JPH04103667A - Saturated fatty acid glyceride composition - Google Patents
Saturated fatty acid glyceride compositionInfo
- Publication number
- JPH04103667A JPH04103667A JP22121890A JP22121890A JPH04103667A JP H04103667 A JPH04103667 A JP H04103667A JP 22121890 A JP22121890 A JP 22121890A JP 22121890 A JP22121890 A JP 22121890A JP H04103667 A JPH04103667 A JP H04103667A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- saturated fatty
- acid glyceride
- butyl
- monoglyceride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 13
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 phenol compound Chemical class 0.000 claims description 10
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims 1
- RNIILMHZBDEEDW-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)phenol Chemical compound CCOP(=O)(OCC)CC1=CC=C(O)C=C1 RNIILMHZBDEEDW-UHFFFAOYSA-N 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 abstract description 5
- 239000000314 lubricant Substances 0.000 abstract description 5
- 239000006082 mold release agent Substances 0.000 abstract description 5
- 150000002989 phenols Chemical class 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 abstract description 2
- 235000021355 Stearic acid Nutrition 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- 239000008117 stearic acid Substances 0.000 abstract description 2
- 125000001424 substituent group Chemical group 0.000 abstract description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 238000002845 discoloration Methods 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- GJDRKHHGPHLVNI-UHFFFAOYSA-N 2,6-ditert-butyl-4-(diethoxyphosphorylmethyl)phenol Chemical compound CCOP(=O)(OCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 GJDRKHHGPHLVNI-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、主としてプラスチックの滑剤、離型剤、帯電
防止剤あるいは流滴剤として用いられる飽和脂肪酸グリ
セリド組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a saturated fatty acid glyceride composition used primarily as a lubricant, mold release agent, antistatic agent or droplet agent for plastics.
（従来の技術および発明の課題）
プラスチックの滑剤、離型剤、帯電防止剤あるいは流滴
剤として用いられる飽和脂肪酸グリセリドは、他の配合
剤とともに加工前あるいは加工時にブレンドされ、押出
機、カレンダーロール、射出成型機等を使って成型され
る。しかし一般に加工温度が高いために、加工中に飽和
脂肪酸グリセリドが揮発し、効果不良を起こしたり、金
型汚染や環境汚染を生じたりして種々問題となっている
。(Prior art and problems to be solved by the invention) Saturated fatty acid glycerides used as lubricants, mold release agents, antistatic agents, or droplet agents for plastics are blended with other ingredients before or during processing, and are used in extruders, calender rolls, etc. , molded using an injection molding machine, etc. However, because the processing temperature is generally high, saturated fatty acid glycerides volatilize during processing, causing various problems such as poor effectiveness, mold contamination, and environmental pollution.
本発明は、上記の問題に鑑みてなされたものであり、そ
の目的は揮発性が低く滑剤、離型剤、帯電防止剤等とし
ての効果が発揮され、かつ金型汚染や環境汚染を生じな
い飽和脂肪酸グリセリド組成物を提供することでる。The present invention was made in view of the above-mentioned problems, and its purpose is to have low volatility, be effective as a lubricant, mold release agent, antistatic agent, etc., and not cause mold contamination or environmental pollution. A saturated fatty acid glyceride composition is provided.
（課題を解決するための手段および作用）従来から、不
飽和脂肪酸グリセリドにヒンダードフェノール系化合物
を添加することは、不飽和部位（二重結合）の自動酸化
防止あるいは加熱劣化防止の目的でよ〈実施されている
が、飽和脂肪酸グリセリドに揮発防止の目的でヒンダー
ドフェノール系化合物を添加する前例はない０本発明者
らは、プラスッチクの高温加工中の飽和脂肪酸グリセリ
ドが揮発することを防止する手段について。(Means and effects for solving the problem) Adding hindered phenol compounds to unsaturated fatty acid glycerides has traditionally been used for the purpose of preventing autooxidation or heat deterioration of unsaturated sites (double bonds). (Although this has been done, there is no precedent for adding hindered phenol compounds to saturated fatty acid glycerides for the purpose of preventing volatilization.) The present inventors have attempted to prevent saturated fatty acid glycerides from volatilizing during high-temperature processing of plastics. About the means.
