JPH0364596A - Paper - Google Patents
PaperInfo
- Publication number
- JPH0364596A JPH0364596A JP20101589A JP20101589A JPH0364596A JP H0364596 A JPH0364596 A JP H0364596A JP 20101589 A JP20101589 A JP 20101589A JP 20101589 A JP20101589 A JP 20101589A JP H0364596 A JPH0364596 A JP H0364596A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- residue
- fruit
- cellulose
- squeezing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 26
- 229920002678 cellulose Polymers 0.000 claims abstract description 18
- 239000001913 cellulose Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 11
- 235000007119 Ananas comosus Nutrition 0.000 claims abstract description 4
- 244000099147 Ananas comosus Species 0.000 claims abstract 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 5
- 241000675108 Citrus tangerina Species 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229920002488 Hemicellulose Polymers 0.000 abstract 2
- 241001672694 Citrus reticulata Species 0.000 abstract 1
- 244000141359 Malus pumila Species 0.000 abstract 1
- 235000021016 apples Nutrition 0.000 abstract 1
- 239000005022 packaging material Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000835 fiber Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002023 wood Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 3
- 241000234671 Ananas Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- -1 thulium (I) Chemical compound 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は紙に関し、訂しくは水利パルプ以外の植物繊維
を主どして用いた紙に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to paper, and more particularly to paper mainly using vegetable fibers other than water-use pulp.
（従来の技術）
−・般に紙は、木（ＡのｍＨｌ及び麻、綿等の非水ＵＩ
Ｊｉ雑を製紙原料どして抄造されている。(Prior art) - In general, paper is made of wood (mHl of A and non-aqueous UI of linen, cotton, etc.).
Paper is made using Ji miscellaneous materials as papermaking raw materials.
（発明が解決しようとする課題）
しかしながら、現イ１−（ま（よとんど木４Ａ繊維が紙
の林料として使用され、近年の紙ｄｌｊ費吊の増加に件
ない、林料と４ｆる森林資源が枯渇しつつあり、木材Ｍ
＆雑に代わる製紙用繊維の研究開発が望まれている。(Problems to be Solved by the Invention) However, at present, 4A fiber from wood is used as forest material for paper, and in response to the recent increase in paper DLJ costs, forestry material and 4F fibers are used as forest material for paper. forest resources are being depleted, and wood m
Research and development of papermaking fibers that can replace miscellaneous fibers is desired.
本発明は、上述した如ぎ従来の技術の有する問題点に鑑
みてなされたものであり、その目的とする処（よ、水利
繊組に代わる製紙拐利による紙で、しかも和紙、西洋紙
とは異なる独特な感じを出し、嗜好性に対応することが
出来る紙を提供づ−ることにある。つまり、果実の果皮
などが混入されることによる、独特の感じの紙を提供す
ることが目的である。The present invention has been made in view of the problems of the conventional technology as described above, and its purpose is to provide a paper made by Kairi, which replaces Suirisengumi, and which is compatible with Japanese paper and Western paper. The purpose of this paper is to provide paper that has a different and unique feel and can be adapted to different tastes.In other words, the purpose is to provide paper that has a unique feel due to the addition of fruit peels, etc. It is.
（課題を解決するだめの手段）
上記目的を達成するために、本発明における紙は、繊組
質系果実の果汁搾汁後の残渣セルロース等を主０とした
ことを特徴とする。(Another Means to Solve the Problems) In order to achieve the above object, the paper of the present invention is characterized in that the paper contains mainly no cellulose or the like remaining after squeezing the juice of a fibrous fruit.
「記の果実残渣としては、リンゴ果実の残渣。``The fruit residue mentioned above is apple fruit residue.
ミカン果実の残渣、パインアップル果実の残渣等が挙げ
られる。また、上記果実の残渣には、セル１コースの外
に、果実を形成づるリグニン＼ゝ）１シ１］−ス等の細
胞間物質も多く含まれる。Examples include tangerine fruit residue and pineapple fruit residue. In addition to the cell course, the fruit residue also contains a large amount of intercellular substances such as lignin, which forms the fruit.
これらの残渣セルロース液に、木材材料を原料とした場
合と同様細かい鉱物質クレーやタルクを填料として調合
する。その割合は製紙しようとする紙に応じて調整する
。Fine mineral clay or talc is added to these residual cellulose liquids as a filler, similar to when wood materials are used as raw materials. The ratio is adjusted depending on the paper to be manufactured.
〈作用）
上記手段によれば、果実の果ン１搾汁後の残渣セルロー
スが木材Ｕ＆維（パルプ）の役をなして、和紙や西洋紙
ど異なる独特の感じを出した紙が得られる。つまり、パ
ルプに相当するものが果実残渣セルロースであるため、
それぞれの果実独特の感じが現出される。<Function> According to the above means, the residual cellulose after squeezing the juice of the fruit acts as wood U and fiber (pulp), and paper with a unique feel different from that of Japanese paper or Western paper can be obtained. In other words, since the pulp equivalent is fruit residue cellulose,
Each fruit has its own unique flavor.
