JPH0345814B2 - - Google Patents
Info
- Publication number
- JPH0345814B2 JPH0345814B2 JP58151121A JP15112183A JPH0345814B2 JP H0345814 B2 JPH0345814 B2 JP H0345814B2 JP 58151121 A JP58151121 A JP 58151121A JP 15112183 A JP15112183 A JP 15112183A JP H0345814 B2 JPH0345814 B2 JP H0345814B2
- Authority
- JP
- Japan
- Prior art keywords
- photosensitive
- resin
- diazo
- weight
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 20
- 229920005989 resin Polymers 0.000 claims description 19
- 239000011347 resin Substances 0.000 claims description 19
- 239000010410 layer Substances 0.000 claims description 14
- 239000002985 plastic film Substances 0.000 claims description 8
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000011247 coating layer Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 239000006224 matting agent Substances 0.000 description 6
- -1 polyethylene terephthalate Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000012461 cellulose resin Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- LKWQZVLRCNRMAR-BTJKTKAUSA-N (z)-but-2-enedioic acid;1-ethenylpyrrolidin-2-one Chemical compound C=CN1CCCC1=O.OC(=O)\C=C/C(O)=O LKWQZVLRCNRMAR-BTJKTKAUSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- MGJXBDMLVWIYOQ-UHFFFAOYSA-N methylazanide Chemical compound [NH-]C MGJXBDMLVWIYOQ-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/805—Photosensitive materials characterised by the base or auxiliary layers characterised by stripping layers or stripping means
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Liquid Crystal (AREA)
Description
【発明の詳細な説明】
本発明はジアゾ感光面が剥離性を有し、かつそ
の裏面が鉛筆等に対しすぐれた筆記性を示すとと
もに透明性にもすぐれたジアゾタイプ感光性フイ
ルムに関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a diazo type photosensitive film whose diazo photosensitive surface has peelability and whose back surface exhibits excellent writing properties with pencils and the like, as well as excellent transparency. .
従来土木測量、建築設計分野においてジアゾタ
イプの第二原図が多く実用に供されている。 Conventionally, many diazo type second original drawings have been put to practical use in the fields of civil engineering surveying and architectural design.
そして前記の第二原図はその用途上必然的に下
記する諸機能が要求される。すなわち、鉛筆や
水性インキ等による筆記性、描画性がすぐれてい
ること。焼付画像が鮮明であり、しかも長期間
の保存中に変質しないこと。鮮明な焼付画像が
得られるべく十分な透明性、平滑表面を具備して
いること。などである。 The second original drawing described above is necessarily required to have the following functions due to its use. In other words, it must have excellent writing and drawing properties with pencils, water-based inks, etc. The printed image must be clear and not deteriorate during long-term storage. It must have sufficient transparency and a smooth surface so that a clear printed image can be obtained. etc.
しかるに現在市販されているジアゾタイプの第
二原図は、その多くがシリカ、アルミナおよびプ
ラスチツク粉末等のマツト剤を感光剤に配合して
筆記特性や他の特性を出している。 However, many of the diazo-type second originals currently on the market incorporate matting agents such as silica, alumina, and plastic powder into the photosensitizer to provide writing and other characteristics.
そしてまたかかる従来のジアゾタイプの第二原
図はベースと感光層との密着が良好で剥離しない
ように感光層を形成している塗膜剤として接着性
良好なものを使用している。 Furthermore, in the conventional second original of the diazo type, a coating agent with good adhesive properties is used to form the photosensitive layer so that the base and the photosensitive layer adhere well and do not peel off.
ところがこのような従来の第二原図は画像形成
後、加筆はできる利点はあるものの分版等を行う
とき、その加筆部分のみを分版することは不可能
であつた。 However, although such conventional second original drawings have the advantage of allowing additions to be made after image formation, it has been impossible to separate only the added portions when performing plate separation.
また、特開昭56−64334号記載のように、支持
体の両面に発色の異なるジアゾ感光層を設け、少
なくとも一方の面が剥離できるように構成するこ
とにより多色第二原図を得るというものもある。
しかし、この方法においても剥離はできるものの
前記第二原図と同様に加筆部分のみを分版するこ
とはできなかつた。さらに、この剥離可能な感光
層はセルロース系樹脂を主体としているため温湿
度の影響を非常に受けやすく、支持体から剥離す
る際に安定な剥離強度が得られなかつた。また、
湿度が低い環境で剥離作業を行い多色画像を形成
すると、セルロース系樹脂の凝集力により、残つ
ている一方の感光層側へのカールが強く作業性が
悪いものであつた。 In addition, as described in JP-A No. 56-64334, a multicolor second original image is obtained by providing diazo photosensitive layers with different color development on both sides of a support and configuring it so that at least one side can be peeled off. There is also.
