JPH0391518A - Unsaturated polyester resin molding material - Google Patents
Unsaturated polyester resin molding materialInfo
- Publication number
- JPH0391518A JPH0391518A JP22758889A JP22758889A JPH0391518A JP H0391518 A JPH0391518 A JP H0391518A JP 22758889 A JP22758889 A JP 22758889A JP 22758889 A JP22758889 A JP 22758889A JP H0391518 A JPH0391518 A JP H0391518A
- Authority
- JP
- Japan
- Prior art keywords
- unsaturated polyester
- flash point
- molding material
- polyester resin
- resin molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012778 molding material Substances 0.000 title claims abstract description 39
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims description 30
- 239000000178 monomer Substances 0.000 claims abstract description 29
- 229920006305 unsaturated polyester Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 4
- 230000002787 reinforcement Effects 0.000 claims abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000383 hazardous chemical Substances 0.000 abstract description 3
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- -1 allyl isocyanurate Chemical compound 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ROLAGNYPWIVYTG-UHFFFAOYSA-N 1,2-bis(4-methoxyphenyl)ethanamine;hydrochloride Chemical compound Cl.C1=CC(OC)=CC=C1CC(N)C1=CC=C(OC)C=C1 ROLAGNYPWIVYTG-UHFFFAOYSA-N 0.000 description 1
- HGOUNPXIJSDIKV-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl 2-methylprop-2-enoate Chemical compound CCC(CO)(CO)COC(=O)C(C)=C HGOUNPXIJSDIKV-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- LYJHVEDILOKZCG-UHFFFAOYSA-N Allyl benzoate Chemical compound C=CCOC(=O)C1=CC=CC=C1 LYJHVEDILOKZCG-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004412 Bulk moulding compound Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000003677 Sheet moulding compound Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012772 electrical insulation material Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は引火点の高い不飽和ポリエステル樹脂成形材料
に関するもので、詳しくは、引火点が４０℃以上で引火
しにくい不飽和ポリエステル樹脂成形材料に関するもの
である。Detailed Description of the Invention (Industrial Field of Application) The present invention relates to an unsaturated polyester resin molding material with a high flash point, and more specifically, an unsaturated polyester resin molding material with a flash point of 40° C. or higher and which is difficult to catch fire. It is related to.
（従来の技術）
不飽和ポリエステル樹脂はタンク、波板、パイプ、バス
タブなどの強化プラスチックを始め化粧板、塗料、電気
絶縁材料などに広く利用されている。(Prior Art) Unsaturated polyester resins are widely used in reinforced plastics such as tanks, corrugated sheets, pipes, and bathtubs, decorative boards, paints, and electrical insulation materials.
不飽和ポリエステル樹脂成形材料としては、−般にプリ
ミックス、バルクモールディングコンパウンド、シート
モールデイングコンパウンドなどとして知られており、
自動車部品、建築資材、電気部品、精密部品などの用途
に広く利用されている。Unsaturated polyester resin molding compounds are generally known as premixes, bulk molding compounds, sheet molding compounds, etc.
It is widely used in applications such as automobile parts, construction materials, electrical parts, and precision parts.
ところが、不飽和ポリエステル樹脂成形材料には架橋剤
として添加されている重合性単量体の引火点はスチレン
モノマーの如く、一般に低いものが多く使用されている
。However, many polymerizable monomers added as crosslinking agents to unsaturated polyester resin molding materials generally have low flash points, such as styrene monomers.
従って不飽和ポリエステル樹脂成形材料の引火点は３２
−４０℃である。Therefore, the flash point of unsaturated polyester resin molding material is 32
-40°C.