（発明の効果）
本発明に係る紙は、繊組質系果実の果汁搾ン（後の残渣
セルロースを主材として抄造したものであるから、和紙
や西洋紙と’Ｅ ＜Ｚる独特の感じを呈する。(Effects of the Invention) Since the paper according to the present invention is made mainly from the cellulose residue after squeezing the juice of fibrous fruits, it has a unique feel similar to that of Japanese paper or Western paper. exhibits.
つまり、果実の残渣セルロースであるため、夫々の果実
の感じを現わすことができ、別途、原材料の果実残渣か
ら抽出した芳香物等を添加することで、果実の香りのす
る嗜好性の高い紙を提供できる。In other words, since it is made from fruit residue cellulose, it can express the feel of each fruit, and by adding aromatic substances extracted from the raw material fruit residue, it is possible to create highly palatable paper with a fruit scent. can be provided.
又、紙料の主材どなる果実の残渣セルロースは、従来、
産業廃棄物とじて１！Ｉ！設または焼却処分され、その
量が益々増大する近年においては処理に要する費用も莫
大なものとなり、且つ焼却の結果生じる煤煙等が新たな
公害源となっている。本発明は、その産業廃棄物を有効
利用することにより、処理問題と水相繊維資源の枯渇と
いう重要な問題を同時に解決することが出来るという大
きなメリットを有する。In addition, the main material of paper stock, cellulose from fruit residues, has traditionally been
Industrial waste 1! I! In recent years, as the amount of such waste is increasing, the costs required for treatment have become enormous, and the soot and smoke produced as a result of incineration have become a new source of pollution. The present invention has the great advantage of being able to simultaneously solve the important problems of treatment and depletion of aqueous fiber resources by effectively utilizing the industrial waste.
（実施例） 以下、本発明の実施例について説明する。(Example) Examples of the present invention will be described below.
尚、本実施例はリンゴ果実の果汁搾汁後の残渣セルロー
スを紙料とする例について説明する。In this example, an example in which cellulose residue after squeezing the juice of an apple fruit is used as paper stock will be described.
先づ、リンゴの搾り滓を粉砕し、該搾り滓の３倍量の水
を加えて５分間ミギ→ノーに掛（プ、しかる後、搾って
残渣を取り出し、その残渣をアヒトンで３回洗浄した後
、濾過して濾過液と残渣に分離し、残渣は乾燥処理を施
こす。First, crush the apple dregs, add 3 times the amount of water to the dregs, and soak for 5 minutes, then squeeze and remove the residue. Wash the residue 3 times with ahiton After that, it is filtered to separate a filtrate and a residue, and the residue is dried.
次いで、乾燥した残渣を分解、漂白するが、今回は、水
酸化ナトリウム（Ｎａ叶）の損を下記の如く４種類に変
え、アルカリ分解を行なった。Next, the dried residue was decomposed and bleached, but this time, alkaline decomposition was performed with the amount of sodium hydroxide (Na leaves) changed to four types as shown below.
試料（残渣）：５３
水酸化ナトリウム： ■ Ｏｇ、■ ５１（ＩＶ＆ａ０
＋１ ） ■ １０ｇ、■ ２０り水
： ２００１１Ｆ水酸化ナ
トリウムの量を変えた４種類を調整し、夫々を１時間攪
拌し、８０℃の恒温水中に４時間置ぎ、しかる後取り出
して１日冷却した。Sample (residue): 53 Sodium hydroxide: ■ Og, ■ 51 (IV&a0
+1) ■ 10g, ■ 20 liters of water
: Four types were prepared with different amounts of 20011F sodium hydroxide, each was stirred for 1 hour, placed in constant temperature water at 80°C for 4 hours, and then taken out and cooled for 1 day.
次に、各溶液に塩酸を加え中性に近づけ、濾過後、残渣
に次亜塩素酸すＩ〜ツリウム ｉｌを加え、６０℃の恒
温水中に１時間３０分放置する。Next, hydrochloric acid was added to each solution to bring it close to neutrality, and after filtration, hypochlorous acid (I) to thulium (I) was added to the residue, and the solution was left in constant temperature water at 60° C. for 1 hour and 30 minutes.
この段階で、試料■はぼは漂白された。At this stage, sample 1 was bleached.
更に、試料■〜■に再び次亜塩素酸ナトリウム５１１を
加え、６０℃の恒温水中に２時間置き、試料■に水酸化
ノトリウムを更に加えた。この段階で、試料■はやや漂
白された。Furthermore, sodium hypochlorite 511 was added again to Samples (1) to (2) and placed in constant temperature water at 60°C for 2 hours, and notrium hydroxide was further added to Sample (2). At this stage, sample ■ was slightly bleached.
