JPH0377791A - Welding wire consisting of nickel-base alloy - Google Patents

Welding wire consisting of nickel-base alloy

Info

Publication number
JPH0377791A
JPH0377791A JP21350889A JP21350889A JPH0377791A JP H0377791 A JPH0377791 A JP H0377791A JP 21350889 A JP21350889 A JP 21350889A JP 21350889 A JP21350889 A JP 21350889A JP H0377791 A JPH0377791 A JP H0377791A
Authority
JP
Japan
Prior art keywords
nickel
weld cracking
less
welding
welding wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP21350889A
Other languages
Japanese (ja)
Other versions
JP2599201B2 (en
Inventor
Eiji Takahashi
英司 高橋
Tadaaki Yamada
山田 忠昭
Masanori Moribe
森部 正典
Osamu Tanaka
治 田中
Masayoshi Takano
正義 高野
Osamu Matsumoto
修 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP21350889A priority Critical patent/JP2599201B2/en
Publication of JPH0377791A publication Critical patent/JPH0377791A/en
Application granted granted Critical
Publication of JP2599201B2 publication Critical patent/JP2599201B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Superconductive Dynamoelectric Machines (AREA)
  • Arc Welding In General (AREA)

Abstract

PURPOSE:To maintain the characteristics of an inconel material to be used for a superconducting rotor, etc., by constituting the welding wire of a nickel based alloy made of a compsn. contg. specific weight % of C, Si, Mn, P, S, Ni, Cr, Mo, Nb, Ti, and B. CONSTITUTION:The welding wire is constituted of the nickel-based alloy. The nickel-based alloy is made of the compsn. contg., by weight %, <=0.25% C, <=0.3% Si, <=5.5% Mn, 45 to 55% Ni, 10 to 30% Cr, 3.4 to 6.0% Mo, 2 to 4.5% Nb, 1.5 to 2% Ti, and <=0.001% B. Welding procedures are executed without generating weld crack in this way.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はニッケル基合金からなる溶接ワイヤに係り、特
に、超電導ロータ用に使用されるインコネル718改良
合金等の溶接用として好適なニッケル基台金溶接ワイヤ
に関するものである。
Detailed Description of the Invention (Industrial Application Field) The present invention relates to a welding wire made of a nickel-based alloy, and in particular to a nickel-based welding wire suitable for welding Inconel 718 improved alloy used for superconducting rotors. This relates to gold welding wire.

(従来の技術及び解決しようとする課題)超電導ロータ
材は構造材料として高強度・非磁性鋼が要求され、引張
強さ100 kg/mm”以上、0.2%耐力が80 
kg / mm”以上が必要であり、これにはインコネ
ル718、A286等が考えられるが、A286は耐力
が低いため、インコネル718が使用されることが多い
。しかし、インコネル718を溶接構造材として用いた
場合、溶接時に割れを発生するという問題がある。
(Prior art and problems to be solved) Superconducting rotor materials require high-strength, non-magnetic steel as a structural material, with a tensile strength of 100 kg/mm or more and a 0.2% yield strength of 80
kg/mm" or more is required, and Inconel 718, A286, etc. can be considered for this, but since A286 has low yield strength, Inconel 718 is often used. However, Inconel 718 is not used as a welded structural material. If it is, there is a problem that cracks will occur during welding.

すなわち、インコネル系材料は、引張強さや耐力が高い
という特性があるが、割れ易いのが欠点である。
That is, Inconel materials have the characteristics of high tensile strength and yield strength, but have the disadvantage of being easily broken.