However, even with this method, although peeling was possible, it was not possible to separate only the added portions as in the case of the second original drawing. Furthermore, since this peelable photosensitive layer is mainly composed of cellulose resin, it is very susceptible to the influence of temperature and humidity, and stable peel strength cannot be obtained when peeling it off from the support. Also,
When a multicolor image was formed by performing a peeling operation in a low humidity environment, the cohesive force of the cellulose resin caused strong curling toward the remaining photosensitive layer, resulting in poor workability.
本発明者は第二原図に加筆後、その加筆部分の
みを第二原図のプラスチツクフイルム上に残し、
ジアゾ感光画像部分をプラスチツクフイルムから
物理的に剥離することにより分版が容易に行える
ことを知見し、また塩化ビニリデン系樹脂を結合
剤の主成分として剥離性の感光性塗膜層を形成さ
せることにより温湿度の変化に対して安定な剥離
強度が得られ、感光層を剥離してもカールせず平
面性の良いことを知見して本発明を完成するに至
つた。 After adding to the second original drawing, the inventor left only the added part on the plastic film of the second original drawing,
It has been discovered that separation can be easily performed by physically peeling off the diazo-sensitive image area from the plastic film, and that a releasable photosensitive coating layer can be formed using vinylidene chloride resin as the main component of the binder. The present invention was completed based on the findings that stable peel strength against changes in temperature and humidity can be obtained, and that even when the photosensitive layer is peeled off, the photosensitive layer does not curl and has good flatness.
すなわち本発明は、透明プラスチツクフイルム
ベースの片面に、塩化ビニリデン系樹脂を結合剤
の主成分としジアゾ系感光色素を含有する剥離性
の感光性塗膜層を設け、他方の面にマツト層を形
成してなる剥離性ジアゾタイプ感光性フイルムで
ある。 That is, in the present invention, a peelable photosensitive coating layer containing vinylidene chloride resin as the main binder and diazo photosensitive dye is provided on one side of a transparent plastic film base, and a matte layer is formed on the other side. This is a peelable diazo type photosensitive film.
本発明に用いられる透明プラスチツクフイルム
ベースとはポリエチレンテレフタレートおよびポ
リエチレンナフタレート等のポリエステルフイル
ム、ポリカーボネートフイルム、セルロースアセ
テートフイルム、ポリプロピレンフイルムなどで
ある。 The transparent plastic film base used in the present invention includes polyester films such as polyethylene terephthalate and polyethylene naphthalate, polycarbonate films, cellulose acetate films, polypropylene films, and the like.
次に前記フイルムの片面に塩化ビニリデン系樹
脂を結合剤の主成分としジアゾ系感光色素を含有
する剥離性の感光性塗膜層を設けるが、前記ジア
ゾ系感光色素としては従来一般に知られている任
意のものでよい。具体的には、例えば、４−モル
ホリノ−２・５−ジプトキシベンゼンジアゾニウ
ム−ZnCl2、４−モルホリノ−２・５−ジエトキ
シベンゼンジアゾニウム−1/2ZnCl2等が使用さ
れる。また、前記ジアゾ系感光色素の塗膜形成成
分としては塩化ビニリデン系樹脂を主成分として
使用する。但し、塩化ビニリデン系樹脂の持つ固
有の性質であるブロツキング性あるいはガス不透
過性（現像性）を改善するために、塗膜調整用と
して例えば塩化ビニル−酢酸ビニル共重合体、塩
化ビニル樹脂、アクリル樹脂、スチレン樹脂、酢
酸ビニル樹脂等の樹脂を配合する必要がある。そ
して前記樹脂は、メチルエチルケトン、メチルイ
ソブチルケトン、シクロヘキサノン、ベンゾー
ル、トルオール、キシロール、メタノール、エタ
ノール、イソプロパノール等の有機溶剤の一種又
は二種以上に溶解または分散して使用される。ま
た前記の塗膜形成剤には、必要に応じて分散剤、
界面活性剤、マツト剤等を添加してもよい。 Next, a removable photosensitive coating layer containing vinylidene chloride resin as the main binder and a diazo photosensitive dye is provided on one side of the film. It can be anything you like. Specifically, for example, 4-morpholino-2,5-diptoxybenzenediazonium- ZnCl2 , 4-morpholino-2,5-diethoxybenzenediazonium-1/2ZnCl2 , etc. are used. Furthermore, as a coating film forming component of the diazo photosensitive dye, a vinylidene chloride resin is used as a main component. However, in order to improve the blocking property or gas impermeability (developability), which are the inherent properties of vinylidene chloride resin, for example, vinyl chloride-vinyl acetate copolymer, vinyl chloride resin, acrylic resin, etc. It is necessary to blend resins such as resin, styrene resin, and vinyl acetate resin. The resin is used by being dissolved or dispersed in one or more organic solvents such as methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, benzol, toluene, xylene, methanol, ethanol, and isopropanol. In addition, the above-mentioned coating film forming agent may include a dispersant,
Surfactants, matting agents, etc. may be added.
