JPH0372658B2 - - Google Patents
Info
- Publication number
- JPH0372658B2 JPH0372658B2 JP58026100A JP2610083A JPH0372658B2 JP H0372658 B2 JPH0372658 B2 JP H0372658B2 JP 58026100 A JP58026100 A JP 58026100A JP 2610083 A JP2610083 A JP 2610083A JP H0372658 B2 JPH0372658 B2 JP H0372658B2
- Authority
- JP
- Japan
- Prior art keywords
- polystyrene beads
- expandable polystyrene
- weight
- colored
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011324 bead Substances 0.000 claims description 64
- 229920006248 expandable polystyrene Polymers 0.000 claims description 58
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 7
- 239000012860 organic pigment Substances 0.000 claims description 3
- 238000004898 kneading Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 description 22
- 239000003086 colorant Substances 0.000 description 14
- 238000004040 coloring Methods 0.000 description 12
- 239000000049 pigment Substances 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 6
- 239000003981 vehicle Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- -1 2- ethylhexyl Chemical group 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000007689 inspection Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Citronensaeure-tributylester Natural products CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001278 adipic acid derivatives Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 229940031769 diisobutyl adipate Drugs 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
【発明の詳細な説明】
本発明は、着色された発泡性ポリスチレンビー
ズの製造法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing colored expandable polystyrene beads.
発泡性ポリスチレンビーズの発泡成形品は緩衝
性、断熱性に優れ、且つ軽量であるので包装材、
断熱材、容器などに広く用いられている。これら
発泡成形品の商品価値を更に上げるために着色す
ることがしばしば行われる。着色された発泡ポリ
スチレン成形品を得るには次の３つの方法が通常
用いられる。すなわち、発泡性ポリスチレン成
形品に塗料等を塗布又はスプレーする方法、発
泡性ポリスチレンビーズ製造時にスチレンモノマ
ーに染料又は顔料を溶解するか、ないしは発泡性
ポリスチレンビーズに染料を含浸させる方法、
発泡性ポリスチレンビーズの表面に染料又は顔料
を添着させる方法である。本発明はこれらのうち
の方法に係るものである。これら３種の方法を
比較すると、の方法は着色後の乾燥などが必要
であり、非常に煩雑であるのでほとんど行われて
いない。の方法は発泡性ポリスチレンビーズの
製造プラントの中で着色を行うものであり、同一
プラントで無着色又は他の色に着色した発泡性ポ
リスチレンビーズを併産するとプラント内に残留
していた着色された発泡性ポリスチレンビーズが
混ざりこみ易く、プラント内の清掃が必要になる
など連続生産を行う上で支障が起る。の方法は
製造後の発泡性ポリスチレンビーズの表面を着色
するものであり、従来は染料又は顔料などの着色
剤を発泡性ポリスチレンビーズと混合することに
より発泡性ポリスチレンビーズを着色処理してい
た。 Foamed products made of expandable polystyrene beads have excellent cushioning and heat insulation properties, and are lightweight, so they can be used as packaging materials,
Widely used in insulation materials, containers, etc. These foam molded products are often colored to further increase their commercial value. The following three methods are commonly used to obtain colored expanded polystyrene moldings. That is, a method of applying or spraying a paint etc. to an expandable polystyrene molded article, a method of dissolving a dye or pigment in a styrene monomer during the production of expandable polystyrene beads, or a method of impregnating expandable polystyrene beads with a dye;
This method involves attaching dyes or pigments to the surface of expandable polystyrene beads. The present invention relates to one of these methods. Comparing these three methods, method (1) requires drying after coloring and is very complicated, so it is rarely used. In this method, coloring is carried out in the plant for manufacturing expandable polystyrene beads, and if uncolored or colored expandable polystyrene beads are co-produced in the same plant, the colored particles remaining in the plant will be removed. Expandable polystyrene beads tend to get mixed in, making it necessary to clean the inside of the plant, which poses problems for continuous production. The method involves coloring the surface of the expandable polystyrene beads after production, and conventionally the expandable polystyrene beads were colored by mixing a coloring agent such as a dye or pigment with the expandable polystyrene beads.
