JPH04108167A - Production of woven glass fiber fabric - Google Patents
Production of woven glass fiber fabricInfo
- Publication number
- JPH04108167A JPH04108167A JP22526990A JP22526990A JPH04108167A JP H04108167 A JPH04108167 A JP H04108167A JP 22526990 A JP22526990 A JP 22526990A JP 22526990 A JP22526990 A JP 22526990A JP H04108167 A JPH04108167 A JP H04108167A
- Authority
- JP
- Japan
- Prior art keywords
- glass fiber
- fiber fabric
- fabric
- sizing agent
- warp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 45
- 239000003365 glass fiber Substances 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 238000004513 sizing Methods 0.000 claims abstract description 19
- 239000002759 woven fabric Substances 0.000 claims description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 abstract description 20
- 238000000034 method Methods 0.000 abstract description 11
- 235000010333 potassium nitrate Nutrition 0.000 abstract description 10
- 239000007787 solid Substances 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0366—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本願はガラス繊維織物の製造方法に関し、特に、ガラス
繊維織物の脱油を効率よくおこなわせるための製造方法
に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present application relates to a method for manufacturing glass fiber fabrics, and particularly to a manufacturing method for efficiently deoiling glass fiber fabrics.
ガラス繊維織物は、通常、ガラスヤーンを製織しガラス
繊維織物原反とし、更にこの原反を脱油し、表面処理を
おこなうことにより、プリント基板用やＦＲＰ用等の各
種用途に使用される。Glass fiber fabrics are usually used for various purposes such as printed circuit boards and FRP by weaving glass yarns to make glass fiber fabric raw fabrics, and then removing oil from the raw fabrics and subjecting them to surface treatment.
ガラス繊維織物の原反を脱油するのは、ガラスヤーンに
付着している澱粉、油剤を主体とした集束剤や、製織工
程に於ける経糸整経時の澱粉、ポリビニルアルコール（
ＰＶＡ）を主体とした経糸糊剤を除去するためである。De-oiling the original glass fiber fabric is done by removing the starch adhering to the glass yarn, the sizing agent mainly consisting of oil, the starch during warping during the weaving process, and polyvinyl alcohol (
This is to remove the warp glue mainly composed of PVA).
ガラス繊維織物の脱油については、湿式法、加熱法等が
あるが、湿式法の場合は集束剤等の有機物の完全除去が
難しく、又織物に目的りや目ずれを発生しやすい等の欠
点があり、現在一般におこなわれている方法は加熱脱油
法である。There are wet methods, heating methods, etc. for deoiling glass fiber fabrics, but wet methods have disadvantages such as difficulty in completely removing organic substances such as sizing agents, and the tendency to cause misalignment of the fabric. The method currently commonly used is the thermal deoiling method.
〔発明が解決しようとする課題］
ガラス繊維織物の加熱脱油は、鉄芯に巻いたロール巻の
状態でバッチ式の加熱炉に入れ、３００°Ｃ〜４５０℃
の温度で一定時間加熱し、ガラス繊維に付着している集
束剤等の有機物を焼きとばす。[Problems to be Solved by the Invention] Glass fiber fabrics are deoiled by heating by placing them in a roll wound around an iron core in a batch-type heating furnace at 300°C to 450°C.
Heating for a certain period of time at a temperature of
温度が低すぎると脱油が充分におこなわれず、又、温度
が高すぎるとガラス繊維の劣化が大きくなり、ガラス繊
維織物の強度低下もそれに比例する。If the temperature is too low, oil removal will not be sufficient, and if the temperature is too high, the glass fibers will deteriorate significantly, and the strength of the glass fiber fabric will decrease proportionally.
脱油されたガラス繊維織物は、残脂量が０．１％以下と
なることが要求される。The deoiled glass fiber fabric is required to have a residual fat content of 0.1% or less.
加熱時間については、織物の種類が巻き長さ等により変
化するが、例えば厚さ０．２閣のガラス繊維織物で長さ
２０００ｍ／ロールの場合、予備加熱時間も含め約７０
時間の加熱を要する。従って、この間ガラス繊維織物は
、加熱炉中に滞留することになり、この長時間の滞留に
よる生産性の低下を補うためには、加熱炉の容量を大き
くするか、加熱炉の数を増やす必要がある。The heating time varies depending on the type of fabric and the winding length, but for example, in the case of a glass fiber fabric with a thickness of 0.2 mm and a length of 2000 m/roll, it will take about 70 minutes including the preheating time.
