JPH04126141A - Artificial crown - Google Patents

Artificial crown

Info

Publication number
JPH04126141A
JPH04126141A JP2247796A JP24779690A JPH04126141A JP H04126141 A JPH04126141 A JP H04126141A JP 2247796 A JP2247796 A JP 2247796A JP 24779690 A JP24779690 A JP 24779690A JP H04126141 A JPH04126141 A JP H04126141A
Authority
JP
Japan
Prior art keywords
crystallized glass
glass
core
color tone
artificial tooth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2247796A
Other languages
Japanese (ja)
Inventor
Toyohide Kurahashi
豊英 倉橋
Kiyoyuki Okunaga
清行 奥長
Takehiro Shibuya
武宏 渋谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Electric Glass Co Ltd
Original Assignee
Nippon Electric Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Electric Glass Co Ltd filed Critical Nippon Electric Glass Co Ltd
Priority to JP2247796A priority Critical patent/JPH04126141A/en
Publication of JPH04126141A publication Critical patent/JPH04126141A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the artifical crown whose color tone is similar to a natural tooth, and which is stable in a mouth extending over a long period, excellent in living body affinity, high in mechanical strength, and also, whose color tone at the time of installation is not influenced by a color tone of a supporting base and dental cement by forming a crystallized glass layer on the outside surface of a core having a cap shape. CONSTITUTION:On the outside surface of a core 4 having a cap shape, a crystallized glass layer 3 is formed. The core 4 has a cap shape in which an inner cavity part exists, and as for its material, a metal, ceramics, crystallized glass, glass, and a composite of ceramics and glass are suitable. As for the crystallized glass layer 3, its color tone is similar to that of a natural tooth, and especially, when calcium phosphate compound crystallized glass or mica compound crystallized glass it used, it is desirable since it has stability and excellent living body affinity in a mouth extending over a long period. Also, as for the crystallized glass, glass is formed in a prescribed shape, and thereafter, subjected to heat treatment and a desired crystal is deposited in the glass.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、人工歯冠に関し、より具体的には結晶化ガラ
スを使用した人工歯冠に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an artificial tooth crown, and more specifically to an artificial tooth crown using crystallized glass.

[従来技術とその問題点] 従来より一般に使用されている人工歯冠の材質としでは
、大きく分けて金属、樹脂、陶材がある。
[Prior art and its problems] Materials for artificial dental crowns that have been commonly used in the past can be broadly classified into metal, resin, and porcelain.

金属としては、金合金、銀合金、金銀パラジウム合金等
の貴金属やN1−Cr合金、Co−Cr合金等の非貴金
属が使用される。これらの材料は、いづれも鋳造によっ
て容易に作製することが可能であるが、色調が天然歯牙
と大幅に異なるという欠点を有している。また特に非貴
金属の場合は、口腔内で長期に亙って使用すると金属中
の有害イオンが溶出し、生体に悪影響を及ぼすことが知
られている。
As the metal, noble metals such as gold alloy, silver alloy, gold-silver-palladium alloy, and non-noble metals such as N1-Cr alloy and Co-Cr alloy are used. All of these materials can be easily produced by casting, but they have the disadvantage that the color tone is significantly different from that of natural teeth. In addition, especially in the case of non-noble metals, it is known that if they are used in the oral cavity for a long period of time, harmful ions in the metals will elute and have an adverse effect on living organisms.

また樹脂としては、メチルメタクリレート系やジメタク
リレート系の高分子あるいはこれらと無機フィラーとの
複合物が使用され、これらの材料からなる人工歯冠は、
色調が天然歯牙に近似しているが、長期に亙って使用す
ると摩耗や変色が生じるなど、口腔内における耐久性が
悪いという問題がある。
In addition, as the resin, methyl methacrylate-based or dimethacrylate-based polymers or composites of these and inorganic fillers are used, and artificial tooth crowns made of these materials are
Although the color tone is similar to that of natural teeth, there are problems with poor durability in the oral cavity, such as wear and discoloration when used over a long period of time.