例えば、第1表に示す従来の市販の溶接ワイヤを使用し
てインコネル系材料(母材寸法:第1図参照)を溶接し
た場合、第2図に示す供試材の拘束状態では、第2表に
示すように溶接条件をどのように制御しても、溶接金属
においてX線や超音波では検出できない微視的割れを止
めることができない、このため、従来の市販の溶接ワイ
ヤは、4に’の超低温で使用する超電導ロータ材の溶接
材料としては、使用時に割れが進展し破壊する危険性が
あるので使用できない。
For example, when welding an Inconel material (base metal dimensions: see Figure 1) using the conventional commercially available welding wire shown in Table 1, in the restrained state of the specimen shown in Figure 2, the second As shown in the table, no matter how welding conditions are controlled, microscopic cracks that cannot be detected by X-rays or ultrasound cannot be stopped in the weld metal.For this reason, conventional commercially available welding wires are It cannot be used as a welding material for superconducting rotor materials used at ultra-low temperatures, as there is a risk of cracking and destruction during use.

本発明は、インコネル系材料の溶接に際し、その特性を
維持しつつ、溶接金属に割れ発生がない新規な溶接ワイ
ヤを提供することを目的とするものである。
An object of the present invention is to provide a new welding wire that does not cause cracks in the weld metal while maintaining its properties when welding Inconel-based materials.

(課題を解決するための手段) かメる目的達成のため、本発明者は、インコネル7L8
の性能を維持しつつ、溶接割れを起こさない溶接材料を
開発すべく鋭意研究を重ねた結果、ここにニッケル基合
金からなる溶接ワイヤを開発したものである。
(Means for Solving the Problems) In order to achieve the objective, the inventor has developed Inconel 7L8
As a result of intensive research to develop a welding material that does not cause weld cracking while maintaining the performance of the welding material, we have developed a welding wire made of a nickel-based alloy.

すなわち、本発明は、C:0.025%以下。That is, in the present invention, C: 0.025% or less.

Si:0.30%以下、Mn:5.5%以下、P:0.
010%以下、S:O,006%以下、Ni:45.0
〜55.0%、Cr:10.0〜30.0%、Mo:3
゜4〜6.0%、Nb:2.0〜4.5%、Ti:1.
50〜2.00%及びB:O,OO1%以下を含む組成
からなることを特徴とするニッケル基合金からなる溶接
ワイヤを要旨とするものである。
Si: 0.30% or less, Mn: 5.5% or less, P: 0.
010% or less, S: O, 006% or less, Ni: 45.0
~55.0%, Cr:10.0~30.0%, Mo:3
°4 to 6.0%, Nb: 2.0 to 4.5%, Ti: 1.
The gist of the present invention is a welding wire made of a nickel-based alloy characterized by having a composition containing 50 to 2.00% and 1% or less of B:O, OO.

以下に本発明を詳述する。The present invention will be explained in detail below.

(作用) 本発明における化学成分の限定理由は以下のとおりであ
る。
(Function) The reasons for limiting the chemical components in the present invention are as follows.

C:0.025%以下 Cは引張強さ及び0.2%耐力を上げる作用があるが、
一方では溶接割れを助長する元素であるため、C量は0
.025%以下に限定する。
C: 0.025% or less C has the effect of increasing tensile strength and 0.2% proof stress, but
On the other hand, since it is an element that promotes weld cracking, the amount of C is 0.
.. Limited to 0.025% or less.

Si:0.30%以下 Siは引張強さや0.2%耐力にはあまり影響を及ぼさ
ないが、溶接割れに大きな影響を与える。
Si: 0.30% or less Si does not have much effect on tensile strength or 0.2% proof stress, but it has a large effect on weld cracking.

第3図はワイヤ(図中の恥は第3表の恥に同じ)中のS
i量を変えて溶接割れの影響を調べたものである。同図
より明らかなように、Si量が0.30%を超えると溶
接割れが発生するようになる。したがって、Si量は0
.30%以下に限定する。
Figure 3 shows S in the wire (Shame in the figure is the same as Shame in Table 3).
The influence of weld cracking was investigated by changing the amount of i. As is clear from the figure, when the Si content exceeds 0.30%, weld cracking begins to occur. Therefore, the amount of Si is 0
.. Limited to 30% or less.