Requires time to heat. Therefore, during this time, the glass fiber fabric will remain in the heating furnace, and in order to compensate for the decrease in productivity due to this long residence time, it is necessary to increase the capacity of the heating furnace or increase the number of heating furnaces. There is.
又、長時間の加熱は、当然エネルギーコストの増加につ
ながる。このように生産性、エネルギーコストの両面か
ら脱油時間の短縮が望まれている。Moreover, long-term heating naturally leads to an increase in energy costs. In this way, it is desired to shorten the deoiling time from both productivity and energy cost standpoints.
〔課題を解決するための手段］
本願発明者等は、前記課題を解決するため、ガラス繊維
織物の製織工程に於て、経糸整経時に用いる経糸糊剤に
ＫＮＯ２を含有する経糸糊剤を用いることにより、課題
の解決が可能であることを見出した。[Means for Solving the Problems] In order to solve the above problems, the inventors of the present application used a warp sizing agent containing KNO2 as a warp sizing agent used during warping in the weaving process of glass fiber fabric. We found that it is possible to solve the problem by doing this.
更にガラス繊維織物の原反をＫＮＯ３溶液処理すること
により、課題の解決が可能であることを見出した。Furthermore, we have found that the problem can be solved by treating the original glass fiber fabric with a KNO3 solution.
ガラス繊維織物の加熱脱油の場合、ガラス繊維を劣化さ
せない程度での充分な高温と、有機物である集束剤等を
燃焼させるのに充分な酸素とが必要になる。酸素は、炉
内を循環する空気中と澱粉やＰＶＡ分子中に含まれる。In the case of thermal deoiling of glass fiber fabrics, a sufficiently high temperature is required to not deteriorate the glass fibers, and sufficient oxygen is required to burn out organic sizing agents and the like. Oxygen is contained in the air circulating in the furnace and in the starch and PVA molecules.
加熱脱油の効率をあげるためには、温度をあげるか、酸
素の供給量を増大させるかであるが、温度を上げること
は、前記したようにガラス繊維の劣化が激しくなるため
に難かしい。又、循環空気中の酸素の量を増やすことも
熱エネルギーコストとの関係で限界がある。In order to increase the efficiency of thermal deoiling, it is possible to raise the temperature or increase the amount of oxygen supplied, but raising the temperature is difficult because, as described above, the glass fibers deteriorate more rapidly. Furthermore, there is a limit to increasing the amount of oxygen in the circulating air due to the cost of thermal energy.
本願発明に使用されるＫＮＯ３は約３３０°Ｃで分解し
て酸素ガスを放出する。従ってこの酸素ガスが集束剤等
の有機物の燃焼を促進し、脱油に必要な加熱時間の短縮
に効果がある。ガラス繊維織物はロール状に巻かれて加
熱炉に入れられるため、ロールの内層部は、どうしても
空気との接触が不充分になりやすく、脱油不良が発生し
やすい。The KNO3 used in the present invention decomposes at about 330°C and releases oxygen gas. Therefore, this oxygen gas promotes the combustion of organic substances such as sizing agents, and is effective in shortening the heating time required for oil removal. Since the glass fiber fabric is wound into a roll and placed in a heating furnace, the inner layer of the roll tends to have insufficient contact with air, which tends to result in poor oil removal.
本願発明のガラス繊維織物は、織物に付着しているＫＮ
Ｏ３が高温になると分解して酸素ガスを放出するため、
ロール内層部でも集束剤等の燃焼が充分におこなわれや
すく、又、全体としても脱油の効率化がはかられる。酸
素放出剤としては、ＫＮＯ３の代りＨ，０□等でも使用
可能である。The glass fiber fabric of the present invention has KN attached to the fabric.
When O3 reaches high temperatures, it decomposes and releases oxygen gas, so
Even in the inner layer of the roll, the sizing agent and the like can be sufficiently burned, and the overall efficiency of oil removal can be improved. As the oxygen releasing agent, H, 0□, etc. can be used instead of KNO3.