さらに陶材からなる人工歯冠としては、全て陶材からで
きているオールポーセレン系やキャップ形状を有する金
属コアーを使用した金属・ボーセレン複合系のものが存
在する。これらの歯科用陶材からなる人工歯冠も色調が
天然歯牙に近似し、口腔内における耐久性も良好である
が、陶材粉末を築盛した後、焼結させて作製するため、
製造時における作業が煩雑であり、またその製造物も緻
密性が悪く、金属コアーを使用したとしても高い強度が
得られ難いという欠点を有している。
Furthermore, as artificial tooth crowns made of porcelain, there are all-porcelain crowns made entirely of porcelain, and metal-beaucelain composite crowns that use a metal core with a cap shape. Artificial tooth crowns made of these dental porcelains also have a color tone similar to that of natural teeth and have good durability in the oral cavity, but because they are made by building up porcelain powder and then sintering it,
The manufacturing process is complicated, the product has poor density, and even if a metal core is used, it is difficult to obtain high strength.

近年上記事情に鑑み、色調が天然歯牙に近似し、長期に
亙って口腔内で安定であり、しかも生体親和性に優れた
結晶化ガラスが各種開発され、これらの結晶化ガラスを
鋳造法によって作製した人工歯冠が注目を集めている。
In recent years, in view of the above circumstances, various types of crystallized glass have been developed that have a color tone similar to that of natural teeth, are stable in the oral cavity for a long period of time, and have excellent biocompatibility. The manufactured artificial tooth crowns are attracting attention.

結晶化ガラスの鋳造体からなる人工歯冠は、樹脂や歯科
用陶材からなる人工歯冠に比べて緻密性に優れているた
めに高い強度を有しているが、口腔内で長期に亙って使
用する部材としてより高い強度が要求されているのが実
情である。
Artificial tooth crowns made of cast crystallized glass have greater density and strength than artificial tooth crowns made of resin or dental porcelain, but they do not remain in the oral cavity for long periods of time. The reality is that higher strength is required for the members used in the construction.

ところで元肥したように結晶化ガラスからなる人工歯冠
は、色調が天然歯牙のそれと近似しているものの、実際
の使用に当たっては他の人工歯冠と同様にその色調を被
装着者(患者)の歯色に合わせて一本一本オーダーメイ
ドで作製される。この際、患者の天然歯牙の色調は、シ
ェードガイドと呼ばれる歯科用歯色色見本を用いて歯科
医師(チェアーサイド)から技工士(ラボサイド)にそ
の色調が伝達され、歯科医師から伝達された色調に合致
するように技工士によって上薬を用いて最終的に色調が
調整される。しかし人工歯冠として使用される結晶化ガ
ラスは、通常色調が半透明であるため一旦上薬を用いて
その色調を天然歯牙のそれに近似するように整えても口
腔内に装着した際に支台や人工歯冠と支台とを接着する
ための歯科用セメントの色調が反映してしまい、その結
果人工歯冠の色調が製作時と装着時とでは異なってしま
うという問題を存している。
By the way, as mentioned earlier, artificial tooth crowns made of crystallized glass have a color tone similar to that of natural teeth. Each one is custom-made to match the color of your teeth. At this time, the color tone of the patient's natural teeth is transmitted from the dentist (chair side) to the technician (lab side) using a dental tooth color sample called a shade guide. The color tone is finally adjusted by the technician using a topical medicine to match. However, the crystallized glass used as an artificial tooth crown is usually translucent in color, so even if the color tone is adjusted to approximate that of a natural tooth using an overcoat, the abutment will not hold when placed in the oral cavity. There is a problem in that the color tone of the dental cement for bonding the artificial tooth crown and the abutment is reflected, and as a result, the color tone of the artificial tooth crown differs between when it is manufactured and when it is installed.

[発明の目的コ 本発明の目的は、色調が天然歯牙に近似しており、長期
に亙って口腔内で安定であり、生体親和性に優れ、機械
的強度が高く、さらに装着時の色調が支台や歯科用セメ
ントの色調の影響を受けない人工歯冠を提供することで
ある。
[Objective of the Invention] The object of the present invention is to have a color tone similar to that of natural teeth, to be stable in the oral cavity for a long period of time, to have excellent biocompatibility, high mechanical strength, and to have a color tone when worn. The purpose of the present invention is to provide an artificial tooth crown that is not affected by the color tone of the abutment or dental cement.

