JPH0362904A - Manufacture of nickel-based ferrite - Google Patents
Manufacture of nickel-based ferriteInfo
- Publication number
- JPH0362904A JPH0362904A JP1198282A JP19828289A JPH0362904A JP H0362904 A JPH0362904 A JP H0362904A JP 1198282 A JP1198282 A JP 1198282A JP 19828289 A JP19828289 A JP 19828289A JP H0362904 A JPH0362904 A JP H0362904A
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- raw material
- oxide
- based ferrite
- ferrite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 25
- 229910000859 α-Fe Inorganic materials 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 229910000480 nickel oxide Inorganic materials 0.000 abstract description 15
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 abstract description 2
- 238000010304 firing Methods 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 5
- 229910007565 Zn—Cu Inorganic materials 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 2
- 229910018661 Ni(OH) Inorganic materials 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229910018583 Ni(O) Inorganic materials 0.000 description 1
- 229910018605 Ni—Zn Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Soft Magnetic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、原料として水酸化ニッケル（Ｎｉ （ＯＨ）
２ ）を使用するニッケル系フェライトの製造方法に関
するものである。[Detailed description of the invention] [Industrial application field] The present invention uses nickel hydroxide (Ni (OH)) as a raw material.
The present invention relates to a method for producing nickel-based ferrite using 2).
従来、ニッケル（Ｎｉ）を成分として含むフェライト（
例えばＮｉ −Ｚｎ系フェライト、Ｎｉ−Ｚｎ−Ｃｕ系
フェライト等）は、酸化ニッケル（Ｎｉｐ）をニッケル
原料として製造していた。Conventionally, ferrite containing nickel (Ni) as a component (
For example, Ni-Zn ferrite, Ni-Zn-Cu ferrite, etc.) have been manufactured using nickel oxide (Nip) as a nickel raw material.
この製造方法では、他の原料、例えば酸化第２鉄（Ｆｅ
、 ｏ、 ）、酸化亜鉛（ＺｎＯ）、酸化銅（Ｃｕｂ）
等と、酸化ニッケル（Ｎｉｐ）を所定の組成となるよう
に秤量、混合し、仮焼成、粉砕、顆粒化、成形、本焼成
を経て所望のフェライトを製造していた。In this production method, other raw materials, such as ferric oxide (Fe
, o, ), zinc oxide (ZnO), copper oxide (Cub)
etc. and nickel oxide (Nip) were weighed and mixed to have a predetermined composition, and the desired ferrite was manufactured through preliminary firing, crushing, granulation, molding, and main firing.
ところで近年、８ＭＣ対策用ノイズフィルターコアにお
いて、ノイズの高周波化に伴ってＮｉ −Ｚｎ系フェラ
イトの需要は増加する一方である。そのため、品質を維
持しつつより安価なニッケル系フェライトを製造する必
要が生じた。Incidentally, in recent years, demand for Ni--Zn-based ferrite has been increasing in noise filter cores for 8MC countermeasures as the frequency of noise has become higher. Therefore, it became necessary to manufacture nickel-based ferrite at a lower price while maintaining quality.
しかるに酸化ニッケルは高価であり、また不純物含有量
（特にコバルト含有量）の少ない酸化ニッケルを得るこ
とは困難であるなどの問題点があったー
本発明は上記の問題点を解決するためになされたもので
、酸化ニッケル以外の安価なニッケル原料を使用するこ
とができ、これにより安価で品質の優れたニッケル系フ
ェライトを製造できる方法を得ることを目的とする。However, nickel oxide is expensive, and it is difficult to obtain nickel oxide with low impurity content (particularly cobalt content).The present invention was made to solve the above problems. The object of the present invention is to provide a method that allows the use of inexpensive nickel raw materials other than nickel oxide, thereby producing inexpensive and high-quality nickel-based ferrite.
本発明のニッケル系フェライトの製造方法は、ニッケル
を成分として含むフェライトの製造方法において、水酸
化ニッケルをニッケル原料として使用する方法である。The method for producing nickel-based ferrite of the present invention is a method for producing ferrite containing nickel as a component, in which nickel hydroxide is used as a nickel raw material.