経糸糊剤中のＫＮ（ｈの量は、ガラス繊維に対する固型
分重量比で０６０１〜１．０％の範囲となるような量が
適当である。The appropriate amount of KN (h) in the warp sizing agent is in the range of 0.601 to 1.0% in solids weight ratio to glass fiber.
０．０１％より低い場合は、本願発明の効果が出現しに
くく、又１．０％より大きい場合は、経糸糊剤の効果が
阻害されることになり、製織性が、低下するため好まし
くない。If it is less than 0.01%, the effect of the present invention is difficult to appear, and if it is more than 1.0%, the effect of the warp sizing agent will be inhibited, and weavability will be reduced, which is not preferable. .
又、ガラス繊維織物の原反にＫＮＯ，溶液を処理する場
合のＫＮＯｓの量は、ガラス繊維織物に対する固形分重
量比でｏ、ｏｉ％以上、好ましくは０．１％以上が望ま
しい。０．０１％より低い場合は、本願発明の効果が不
充分となる。織物に対する処理方法としては、溶液に含
浸させる方法、ローラーコーテング方法、スプレー法等
いずれの方法でも可能である。尚、本明細書で原反とい
う場合は、製織揚りの織物で集束剤や経糸糊剤が付着し
た状態のものをいう。Further, when treating a raw glass fiber fabric with KNO and a solution, the amount of KNOs is desirably at least o, oi%, preferably at least 0.1%, based on the weight ratio of solids to the glass fiber fabric. If it is lower than 0.01%, the effect of the present invention will be insufficient. The textile may be treated by any method such as impregnating it in a solution, roller coating, or spraying. In this specification, the term "raw fabric" refers to a finished woven fabric to which a sizing agent or warp sizing agent is attached.
又、ガラス繊維織物にＫＮＯ３を含有させた場合、脱油
後に織物の表面にに２０が残ることになり、ガラス繊維
織物をプリント基板用やＦＲＰ用に使用した場合の電気
特性や吸水性に悪影響を与えることが懸念される。これ
に対しては、脱油工程の後の表面処理工程に於て、水洗
工程を入れるか、又は、表面処理槽でのオーバーフロー
を充分におこなうことによりに２０を除去することがで
きる。In addition, when glass fiber fabric contains KNO3, KNO3 remains on the surface of the fabric after oil removal, which adversely affects the electrical properties and water absorption when the glass fiber fabric is used for printed circuit boards or FRP. There is a concern that To deal with this, 20 can be removed by adding a water washing step in the surface treatment step after the oil removal step or by sufficiently overflowing the surface treatment tank.
〔実施例１］
（ｉ） ガラス繊維織物〔日東紡績（株）商品名ＷＥ
Ａ１８Ｗ）を製織するにあたり、ガラスヤーンＥＣＧ７
５１１０１Ｚを経糸として整経糊付し経糸ビームを作る
。[Example 1] (i) Glass fiber fabric [Nitto Boseki Co., Ltd. trade name WE]
A18W), glass yarn ECG7
51101Z is used as a warp thread and warp glued to make a warp thread beam.
経糸糊剤の組成は、
ＰＶＡ２０５ ３．０％
〔クラレ（株）製〕
コーンスターチ ２．０％
トメノリンＦ
〔松本油脂（株）製〕０．８％
ホルマリン ０．１％
ＫＮ０． ５．０％水 残
量
経糸糊剤の付着率は１．７％であった。The composition of the warp sizing agent is as follows: PVA205 3.0% [manufactured by Kuraray Co., Ltd.] Cornstarch 2.0% Tomenolin F [manufactured by Matsumoto Yushi Co., Ltd.] 0.8% Formalin 0.1% KN0. 5.0% water Remaining amount The adhesion rate of the warp sizing agent was 1.7%.
（ｉｉ）（ｉ）で作った経糸ビームを用い、エアシェン
ト織機によりガラス繊維織物ＷＥＡ１８Ｗを製織する。(ii) Using the warp beams made in (i), weave a glass fiber fabric WEA18W using an air stent loom.