[発明の構成コ 本発明の人工歯冠は、キャップ形状を有するコアーの外
表面に、結晶化ガラス層が形成されてなることを特徴と
する。
[Structure of the Invention] The artificial tooth crown of the present invention is characterized in that a crystallized glass layer is formed on the outer surface of a core having a cap shape.

本発明におけるコアーは、内腔所が存在するキャップ形
状を有しており、その材料としては金属、セラミックス
、結晶化ガラス、ガラス、セラミックスとガラスとの複
合物が適している。金属、ガラスあるいは結晶化ガラス
を使用する場合は、鋳造によって作製するが、薄い金属
箔を使用する場合は、圧接によって作製する。またセラ
ミック、結晶化ガラス、ガラスあるいはガラスとセラミ
ックとの複合物を使用する場合は、それらの材料の粉末
を水やグリセリン等の液と混合し、スラリー状に練和し
た後、築盛し、焼成することによって作製することがで
きる。コアーは、人工歯冠の強度を向上させると共に支
台や歯科用セメントの色調が人工歯冠の色調に反映する
のを防止する作用を有している。その色調としては、金
属の場合は黄金色が好ましく、それ以外の材料の場合は
白色や黄色が好ましい。またその肉厚は部位によって異
なるが、金属の場合は0.02〜0.8w+m 、それ
以外の材料の場合は0.2〜G、[immである。肉厚
が薄くなりすぎるとコアーとしての強度が低下して高強
度の人工歯冠が得られ難くなり、一方厚くなりすぎると
結晶化ガラス層の厚みを薄くする必要があるため、ガラ
スの成形が困難となると共にコアーの色調が結晶化ガラ
ス層に反映しやすくなるために好ましくない。
The core in the present invention has a cap shape with a cavity, and suitable materials for the core include metals, ceramics, crystallized glass, glass, and composites of ceramics and glass. When metal, glass, or crystallized glass is used, it is produced by casting, but when a thin metal foil is used, it is produced by pressure welding. In addition, when using ceramic, crystallized glass, glass, or a composite of glass and ceramic, the powder of those materials is mixed with a liquid such as water or glycerin, kneaded into a slurry, then piled up and fired. It can be produced by The core has the function of improving the strength of the artificial tooth crown and preventing the color tone of the abutment or dental cement from being reflected in the color tone of the artificial tooth crown. The color tone is preferably golden in the case of metal, and white or yellow in the case of other materials. The thickness varies depending on the part, but in the case of metal, it is 0.02 to 0.8 W+m, and in the case of other materials, it is 0.2 to G, [imm]. If the wall thickness becomes too thin, the strength of the core will decrease, making it difficult to obtain a high-strength artificial tooth crown.On the other hand, if the wall thickness becomes too thin, the crystallized glass layer will need to be thinned, making it difficult to form the glass. This is not preferable because it becomes difficult and the color tone of the core tends to be reflected in the crystallized glass layer.

本発明における結晶化ガラス層は、色調が天然歯牙のそ
れに近似しており、特にリン酸カルシウム系結晶化ガラ
スあるいはマイカ系結晶化ガラスを使用すると長期に亙
る口腔内での安定性や優れた生体親和性を有しているの
で好ましい。また本発明の結晶化ガラスは、ガラスを所
定形杖に成形した後、熱処理してガラス中に所望の結晶
を析出させたものであり、非常に緻密な構造を有してい
るため築盛によって作製される歯科用陶材に比べて高い
強度が得られる。
The crystallized glass layer in the present invention has a color tone similar to that of natural teeth, and especially when calcium phosphate-based crystallized glass or mica-based crystallized glass is used, it has long-term stability in the oral cavity and excellent biocompatibility. It is preferable because it has the following. In addition, the crystallized glass of the present invention is obtained by forming glass into a cane of a predetermined shape and then heat-treating it to precipitate desired crystals in the glass.Since it has a very dense structure, it can be produced by building up. It has higher strength than other dental porcelain materials.

