JPH041105B2 - - Google Patents

Info

Publication number
JPH041105B2
JPH041105B2 JP8111187A JP8111187A JPH041105B2 JP H041105 B2 JPH041105 B2 JP H041105B2 JP 8111187 A JP8111187 A JP 8111187A JP 8111187 A JP8111187 A JP 8111187A JP H041105 B2 JPH041105 B2 JP H041105B2
Authority
JP
Japan
Prior art keywords
fiber bundle
plating
fiber
bar
swing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP8111187A
Other languages
Japanese (ja)
Other versions
JPS63249773A (en
Inventor
Masashi Ogasawara
Mikio Hayashi
Atsushi Kitamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP8111187A priority Critical patent/JPS63249773A/en
Publication of JPS63249773A publication Critical patent/JPS63249773A/en
Publication of JPH041105B2 publication Critical patent/JPH041105B2/ja
Granted legal-status Critical Current

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  • Treatment Of Fiber Materials (AREA)
  • Chemically Coating (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、メツキ浴内で繊維束を解しながら均
一なメツキを施すようにした繊維束のメツキ方法
に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for plating fiber bundles in which uniform plating is applied to the fiber bundles while unraveling them in a plating bath.

〔従来の技術〕[Conventional technology]

連続的に移送される繊維束をメツキ浴中でメツ
キする繊維束のメツキ方法においては、集束状態
にある繊維束をいかに開繊させて各繊維素線に均
一なメツキを施すかが、従来からの共通の技術的
課題である。この課題を解決する方法として、メ
ツキ槽内にノズルを設けてメツキ液の噴流を作
り、その噴流による流体力学的な合力により開繊
を行うと同時にメツキの均一化をはかつた方法
が、特開昭57−77342号公報、特開昭58−174593
号公報、特開昭58−193391号公報、特開昭59−
215497号公報、特開昭60−119269号公報、特開昭
60−141895号公報等に開示されている。この方法
では、たとえば第3図に示すように、メツキ槽1
内のメツキ液2中に繊維束3を通し、繊維束3が
導電性のものである場合にはたとえば陰極電極ロ
ーラ4と陽極板5間に所定の電位を印加してメツ
キを行うもので、メツキ槽1内に噴流ノズル6が
設けられる。繊維束3を引取りローラ7で引取る
に際し、ダンサーロール8等を用いて所定の張力
がかかるよう制御される。そして、噴流ノズル6
からの噴流により、移送中の繊維束3の開繊が行
われる。
In the method of plating fiber bundles in which continuously transported fiber bundles are plated in a plating bath, it has traditionally been difficult to spread out the bundled fiber bundles and apply uniform plating to each fiber strand. This is a common technical issue. As a method to solve this problem, a method is proposed in which a nozzle is installed in the plating tank to create a jet of plating liquid, and the hydrodynamic resultant force of the jet is used to spread the fibers and at the same time make the plating uniform. Publication No. 57-77342, Japanese Patent Publication No. 58-174593
Publication No. 193391, Japanese Patent Application Publication No. 1983-19339, Japanese Patent Application Publication No. 1987-
Publication No. 215497, Japanese Patent Publication No. 60-119269, Publication No. 119269, Japanese Patent Publication No.
It is disclosed in Publication No. 60-141895 and the like. In this method, for example, as shown in FIG.
The fiber bundle 3 is passed through the plating liquid 2 in the plating solution 2, and if the fiber bundle 3 is conductive, plating is performed by applying a predetermined potential between the cathode electrode roller 4 and the anode plate 5, for example. A jet nozzle 6 is provided in the plating tank 1. When the fiber bundle 3 is taken up by the take-up roller 7, it is controlled to apply a predetermined tension using a dancer roll 8 or the like. And the jet nozzle 6
The fiber bundle 3 being transferred is opened by the jet stream from the fiber bundle 3 .

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかしながら、上記のような方法においては、
メツキ液2中を搬送される繊維束3には移送のた
めの張力がかかるため、メツキ液中での噴流によ
る開繊のためには噴流の強さを相当強くせざるを
得ず、比重の高いメツキ液のアジテーシヨンが相
当強くなる。繊維束3は通常数μ程度の素線が数
千本集束されたものであるが、上記張力および噴
流のために、一部の繊維が切れたり、あるいは切
れた繊維が繊維束3に巻き付いたりするトラブル
が生じるおそれがある。そのため、結局、メツキ
を均一に行うために必要な適度の開繊を十分に行
うことができなかつた。
However, in the above method,
Since tension is applied to the fiber bundle 3 transported through the plating liquid 2, the strength of the jet must be considerably increased in order to spread the fibers by the jet flow in the plating liquid. The agitation of high-metallic liquid becomes considerably stronger. The fiber bundle 3 is usually made up of several thousand wires of several micrometers in diameter, but due to the tension and jet flow, some of the fibers may break or the cut fibers may wrap around the fiber bundle 3. There is a risk that problems may occur. Therefore, in the end, it was not possible to sufficiently perform the appropriate fiber opening required for uniform plating.