Mn:5.5%以下。Mn: 5.5% or less.

Mnはビード表面に発生するスラグに影響を与え、5.
5%を超えるとビード表面にスラグが多量に発生するよ
うになり、それに伴ってビードのなじみが悪くなり、ビ
ード幅が安定しなくなる。
Mn affects the slag generated on the bead surface, 5.
If it exceeds 5%, a large amount of slag will be generated on the bead surface, resulting in poor bead conformability and unstable bead width.

したがって、Mn量は5.5%以下に限定する。Therefore, the amount of Mn is limited to 5.5% or less.

P:0.010%以下、 Pは溶接割れを助長する元素であり、極力低い方が好ま
しいが、Sに比較し、その効果が低いので、0.010
%以下に限定する。
P: 0.010% or less, P is an element that promotes weld cracking and is preferably as low as possible, but its effect is lower than S, so 0.010%
% or less.

S:O,Oos% Sは、Pと同様1粒界に析出し、溶接割れの原因となり
、その程度はPより大きいため、本発明では0.006
%以下に限定する。
S: O, Oos% S, like P, precipitates at one grain boundary and causes weld cracking, and the degree of this is greater than P, so in the present invention, 0.006
% or less.

Ni:45.0〜55.0% 本ワイヤは、極低温で使用する超電導ロータ材としての
インコネル系材料の溶接用ワイヤの開発を主目的として
いるため、低温靭性の良いニッケル系合金にするため、
Ni量を45.0〜55.0%の範囲に限定する。
Ni: 45.0 to 55.0% The main purpose of this wire is to develop a wire for welding Inconel-based materials as superconducting rotor materials used at extremely low temperatures, so we created a nickel-based alloy with good low-temperature toughness. ,
The amount of Ni is limited to a range of 45.0 to 55.0%.

Cr:10.0〜30.0% Crは10.0%未満では一般に耐食性が悪くなるため
、それ以上の添加が必要である。しかし、30.0%を
超えると熱間加工性が悪くなり、溶接ワイヤの製造が困
難になるので、Cr量は10゜0〜30.0%の範囲と
する。
Cr: 10.0 to 30.0% If Cr is less than 10.0%, corrosion resistance generally deteriorates, so it is necessary to add more than that. However, if it exceeds 30.0%, hot workability deteriorates and manufacturing of welding wire becomes difficult, so the Cr content is set in the range of 10°0 to 30.0%.

Mo:3.4〜6.0% 本威分系において、特にMoを3.4以上、6゜0%以
下に規制することにより、溶接割れを抑制する効果を有
することが明らかとなったため、Mo量を3.4〜6.
0%の範囲とする。
Mo: 3.4-6.0% It has been found that regulating Mo to 3.4% or more and 6°0% or less has the effect of suppressing weld cracking in this system. The amount of Mo is 3.4 to 6.
The range is 0%.

Nb: 2 、 0〜4.5% Nbは引張強さ及び0.2%耐力の向上に効果を持ち、
添加量をますと引張強さ及び0.2%耐力が増加するが
、同時に溶接割れが発生し易くなる。
Nb: 2, 0-4.5% Nb has the effect of improving tensile strength and 0.2% proof stress,
If the addition amount is increased, the tensile strength and 0.2% proof stress will increase, but at the same time, weld cracking will be more likely to occur.

第4図はワイヤ(@中の恥は第3表の恥に同じ)中のN
b量を変えて溶接割れの影響を調べたものである。同図
より明らかなように、Nb量が4.5%を超えると溶接
割れを発生するようになる。したがって9強度を確保し
つつ溶接割れを防止するために、Nb量は2.0〜4.
5%の範囲とする。
Figure 4 shows the N in the wire (the shame in @ is the same as the shame in Table 3).
The influence of weld cracking was investigated by changing the amount of b. As is clear from the figure, when the amount of Nb exceeds 4.5%, weld cracking begins to occur. Therefore, in order to prevent weld cracking while ensuring 9 strength, the amount of Nb should be 2.0 to 4.
The range shall be 5%.