鋭意検討したところ、飽和脂肪酸グリセリドにヒンダー
ドフェノール系化合物を均一に溶融混合したものがその
目的に適う組成物であることを見比し１本発明を完成す
るに至った。As a result of extensive research, it was determined that a composition in which a hindered phenol compound is uniformly melt-mixed with saturated fatty acid glyceride is a composition suitable for the purpose, and the present invention was completed.
即ち、本発明の要旨は「飽和脂肪酸グリセリドにヒンダ
ードフェノール系化合物を含有することを特徴とする飽
和脂肪酸グリセリド組成物」である。That is, the gist of the present invention is "a saturated fatty acid glyceride composition characterized by containing a hindered phenol compound in a saturated fatty acid glyceride."
本発明に用いる飽和脂肪酸グリセリドは炭素数１２〜２
２の飽和脂肪酸グリセリドである。即ちラウリン酸、ミ
リスチン酸、バルミチン酸、ステアリン酸、イソステア
リン酸、アラキシン酸、ベヘニン酸及び１２−ヒドロキ
システアリン酸のそれぞれ単独あるいは混合物をグリセ
リンとエステル化するか、もしくはこれらの脂肪酸から
なる油脂またはメチルエステルをグリセリンとエステル
交換し、さらに必要ならば、これらの反応物を高真空蒸
溜してモノグリセリドだけを採取することによって得ら
れる。そして、これらの飽和脂肪酸グリセリド中のモノ
グリセリドの含量は、５０〜１００％の範囲のものが好
ましい。５０％より低いと本来の機能である滑性、離型
性、帯電防止性あるいは流滴性が乏しくなって好ましく
ない、またモノグリセリド含量が５０％より低くなるこ
とは、不揮発性化合物のジグリセリド、トリグリセリド
の含量が多くなることにつながり、揮発防止効果の度合
が低くなり好ましくない。The saturated fatty acid glyceride used in the present invention has 12 to 2 carbon atoms.
2 saturated fatty acid glyceride. That is, lauric acid, myristic acid, valmitic acid, stearic acid, isostearic acid, araxic acid, behenic acid, and 12-hydroxystearic acid, each singly or as a mixture, are esterified with glycerin, or oils and fats or methyl esters made of these fatty acids are esterified with glycerin. is obtained by transesterifying with glycerin and, if necessary, distilling these reactants under high vacuum to collect only the monoglyceride. The monoglyceride content in these saturated fatty acid glycerides is preferably in the range of 50 to 100%. If the content is less than 50%, the original functions such as lubricity, mold release properties, antistatic properties, or droplet properties will become poor, which is undesirable.Moreover, if the monoglyceride content is less than 50%, it is not preferable that the monoglyceride content is less than 50%, which is due to the non-volatile compounds diglyceride and triglyceride. This leads to an increase in the content of , which is undesirable as it lowers the degree of volatilization prevention effect.
つぎに本発明に用いるヒンダードフェノール系化合物は
、オルト位に立体障害作用のある置換基（例えばｔｅｒ
ｔ−ブチル基）をもったアルキルフェノールであり、特
に限定されるものではないが具体的にはトリエチレング
リコール−ビス［３−（３−ｔ−ブチル−５−メチル−
４−ヒドロキシフェニル）プロピオネ−トコ、オクタデ
シル−３−（３，５−ジ−ｔ−ブチル−４−ヒドロキシ
フェニル）プロピオネートあるいは３．５−ジ−ｔ−ブ
チル−４−ヒドロキシベンジルフォスフォネート−ジエ
チルエステル等が好ましい、そしてヒンダードフェノー
ル系化合物の添加量は、飽和脂肪酸グリセリドに対して
０．０５〜２．０％の範囲が好ましい、０．０５％より
少ないと揮発防止効果が乏しくなる。また２、０％より
多く使用しても、揮発防止効果は１．５％〜２．０％の
ものと大差なく、むしろ着色したり、配合コストを上昇
させたりするので好ましくない。Next, the hindered phenol compound used in the present invention has a substituent having a steric hindrance effect at the ortho position (for example, ter
It is an alkylphenol having a t-butyl group), and is not particularly limited, but specifically, triethylene glycol-bis[3-(3-t-butyl-5-methyl-
4-hydroxyphenyl)propionate, octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate or 3,5-di-t-butyl-4-hydroxybenzylphosphonate-diethyl Ester and the like are preferred, and the amount of the hindered phenol compound added is preferably in the range of 0.05 to 2.0% based on the saturated fatty acid glyceride.If it is less than 0.05%, the volatilization prevention effect will be poor. Moreover, even if it is used in an amount of more than 2.0%, the volatilization prevention effect is not much different from that of 1.5% to 2.0%, but rather it causes coloring and increases the formulation cost, which is not preferable.