このような噴流の悪影響を除去するために、た
とえば第4図および第5図に示すように、繊維束
3をベルトコンベア9又は10上にのせて移送
し、ベルトコンベア9又は10上の繊維束3を無
張力状態に保ち、無張力状態の繊維束3を比較的
弱い噴流で開繊させる方法も考えられるが、ベル
トコンベア9又は10上にランダムに蛇行する繊
維束3、あるいはその素線が互にからまり、操業
性をやや低下させてしまうおそれがあるという問
題が残る。
In order to eliminate the adverse effects of such a jet flow, for example, as shown in FIGS. 4 and 5, the fiber bundle 3 is placed on a belt conveyor 9 or 10 and transported, and the fiber bundle on the belt conveyor 9 or 10 is transported. 3 in a tension-free state and opening the tension-free fiber bundle 3 with a relatively weak jet stream is also considered, but if the fiber bundle 3 meandering randomly on the belt conveyor 9 or 10 or its strands is There remains the problem that they may become entangled with each other, resulting in a slight decrease in operability.

本発明の目的は、従来の噴流による方法におけ
る単糸切れを防止し、効率よくかつ適切に繊維束
を開繊し、トラブルを生じさせることなく均一な
メツキを施すことのできる方法を提供することに
ある。
An object of the present invention is to provide a method that can prevent single yarn breakage in conventional methods using jet flow, open fiber bundles efficiently and appropriately, and uniformly plate the fiber bundles without causing any trouble. It is in.

〔問題点を解決するための手段〕[Means for solving problems]

この目的に沿う本発明の繊維束のメツキ方法
は、連続的に移送される繊維束にメツキ浴中でメ
ツキを施す繊維束のメツキ方法において、前記繊
維束をメツキ浴内に設けられた揺動バーにのせて
該揺動バー上を通過させ、該揺動バーを繊維束移
送方向に揺動させることにより、繊維束を解しな
がらメツキを施す方法から成る。
The fiber bundle plating method of the present invention which meets this objective is a fiber bundle plating method in which continuously transported fiber bundles are plated in a plating bath. It consists of a method in which the fiber bundle is placed on a bar and passed over the rocking bar, and the rocking bar is rocked in the fiber bundle transport direction, thereby plating the fiber bundle while unraveling it.

繊維束はメツキ浴中では適当に弛緩されて移送
され、弛緩された繊維束が揺動バーにのせられて
揺動バー上を通過する。揺動バーとしては、繊維
束を適当に案内しながらその上に繊維束を通過さ
せることができ、かつ繊維束移送に沿う方向に往
復動できるものであれば、機構的にはとくに限定
されないが特に単振子状に揺動させるのが好まし
い。
The fiber bundle is suitably relaxed and transported in the plating bath, and the relaxed fiber bundle is placed on a rocking bar and passed over the rocking bar. The swing bar is not particularly limited mechanically as long as it can pass the fiber bundle over it while guiding the fiber bundle appropriately and can reciprocate in the direction along the fiber bundle transport. In particular, it is preferable to oscillate in a single pendulum shape.

〔作用〕[Effect]

このような方法においては、メツキ浴中で繊維
束は適度に弛緩されているから、繊維束は極小張
力状態あるいは実質的に無張力に近い状態に保た
れる。そして、揺動バーの揺動により、繊維束移
送方向にメツキ液のアジテーシヨンによる往復流
が発生するが、揺動バーの揺動速度を適当に小さ
く抑えることにより、ゆるやかな液流のアジテー
シヨンを発生させることができる。ゆるやかなア
ジテーシヨンであるから、繊維束に局部的に大き
な力は加わらず、単糸切れの発生が防止されると
ともに、往復流に伴う繊維束の解し作用により、
極めて均一な開繊が可能となる。その結果、トラ
ブルを発生させることなく、適度に開繊された各
繊維素線に均一なメツキが施される。
In such a method, since the fiber bundle is moderately relaxed in the plating bath, the fiber bundle is maintained in a state of minimal tension or a state close to substantially no tension. The swinging of the swinging bar generates a reciprocating flow due to agitation of the plating liquid in the fiber bundle transfer direction, but by keeping the swinging speed of the swinging bar to an appropriate low level, a gentle agitation of the liquid flow is generated. can be done. Since the agitation is gentle, large forces are not applied locally to the fiber bundle, preventing the occurrence of single yarn breakage, and the unraveling action of the fiber bundle due to the reciprocating flow,
Extremely uniform opening is possible. As a result, uniform plating is applied to each appropriately opened fiber strand without causing any trouble.