Ti:1.50〜2.00% 溶接割れを抑制するためにNb量を4.5%以下に抑え
ると引張強さ及び0.2%耐力が規格値に対し不充分に
なるため、引張強さ及び0.2%耐力を上げ、かつ、溶
接割れを発生しない添加元素が必要である。Tjは、第
5図に示すように、その目的に合致した元素であり、そ
のためにTi量を1.50〜2.00%の範囲とするの
が最適であることが判明した。なお、第5図はワイヤ(
図中の恥は第3表の尚に同じ)中のTifiを変えて溶
接割れの影響を調べたものである。
Ti: 1.50-2.00% If the Nb content is suppressed to 4.5% or less to suppress weld cracking, the tensile strength and 0.2% yield strength will be insufficient compared to the standard values, so the tensile strength It is necessary to add an element that increases the strength and 0.2% proof stress and does not cause weld cracking. As shown in FIG. 5, Tj is an element that meets this purpose, and for this purpose it has been found that the optimum Ti content is in the range of 1.50 to 2.00%. In addition, Fig. 5 shows the wire (
The values in the figure are the same as those in Table 3), and the effect of weld cracking was investigated by changing Tifi.

B:Q、QO1%以下。B: Q, QO 1% or less.

Bは溶接割れに悪影響をもたらす元素であるため、極力
下げる必要がある元素であり、本発明ではB量を0.0
01%以下に限定する。
Since B is an element that has a negative effect on weld cracking, it is an element that needs to be reduced as much as possible. In the present invention, the amount of B is set to 0.0.
Limited to 0.1% or less.

なお、上記成分以外は、不純物であるが、不純物量は可
及的に少ないことが望ましい。
Note that components other than the above-mentioned components are impurities, but it is desirable that the amount of impurities be as small as possible.

上記化学成分を有するワイヤを使用すると溶接割れが発
生しないのは、これらの成分が適正にバランスされてい
るためと考えられる。すなわち、本発明者が溶接割れ部
を調べたところ、第6図の写真に示すように、溶接割れ
部は粒界部であり。
The reason why weld cracking does not occur when a wire having the above chemical components is used is thought to be because these components are properly balanced. That is, when the present inventor investigated the weld crack, as shown in the photograph of FIG. 6, the weld crack was found to be a grain boundary region.

粒界部には偏析が起こっており、割れ先端部を線分析し
た結果、Nb、Ti、Mo、S、P、Si、C。
Segregation occurs at grain boundaries, and line analysis of the crack tip reveals Nb, Ti, Mo, S, P, Si, and C.

B等が存在していることがわかった。したがって、これ
ら成分を制御すると共にNi等の他の成分をバランスよ
く調整することにより、初期の効果が得られるものと考
えられる。
It was found that B etc. exist. Therefore, it is considered that initial effects can be obtained by controlling these components and adjusting other components such as Ni in a well-balanced manner.

なお、溶接対象は主にインコネル系材利用であり、その
組成は何ら制限されるものではない。また溶接条件も適
宜選定できる。
It should be noted that the objects to be welded are mainly Inconel-based materials, and the composition thereof is not limited in any way. Furthermore, welding conditions can be selected as appropriate.

次に本発明の実施例を示す。Next, examples of the present invention will be shown.