しかる後、試料■〜■をＰ１１７に調整し、ブフナロー
ト、ガラスａｍを用いて吸引濾過して紙料となる残渣セ
ルロースが得られる。Thereafter, samples ① to ② are adjusted to P117 and filtered with suction using a Buchna funnel and glass am to obtain residual cellulose which becomes paper stock.
上記４種類の濾過液及び残渣の色は次のようになった。The colors of the four types of filtrate and residue were as follows.
尚、紙料の色や果皮の混ざり具合は、最初の粉砕工程の
程度を変えることで、さまざまなものをつくることが可
能である。By changing the degree of the initial crushing process, it is possible to create a wide variety of paper stock colors and blends of pericarp.
以上の如くして得られた残渣セルロース（紙料）を、所
定の濃度（例えば、０．１％前後の薄いｍ度〉になるよ
うに水を入れて攪拌し、これを今日周知の手すき用具、
或いは一定の速度で運転される長網抄紙機１円網抄紙機
等によって抄造することにより、組が完成される。The residual cellulose (paper stock) obtained as described above is mixed with water to a predetermined concentration (for example, a thin concentration of around 0.1%) and stirred, using a handmade tool known today. ,
Alternatively, the set is completed by making paper using a fourdrinier paper machine, a fourdrinier paper machine, etc., which is operated at a constant speed.
以上の如くして、得られた紙は、和紙や西洋紙と異なり
独特の感じを出し、包装紙、包装祠として、更にはノー
トや便箋、ハカキ等に用いることができる。The paper obtained as described above has a unique feel unlike Japanese paper or Western paper, and can be used as wrapping paper, wrapping paper, notebooks, stationery, postcards, etc.
同様にして、ミカン果実の残渣セルロースを紙料とした
紙は、木材繊維を材料としたものと同様、あらゆる紙製
品を作ることができるが、特に印刷用紙として用いると
独特な仕上りとなる。Similarly, paper made from cellulose residues from tangerine fruits can be used to make all kinds of paper products, just like those made from wood fibers, but it has a unique finish especially when used as printing paper.
又、パインアップル果実の残渣セルロースを紙料として
抄造した紙は、他のしのに比較して強度が高く、包装用
紙としての使用に最適である。In addition, paper made from pineapple fruit cellulose residue has higher strength than other types of paper, making it ideal for use as packaging paper.
Claims (4)
びセミセルロース等類似物質を主材として抄造したこと
を特徴とする紙。(1) A paper characterized in that it is made from cellulose residue after squeezing the juice of fibrous fruits and similar substances such as semicellulose as the main material.
る請求項（１）記載の紙。(2) The paper according to claim (1), wherein the residual cellulose or the like is apple fruit residue.
る請求項（１）記載の紙。(3) The paper according to claim (1), wherein the residual cellulose or the like is a residue of tangerine fruit.
渣である請求項（１）記載の紙。(4) The paper according to claim (1), wherein the residual cellulose or the like is a residue of pineapple fruit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20101589A JPH0364596A (en) | 1989-08-01 | 1989-08-01 | Paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20101589A JPH0364596A (en) | 1989-08-01 | 1989-08-01 | Paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0364596A true JPH0364596A (en) | 1991-03-19 |
| JPH0532520B2 JPH0532520B2 (en) | 1993-05-17 |
Family
ID=16434065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20101589A Granted JPH0364596A (en) | 1989-08-01 | 1989-08-01 | Paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0364596A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0834616A1 (en) * | 1996-10-02 | 1998-04-08 | Geopolimeri S.r.l. | Production of paper containing citrus-fruit residuals |
| JP2010195725A (en) * | 2009-02-26 | 2010-09-09 | Aomori Prefectural Industrial Technology Research Center | Incense stick of apple scent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5352702A (en) * | 1976-10-19 | 1978-05-13 | Kogyo Gijutsuin | Process for making fine cellulose fiber from raw fiber obtained from pine apple leaves and its use |
| JPS56144300A (en) * | 1980-04-10 | 1981-11-10 | Dainippon Shigiyou Kk | Paper making method using fiber substance of citrus fruits |
-
1989
- 1989-08-01 JP JP20101589A patent/JPH0364596A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5352702A (en) * | 1976-10-19 | 1978-05-13 | Kogyo Gijutsuin | Process for making fine cellulose fiber from raw fiber obtained from pine apple leaves and its use |
| JPS56144300A (en) * | 1980-04-10 | 1981-11-10 | Dainippon Shigiyou Kk | Paper making method using fiber substance of citrus fruits |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0834616A1 (en) * | 1996-10-02 | 1998-04-08 | Geopolimeri S.r.l. | Production of paper containing citrus-fruit residuals |
| JP2010195725A (en) * | 2009-02-26 | 2010-09-09 | Aomori Prefectural Industrial Technology Research Center | Incense stick of apple scent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0532520B2 (en) | 1993-05-17 |
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