発泡ポリスチレンの成形品の製造は、発泡性ポ
リスチレンビーズを予め蒸気加熱その他の方法で
一次発泡させた予備発泡粒子を金型内に充填し、
再加熱によつて予備発泡粒子を熱融着させること
により得られる。従つて発泡性ポリスチレンビー
ズの表面だけが着色されていれば発泡成形品の表
面に無着色部が露出することはない。しかも発泡
性ポリスチレンビーズと着色剤を混合するだけで
あり、非常に簡便に着色された発泡性ポリスチレ
ンビーズを得ることができる。しかしながら従来
の方法では、発泡性ポリスチレンビーズと粉末状
の着色剤が混合処理されているだけであるために
発泡性ポリスチレンビーズと着色剤が分離し易い
という欠点を有していた。 The production of foamed polystyrene molded products involves filling a mold with pre-expanded particles of expandable polystyrene beads that have been primarily foamed by steam heating or other methods.
It is obtained by thermally fusing pre-expanded particles by reheating. Therefore, if only the surface of the expandable polystyrene beads is colored, no uncolored portions will be exposed on the surface of the foam molded product. Moreover, colored expandable polystyrene beads can be obtained very simply by simply mixing expandable polystyrene beads and a coloring agent. However, in the conventional method, the expandable polystyrene beads and the powdered colorant are simply mixed and processed, and therefore, the expandable polystyrene beads and the colorant tend to separate.
発泡性ポリスチレンビーズの成形加工工程は基
本的には、(i)発泡性ポリスチレンビーズの予備発
泡工程、(ii)予備発泡粒子の養生工程、(iii)養生され
た予備発泡粒子の成形工程からなる。これらの各
工程において、上記従来方法の着色発泡性ポリス
チレンビーズでは機器、配管などに分離した着色
剤が付着し、次に同一工程で無着色や他の色調に
着色された発泡性ポリスチレンビーズの成形加工
を行う場合、機器、配管に付着していた着色剤に
よつて汚染される。従つて前記の方法によつて
製造された着色された発泡性ポリスチレンビーズ
を成形加工した後は機器、配管を充分に清掃する
必要があつた。このようなの方法の欠点を改良
する方法として、着色剤と発泡性ポリスチレンビ
ーズの分離を防ぐために、例えばステアリン酸モ
ノグリセライドなどの粉末状バインダーを着色剤
と予め混合処理しておく方法もあるが、その効果
は充分とは云えない。又、特公昭52−41303号に
見られるように、染料を溶媒と水の混合系に溶か
しておき、これに発泡性ポリスチレンビーズを浸
漬して着色する方法も提案されているが、着色
後、乾燥工程が加わるなど煩雑になり実用的では
ない。 The molding process of expandable polystyrene beads basically consists of (i) a step of pre-expanding the expandable polystyrene beads, (ii) a step of curing the pre-expanded particles, and (iii) a step of molding the cured pre-expanded particles. . In each of these processes, the colored expandable polystyrene beads of the conventional method described above have a separated coloring agent attached to equipment, piping, etc., and then in the same process, expandable polystyrene beads that are uncolored or colored in other colors are molded. When processing, equipment and piping are contaminated by colorants that have adhered to them. Therefore, after molding the colored expandable polystyrene beads produced by the above method, it was necessary to thoroughly clean the equipment and piping. As a method to improve the drawbacks of these methods, there is a method in which a powdered binder such as stearic acid monoglyceride is mixed with the colorant in advance in order to prevent the colorant from separating from the expandable polystyrene beads. The effect cannot be said to be sufficient. In addition, as seen in Japanese Patent Publication No. 52-41303, a method has been proposed in which the dye is dissolved in a mixed system of solvent and water, and the expandable polystyrene beads are immersed in this solution for coloring. It is not practical because it is complicated due to the addition of a drying process.
本発明者らは従来の上記欠点を解消すべく種々
検討した結果、簡便にして工業的に有利である。
着色された発泡性ポリスチレンビーズの製造法を
発明するに至つた。 The present inventors have conducted various studies to solve the above-mentioned drawbacks of the conventional technology, and as a result, the present invention has been found to be simple and industrially advantageous.
