface. Various known methods for making the material hydrophilic include methods such as providing a hydrophilic layer on the surface.
ポリマーの親水化は、焼結成形前の粉末の状態で行なっ
てもよいが、焼結成形した後に行なうことも可能である
。Hydrophilicization of the polymer may be carried out in the powder state before sintering, but it can also be carried out after sintering.
また、親水性、水分蒸散性を損なわない限り、連続気孔
を有する吸水性多孔質体に、着色剤、香料、熱安定剤、
紫外線吸収剤、防カビ剤等の添加剤を添加することが可
能である。In addition, colorants, fragrances, heat stabilizers,
Additives such as ultraviolet absorbers and antifungal agents can be added.
次に、実施例により本発明を具体的に説明するが、本発
明はこれらの例によってなんら限定されるものではない
。Next, the present invention will be specifically explained with reference to examples, but the present invention is not limited to these examples in any way.
なお、吸水率(%)は、次のようにして測定される。Note that the water absorption rate (%) is measured as follows.
まず、焼結成形品の乾燥重量WI(g)を測定する。First, the dry weight WI (g) of the sintered product is measured.
次に、シートを永に十分に浸漬した後、水中から引き上
げて雫を切り、濡れた状態における重量W2(g)を測
定し、次の式から算出する。Next, after soaking the sheet sufficiently for a long time, it is taken out of the water and dripped, and the weight W2 (g) in the wet state is measured and calculated from the following formula.
吸収率(%)= (W2−W、)/W2X100実施例
1
第1図は、気孔率35%、吸水率35%、見掛は密度0
.61g/carの親水性ポリオレフィンの焼結成形品
(商品名:サンファインAQ−800、旭化成工業株に
会社型)の円板(寸法:厚さ2mm、直径90mm)の
23℃、50%RHにおける乾燥曲線である。Absorption rate (%) = (W2-W,)/W2X100 Example 1 Figure 1 shows porosity of 35%, water absorption rate of 35%, and apparent density of 0.
.. 61 g/car of a sintered molded product of hydrophilic polyolefin (trade name: Sunfine AQ-800, manufactured by Asahi Kasei Industries, Ltd.) at 23°C and 50% RH. This is a drying curve.
また23°C150%RHの雰囲気のもとに約10時間
放置しておいた乾燥状態の上記焼結成形品円板にスポッ
トで水を約0.1J滴下させたところ、約2秒で全量成
形体内部に吸収された。In addition, when approximately 0.1 J of water was dripped onto the dry sintered molded disc that had been left in an atmosphere of 23°C and 150% RH for approximately 10 hours, the entire volume was molded in approximately 2 seconds. absorbed into the body.
さらに、上記円板を水中に1時間浸漬して取り出し、濡
れたままの状態で寸法を測定した結果、はとんど形状の
変化は認められなかった。Further, the disk was immersed in water for 1 hour, taken out, and its dimensions were measured while still wet. As a result, almost no change in shape was observed.
上記焼結成形品円板より20mm X loffImの
直角三角形板を2枚切り出し、安全口がね(山水光学社
製、YM−2タイプ)の両サイドカバーの内側に接着剤
(商品名ニス−パーゲル、ヘンケル白水株式会社製)で
添着させ、23℃、50%RHの雰囲気において約0.
0002 g / min、の水分蒸散機能を有する目
がねを得た。Cut out two right-angled triangular plates of 20mm x loffIm from the above sintered molded disk, and apply adhesive (product name: Varnish-Pergel) to the inside of both side covers of safety glasses (manufactured by Sansui Kogaku Co., Ltd., YM-2 type). (manufactured by Henkel Hakusui Co., Ltd.), and in an atmosphere of 23°C and 50% RH, approximately 0.
An eyeglass having a water evaporation function of 0,002 g/min was obtained.
本発明の目かねは、連続気孔を有する吸水性多孔質体か
らの水分の蒸散機能によって眼周辺における湿度を高め
、簡単にドライアイ患者の不快感を軽減させることので
きる有用性がある。The eye cane of the present invention is useful in that it can increase the humidity around the eyes by evaporating water from the water-absorbing porous material having continuous pores, and can easily alleviate the discomfort of dry eye patients.
第1図は、吸水性多孔質体として使用したサイファイン
A Q −800の23℃、
50%RHにおける乾
燥曲線である。FIG. 1 is a drying curve of Cyfine A Q-800 used as a water-absorbing porous material at 23° C. and 50% RH.
Claims (1)
側の、一部又は全部が、連続気孔を有する吸水性多孔質
体によって構成されることを特徴とする吸水性多孔質体
付き目がねA non-optical component for an eyeglass, wherein at least a part or the entire inside of the component is constituted by a water-absorbing porous material having continuous pores.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24879090A JPH04129551A (en) | 1990-09-20 | 1990-09-20 | Glasses having water absorptive porous body |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24879090A JPH04129551A (en) | 1990-09-20 | 1990-09-20 | Glasses having water absorptive porous body |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04129551A true JPH04129551A (en) | 1992-04-30 |
Family
ID=17183439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24879090A Pending JPH04129551A (en) | 1990-09-20 | 1990-09-20 | Glasses having water absorptive porous body |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04129551A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007514493A (en) * | 2003-12-19 | 2007-06-07 | ミシェル ギヨン、 | Apparatus and method for providing a controlled environment around the eye |
-
1990
- 1990-09-20 JP JP24879090A patent/JPH04129551A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007514493A (en) * | 2003-12-19 | 2007-06-07 | ミシェル ギヨン、 | Apparatus and method for providing a controlled environment around the eye |
JP4837568B2 (en) * | 2003-12-19 | 2011-12-14 | ミシェル ギヨン、 | Device for providing a controlled environment around the eyes |
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