しかし、昭和６３年Ｓ月２４日（法律第５５号）公布さ
れ、平成２年５月２３８施行される予定の消防法による
と、不飽和ポリエステル樹脂成形材料は第２類可燃性固
体で、固形アルコール、その他−気圧において、引火点
が４０℃未満と規定している引火性固体に該当する恐れ
がある。However, according to the Fire Service Act, which was promulgated on S. 24, 1988 (Law No. 55) and is scheduled to come into force on May 238, 1990, unsaturated polyester resin molding materials are class 2 flammable solids, and solid Alcohol and others - At atmospheric pressure, there is a possibility that it falls under the category of flammable solids, which are stipulated to have a flash point of less than 40°C.
もし、引火性固体に該当し、その規制を受けることにな
ると、不飽和ポリエステル樹脂成形材料の貯蔵や取扱い
について、大幅な規制を受けることになる。If it falls under the category of flammable solid and is subject to such regulations, the storage and handling of unsaturated polyester resin molding materials will be subject to significant regulations.
不飽和ポリエステル樹脂成形材料で前記した成形品を成
形する成形メーカーや不飽和ポリエステル樹脂成形材料
を貯蔵する倉庫業者は法律で定められた取り扱い基準を
守るために、莫大な設備投資をしなければならず、大き
な負担となるばかりでなく、成形品の大幅なコストアッ
プをもたらす。Molding manufacturers who mold the above-mentioned molded products using unsaturated polyester resin molding materials and warehouse operators who store unsaturated polyester resin molding materials must make huge capital investments in order to comply with the handling standards stipulated by law. This not only creates a large burden, but also significantly increases the cost of the molded product.
（発明が解決しようとする課題）
本発明の目的は前記の従来技術の欠点を除去して、引火
点を消防法の危険物の指定を受けない４０℃以上にした
成形性良好な不飽和ポリエステル樹脂成形材料を提供す
ることにある。(Problems to be Solved by the Invention) The purpose of the present invention is to eliminate the drawbacks of the above-mentioned prior art, and to produce an unsaturated polyester with good moldability that has a flash point of 40°C or higher, which is not designated as a hazardous material by the Fire Service Act. Our objective is to provide resin molding materials.
（課題を解決するための手段）
本発明は、
（Ａ） 不飽和ポリエステル５〜２０重量％、（Ｂ）
重合性単量体５〜２０重量％、（Ｃ） 充填剤４
０〜７５重量％。(Means for Solving the Problems) The present invention comprises: (A) 5 to 20% by weight of unsaturated polyester; (B)
Polymerizable monomer 5 to 20% by weight, (C) filler 4
0-75% by weight.
（Ｄ） 低収縮剤０〜１０重量％及び（Ｅ） 繊維
状補強材５〜３０重量％からなる成形材料において、重
合性単量体として引火点４０℃以下の単量体を成形材料
中８重量％以下で且つ引火点４０”Ｃより高い単量体を
成形材料中１〜２０重量％の範囲で用いることを特徴と
する引火点が４０℃以上である不飽和ポリエステル樹脂
成形材料である。In a molding material consisting of (D) 0 to 10% by weight of a low shrinkage agent and (E) 5 to 30% by weight of a fibrous reinforcing material, a monomer with a flash point of 40°C or lower is contained as a polymerizable monomer in the molding material. This is an unsaturated polyester resin molding material having a flash point of 40"C or higher, characterized in that a monomer with a flash point higher than 40"C is used in the molding material in an amount of 1 to 20% by weight.
本発明者らは不飽和ポリエステル樹脂成形材料中に、含
有する引火点４０”Ｃ以下の共重合性単量体が８％以下
であれば不飽和ポリエステル樹脂成形材料の引火点は４
０℃以上となり、危険物の第２類可燃性固体の引火性固
体に該当せず、その取扱いが大幅に緩和されることを見
出だした。The present inventors believe that if the unsaturated polyester resin molding material contains 8% or less of a copolymerizable monomer with a flash point of 40"C or less, the flash point of the unsaturated polyester resin molding material is 4.
It has been found that the temperature reaches 0°C or higher, and it does not fall under the class 2 flammable solids of dangerous substances, which greatly eases its handling.