A method for producing colored expandable polystyrene beads was invented.
すなわち本発明は、発泡性ポリスチレンビーズ
とある程度の相溶性を有する有機液状展色剤と有
機顔料とを予め混練してなるペースト状トナー
0.1〜1.0重量部を発泡性ポリスチレンビーズ100
重量部に混合し、該ビーズの表面に均一に付着さ
せることを特徴とする着色された発泡性ポリスチ
レンビーズの製造法を要旨とする。 That is, the present invention provides a paste toner prepared by kneading in advance an organic liquid color vehicle and an organic pigment that have a certain degree of compatibility with expandable polystyrene beads.
0.1-1.0 parts by weight of expandable polystyrene beads 100
The gist of the present invention is a method for producing colored expandable polystyrene beads, which is characterized in that the colored polystyrene beads are mixed in parts by weight and uniformly adhered to the surface of the beads.
本発明でいう発泡性ポリスチレンビーズとは、
ポリスチレンビーズ中に発泡剤を含有させたもの
であり、ポリスチレンビーズとはスチレンの単独
重合体、スチレンと他の単量体との共重合体、又
はスチレン重合体と他の重合体との混合物を云
い、少くともスチレン含有量が50％以上のものを
いう。ここでいうところの他の単量体とはα−メ
チルスチレン、ｔ−ブチルスチレン、ビニルトル
エン、ジビニルベンゼン、アクリル酸ブチル、ア
クリル酸エチル、メタクリル酸メチル、メタクリ
ル酸ブチル、アクリロニトリル、酢酸ビニル等の
単量体をいう。発泡剤としてはプロパン、ブタ
ン、ペンタン、塩化メチル等が用いられる。 The expandable polystyrene beads in the present invention are:
Polystyrene beads contain a foaming agent, and polystyrene beads are styrene homopolymers, copolymers of styrene and other monomers, or mixtures of styrene polymers and other polymers. This means that the styrene content is at least 50%. Other monomers mentioned here include α-methylstyrene, t-butylstyrene, vinyltoluene, divinylbenzene, butyl acrylate, ethyl acrylate, methyl methacrylate, butyl methacrylate, acrylonitrile, vinyl acetate, etc. A monomer. As the blowing agent, propane, butane, pentane, methyl chloride, etc. are used.
着色に使用される有機顔料（以下、単に顔料と
略す）は、予め発泡性ポリスチレンビーズとある
程度の相溶性を有する有機液状展色剤と混合しペ
ースト状トナーにしておく。本発明において、発
泡性ポリスチレンビーズとある程度の相溶性を有
する有機液状展色剤とは、可塑剤類、乾性油類、
低揮発性溶剤類等であつて、前記ペースト状の顔
料含有トナーが発泡性ポリスチレンビーズの表面
に容易に均一に付着し、かつ付着したトナーが剥
離せず、従つて機器、配管等を汚染することがな
い程度の発泡性ポリスチレンビーズに対する相溶
性と親和性を有するものである。ここでで注意す
ることは、発泡性ポリスチレンビーズを溶解する
ような過剰な相溶性を有する展色剤はビーズの凝
集や固着を招くので避けるべきであるが、他の相
溶性の低い展色剤と混合すれば使用できる。 The organic pigment used for coloring (hereinafter simply referred to as pigment) is mixed in advance with an organic liquid coloring agent having a certain degree of compatibility with the expandable polystyrene beads to form a paste toner. In the present invention, organic liquid vehicles having a certain degree of compatibility with expandable polystyrene beads include plasticizers, drying oils,
The paste-like pigment-containing toner easily and uniformly adheres to the surface of the expandable polystyrene beads using a low-volatile solvent, etc., and the adhered toner does not peel off, thereby contaminating equipment, piping, etc. It has a degree of compatibility and affinity with expandable polystyrene beads. It should be noted here that color vehicles with excessive compatibility, such as those that dissolve expandable polystyrene beads, should be avoided as they may cause beads to aggregate or stick, but other color vehicles with low compatibility should be avoided. It can be used by mixing with.