〔実施例〕〔Example〕

以下に、本発明の望ましい実施態様および具体
的な実施結果を、図面を参照して説明する。
Preferred embodiments and specific implementation results of the present invention will be described below with reference to the drawings.

第1図および第2図は、本発明の一実施態様に
係る方法を実施するための装置を示している。本
装置は、2段浴槽を用いたものであるが、段数は
任意でよい。図において、11はメツキ槽、12
はその中に収容されたメツキ液、13はメツキ液
12中を順次連続的に移送される繊維束を、それ
ぞれ示している。
1 and 2 show an apparatus for carrying out a method according to an embodiment of the invention. Although this device uses a two-stage bathtub, the number of stages may be arbitrary. In the figure, 11 is a plating tank, 12
13 indicates a plating liquid contained therein, and 13 indicates a fiber bundle that is sequentially and continuously transferred through the plating liquid 12.

本発明は、繊維束13としては、炭素等の導電
性材料、ボロン、炭化ケイ素、アルミナ等の無機
質の非導電性材料、又はナイロン、ポリエチレン
テレフタレート等の合成繊維材料等のいずれにも
適用でき、メツキ方法としては、電気メツキある
いは無電解メツキいずれにも適用できる。本実施
態様では、繊維束13は導電性材料から成つてお
り、メツキ槽11外に陰極電極としての金属ロー
ラ14と、メツキ液12中に陽極電極としての電
極板15が設けられており、この間に必要な電位
が印加されるようになつている。
The present invention can be applied to any of conductive materials such as carbon, inorganic non-conductive materials such as boron, silicon carbide, alumina, or synthetic fiber materials such as nylon and polyethylene terephthalate as the fiber bundle 13. As the plating method, either electric plating or electroless plating can be applied. In this embodiment, the fiber bundle 13 is made of a conductive material, and a metal roller 14 as a cathode electrode is provided outside the plating tank 11, and an electrode plate 15 as an anode electrode is provided in the plating solution 12. The required potential is applied to the

繊維束13は、ニツプローラ16と陰極電極ロ
ーラ14とにより、図の矢印の方向に連続的に移
送され、固定バー17下面側を通過することによ
り、メツキ液12中に十分に浸漬される。
The fiber bundle 13 is continuously transported in the direction of the arrow in the figure by the nip roller 16 and the cathode roller 14, and is sufficiently immersed in the plating liquid 12 by passing under the fixed bar 17.

メツキ浴内(メツキ槽11内のメツキ液12
中)には、揺動バー18が設けられており、繊維
側13は、固定バー17の下面側、揺動バー18
の上面側、固定バー17の下面側と順に通過して
いく。この揺動バー18は、支点19を中心に、
揺動バー18の移送方向に単振子状に(図の矢印
方向に)比較的低速で揺動される。そして、この
揺動バー18の揺動が可能なように、固定バー1
7,17間において、繊維束13は適度に弛緩さ
れている。
Inside the plating bath (plating liquid 12 in the plating tank 11)
A swing bar 18 is provided in the middle), and the fiber side 13 is located on the lower surface side of the fixed bar 17, and the swing bar 18
It passes through the upper surface side and the lower surface side of the fixing bar 17 in this order. This swing bar 18 is centered around a fulcrum 19.
The swing bar 18 swings at a relatively low speed in a single pendulum-like manner (in the direction of the arrow in the figure) in the transport direction. The fixed bar 1 is arranged so that the swing bar 18 can swing.
Between 7 and 17, the fiber bundle 13 is moderately relaxed.

揺動バー18およびその揺動機構については、
第1図および第2図に示した構造に限られず、繊
維束13の移送方向に往復できるものであればよ
く、第1図に示したような円弧状に揺動するもの
の他、直線状に往復動するものであつてもよい。
また、固定バー17,17間の繊維束13のパス
長が極力変化しないよう、第1図に示したものと
は天地逆の円弧状に揺動する構造であつてもよ
い。揺動バー18の揺動駆動源には、周知の適当
なものを使用すればよい。
Regarding the swing bar 18 and its swing mechanism,
It is not limited to the structure shown in FIGS. 1 and 2, and any structure that can reciprocate in the transport direction of the fiber bundle 13 may be used.In addition to the structure that swings in an arc shape as shown in FIG. It may be one that moves back and forth.
Further, in order to prevent the path length of the fiber bundle 13 between the fixed bars 17, 17 from changing as much as possible, the structure may be such that the fiber bundle 13 swings in an arc shape that is upside down from that shown in FIG. As the swing drive source for the swing bar 18, any known suitable source may be used.