なお飽和脂肪酸グリセリドとヒンダードフェノール系化
合物との組み合わせによっては、強く着色する場合があ
り、このような時にはリン系化合物（例えばトリス（ノ
ニルフェニル）ホスファイト）を併用すれば着色は防止
できる。Note that depending on the combination of saturated fatty acid glyceride and hindered phenol compound, strong coloring may occur, and in such cases, coloring can be prevented by using a phosphorus compound (for example, tris(nonylphenyl) phosphite) in combination.
以下実施例に基づいて本発明を説明を説明する。The present invention will be explained below based on Examples.
（実施例）
（１）第１表に示す組成のものを１００℃で１０分間加
熱撹拌し、その後固化させたものを試験用サンプルとし
た。(Example) (1) The composition shown in Table 1 was heated and stirred at 100° C. for 10 minutes, and then solidified to be used as a test sample.
第１表において飽和脂肪酸グリセリドは次のとおりであ
る。In Table 1, the saturated fatty acid glycerides are as follows.
Ａニステアリン酸モノグリセリド（モノグリセリド純度
＝９６％）
Ｂニステアリン酸モノ、ジグリセリド（モノグリセリド
純度＝５２％）
Ｃ：ベヘニン酸モノグリセリド（モノグリセリド純度＝
９３％
Ｄ：１２ヒドロキシステアリン酸モノグリセリド（モノ
グリセリド純度＝９３％）
第１表においてヒンダードフェノール系化合物は次のと
おりである。A: Nystearic acid monoglyceride (monoglyceride purity = 96%) B: Nystearic acid mono-, diglyceride (monoglyceride purity = 52%) C: Behenic acid monoglyceride (monoglyceride purity =
93% D: 12-hydroxystearic acid monoglyceride (monoglyceride purity = 93%) In Table 1, the hindered phenol compounds are as follows.
ａニトリエチレングリコール−ビス［３−（３−ｔ−ブ
チル−５−メチル−４−ヒドロキシフェニル）プロピオ
ネート］
ｂ＝ニオフタデシル３−（３，５〜ジーｔ−ブチル−４
−ヒドロキシフェニル）プロピオネート
Ｃ：３．５−ジー上ブチル−４−ヒドロキシベンジルフ
オスフオネートージエチルエステル
であり、同表のその他はトリスノニルフェニルフォスフ
ェートである。a Nitriethylene glycol-bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate] b = Niophtadecyl 3-(3,5-di-t-butyl-4
-Hydroxyphenyl)propionate C: 3.5-di-butyl-4-hydroxybenzyl phosphonate diethyl ester; others in the same table are trisnonylphenyl phosphate.
（２）第１表の各サンプル３０ｇを、内径５ｃｍ高さ７
■のビーカーに精秤し、イーヤ−オーブン中で、１８０
℃および２３０℃で、３０分および６０分間加熱し、各
サンプルの揮発減量、着色度並びにモノグリセリド純度
を測定した。その結果を第２表に示す。(2) Take 30g of each sample in Table 1 and
Weigh it accurately in a beaker and place it in an oven at 180℃.
The samples were heated at 230°C and 230°C for 30 and 60 minutes, and the loss of volatile matter, degree of coloration, and monoglyceride purity of each sample were measured. The results are shown in Table 2.
（３）ポリプロピレン（ｐｐ）樹脂（三井石油化学製ハ
イボールＪ−３００）に、第１表に示した各サンプルを
、樹脂１００部に対し５部の割合で添加し、ラボプラス
トミルＴ台押出機（成型温度二Ｔｌ／Ｔ２／Ｔ３／ダイ
ス−１５０℃／１７０℃７２００℃７２３０℃）を使用
して、厚さ０．０２〜０．０３ｎｎのフィルムを作成し
た。(3) Add each sample shown in Table 1 to polypropylene (PP) resin (Mitsui Petrochemical Highball J-300) at a ratio of 5 parts to 100 parts of the resin, and extrude it on the Labo Plastomill T-stand. A film having a thickness of 0.02 to 0.03 nn was produced using a molding machine (molding temperature: 2 Tl/T2/T3/Dice: 150°C/170°C, 7200°C, 7230°C).