本発明にいう可塑剤類とは、フタル酸ジ（２−
エチルヘキシル）、フタル酸ブチルベンジル等の
フタル酸ジエステル類；アジピン酸ジ（２−エチ
ルヘキシル）、アジピン酸ジイソブチル等のアジ
ピン酸エステル類；リン酸トリクレジル等のリン
酸トリエステル類；クエン酸アセタールトリブチ
ル等のクエン酸エステル類等のポリスチレンをあ
る程度溶解又は膨潤させる性能を持つものをい
う。乾性油類としては、あまに油、桐油、荏油等
があげられる。また低揮発性溶剤類とは沸点が60
℃以上の有機溶剤類をいう。 The plasticizers referred to in the present invention are phthalic acid di(2-
ethylhexyl), butylbenzyl phthalate; adipic acid esters such as di(2-ethylhexyl) adipate and diisobutyl adipate; phosphoric acid triesters such as tricresyl phosphate; acetal tributyl citrate, etc. Refers to substances that have the ability to dissolve or swell polystyrene to some extent, such as citric acid esters. Examples of drying oils include linseed oil, tung oil, and perilla oil. In addition, low-volatile solvents have a boiling point of 60
Refers to organic solvents with temperatures above ℃.
顔料と、上記有機液状展色剤とを混合する方法
としては３本ロールミルなど混練して均一なペー
スト状トナーが得られる手段であればよい。 The pigment and the organic liquid vehicle may be mixed by any means such as a three-roll mill that can be kneaded to obtain a uniform paste toner.
発泡性ポリスチレンビーズ100重量部に対して、
通常、顔料を含んだペースト状トナーは0.1〜1.0
重量部、特に好ましくは0.3〜0.5重量部添加、混
合される。0.1重量部より少ないと均一付着に不
充分であり、また1.0重量部をこえて多量になる
とビーズから垂れ落ちることがあるの好ましくな
い。 For 100 parts by weight of expandable polystyrene beads,
Usually, paste toner containing pigment is 0.1 to 1.0
Part by weight, particularly preferably 0.3 to 0.5 part by weight, is added and mixed. If it is less than 0.1 part by weight, it is insufficient for uniform adhesion, and if it exceeds 1.0 part by weight, it may drip from the beads, which is undesirable.
このようにして得られた顔料と有機液状展色剤
とを混合したペースト状トナーを発泡性ポリスチ
レンビーズと混合処理することによつて均一に着
色された発泡性ポリスチレンビーズが得られる。
この混合工程において、顔料と有機液状展色剤と
を不均一に混合したり、別々に添加、混合するこ
とは発泡性ポリスチレン系ビーズ表面の不均一な
着色をひき起し好ましくない。 Uniformly colored expandable polystyrene beads are obtained by mixing the paste toner obtained by mixing the pigment and organic liquid coloring agent with expandable polystyrene beads.
In this mixing step, it is not preferable to mix the pigment and the organic liquid color vehicle non-uniformly, or to add and mix them separately, as this will cause non-uniform coloring of the surface of the expandable polystyrene beads.
本発明において用いる混合装置としては、リボ
ンブレンダー、タンブラー型ブレンダー、ヘンシ
エル型ミキサー等、均一に混合できるものあれば
よく、混合能力及び目的とする着色度合によつて
顔料、有機液状展色剤の種類及び混合比率、混合
時間等を調整することにより、上記いずれのタイ
プの混合機であつても均一に着色された発泡性ポ
リスチレンビーズを得ることができる。 The mixing device used in the present invention may be any device that can mix uniformly, such as a ribbon blender, tumbler type blender, or Henschel type mixer. By adjusting the mixing ratio, mixing time, etc., uniformly colored expandable polystyrene beads can be obtained using any of the above types of mixers.
本発明の着色された発泡性ポリスチレンビーズ
を使用して成形加工を行つた後、同一装置で無着
色の発泡性ポリスチレンビーズの成形加工を行つ
ても顔料による汚染は見られない。 After molding using the colored expandable polystyrene beads of the present invention, no pigment contamination is observed even when uncolored expandable polystyrene beads are molded using the same equipment.