本発明の人工歯冠を作製するには、コアーを鋳型の所定
箇所に配置してからガラスを鋳造し、熱処理することに
よって作製する方法やコアーと結晶化ガラス層とを別々
に作製してから両者を接着剤を用いて接着する方法等が
ある。
The artificial tooth crown of the present invention can be manufactured by placing the core in a predetermined position in a mold, casting glass, and heat-treating it, or by separately manufacturing the core and the crystallized glass layer. There is a method of bonding the two using an adhesive.

[実施例コ 以下、本発明を実施例および比較例に基づいて詳細に説
明する。
[Examples] The present invention will be described in detail below based on Examples and Comparative Examples.

(実施例1) 図面は、本発明の人工歯冠lを口腔内の支台歯2に装着
した状態を示す説明図であり、3は結晶化ガラス層、4
は金属箔からなるコアー、5は歯科用セメント層、6は
歯肉である。
(Example 1) The drawing is an explanatory diagram showing a state in which the artificial tooth crown l of the present invention is attached to an abutment tooth 2 in the oral cavity, and 3 is a crystallized glass layer, 4
5 is a core made of metal foil, 5 is a dental cement layer, and 6 is a gingiva.

図面の人工歯冠lは、上顎中切歯として用いられ、その
作製方法は以下のとおりである。
The artificial tooth crown I shown in the drawing is used as an maxillary central incisor, and its manufacturing method is as follows.

まず石膏製作業用模型の上に約0.05m鵬の厚みにな
るようにスペーサ材、すなわち支台歯2に人工歯冠lを
接着した際の歯科用セメント層5となる部分を確保する
ために使用される有機質塗料を塗布し、さらにその上に
約0.05mmの厚みを有する金と白金の合金からなる
金属箔を巻き、圧接することにより、コアー4を作製し
た。その後コアー4の外表面にパラフィンやカーナバか
らなる歯科用ワックスを築盛してコアー4とワックスが
一体化した鋳造パターンを作製した。次いでこの鋳造パ
ターンにワックスからなるスプルー線を溶着した後、石
膏製作業用模型から取り外し、スプルー線を円錐台に取
り付け、その円錐台の外周縁部に鋳造用金属リングを配
置し、このリング内にシリカとリン酸塩とを混合した鋳
型材を注入した。鋳型材が硬化した後、円錐台を取り外
し、鋳型を電気炉内に入れ、室温から約900℃まで昇
温し、ワックスとスプルー線を燃焼させてコアー4付の
鋳型を作製した。その後重量百分率で5i0250%、
P2O57%、Al20318%、MgO5%、Ca0
14%、L1203%、TIo、 3%の組成を有する
ガラス融液を小さなブロックに成形し、これを約150
0℃の温度で再溶融して該鋳型に注入し、遠心鋳造する
ことによってコアー4の外表面にガラス層を形成した。
First, in order to secure a spacer material, that is, a portion that will become the dental cement layer 5 when the artificial tooth crown 1 is bonded to the abutment tooth 2, to a thickness of about 0.05 m on the plaster working model. The core 4 was prepared by applying an organic paint used in the above, and then wrapping a metal foil made of an alloy of gold and platinum having a thickness of about 0.05 mm thereon and pressing it together. Thereafter, a dental wax made of paraffin or carnauba was applied to the outer surface of the core 4 to create a casting pattern in which the core 4 and the wax were integrated. Next, after welding a sprue wire made of wax to this casting pattern, it is removed from the plaster working model, the sprue wire is attached to a truncated cone, a metal ring for casting is placed around the outer periphery of the truncated cone, and a metal ring for casting is placed on the outer periphery of the truncated cone. A molding material mixed with silica and phosphate was injected into the mold. After the mold material had hardened, the truncated cone was removed, the mold was placed in an electric furnace, and the temperature was raised from room temperature to approximately 900° C., and the wax and sprue wire were burned to produce a mold with four cores. After that, the weight percentage is 5i0250%,
P2O57%, Al20318%, MgO5%, Ca0
A glass melt with a composition of 14%, L1203%, TIo, 3% was formed into small blocks, which
A glass layer was formed on the outer surface of the core 4 by remelting it at a temperature of 0° C., injecting it into the mold, and performing centrifugal casting.