上記のような装置を用いて本発明方法は次のよ
うに実施される。
The method of the present invention is carried out as follows using the apparatus as described above.

繊維束13は、入口側の陰極電極ローラ14と
ニツプローラ16によりメツキ槽11中に送り込
まれ、該入口側のローラ14,16と中間のロー
ラ14,16、および中間のローラ14,16と
出口側のローラ14,16との間でメツキ槽11
内の弛緩長が略一定に保たれながら、出口側の陰
極電極ローラ14とニツプローラ16により引き
出される。メツキ液12中に浸漬された繊維束1
3は、固定バー17、揺動バー18、固定バー1
7と通過するが、揺動バー18が繊維束13移送
方向に揺動されるので、この揺動バー18近傍に
は繊維束13移送方向に往復する、ゆるやかな液
流のアジテーシヨンが発生する。このアジテーシ
ヨンにより、弛緩されている繊維束13は、適度
に集束状態が解され、とくに第2図に示すように
メツキ槽幅方向に開繊される。
The fiber bundle 13 is fed into the plating tank 11 by a cathode electrode roller 14 and a nip roller 16 on the entrance side, and between the entrance side rollers 14, 16, intermediate rollers 14, 16, and between the intermediate rollers 14, 16 and the exit side. plating tank 11 between the rollers 14 and 16 of
It is pulled out by the cathode electrode roller 14 and the nip roller 16 on the exit side while the inner relaxation length is kept substantially constant. Fiber bundle 1 immersed in plating liquid 12
3 is a fixed bar 17, a swing bar 18, and a fixed bar 1.
However, since the swing bar 18 is swung in the direction of transporting the fiber bundle 13, agitation of a gentle liquid flow that reciprocates in the direction of transport of the fiber bundle 13 is generated in the vicinity of the swing bar 18. As a result of this agitation, the relaxed fiber bundle 13 is appropriately decondensed and spread, particularly in the width direction of the plating tank, as shown in FIG.

この開繊は、上記アジテーシヨンに伴なつて行
われるものであり、揺動バー18のゆるやかな揺
動によつて引き起こされるアジテーシヨンは、従
来の噴流に比べはるかに弱いものであり、かつ繊
維束13はこの部分で適度に弛緩され無張力に近
い状態になつているから、繊維束に単糸切れは発
生せず、したがつて切れた単糸が巻き付くトラブ
ルも発生しない。また、揺動バー18の揺動は連
続的に行われるので、移送中の繊維束13は順次
良好に開繊される。さらに、弛緩されてはいるも
のの、繊維束13は揺動バー13上を略一定のパ
スに沿つて案内されることになるので、繊維束1
3同士がからまつたりすることもない。
This fiber opening is performed in conjunction with the agitation described above, and the agitation caused by the gentle rocking of the rocking bar 18 is much weaker than the conventional jet flow, and the fiber bundle 13 is much weaker than the conventional jet flow. Since the fiber bundle is moderately relaxed in this part and has almost no tension, no breakage of single threads will occur in the fiber bundle, and therefore no trouble will occur where broken single threads will become entangled. Furthermore, since the swinging bar 18 is continuously oscillated, the fiber bundles 13 being transferred are successively opened in good order. Furthermore, although the fiber bundle 13 is relaxed, it is guided along a substantially constant path on the swing bar 13, so the fiber bundle 13 is guided along a substantially constant path on the swing bar 13.
There is no chance for the three to become entangled with each other.

繊維束13は、適度にかつ均一に開繊されつつ
メツキ液12中を通過するので、開繊された各繊
維素線に均一なメツキが施される。
Since the fiber bundle 13 passes through the plating liquid 12 while being spread appropriately and uniformly, each spread fiber strand is uniformly plated.

開繊された繊維束13は、その後に位置が一定
に固定された固定バー17、ローラ14,16を
通過することにより、再び適度に集束される。
The opened fiber bundle 13 then passes through a fixed bar 17 and rollers 14, 16 whose positions are fixed, and is appropriately focused again.