(実施例) 第3表に示す化学成分を有するワイヤを用い、インコネ
ル718(化学成分:第1表参照)を母材とし、以下の
溶接条件で溶接試験を行った6〈溶接条件〉 溶接法: TIG溶接 電流:22OA 溶接速度ニアc■/■in ワイヤ径:1.2mmφ Ar流量: 2011 /win 得られた溶接金属の引張強さ、0.2%耐力、溶接割れ
状況を同表に併記する。なお、溶接割れは第2表の脚注
2の要領で調べ、0(溶接割れなし)、×(溶接割れ発
生)にて評価した。
(Example) A welding test was conducted under the following welding conditions using a wire having the chemical composition shown in Table 3, using Inconel 718 (chemical composition: see Table 1) as the base material.6〈Welding conditions〉 Welding method : TIG welding current: 22OA Welding speed near c/■in Wire diameter: 1.2mmφ Ar flow rate: 2011/win The tensile strength, 0.2% proof stress, and weld cracking condition of the obtained weld metal are also listed in the same table. do. Note that weld cracking was investigated as described in footnote 2 of Table 2, and evaluated as 0 (no weld cracking) and × (weld crack occurrence).

第3表より、以下の如く考察される。From Table 3, the following considerations can be made.

比較例Ha lはC,Nb、B、Sが高く、Moが低い
ために溶接割れを生じている。
Comparative Example Hal has high C, Nb, B, and S contents and low Mo content, so weld cracking occurs.

比較例Nci 2はC,SLが高く、MOが低いために
溶接割れを生じている。
Comparative example Nci 2 has high C and SL and low MO, so weld cracking occurs.

比較例No3はNb、Sが高く、Moが低いために溶接
割れを生じている。
Comparative Example No. 3 has high Nb and S content and low Mo content, so weld cracking occurs.

比較例N(14では、溶接割れは生じないものの、Ti
が低いために、0.2%耐力が低くなっている。
Comparative Example N (14, although no weld cracking occurs, Ti
As a result, the 0.2% yield strength is low.

比較例Na 5はNbが低く、引張強さ及び0.2%耐
力が不足している。
Comparative Example Na 5 has a low Nb content and is insufficient in tensile strength and 0.2% proof stress.

比較例N(16はTiが低く、0.2%耐力が不足して
いる。
Comparative Example N (16) has low Ti content and lacks 0.2% yield strength.

比較例&7はTiが不足し、0.2%耐力が不足してい
る。
Comparative Example &7 lacks Ti and lacks 0.2% yield strength.

比較例Nci 8はNb、Ti、Moが低く、引張強さ
及び0.2%耐力が不足している。
Comparative example Nci 8 is low in Nb, Ti, and Mo, and is insufficient in tensile strength and 0.2% proof stress.

比較例Ha 9はNb、Ti、Moが不足しているため
、引張強さ及び0.2%耐力が不足している。
Comparative Example Ha 9 lacks Nb, Ti, and Mo, so it lacks tensile strength and 0.2% proof stress.

比較例Ha 10はTiが不足しているために、0゜2
%耐力が不足している。
Comparative example Ha 10 is 0°2 due to the lack of Ti.
% yield strength is insufficient.

比較例NQ11はPが高く、MOが不足しているために
溶接割れを生じている。
Comparative example NQ11 has a high P content and lacks MO, which causes weld cracking.

比較例Ha l 3はMOが低いために溶接割れを生じ
ている。
In Comparative Example Hal 3, weld cracking occurred due to the low MO content.

比較例Na14〜&16はSiが高いために溶接割れを
生じている。
In Comparative Examples Na14 to &16, weld cracking occurred due to high Si content.

比較例NQ19はMoが高すぎ、溶接割れを発生させて
いる。
In Comparative Example NQ19, Mo content was too high, causing weld cracking.

比較例恥21はCが高すぎて溶接割れを生じている。In Comparative Example 21, C was too high and weld cracking occurred.

一方1本発明例恥工2、Nα17〜N018.1l11
120、NQ22〜NG23は本発明範囲内の戊分組戊
を有するワイヤを用いたので、引張強さ及び0.2%耐
力を満足し、かつ、溶接割れが生じない。
On the other hand, 1 invention example 2, Nα17~N018.1l11
No. 120 and NQ22 to NG23 used wires having a splitting structure within the scope of the present invention, so they satisfied the tensile strength and 0.2% proof stress and did not cause weld cracking.