以下、実施例について詳述するが、本発明はこ
れら実施例にて何ら制約されるものではない。 Examples will be described in detail below, but the present invention is not limited to these examples in any way.
実施例 １
黄色顔料ジスアゾイエロー25重量部に可塑剤
DOP75重量部を加え、この混合物を３本ロール
ミル混練し、ペースト状トナーとする。このペー
スト状トナー0.3重量部を発泡性ポリスチレンビ
ーズ（鐘淵化学工業(株)製：カネパール）100重量
部に加え、ヘンシエル型ミキサーで常温にて３分
間撹拌混合する。この結果、均一に着色された発
泡性ポリスチレンビーズが得られた。Example 1 25 parts by weight of yellow pigment disazo yellow and plasticizer
75 parts by weight of DOP is added, and the mixture is kneaded in a three-roll mill to form a paste toner. 0.3 parts by weight of this paste-like toner was added to 100 parts by weight of expandable polystyrene beads (manufactured by Kaneru Kagaku Kogyo Co., Ltd.: Kanepal), and the mixture was stirred and mixed for 3 minutes at room temperature using a Henschel type mixer. As a result, uniformly colored expandable polystyrene beads were obtained.
この着色された発泡性ポリスチレンビーズにブ
ロツキング防止剤としてステアリン酸亜鉛0.1重
量部を加え、予備発泡、養生、成形を行つた。生
産終了後、使用した装置、配管内への色材の付着
状況を観察したところ色材の付着はほとんどな
く、続けて無着色の発泡性ポリスチレンビーズを
同一工程にて予備発泡、養生、成形を行つたとこ
ろ、これにも色材の付着、成形品の汚染は見られ
なかつた。 0.1 part by weight of zinc stearate was added as an antiblocking agent to the colored expandable polystyrene beads, and the beads were pre-foamed, cured, and molded. After production was completed, we observed the adhesion of coloring material to the equipment used and inside the piping, and found that there was almost no adhesion of coloring material.Continuing, uncolored expandable polystyrene beads were pre-foamed, cured, and molded in the same process. Upon inspection, no colorant adhesion or contamination of the molded product was found.
実施例 ２
青色顔料シアニンブルー20重量部に可塑剤
DBP79重量部、分散剤としてラウリルスルフオ
ン酸ソーダ１重量部を加え、この混合物を３本ロ
ールミルで混練しペースト状トナーにする。この
ペースト状トナー0.5重量部を発泡性ポリスチレ
ンビーズ（鐘淵化学工業(株)製：カネパール）100
重量部に加え、リボンブレンダーで常温にて30分
間撹拌混合する。この結果、均一に着色された発
泡性ポリスチレンビーズが得られた。Example 2 20 parts by weight of blue pigment cyanine blue plus plasticizer
79 parts by weight of DBP and 1 part by weight of sodium lauryl sulfonate as a dispersant were added, and the mixture was kneaded in a three-roll mill to form a paste toner. Add 0.5 parts by weight of this paste toner to 100% of expandable polystyrene beads (manufactured by Kanebuchi Kagaku Kogyo Co., Ltd.: Kanepal).
Add the parts by weight and mix with a ribbon blender at room temperature for 30 minutes. As a result, uniformly colored expandable polystyrene beads were obtained.
この着色された発泡性ポリスチレンビーズにブ
ロツキング防止剤としてステアリン酸亜鉛を0.1
重量部加え、予備発泡、養生、成形を行つた。生
産終了後、使用した装置、配管内への色材の付着
状況を観察したが色材の付着はほとんどなく、続
けて無着色の発泡性ポリスチレンビーズを同一工
程にて予備発泡、養生、成形を行つたところ、こ
れにも色材の付着、成形品の汚染は見られなかつ
た。 Add 0.1% zinc stearate to these colored expandable polystyrene beads as an anti-blocking agent.
Parts by weight were added, pre-foamed, cured and molded. After production was completed, we observed the adhesion of coloring material to the equipment and piping used, and found that there was almost no adhesion of coloring material.Continuing, uncolored expandable polystyrene beads were pre-foamed, cured, and molded in the same process. Upon inspection, no colorant adhesion or contamination of the molded product was found.