しかし、引火点４０℃以下の共重合性単量体を８％以下
にした不飽和ポリエステル樹脂成形材料は非常に固く、
金型に入れて成形する時に、高い成形圧力を必要とする
ばかりでなく、不飽和ポリエステル樹脂成形材料の流動
性が悪く、欠陥のない成形品は出来ない０本発明者らは
、更に、引火点が４０℃以上で、不飽和ポリエステルと
共重合性のある単量体を併用することにより、不飽和ポ
リエステル樹脂成形材料の流動性を改良し、更に。However, unsaturated polyester resin molding materials containing 8% or less of copolymerizable monomers with a flash point of 40°C or lower are extremely hard.
In addition to requiring high molding pressure when molding in a mold, the fluidity of the unsaturated polyester resin molding material is poor, making it impossible to mold a defect-free molded product. By using a copolymerizable monomer with an unsaturated polyester at a temperature of 40°C or higher, the fluidity of the unsaturated polyester resin molding material is improved.
不飽和ポリエステル樹脂成形材料の引火点を４０℃以上
に上げることを合わせて見出だし１本発明に至ったので
ある。Together with raising the flash point of the unsaturated polyester resin molding material to 40° C. or higher, the present invention under the heading 1 was achieved.
本発明で使用される不飽和ポリエステルは酸成分と多価
アルコールとを、常法により、重縮合反応させることに
より得られる。The unsaturated polyester used in the present invention can be obtained by subjecting an acid component and a polyhydric alcohol to a polycondensation reaction using a conventional method.
酸成分である不飽和多塩基酸としては１例えば無水マレ
イン酸、フマル酸、イタコン酸等が使用される。As the unsaturated polybasic acid which is the acid component, for example, maleic anhydride, fumaric acid, itaconic acid, etc. are used.
また、所望により酸成分として、併用される飽和多塩基
酸としては、無水フタル酸、イソフタル酸、テレフタル
酸、コハク酸、アジピン酸等が使用される。Further, as the saturated polybasic acid used in combination as an acid component if desired, phthalic anhydride, isophthalic acid, terephthalic acid, succinic acid, adipic acid, etc. are used.
一方、多価アルコールとしてはエチレングリコール、プ
ロピレングリコール、ネオペンチルグリコール、ビスフ
ェノールＡ１等の単独又は２〜３種類の併用で使用され
る。On the other hand, as the polyhydric alcohol, ethylene glycol, propylene glycol, neopentyl glycol, bisphenol A1, etc. are used alone or in combination of two or three types.
本発明に使用される共重合性単量体としては、メチルメ
タクリレート、酢酸ビニル、スチレンモノマーなどが使
用されるが、最も安価で、反応性に富み、最も優れた共
重合性単量体として、広くスチレンモノマーが使用され
ている。As the copolymerizable monomer used in the present invention, methyl methacrylate, vinyl acetate, styrene monomer, etc. are used, but as the cheapest, most reactive, and most excellent copolymerizable monomer, Styrene monomers are widely used.
しかし、スチレンモノマーの引火点は３２℃であり、ま
た不飽和ポリエステル樹脂成形材料に含まれるスチレン
モノマーの量は普通８％以上であるため、不飽和ポリエ
ステル樹脂成形材料の引火点は４０℃以下となる。However, the flash point of styrene monomer is 32°C, and the amount of styrene monomer contained in unsaturated polyester resin molding materials is usually 8% or more, so the flash point of unsaturated polyester resin molding materials is 40°C or lower. Become.
充填剤としては、炭酸力ルシュウム、クレー水酸化アル
ミニュウム、硫酸バリウム、などの無機化合物がある。Examples of fillers include inorganic compounds such as lucium carbonate, clay aluminum hydroxide, and barium sulfate.
低収縮剤としては、ポリスチレン、ポリ酢酸ビニル、ポ
リメタクリル酸メチル、飽和ポリエステル、あるいはポ
リブタジェン−スチレン共重合物等が使用される。As the low shrinkage agent, polystyrene, polyvinyl acetate, polymethyl methacrylate, saturated polyester, polybutadiene-styrene copolymer, etc. are used.
