JPH0387285A - Material for seal composed of organic porous material and preparation thereof - Google Patents
Material for seal composed of organic porous material and preparation thereofInfo
- Publication number
- JPH0387285A JPH0387285A JP22526089A JP22526089A JPH0387285A JP H0387285 A JPH0387285 A JP H0387285A JP 22526089 A JP22526089 A JP 22526089A JP 22526089 A JP22526089 A JP 22526089A JP H0387285 A JPH0387285 A JP H0387285A
- Authority
- JP
- Japan
- Prior art keywords
- org
- porous material
- polymer
- wood
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 30
- 239000011148 porous material Substances 0.000 title claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 19
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000001704 evaporation Methods 0.000 claims abstract description 3
- 230000008020 evaporation Effects 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002023 wood Substances 0.000 abstract description 14
- 238000007789 sealing Methods 0.000 abstract description 3
- 230000000704 physical effect Effects 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 241001116498 Taxus baccata Species 0.000 abstract 1
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 241000218691 Cupressaceae Species 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- -1 2-hydroxypropyl Chemical group 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000004415 Burchellia bubalina Nutrition 0.000 description 1
- 240000008537 Burchellia bubalina Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
この発明は、木材、木質材及び動物性有機多孔質材の如
き有機質の多孔性材料からなる印材並びにその製造方法
に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a stamp material made of an organic porous material such as wood, wood material, and animal organic porous material, and a method for manufacturing the same.
(従来の技術)
従来、印判を作るための印材は、印面の硬度が均一であ
ることが要求され、特に、機械による印刻を行う場合、
印面の硬度が均一でないと、柔い部分において印刻用の
刃物がスペルため正確な印刻を行うことが出来なかった
。このため、従来は印面の硬度が均一な象牙や水牛の角
等の動物の骨材或は木材としては柘植が一般に用いられ
ている。(Prior Art) Conventionally, stamp materials for making stamps are required to have uniform hardness on the stamp surface, especially when stamping is done by machine.
If the hardness of the stamp surface was not uniform, the knife for stamping would not be able to make accurate stamps on the soft parts. For this reason, conventionally, Tsuge is generally used as animal aggregate or wood such as ivory or buffalo horn, which has a uniform hardness on the stamp surface.
しかしながら、これらの印材は、いずれも現在原材料が
不足し、入手が困難な現状にある為、これらの印材に代
る印材の開発が要望されている。However, since raw materials for all of these stamp materials are currently in short supply and difficult to obtain, there is a demand for the development of a stamp material to replace these stamp materials.
(発明が解決しようとする課題〉
この発明は、従来の印材に代る印材を開発せんとするも
のであり、特に従来年輪があり、硬度が均一でない木材
や木質材或は動物性有機多孔質材等を印材として利用可
能とせんとするものである。(Problems to be Solved by the Invention) This invention aims to develop a stamp material to replace conventional stamp materials, and in particular, it is an object of the present invention to develop a stamp material that can replace conventional stamp materials. The purpose is to make it possible to use materials such as wood as stamp materials.
(課題を解決するための手段)
上記課題を解決するために、第1の発明が採った手段は
、有機多孔質材料に、重合触媒を含有せる高分子含浸剤
を含浸させて高分子硬化させ、材料の微細孔を封孔、密
閉したことを特徴とする。(Means for Solving the Problem) In order to solve the above problem, the first invention adopts a method of impregnating an organic porous material with a polymer impregnating agent containing a polymerization catalyst and curing the polymer. , characterized by sealing and sealing the micropores of the material.
又、第2の発明は、第1の発明の印材を製造するための
方法であって、有機多孔質材料に重合触媒を含有する高
分子含浸剤を含浸させた後、高分子含浸剤の蒸発を防止
しつつ高分子硬化させることを特徴とする。A second invention is a method for manufacturing the stamp material of the first invention, which comprises impregnating an organic porous material with a polymeric impregnating agent containing a polymerization catalyst, and then evaporating the polymeric impregnating agent. It is characterized by curing the polymer while preventing it.
本発明において用いる高分子含浸剤としては、アクリル
酸又はメタクリル酸のメチル、エチル、ブチル、2−ヒ
ドロキシエチル、2−ヒドロキシプロピル、2−エチル
ヘキシル、ラウリル、ステアリン酸エステル等の単官能
エステル或はエチレングリコール、ジエチレングリコー
ル、トリエチレングリコール、トリメチロールプロパン
等の多官能エステル、又はこれらの混合物が好適である
。The polymer impregnating agent used in the present invention includes monofunctional esters of acrylic acid or methacrylic acid such as methyl, ethyl, butyl, 2-hydroxyethyl, 2-hydroxypropyl, 2-ethylhexyl, lauryl, and stearate, or ethylene. Polyfunctional esters such as glycol, diethylene glycol, triethylene glycol, trimethylolpropane, or mixtures thereof are preferred.