（緯糸はガラスヤーンＥＣＧ７５ １１０ ＩＺを使
用）
［実施例２〕
ガラス繊維織物〔日東紡績（株）商品名ＷＥＡ１８Ｗ〕
の原反をＫＮＯ３水溶液（濃度１０％）中に浸漬して、
マングルで絞液後乾燥する。ＫＮＯ３の付着率は２゜０
％であった。(Glass yarn ECG75 110 IZ was used for the weft) [Example 2] Glass fiber fabric [Nittobo Co., Ltd. trade name WEA18W]
The original fabric was immersed in a KNO3 aqueous solution (concentration 10%),
Squeeze the liquid with a mangle and dry. The adhesion rate of KNO3 is 2゜0
%Met.
常法によりガラス繊維織物〔日東紡績（株）商品名ＷＥ
Ａ１８Ｗ）を製織。Glass fiber fabric (Nitto Boseki Co., Ltd. trade name: WE) by a conventional method
A18W) is woven.
■ 実施例及び比較例から得られたガラス繊維織物３種
類について夫々最適脱油条件を検討した結果、第１表に
示すような条件で脱油可能であることが判った。(2) As a result of examining the optimum deoiling conditions for each of the three types of glass fiber fabrics obtained from Examples and Comparative Examples, it was found that deoiling was possible under the conditions shown in Table 1.
■ ■で得られた脱油ガラス繊維織物を水洗処理後、エ
ポキシシランＡ−１８７［日本ユニカー味製〕で表面処
理。■ After washing the deoiled glass fiber fabric obtained in step (■) with water, the surface was treated with epoxy silane A-187 [manufactured by Nippon Unicar Aji].
■ Ｇ−１０組成のエポキシワニスに含浸し、プリプレ
グを作成、常法により厚さ１．６０の積層板を得た。(2) A prepreg was prepared by impregnating it with an epoxy varnish having a composition of G-10, and a laminate with a thickness of 1.60 mm was obtained using a conventional method.
■ ■で得られた３種類の積層板について（イ） 積層
板の色調
（ロ） 半田耐熱性
（ハ） 電気絶縁抵抗
を測定し第１表に示す。■ Regarding the three types of laminates obtained in (i), (a) Color tone of the laminate (b) Soldering heat resistance (c) Electrical insulation resistance was measured and shown in Table 1.
ガラス繊維織物の経糸糊剤中にＫＮＯ３を含ませること
により、又、ガラス繊維織物の原反をＫＮ（ｈ溶液で処
理することにより、ガラス繊維織物の加熱脱油時間を短
縮することが可能となった。その結果、脱油に要するエ
ネルギーコストの削減が可能となり、又、脱油時間の短
縮により、脱油工程の生産性を向上させることも可能と
なった。By incorporating KNO3 into the warp sizing agent for glass fiber fabrics, and by treating the original fabric of glass fiber fabrics with a KN(h solution), it is possible to shorten the heating deoiling time of glass fiber fabrics. As a result, it has become possible to reduce the energy cost required for deoiling, and it has also become possible to improve the productivity of the deoiling process by shortening the deoiling time.
Claims (2)
る経糸糊剤にＫＮＯ＿３を含有する経糸糊剤を用いるこ
とを特徴とするガラス繊維織物の製造方法。(1) A method for producing a glass fiber fabric, which comprises using a warp sizing agent containing KNO_3 as the warp sizing agent used during warping in the manufacturing process of the glass fiber woven fabric.
ことを特徴とするガラス繊維織物の製造方法。(2) A method for producing a glass fiber fabric, which comprises treating an original glass fiber fabric with a KNO_3 solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22526990A JPH04108167A (en) | 1990-08-29 | 1990-08-29 | Production of woven glass fiber fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22526990A JPH04108167A (en) | 1990-08-29 | 1990-08-29 | Production of woven glass fiber fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04108167A true JPH04108167A (en) | 1992-04-09 |
Family
ID=16826679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22526990A Pending JPH04108167A (en) | 1990-08-29 | 1990-08-29 | Production of woven glass fiber fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04108167A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851848A (en) * | 2012-09-27 | 2013-01-02 | 凤翔县玻璃纤维有限责任公司 | Novel glass fiber water jet loom weaving production line-dedicated facility |
-
1990
- 1990-08-29 JP JP22526990A patent/JPH04108167A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851848A (en) * | 2012-09-27 | 2013-01-02 | 凤翔县玻璃纤维有限责任公司 | Novel glass fiber water jet loom weaving production line-dedicated facility |
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