このコアー4付のガラス層を約900℃で2時間熱処理
することによってガラス中にアパタイト結晶を析出させ
てリン酸カルシウム結晶化ガラス層3とした後、鋳型か
ら取り出し、スプルー線を切断した。
The glass layer with the core 4 was heat-treated at about 900° C. for 2 hours to precipitate apatite crystals in the glass to form the calcium phosphate crystallized glass layer 3, which was then taken out from the mold and the sprue wire was cut.

こうして作製した人工歯冠lの破折強度を測定したとこ
ろ55kgfであった。
The fracture strength of the artificial tooth crown I produced in this way was measured and found to be 55 kgf.

(実施例2) 重量百分率でS10゜88%、820315%、A1.
0゜3%、BaO3%、Llto  2%、Na2O2
%、K2O3%の組成を有するガラス粉末50%とアル
ミナ粉末50%からなるコアー材料を水で練和し、スラ
リー状物質とした。次いでこのスラリー状物質を実施例
1と同様のスペーサ材が塗布された耐火性作業用模型上
に焼成後の厚みが約0.51になるように築盛し、電気
炉を用いて乾燥した後、100℃/分で約1100℃ま
で昇温し、該温度で3分間保持するというスケジュール
で焼成を行うことによってコアーを作製した。
(Example 2) S10°88%, 820315%, A1.
0°3%, BaO3%, Llto2%, Na2O2
A core material consisting of 50% glass powder and 50% alumina powder having a composition of %, K2O and 3% was kneaded with water to form a slurry-like material. Next, this slurry-like material was piled up on a fire-resistant work model coated with a spacer material similar to that in Example 1 so that the thickness after firing was about 0.51 mm, and after drying using an electric furnace, A core was produced by firing according to a schedule in which the temperature was raised to about 1100°C at a rate of 100°C/min and held at this temperature for 3 minutes.

その後このコアーを使用して、実施例1と同様の方法で
コアー付の鋳型を作製した後、重量百分率でStO□ 
57.1%、MgO11,7%、F 5.9%、K2O
13,0%、ZrO24,8%、CaO3,1%、P2
O32,lli%、CeO,1,8%の組成を有するガ
ラス融液を小さなブロックに成形し、これを約1400
℃の温度で再溶融して該鋳型に注入し、遠心鋳造するこ
とによってコアーの外表面にガラス層を形成した。この
コアー付のガラス層を約1050℃で4時間熱処理する
ことによってガラス中に四球化フルオロマイカ結晶とア
パタイト結晶を析出させてマイカ結晶化ガラスとした後
、鋳型から取り出し、スプルー線を切断した。
Thereafter, using this core, a mold with a core was produced in the same manner as in Example 1, and then the weight percentage of StO□
57.1%, MgO 11.7%, F 5.9%, K2O
13.0%, ZrO24.8%, CaO3.1%, P2
A glass melt having a composition of O32,lli%, CeO,1,8% was formed into small blocks, which were
A glass layer was formed on the outer surface of the core by remelting it at a temperature of 0.degree. C. and pouring it into the mold, followed by centrifugal casting. This glass layer with a core was heat-treated at about 1050° C. for 4 hours to precipitate tetraspherical fluoromica crystals and apatite crystals in the glass to obtain mica crystallized glass, which was then taken out from the mold and the sprue wire was cut.

こうして作製した人工歯冠の破折強度を測定したところ
62kgfであった。
The fracture strength of the thus produced artificial tooth crown was measured and was found to be 62 kgf.

(比較例1) 実施例1の人工歯冠と同じ形状で、コアーを有さない結
晶化ガラスからなる人工歯冠を実施例1と同様の方法に
よって作製し、その破折強度を測定したところ35kg
fであった。
(Comparative Example 1) An artificial tooth crown made of crystallized glass without a core and having the same shape as the artificial tooth crown of Example 1 was prepared by the same method as Example 1, and its fracture strength was measured. 35kg
It was f.