特に単官能エステルと多官能エステルとの混合物が好し
い。Particularly preferred are mixtures of monofunctional esters and polyfunctional esters.
高分子含浸剤に含有される重合触媒としては、過酸化物
系、レドックス系、アゾビス系などの公知のものが使用
出来る。As the polymerization catalyst contained in the polymer impregnating agent, known catalysts such as peroxide type, redox type, and azobis type can be used.
この発明は桧材、−位材、プライヤー等のほとんど全て
の木材、或はこれら木材片又は粉を固めた木質材、更に
は動物性有機多孔質材等のはとんど全ての有機多孔質材
料に適用することが出来る。This invention can be applied to almost all types of wood such as Japanese cypress wood, cypress wood, pliers, etc., wood materials made by hardening these wood pieces or powder, and also almost all organic porous materials such as animal organic porous materials. It can be applied to materials.
これらの有機多孔質材料に、前記重合触媒を含有した高
分子含浸剤を、真空減圧下において脱気しつつ含浸せし
め(真空加圧の併用も可)、含浸剤の蒸発を防止しつつ
高分子硬化させる。These organic porous materials are impregnated with the polymer impregnating agent containing the polymerization catalyst while degassing under vacuum and reduced pressure (vacuum pressure can also be used in combination). Let it harden.
高分子含浸剤の高分子硬化により、有機多孔質材料の微
細孔が封孔、密閉され、圧縮強度、表面硬度、その他の
物性が向上し、均一な印面硬度を有する優れた印材を得
ることが出来た。The polymer curing of the polymer impregnating agent seals and seals the micropores of the organic porous material, improving compressive strength, surface hardness, and other physical properties, making it possible to obtain an excellent stamp material with uniform stamp surface hardness. done.
次に、実、施例によって本発明を更にくわしく説明する
。Next, the present invention will be explained in more detail with reference to Examples.
実施例1
印材用材料として、桧材、−位材、プライヤーの小片を
作り、試片とした。この試片を真空槽内に設置し、重合
触媒を含有した高分子含浸剤で、比重1.015、粘度
7.6センチボイズのアクリル系樹脂含浸剤KM−3V
(有限会社希羊産業製)を注入後、槽内を2mzHGに
減圧しつつ、15分間含浸させた。Example 1 As stamp materials, small pieces of cypress wood, cypress wood, and pliers were made and used as test pieces. This test piece was placed in a vacuum chamber, and an acrylic resin impregnating agent KM-3V containing a polymerization catalyst and a specific gravity of 1.015 and a viscosity of 7.6 centivoise was used.
(manufactured by Kiyo Sangyo Co., Ltd.) was injected, and the tank was impregnated for 15 minutes while the pressure inside the tank was reduced to 2 mzHG.
含浸後、試片を取り出し養生、乾燥後高分子硬化させた
。試片への高分子含浸剤の充填量は80%であり、圧縮
強度、引張強度とも通常の4〜6倍と強度の向上が認め
られ、均一な硬度の印面を有する印材を得ることが出来
た。After impregnation, the specimen was taken out, cured, dried, and then cured with polymer. The filling amount of the polymer impregnating agent in the specimen was 80%, and the compressive strength and tensile strength were both 4 to 6 times higher than normal strength, and it was possible to obtain a stamp material with a stamp surface of uniform hardness. Ta.
Claims (2)
浸剤を含浸させて高分子硬化させ、材料の微細孔を封孔
、密閉したことを特徴とする印材。(1) A stamp material characterized by impregnating an organic porous material with a polymer impregnating agent containing a polymerization catalyst and curing the polymer to seal and seal the micropores of the material.
剤を含浸させた後、高分子含浸剤の蒸発を防止しつつ高
分子硬化させることを特徴とする印材の製造方法。(2) A method for manufacturing a stamp material, which comprises impregnating an organic porous material with a polymer impregnating agent containing a polymerization catalyst, and then curing the polymer while preventing evaporation of the polymer impregnating agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22526089A JPH0387285A (en) | 1989-08-31 | 1989-08-31 | Material for seal composed of organic porous material and preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22526089A JPH0387285A (en) | 1989-08-31 | 1989-08-31 | Material for seal composed of organic porous material and preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0387285A true JPH0387285A (en) | 1991-04-12 |
Family
ID=16826528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22526089A Pending JPH0387285A (en) | 1989-08-31 | 1989-08-31 | Material for seal composed of organic porous material and preparation thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0387285A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005262809A (en) * | 2004-03-22 | 2005-09-29 | Tottori Prefecture | Seal |
-
1989
- 1989-08-31 JP JP22526089A patent/JPH0387285A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005262809A (en) * | 2004-03-22 | 2005-09-29 | Tottori Prefecture | Seal |
JP4620958B2 (en) * | 2004-03-22 | 2011-01-26 | 地方独立行政法人鳥取県産業技術センター | seal |
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