具体的な製造方法は従来と同様の方法が採用でき、例え
ば酸化第２鉄、酸化亜鉛、酸化銅等の他の原料と水酸化
ニッケルを所定の組成となるように秤量して混合し、仮
焼成、粉砕、顆粒化、成形、本焼成を経てフェライトを
製造する。The specific manufacturing method can be the same as conventional methods. For example, other raw materials such as ferric oxide, zinc oxide, copper oxide, etc. and nickel hydroxide are weighed and mixed to have a predetermined composition, and then temporarily mixed. Ferrite is manufactured through firing, crushing, granulation, molding, and main firing.
本発明のニッケル系フェライトの製造方法においては、
水酸化ニッケル（Ｎｉ（Ｏ）ｌ）ａ）は酸化ニッケル（
Ｎｉｐ）と比較して水（Ｈ，０） １分子を多く含むの
みであるので、他のニッケル原料を使用する場合に比べ
て原料変更に伴う製造プロセスに与える影響が小さい。In the method for producing nickel-based ferrite of the present invention,
Nickel hydroxide (Ni(O)l)a) is nickel oxide (
Since it contains only one molecule of water (H,0) more than nickel (Nip), the influence on the manufacturing process due to a change in raw materials is smaller than when other nickel raw materials are used.
例えば塩化ニッケル（ＮｉＣＱｚ ）を使用すると、焼
成時に塩素ガス（ＣＱ２）が発生するため、排気装置の
増設、焼成条件の大きな変更等、製造設備に大きな変更
を必要とするが、水酸化ニッケルを使用すると、水蒸気
が発生するのみで、酸化ニッケル（Ｎｉｐ）を用いる従
来の製造設備をなんら変更することなく、ニッケル系フ
ェライトが得られる。For example, if nickel chloride (NiCQz) is used, chlorine gas (CQ2) is generated during firing, which requires major changes to manufacturing equipment, such as adding an exhaust system and changing firing conditions, but using nickel hydroxide Then, only water vapor is generated, and nickel-based ferrite can be obtained without making any changes to conventional manufacturing equipment that uses nickel oxide (NIP).
Ｎｉ −Ｚｎ −Ｃｕ系フェライトにおいて、ニッケル
原料として不純物濃度の低い水酸化ニッケル（Ｎｉ（Ｏ
Ｈ）ｚ）を用いて製造したところ、従来の生産設備およ
び製造工程に何の変更を加えることなく、従来と同等の
特性をもつフェライトが１組成により多少変化するが、
１０％以上低コストで得られた。In Ni-Zn-Cu ferrite, nickel hydroxide (Ni(O
H) When manufactured using z), without making any changes to the conventional production equipment and manufacturing process, ferrite with the same characteristics as the conventional one changed somewhat depending on the composition, but
It was obtained at a cost lower than 10%.
実施例として、 Ｆｅ２Ｏ，を４８％、 ＺｎＯを３１
％、Ｎ１（ＯＨ）、を１４．７％、ＣｕＯを６．３％（
すべて＋１０１％）の割合で混合し、仮焼成、粉砕して
得たＮｉ −Ｚｎ −Ｃｕ系フェライトを、１ ｔｏｎ
／−でプレスし、１０６０℃で焼成することにより供試
体を得た。この供試体は初透磁率μｌが７００、キュリ
ー温度Ｔｃが１５０℃の特性を有するものであった。こ
れは酸化ニッケル（Ｎｉｐ）を用いて同一組成で作った
フェライトと同等の特性である。As an example, Fe2O, 48%, ZnO 31%
%, N1(OH), 14.7%, CuO 6.3% (
1 ton of Ni-Zn-Cu-based ferrite obtained by mixing, pre-calcining and pulverizing at a ratio of +101%)
A specimen was obtained by pressing at /- and firing at 1060°C. This specimen had an initial magnetic permeability μl of 700 and a Curie temperature Tc of 150°C. This property is equivalent to that of ferrite made with the same composition using nickel oxide (Nip).
原料の混合比としては上記に限らず、Ｆｅ、 Ｏ，が４
７〜４９．５％、ＺｎＯが１５〜３５％、Ｎｉ（ＯＨ）
２が１０〜２５％、ＣｕＯが４〜１０％（すべてｍｏ１
％）の範囲でμ、が１００〜２０００の範囲の特性をも
つフェライトが得られた。The mixing ratio of raw materials is not limited to the above, but Fe, O, is 4
7-49.5%, ZnO 15-35%, Ni(OH)
2 is 10-25%, CuO is 4-10% (all mo1
%) and a ferrite having a characteristic μ in the range of 100 to 2000 was obtained.