上記のような装置を用いて、直径7μの単繊維
6000本からなる炭素繊維束をメツキした。繊維束
13を陰極電極ローラ14に接触させ、陽極電極
板15としてニツケル板を配設し、揺動バー18
を揺動させて開繊しながらメツキを行つたとこ
ろ、単糸切れのない、かつ均一なメツキ糸が得ら
れた。メツキ液組成は、硫酸ニツケル150g/、
塩化アンモニウム15g/、硼酸15g/の普通
浴で、メツキ液のPHは6.0、液温は25℃とした。
炭素繊維束の走行速度は50cm/分、メツキ浴滞在
時間は3分、全電流は10Aでメツキを行つた。
Using the device as described above, a single fiber with a diameter of 7μ is produced.
A carbon fiber bundle consisting of 6,000 fibers was plated. The fiber bundle 13 is brought into contact with the cathode electrode roller 14, a nickel plate is provided as the anode electrode plate 15, and the swing bar 18
When plating was performed while opening the fibers by swinging the fibers, a uniform plating yarn with no single yarn breakage was obtained. The composition of the plating liquid is nickel sulfate 150g/,
The pH of the plating solution was 6.0 and the temperature was 25°C in a normal bath containing 15 g of ammonium chloride and 15 g of boric acid.
The traveling speed of the carbon fiber bundle was 50 cm/min, the residence time in the plating bath was 3 minutes, and the plating was performed at a total current of 10 A.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、本発明の繊維束のメツキ
方法によるときは、メツキ浴中にて、揺動バーの
揺動により繊維束を略無張力に近い状態で均一に
開繊させることができ、単糸切れ等のトラブルを
発生させることなく、色調むら、メツキ欠陥等の
ない均一なメツキを施すことができるという効果
が得られる。
As explained above, when using the fiber bundle plating method of the present invention, the fiber bundle can be uniformly opened in a substantially tension-free state by swinging the rocking bar in the plating bath, It is possible to achieve the effect that uniform plating without color tone unevenness, plating defects, etc. can be performed without causing troubles such as single thread breakage.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施態様に係る繊維束のメ
ツキ方法の実施に用いるメツキ装置の概略側面
図、第2図は第1図の装置の平面図、第3図は従
来のメツキ装置の概略側面図、第4図はベルトコ
ンベアを用いたメツキ装置の概略側面図、第5図
はベルトコンベアを用いた別のメツキ装置の概略
側面図、である。 11……メツキ槽、12……メツキ液、13…
…繊維束、14……陰極電極ローラ、15……陽
極電極板、16……ニツプローラ、17……固定
バー、18……揺動バー、19……支点。
FIG. 1 is a schematic side view of a plating device used for carrying out a fiber bundle plating method according to an embodiment of the present invention, FIG. 2 is a plan view of the device shown in FIG. 1, and FIG. FIG. 4 is a schematic side view of a plating device using a belt conveyor, and FIG. 5 is a schematic side view of another plating device using a belt conveyor. 11... plating tank, 12... plating liquid, 13...
... fiber bundle, 14 ... cathode electrode roller, 15 ... anode electrode plate, 16 ... nip roller, 17 ... fixed bar, 18 ... swinging bar, 19 ... fulcrum.

Claims (1)

【特許請求の範囲】[Claims] 1 連続的に移送される繊維束にメツキ浴中でメ
ツキを施す繊維束のメツキ方法において、前記繊
維束をメツキ浴内に設けられた揺動バーにのせて
該揺動バー上を通過させ、該揺動バーを繊維束移
送方向に揺動させることにより、繊維束を解しな
がらメツキを施すことを特徴とする繊維束のメツ
キ方法。
1. A fiber bundle plating method in which a continuously transferred fiber bundle is plated in a plating bath, the fiber bundle being placed on a rocking bar provided in the plating bath and passing over the rocking bar, A method for plating a fiber bundle, characterized in that plating is performed while unraveling the fiber bundle by swinging the rocking bar in the fiber bundle transport direction.
JP8111187A 1987-04-03 1987-04-03 Method for plating fiber bundle Granted JPS63249773A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8111187A JPS63249773A (en) 1987-04-03 1987-04-03 Method for plating fiber bundle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8111187A JPS63249773A (en) 1987-04-03 1987-04-03 Method for plating fiber bundle

Publications (2)

Publication Number Publication Date
JPS63249773A JPS63249773A (en) 1988-10-17
JPH041105B2 true JPH041105B2 (en) 1992-01-09

Family

ID=13737267

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8111187A Granted JPS63249773A (en) 1987-04-03 1987-04-03 Method for plating fiber bundle

Country Status (1)

Country Link
JP (1) JPS63249773A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6045876A (en) * 1996-04-10 2000-04-04 Fellers; John F. System and method for impregnating a continuous fiber strand with a polymer melt

Also Published As

Publication number Publication date
JPS63249773A (en) 1988-10-17

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