(比較例2) 実施例1と同様の方法で金属箔からなるコアーを作製し
た後、その外表面に歯科用陶材を築盛し、適法どおり乾
燥、焼成を行った。焼成後、研削により形態を整ること
によって人工歯冠を作製し、その破折強度を測定したと
ころ31kgfであった。
(Comparative Example 2) After producing a core made of metal foil in the same manner as in Example 1, dental porcelain was built up on the outer surface of the core, and the core was dried and fired as required. After firing, an artificial tooth crown was prepared by adjusting the shape by grinding, and its fracture strength was measured and found to be 31 kgf.

尚、破折強度は、人工歯冠を金属製の支台に歯科用リン
酸亜鉛セメントで接着し、万能試験機を用いて破壊する
までの荷重を測定したものである。
The fracture strength was determined by bonding the artificial tooth crown to a metal abutment with dental zinc phosphate cement and measuring the load required to break it using a universal testing machine.

荷重は、歯輪に対して45″の角度、0.5mm /分
の速さで切端、すなわち歯の先端に負荷した。
The load was applied to the incisal end, ie, the tip of the tooth, at an angle of 45″ to the tooth ring and at a rate of 0.5 mm /min.

[発明の効果] 以上のように本発明の人工歯冠は、表面部が結晶化ガラ
スからなるため色調が天然歯牙に近似し、長期に亙って
口腔内で安定で、生体親和性に優れており、またコアー
を有するため機械的強度が高く、且つその色調が支台や
歯科用セメントの色調の影響を受けないため製作時の色
調が装着時に正確に再現される。
[Effects of the Invention] As described above, the artificial tooth crown of the present invention has a color tone similar to that of a natural tooth because the surface portion is made of crystallized glass, is stable in the oral cavity for a long period of time, and has excellent biocompatibility. Moreover, since it has a core, it has high mechanical strength, and its color tone is not affected by the color tone of the abutment or dental cement, so the color tone at the time of manufacture is accurately reproduced when installed.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は、本発明の人工歯冠を口腔内の支台歯に装着した
状態を示す説明図である。 l・・・人工歯冠 3・・・結晶化ガラス層 2・・・支台歯 4・・・コアー 特許出願人  日本電気硝子株式会社 代表者  岸 1)清 作
The drawing is an explanatory diagram showing a state in which the artificial tooth crown of the present invention is attached to an abutment tooth in the oral cavity. l...Artificial tooth crown 3...Crystalline glass layer 2...Abutment tooth 4...Core patent applicant Nippon Electric Glass Co., Ltd. Representative Kishi 1) Saku Kiyoshi

Claims (2)

【特許請求の範囲】[Claims] (1)キャップ形状を有するコアーの外表面に、結晶化
ガラス層が形成されてなることを特徴とする人工歯冠。
(1) An artificial tooth crown, characterized in that a crystallized glass layer is formed on the outer surface of a core having a cap shape.
(2)結晶化ガラス層が、リン酸カルシウム系結晶化ガ
ラスあるいはマイカ系結晶化ガラスからなることを特徴
とする特許請求の範囲第1項記載の人工歯冠。
(2) The artificial tooth crown according to claim 1, wherein the crystallized glass layer is made of calcium phosphate-based crystallized glass or mica-based crystallized glass.
JP2247796A 1990-09-17 1990-09-17 Artificial crown Pending JPH04126141A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2247796A JPH04126141A (en) 1990-09-17 1990-09-17 Artificial crown

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2247796A JPH04126141A (en) 1990-09-17 1990-09-17 Artificial crown

Publications (1)

Publication Number Publication Date
JPH04126141A true JPH04126141A (en) 1992-04-27

Family

ID=17168784

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2247796A Pending JPH04126141A (en) 1990-09-17 1990-09-17 Artificial crown

Country Status (1)

Country Link
JP (1) JPH04126141A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012105983A (en) * 2010-11-15 2012-06-07 Ivoclar Vivadent Ag Oven

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012105983A (en) * 2010-11-15 2012-06-07 Ivoclar Vivadent Ag Oven

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