繊維状補強材としては、ガラス繊維や合成繊維等が使用
されている。Glass fibers, synthetic fibers, etc. are used as the fibrous reinforcing material.
本発明の不飽和ポリエステル樹脂成形材料には、上記し
た各成分の他に、硬化の為に通常用いられるジ−ｔ−ブ
チルパーオキサイド、ジクミルパーオキサイド、ラウロ
イルパーオキサイド等の公知の硬化剤が使用される。In addition to the above-mentioned components, the unsaturated polyester resin molding material of the present invention contains known curing agents such as di-t-butyl peroxide, dicumyl peroxide, and lauroyl peroxide, which are commonly used for curing. used.
また、必要に応じて、ステアリン酸亜鉛、ステアリン酸
カルシュウム、ステアリン酸アルミニュウムの如き内部
離型剤、ハイドロキノン、ｐ−ベンゾキノン、ｔ−ブチ
ルカテコールなどの安定剤、酸化マグネシュウム、水酸
化カルシュラムなどの増粘剤、各種の着色剤などの公知
の添加剤を配合しても差し支えない。In addition, if necessary, internal mold release agents such as zinc stearate, calcium stearate, and aluminum stearate, stabilizers such as hydroquinone, p-benzoquinone, and t-butylcatechol, and thickeners such as magnesium oxide and calcium hydroxide may be added. Known additives such as coloring agents and various coloring agents may be added.
本発明の目的は４０℃以下の引火点の共重合性単量体を
８％以下とし、その時に出てくる不飽和ポリエステル樹
脂成形材料の流動性不良を、４０℃以上の共重合性単量
体を加えることにより改善し、不飽和ポリエステル樹脂
成形材料の引火点を４０℃以上にすることにあるが、本
発明の目的を達成する為に使用する引火点が４０℃以上
の共重合性単量体としては、アリルアルコールから誘導
されるもので、マレイン酸ジアリル、アジピン酸ジアリ
ル、安息香酸アリル、ジアリルフタレート（１６６℃引
火点、以下同じ）、ジアリルイソフタレート（３４０℃
）、イソシアヌル酸アリル等がある。また、ビニルトル
エン（１７１℃）、α−メチルスチレン（１６５℃）な
どのスチレン誘導体、トリメチロールプロパンメタクリ
レート（１８１’Ｃ）などのメタクリル酸やアクリル酸
のエステル化合物等が挙げられ、これらの単独又は２〜
３種を併用することも出来る。The purpose of the present invention is to reduce the amount of copolymerizable monomers with a flash point of 40°C or lower to 8% or less, and to reduce the poor flowability of the unsaturated polyester resin molding material produced at that time. The objective of the present invention is to improve the flash point of the unsaturated polyester resin molding material by adding a polymer to 40°C or higher. The polymers are those derived from allyl alcohol, including diallyl maleate, diallyl adipate, allyl benzoate, diallyl phthalate (flash point 166°C, same hereinafter), diallyl isophthalate (340°C).
), allyl isocyanurate, etc. Other examples include styrene derivatives such as vinyltoluene (171°C) and α-methylstyrene (165°C), ester compounds of methacrylic acid and acrylic acid such as trimethylolpropane methacrylate (181'C), and these may be used alone or 2～
It is also possible to use three types in combination.
云うまでもなく引火点が４０℃以上の上記共重合性単量
体の量を増加させると不飽和ポリエステル樹脂成形材料
の引火点は上昇し、本目的を達成するが、コスト高にな
ったり品質が過剰になるなど、やや汎用性に欠ける点が
出てくる。Needless to say, if the amount of the copolymerizable monomer with a flash point of 40°C or higher is increased, the flash point of the unsaturated polyester resin molding material will be increased, and this objective will be achieved, but the cost will increase and the quality will deteriorate. There are some points where it lacks versatility, such as excessive numbers.