なお本発明においては、透明プラスチツクフイ
ルムの片面に前記の感光性塗膜形成剤を付与し、
他方の面にマツト層を形成せしめるが、前記のマ
ツト層を設けるにはマツト剤を結合樹脂に分散さ
せた塗剤をプラスチツクフイルムに塗布すること
によりなされる。 In addition, in the present invention, the above-mentioned photosensitive coating film forming agent is applied to one side of a transparent plastic film,
A matte layer is formed on the other side, and the matte layer is provided by applying a coating material in which a matting agent is dispersed in a binder resin to the plastic film.
本発明に用いられるマツト剤としてはガラス粉
末、シリカ粉末、粘土粉末、酸化チタン、澱粉、
溶融アルミナ微粉末等が挙げられ、平均粒子が
0.1〜50μmのものが使用されるが特に１〜10μm
のものが好ましい。 Matting agents used in the present invention include glass powder, silica powder, clay powder, titanium oxide, starch,
Examples include fused alumina fine powder, etc., with an average particle size of
0.1 to 50 μm is used, but especially 1 to 10 μm
Preferably.
また、結合樹脂としてはメチルセルロース、ヒ
ドロキシエチルセルロース、ソジウムカルボキシ
メチルセルロース、マレイン酸−ビニルピロリド
ン共重合体樹脂、ポリスチレン樹脂、マレイン酸
樹脂、キシレン樹脂、フエノール樹脂、アクリル
樹脂、ポリウレタン樹脂、アルキツド樹脂等が挙
げられる。 Examples of the binding resin include methylcellulose, hydroxyethylcellulose, sodium carboxymethylcellulose, maleic acid-vinylpyrrolidone copolymer resin, polystyrene resin, maleic acid resin, xylene resin, phenolic resin, acrylic resin, polyurethane resin, and alkyd resin. It will be done.
なお本発明の剥離性ジアゾタイプ感光性フイル
ムを製造するに当たつては前記の如き塗膜形成剤
に所望のジアゾ感光色素の必要量を配合してこれ
を透明プラスチツクフイルムの片面に塗布し、次
いで他方のクリヤー面に前記の如きマツト剤を結
合樹脂に分散させた塗剤を塗布することによつて
なされる。 In producing the peelable diazo-type photosensitive film of the present invention, the necessary amount of the desired diazo-sensitive dye is mixed with the above-mentioned coating film forming agent, and this is coated on one side of a transparent plastic film. Next, the other clear surface is coated with a coating material in which the above-mentioned matting agent is dispersed in a binding resin.
本発明の剥離性ジアゾタイプ感光性フイルムは
ジアゾ感光面がカツター等による物理的な剥離手
段による剥離性を有しており、また該ジアゾ感光
面の裏面はマツト層が設けてあるため満足すべき
加筆性を有し、その透明度も極めて良好である。 The peelable diazo type photosensitive film of the present invention is satisfactory because the diazo photosensitive surface has peelability by physical peeling means such as a cutter, and the back side of the diazo photosensitive surface is provided with a matte layer. It is easy to write on and its transparency is extremely good.
従つて本発明の剥離性ジアゾタイプ感光性フイ
ルムを使用し、地図等を作成すると、修正加筆し
た部分をベースフイルムに残し、基になる感光画
像をベースフイルムから剥離して除去することが
できるので基になる感光画像をよごさずに分版等
の作成が容易に行えるすぐれた特性を有する。 Therefore, when the peelable diazo type photosensitive film of the present invention is used to create a map, etc., the corrected and added portions remain on the base film, and the underlying photosensitive image can be peeled off and removed from the base film. It has excellent properties that allow for easy creation of separations without disturbing the underlying photosensitive image.
以下、実施例により本発明を具体的に説明す
る。 Hereinafter, the present invention will be specifically explained with reference to Examples.
（実施例）
75μmのポリエステルベースフイルムの片面に、
下記処方のジアゾ感光液を塗布し、乾燥して、剥
離性を有する感光性塗膜層を設けた。(Example) On one side of a 75 μm polyester base film,
A diazo photosensitive solution having the following formulation was applied and dried to provide a photosensitive coating layer with peelability.