実施例 ３
青色顔料シアニンブルー20重量部にシクロヘキ
サン79重量部、ラウリルスルフオン酸ソーダ１重
量部を加え、この混合物を３本ロールミルで混練
しペースト状トナーにする。このペースト状トナ
ー0.5重量部を発泡性ポリスチレンビーズ（鐘淵
化学工業(株)製：カネパール）100重量部に加え、
ヘンシエル型ミキサーでで常温にて３分間撹拌混
合する。この結果、均一に着色された発泡性ポリ
スチレンビーズが得られた。Example 3 79 parts by weight of cyclohexane and 1 part by weight of sodium lauryl sulfonate are added to 20 parts by weight of blue pigment cyanine blue, and the mixture is kneaded in a three-roll mill to form a paste toner. Add 0.5 parts by weight of this paste toner to 100 parts by weight of expandable polystyrene beads (Kanebuchi Chemical Co., Ltd.: Kanepal),
Stir and mix for 3 minutes at room temperature using a Henschel type mixer. As a result, uniformly colored expandable polystyrene beads were obtained.
この着色発泡性ポリスチレンビーズにブロツキ
ング防止剤としてタルカムパウダー0.1重量部を
加え、予備発泡、養生、成形を行つた。生産終了
後、使用した装置、配管内への色材の付着状況を
観察したところ色材の付着はほとんどなく、続け
て無着色の発泡性ポリスチレンビーズを同一工程
にて予備発泡、養生、成形を行つたところ、これ
にも色材の付着、成形品の汚染は見られなかつ
た。 To the colored expandable polystyrene beads, 0.1 part by weight of talcum powder was added as an anti-blocking agent, and the beads were pre-foamed, cured and molded. After production was completed, we observed the adhesion of coloring material to the equipment used and inside the piping, and found that there was almost no adhesion of coloring material.Continuing, uncolored expandable polystyrene beads were pre-foamed, cured, and molded in the same process. Upon inspection, no colorant adhesion or contamination of the molded product was found.
Claims (1)
性を有する有機液状展色剤と有機顔料とを予め混
練してなるペースト状トナー0.1〜1.0重量部を発
泡性ポリスチレンビーズ100重量部に混合し、該
ビーズの表面に均一に付着させることを特徴とす
る着色された発泡性ポリスチレンビーズの製造
法。1. 0.1 to 1.0 parts by weight of a paste toner prepared by previously kneading an organic liquid color vehicle and an organic pigment that have a certain degree of compatibility with expandable polystyrene beads is mixed with 100 parts by weight of expandable polystyrene beads, and A method for producing colored expandable polystyrene beads characterized by uniformly adhering them to the surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2610083A JPS59152933A (en) | 1983-02-17 | 1983-02-17 | Colored expandable polystyrene bead |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2610083A JPS59152933A (en) | 1983-02-17 | 1983-02-17 | Colored expandable polystyrene bead |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59152933A JPS59152933A (en) | 1984-08-31 |
| JPH0372658B2 true JPH0372658B2 (en) | 1991-11-19 |
Family
ID=12184170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2610083A Granted JPS59152933A (en) | 1983-02-17 | 1983-02-17 | Colored expandable polystyrene bead |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59152933A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4653507B2 (en) * | 2005-02-04 | 2011-03-16 | 積水化成品工業株式会社 | Expandable styrene resin particles |
| JP6371711B2 (en) * | 2015-01-28 | 2018-08-08 | 株式会社カネカ | Colored polystyrene-based expandable resin particles, pre-expanded particles, and molded article |
| CN108841033A (en) * | 2016-05-19 | 2018-11-20 | 晋江国盛新材料科技有限公司 | A method of formed body being made with dyeing TPU expanded bead |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58204034A (en) * | 1982-05-24 | 1983-11-28 | Tokyo Ink Kk | Method for coloring expanded polystyrene particle |
-
1983
- 1983-02-17 JP JP2610083A patent/JPS59152933A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58204034A (en) * | 1982-05-24 | 1983-11-28 | Tokyo Ink Kk | Method for coloring expanded polystyrene particle |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59152933A (en) | 1984-08-31 |
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