１検体につき６０分間連続運転し、ダイス出口近傍上側
に取付けた鏡面の汚れ度合並びにフィルムの着色度を観
察した。その結果を第３表に示す。Each sample was operated continuously for 60 minutes, and the degree of dirt on the mirror surface attached above the die exit and the degree of coloration of the film were observed. The results are shown in Table 3.
本発明品１〜３と比較量１〜２、本発明品４と比較量３
、本発明品５と比較量４および本発明品６と比較量５の
対比において、第２表の１８０℃および２３０℃におけ
る揮発減量は、いずれも本発明品の方が半量以下と低く
なっている。また第３表のＰＰの加工試験においても、
いずれも本発明品の方が鏡面の汚れが少なくなっている
ことが明らかである。Inventive products 1 to 3 and comparative amounts 1 to 2, inventive products 4 and comparative amount 3
Comparing Inventive Product 5 with Comparative Amount 4 and Inventive Product 6 with Comparative Amount 5, the volatilization loss at 180°C and 230°C in Table 2 was lower for the Inventive Product at less than half the amount. There is. Also, in the PP processing test shown in Table 3,
In both cases, it is clear that the product of the present invention has less dirt on the mirror surface.
（発明の効果）
本発明によれば、飽和脂肪酸グリセリドの揮発減量が少
なく、滑剤、離型剤、帯電防止剤あるいは流滴剤として
の効果が発揮され、かつ金型汚染や環境汚染を生じない
ので、その実用上の価値は大なるものがある。(Effects of the Invention) According to the present invention, the volatilization loss of saturated fatty acid glyceride is small, and the effect as a lubricant, mold release agent, antistatic agent, or droplet agent is exhibited, and no mold contamination or environmental pollution occurs. Therefore, its practical value is great.
Claims (4)
化合物を含有することを特徴とする飽和脂肪酸グリセリ
ド組成物。(1) A saturated fatty acid glyceride composition characterized by containing a hindered phenol compound in the saturated fatty acid glyceride.
、５０〜１００％である請求項（１）記載の飽和脂肪酸
グリセリド組成物。(2) The saturated fatty acid glyceride composition according to claim 1, wherein the monoglyceride content in the saturated fatty acid glyceride is 50 to 100%.
リコール−ビス［３−（３−ｔ−ブチル−５−メチル−
４−ヒドロキシフェニル）プロピオネート］、オクタデ
シル−３−（３、５−ジ−ｔ−ブチル−４−ヒドロキシ
フェニル）プロピオネート、３、５−ジ−ｔ−ブチル−
４−ヒドロキシベンジルフォスフォネート−ジエチルエ
ステルのうち何れか一つ以上である請求項（１）記載の
飽和脂肪酸グリセリド組成物。(3) The hindered phenol compound is triethylene glycol-bis[3-(3-t-butyl-5-methyl-
4-hydroxyphenyl)propionate], octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate, 3,5-di-t-butyl-
The saturated fatty acid glyceride composition according to claim 1, which is any one or more of 4-hydroxybenzylphosphonate-diethyl ester.
セリドに対して０．０５〜２．０％の割合で含有する請
求項（１）記載の飽和脂肪酸グリセリド組成物。(4) The saturated fatty acid glyceride composition according to claim 1, wherein the hindered phenol compound is contained in a proportion of 0.05 to 2.0% based on the saturated fatty acid glyceride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22121890A JPH04103667A (en) | 1990-08-24 | 1990-08-24 | Saturated fatty acid glyceride composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22121890A JPH04103667A (en) | 1990-08-24 | 1990-08-24 | Saturated fatty acid glyceride composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04103667A true JPH04103667A (en) | 1992-04-06 |
Family
ID=16763317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22121890A Pending JPH04103667A (en) | 1990-08-24 | 1990-08-24 | Saturated fatty acid glyceride composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04103667A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6117922A (en) * | 1997-03-21 | 2000-09-12 | Clariant Gmbh | Solid, storage-stable antistat mixtures and process for their preparation |
-
1990
- 1990-08-24 JP JP22121890A patent/JPH04103667A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6117922A (en) * | 1997-03-21 | 2000-09-12 | Clariant Gmbh | Solid, storage-stable antistat mixtures and process for their preparation |
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