実施例 実施例を挙げ具体的に、本発明を説明する。Example The present invention will be specifically explained with reference to Examples.
０）不飽和ポリエステルの合成
ネオペンチルグリコール５５モル、プロピレングリコー
ル５５モル、イソフタル酸２０モル、フマル酸８０モル
を二段反応で常法により、エステル化反応を行い、反応
の末期にハイドロキノン０．０３部を入れて、酸価３８
ＫＯＨ■／ｇの不飽和ポリエステルを合成した。0) Synthesis of unsaturated polyester 55 moles of neopentyl glycol, 55 moles of propylene glycol, 20 moles of isophthalic acid, and 80 moles of fumaric acid were subjected to an esterification reaction using a conventional method in a two-step reaction, and at the end of the reaction, 0.03 moles of hydroquinone was added. acid value 38
An unsaturated polyester of KOH/g was synthesized.
（２）不飽和ポリエステル樹脂成形材料の製法不飽和ポ
リエステル、低収縮剤、引火点が４０℃以下の共重合性
単量体、引火点が４０℃以上の共重合性単量体、硬化剤
、内部離型剤、顔料をニーダ−に入れ、４０分混練りし
、パテ化させる。(2) Manufacturing method of unsaturated polyester resin molding material Unsaturated polyester, low shrinkage agent, copolymerizable monomer with a flash point of 40°C or lower, copolymerizable monomer with a flash point of 40°C or higher, curing agent, Put the internal mold release agent and pigment into a kneader and knead for 40 minutes to form a putty.
その後ガラス繊維を加え、１０分間混練りして仕上げて
、成形性や引火点測定の供試体とした。Thereafter, glass fiber was added and the mixture was kneaded for 10 minutes to complete the mixture, and it was used as a specimen for moldability and flash point measurements.
（３）不飽和ポリエステル樹脂成形材料の成形性テスト
法
長さ４０ｃｍＸ幅２０ｃｍＸ厚み５ａｎの平板が成形で
きる金型を１００トンのプレスに取りつけて、下記の条
件で成形を行い、目視で成形品に欠陥がないかを確認し
、流動性が悪く成形品にピンホール等が出来て、充填不
良となったものを不可とした。(3) Moldability test method for unsaturated polyester resin molding material A mold capable of forming a flat plate of length 40 cm x width 20 cm x thickness 5 ann was attached to a 100 ton press, molding was performed under the following conditions, and the molded product was visually inspected. We checked to see if there were any defects, and those with poor fluidity and pinholes in the molded products, resulting in poor filling, were rejected.
金型温度 上型１５０℃ 下型１４５℃成形圧力
５０ ｋｇ／ａＪ
（４）不飽和ポリエステル樹脂成形材料の引火点測定
今回改正される消防法に定められたセメ密閉式引火点測
定器を用いて引火点を測定した。Mold temperature Upper mold 150℃ Lower mold 145℃ Molding pressure
50 kg/aJ (4) Measurement of flash point of unsaturated polyester resin molding material The flash point was measured using a sealed flash point measuring device specified in the Fire Service Act, which is being revised this time.
（５）評価結果
上記の製法で、各配合の不飽和ポリエステル樹脂成形材
料を作り成形性テストと引火点測定を行った結果を第１
表に示す。(5) Evaluation results Using the above manufacturing method, unsaturated polyester resin molding materials of various formulations were made and moldability tests and flash point measurements were conducted.
Shown in the table.
尚、本発明は上述の実施例の不飽和ポリエステルの組成
や引火点４０℃以下の共重合性単量体や引火点４０℃以
上の共重合性単量体の種類に限定されるものでないこと
を申し述べる。It should be noted that the present invention is not limited to the composition of the unsaturated polyester of the above-mentioned examples or the type of copolymerizable monomer with a flash point of 40°C or lower or a copolymerizable monomer with a flashpoint of 40°C or higher. I state this.