また焼成温度は９５０〜１２００℃の範囲で、組成と必
要な特性に適した温度を選択することが可能である。Further, the firing temperature is in the range of 950 to 1200°C, and it is possible to select a temperature suitable for the composition and required properties.
すなわち上記実施例において、従来の酸化ニッケルを使
用したフェライトと同等の緒特性を持つフェライトが容
易に得られた。また水酸化ニッケル（Ｎｉ（Ｏｌｌ）２
）を使用した場合の方が焼成時の焼結性が良好であった
。そのためプレス条件や焼成条件を従来より緩和するこ
とが可能となり、製造コストが低減する。That is, in the above examples, ferrite having the same mechanical characteristics as conventional ferrite using nickel oxide was easily obtained. Also, nickel hydroxide (Ni(Oll)2
) had better sinterability during firing. Therefore, it becomes possible to relax the pressing conditions and firing conditions compared to the conventional ones, and the manufacturing cost is reduced.
なお、水酸化ニッケル（Ｎｉ（ＯＨ）、）の使用可能な
組成範囲は上記実施例の範囲のみに限られない。Note that the usable composition range of nickel hydroxide (Ni(OH)) is not limited to the range of the above embodiments.
酸化ニッケルと比較して水酸化ニッケルは水（Ｎ２０）
１分子を多く含むだけの違いであるので、酸化ニッケル
が使用可能であった全組成域で、水酸化ニッケルも使用
可能である。事実、上記実施例では上記組成範囲におけ
る試作時には、水酸化ニッケルの使用限界の組成を示す
ような状況は、外観上および特性上−切ａ測されなかっ
た。Compared to nickel oxide, nickel hydroxide is water (N20)
Since the difference is only that it contains more one molecule, nickel hydroxide can also be used in the entire composition range where nickel oxide can be used. In fact, in the above-mentioned example, during the trial production in the above-mentioned composition range, no situation in which the composition of nickel hydroxide was at the limit of use was observed in terms of appearance and properties.
以上の通り、本発明によれば、ニッケル原料として水酸
化ニッケルを使用することにより、現在の酸化ニッケル
を使用する設備をそのまま使用し。As described above, according to the present invention, by using nickel hydroxide as a nickel raw material, current equipment that uses nickel oxide can be used as is.
工程変更をすることなく、低コストで従来と同等の特性
を持ち、焼結性の良好なニッケル系フェライトを製造す
ることができる。Without changing the process, it is possible to produce nickel-based ferrite at low cost, with properties equivalent to conventional ones, and with good sinterability.
Claims (1)
において、水酸化ニッケルをニッケル原料として使用す
ることを特徴とするニッケル系フェライトの製造方法。(1) A method for producing ferrite containing nickel as a component, characterized in that nickel hydroxide is used as a nickel raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1198282A JPH0362904A (en) | 1989-07-31 | 1989-07-31 | Manufacture of nickel-based ferrite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1198282A JPH0362904A (en) | 1989-07-31 | 1989-07-31 | Manufacture of nickel-based ferrite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0362904A true JPH0362904A (en) | 1991-03-19 |
Family
ID=16388535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1198282A Pending JPH0362904A (en) | 1989-07-31 | 1989-07-31 | Manufacture of nickel-based ferrite |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0362904A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2790039A1 (en) | 1999-02-18 | 2000-08-25 | Usui Kokusai Sangyo Kk | FUEL SUPPLY RAMP ASSEMBLY |
| CN108675360A (en) * | 2018-06-01 | 2018-10-19 | 五邑大学 | A kind of β-nickel hydroxide/iron oxide ultrathin nanometer piece, and preparation method thereof |
-
1989
- 1989-07-31 JP JP1198282A patent/JPH0362904A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2790039A1 (en) | 1999-02-18 | 2000-08-25 | Usui Kokusai Sangyo Kk | FUEL SUPPLY RAMP ASSEMBLY |
| US6354273B1 (en) | 1999-02-18 | 2002-03-12 | Usui Kokusai Sangyo Kaisha Ltd. | Fuel delivery rail assembly |
| US6470859B2 (en) | 1999-02-18 | 2002-10-29 | Usai Kokusai Sangyo Kaisha Ltd. | Fuel delivery rail assembly |
| CN108675360A (en) * | 2018-06-01 | 2018-10-19 | 五邑大学 | A kind of β-nickel hydroxide/iron oxide ultrathin nanometer piece, and preparation method thereof |
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