【以下余白] (発明の効果) 以上詳述したように、本発明によれば、特定組成を有す
るニッケル基合金からなる溶接ワイヤとするので、超電
導ロータ材等に使用されるインコネル系材料の持つ特性
を維持し、且つ溶接割れを起こさないで溶接施工できる
[Blank below] (Effects of the Invention) As detailed above, according to the present invention, since the welding wire is made of a nickel-based alloy having a specific composition, It can be welded while maintaining its properties and without causing weld cracks.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は供試材の寸法を示す説明図、 第2図は供試材の拘束状態を示す説明1図、第3図は溶
接割れに及ぼすSiの影響を示す図、第4図は引張強さ
と0.2%耐力及び溶接割れに及ぼすNbの影響を示す
図。 第5図は引張強さと0.2%耐力及び溶接割れに及ぼす
Tiの影響を示す図。 第6図(a)、(b)は溶接割れ発生部分の金属組織を
示す図で、(a)は2次電子線像(x 480)、(b
)は組成像(x480)を示している。
Figure 1 is an explanatory diagram showing the dimensions of the sample material, Figure 2 is an explanatory diagram showing the restraint state of the specimen material, Figure 3 is a diagram showing the influence of Si on weld cracking, and Figure 4 is a diagram showing the tensile strength of the specimen. A diagram showing the influence of Nb on strength, 0.2% proof stress, and weld cracking. FIG. 5 is a diagram showing the influence of Ti on tensile strength, 0.2% proof stress, and weld cracking. Figures 6 (a) and (b) are diagrams showing the metal structure of the weld crack occurrence area, (a) is a secondary electron beam image (x 480), (b)
) shows a composition image (x480).

Claims (1)

【特許請求の範囲】[Claims] 重量%で(以下、同じ)、C:0.025%以下、Si
:0.30%以下、Mn:5.5%以下、P:0.01
0%以下、S:0.006%以下、Ni:45.0〜5
5.0%、Cr:10.0〜30.0%、Mo:3.4
〜6.0%、Nb:2.0〜4.5%、Ti:1.50
〜2.00%及びB:0.001%以下を含む組成から
なることを特徴とするニッケル基合金からなる溶接ワイ
ヤ。
In weight% (hereinafter the same), C: 0.025% or less, Si
: 0.30% or less, Mn: 5.5% or less, P: 0.01
0% or less, S: 0.006% or less, Ni: 45.0-5
5.0%, Cr: 10.0-30.0%, Mo: 3.4
~6.0%, Nb: 2.0~4.5%, Ti: 1.50
A welding wire made of a nickel-based alloy, characterized in that it has a composition containing ~2.00% and B:0.001% or less.
JP21350889A 1989-08-19 1989-08-19 Welding wire made of nickel base alloy Expired - Fee Related JP2599201B2 (en)

Priority Applications (1)

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JP21350889A JP2599201B2 (en) 1989-08-19 1989-08-19 Welding wire made of nickel base alloy

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JP21350889A JP2599201B2 (en) 1989-08-19 1989-08-19 Welding wire made of nickel base alloy

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010013565A1 (en) 2008-07-30 2010-02-04 三菱重工業株式会社 Welding material for ni-based alloy
CN112705700A (en) * 2020-12-18 2021-04-27 山东大学 Method for improving high-temperature strength of Inconel 718 laser deposition layer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010013565A1 (en) 2008-07-30 2010-02-04 三菱重工業株式会社 Welding material for ni-based alloy
CN112705700A (en) * 2020-12-18 2021-04-27 山东大学 Method for improving high-temperature strength of Inconel 718 laser deposition layer
CN112705700B (en) * 2020-12-18 2022-02-08 山东大学 Method for improving high-temperature strength of Inconel 718 laser deposition layer

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