（発明の効果）
本発明の不飽和ポリエステル樹脂成形材料は消防法で定
めた危険物に該当しない。(Effects of the Invention) The unsaturated polyester resin molding material of the present invention does not fall under the category of hazardous materials defined by the Fire Service Act.
Claims (1)
性単量体５〜２０重量％。 （Ｃ）充填剤４０〜７５重量％、 （Ｄ）低収縮剤０〜１０重量％及び （Ｅ）繊維状補強材５〜３０重量％ からなる成形材料において、重合性単量体として引火点
４０℃以下の単量体を成形材料中８重量％以下で且つ引
火点４０℃より高い単量体を成形材料中１〜２０重量％
の範囲で用いることを特徴とする引火点が４０℃以上で
ある不飽和ポリエステル樹脂成形材料。[Scope of Claims] (A) 5 to 20% by weight of unsaturated polyester, (B) 5 to 20% by weight of polymerizable monomer. In a molding material consisting of (C) 40 to 75% by weight of filler, (D) 0 to 10% by weight of low shrinkage agent, and (E) 5 to 30% by weight of fibrous reinforcement, the polymerizable monomer has a flash point of 40%. 8% by weight or less of monomers with a temperature below 40°C in the molding material, and 1 to 20% by weight of monomers with a flash point higher than 40°C in the molding material.
An unsaturated polyester resin molding material having a flash point of 40°C or higher, characterized in that it is used within the range of 40°C or higher.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22758889A JPH0391518A (en) | 1989-09-04 | 1989-09-04 | Unsaturated polyester resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22758889A JPH0391518A (en) | 1989-09-04 | 1989-09-04 | Unsaturated polyester resin molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0391518A true JPH0391518A (en) | 1991-04-17 |
Family
ID=16863274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22758889A Pending JPH0391518A (en) | 1989-09-04 | 1989-09-04 | Unsaturated polyester resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0391518A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03192108A (en) * | 1989-12-21 | 1991-08-22 | Matsushita Electric Works Ltd | Unsaturated polyester resin molding material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51103994A (en) * | 1975-03-12 | 1976-09-14 | Dainippon Ink & Chemicals | FUHOWAHORIESUTERUJUSHISOSEIBUTSU |
| JPS5421491A (en) * | 1977-07-20 | 1979-02-17 | Mitsubishi Petrochem Co Ltd | Curable solid unsaturated polyester resin |
| JPS55144014A (en) * | 1979-04-02 | 1980-11-10 | Hitachi Chem Co Ltd | Unsaturated polyester resin composition for casting electrical equipment |
| JPS56152820A (en) * | 1979-11-13 | 1981-11-26 | Union Carbide Corp | Improved polyester formed article |
| JPS60235820A (en) * | 1984-05-09 | 1985-11-22 | Hitachi Chem Co Ltd | Curable resin composition |
-
1989
- 1989-09-04 JP JP22758889A patent/JPH0391518A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51103994A (en) * | 1975-03-12 | 1976-09-14 | Dainippon Ink & Chemicals | FUHOWAHORIESUTERUJUSHISOSEIBUTSU |
| JPS5421491A (en) * | 1977-07-20 | 1979-02-17 | Mitsubishi Petrochem Co Ltd | Curable solid unsaturated polyester resin |
| JPS55144014A (en) * | 1979-04-02 | 1980-11-10 | Hitachi Chem Co Ltd | Unsaturated polyester resin composition for casting electrical equipment |
| JPS56152820A (en) * | 1979-11-13 | 1981-11-26 | Union Carbide Corp | Improved polyester formed article |
| JPS60235820A (en) * | 1984-05-09 | 1985-11-22 | Hitachi Chem Co Ltd | Curable resin composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03192108A (en) * | 1989-12-21 | 1991-08-22 | Matsushita Electric Works Ltd | Unsaturated polyester resin molding material |
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