●塩化ビニル−酢酸ビニル共重合体 ８重量部
●塩化ビニリデン樹脂 12重量部
●メチルメタクリレート樹脂 ５重量部
●スルホサリチル酸 10重量部
●塩化亜鉛 ２重量部
●ｍ−オキシエチルフエノール 10重量部
●レゾルシン １重量部
●３−スルホン酸−１−オキシナフタリン−８−
スルホン酸メチルアミド ２重量部
●４−モルホリノベンゼンジアゾニウムジンクロ
ライドの複塩 ７重量部
●メチルセロソルブ 400重量部
●メチルエチルケトン 440重量部
●エタノール 100重量部
●微粉末シリカ ５重量部
（商品名：サイロイド978 富士デヴイソン社製）
次いで、前記ポリエステルベースフイルムの裏
面に下記処方のマツト剤塗布液をグラビアロール
コーターにて乾燥後の塗膜量が1.7ｇ／m2になる
ように塗布して剥離性ジアゾタイプ感光性フイル
ムを得た。● Vinyl chloride-vinyl acetate copolymer 8 parts by weight ● Vinylidene chloride resin 12 parts by weight ● Methyl methacrylate resin 5 parts by weight ● Sulfosalicylic acid 10 parts by weight ● Zinc chloride 2 parts by weight ● m-oxyethylphenol 10 parts by weight ● Resorcinol 1 Part by weight●3-sulfonic acid-1-oxynaphthalene-8-
Sulfonic acid methylamide 2 parts by weight ● Double salt of 4-morpholinobenzenediazonium dichloride 7 parts by weight ● Methyl cellosolve 400 parts by weight ● Methyl ethyl ketone 440 parts by weight ● Ethanol 100 parts by weight ● Finely powdered silica 5 parts by weight (Product name: Cyroid 978 Fuji) (Manufactured by Davison Co.) Next, a matting agent coating solution with the following formulation was applied to the back side of the polyester base film using a gravure roll coater so that the coating amount after drying was 1.7 g/ m2 , and a peelable diazo type photosensitive film was applied. Got a sex film.
●微粉末シリカ ５重量部
●ロジン変性マレイン酸樹脂 80重量部
●酢酸ビニル−ビニルピロリドン共重合体樹脂
20重量部
●キシレン 25重量部
●イソプロピルアルコール 200重量部
得られた感光性フイルムのジアゾ感光層とオリ
ジナルとを合わせて螢光灯にて露光後アンモニア
現像して第二原図を得た。●Fine powder silica 5 parts by weight ●Rosin-modified maleic acid resin 80 parts by weight ●Vinyl acetate-vinylpyrrolidone copolymer resin
20 parts by weight ● 25 parts by weight of xylene ● 200 parts by weight of isopropyl alcohol The diazo photosensitive layer of the obtained photosensitive film and the original were combined, exposed to a fluorescent lamp, and then developed with ammonia to obtain a second original.
この第二原図の裏面、すなわちマツト層は加筆
性、消しゴム消去性にすぐれ透光性も良好であつ
た。また、この第二原図の感光面の接着強度は40
ｇ／２mmであり、カツターナイフなどによつて、
容易にポリエステルベースフイルムから剥離する
ことができた。 The back surface of this second original, that is, the matte layer, had excellent writing properties and erasability with an eraser, and also had good translucency. In addition, the adhesive strength of the photosensitive surface of this second original drawing is 40
g/2mm, with a cutter knife etc.
It could be easily peeled off from the polyester base film.
Claims (1)
塩化ビニリデン系樹脂を結合剤の主成分としジア
ゾ系感光色素を含有する剥離性の感光性塗膜層を
設け、他方の面にマツト層を形成してなる剥離性
ジアゾタイプ感光性フイルム。1 On one side of the transparent plastic film base,
A peelable diazo type photosensitive film comprising a peelable photosensitive coating layer containing a vinylidene chloride resin as a main component as a binder and a diazo photosensitive dye, and a matte layer formed on the other side.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15112183A JPS6043653A (en) | 1983-08-19 | 1983-08-19 | Peelable diazo type photosensitive film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15112183A JPS6043653A (en) | 1983-08-19 | 1983-08-19 | Peelable diazo type photosensitive film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6043653A JPS6043653A (en) | 1985-03-08 |
| JPH0345814B2 true JPH0345814B2 (en) | 1991-07-12 |
Family
ID=15511821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15112183A Granted JPS6043653A (en) | 1983-08-19 | 1983-08-19 | Peelable diazo type photosensitive film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6043653A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5664334A (en) * | 1979-10-29 | 1981-06-01 | Ricoh Co Ltd | Manufacture of diazo type multicolor copied drawing |
| JPS58102229A (en) * | 1981-11-23 | 1983-06-17 | オセ−ネ−デルランド・ベ−・ヴエ− | Diazo-type material |
-
1983
- 1983-08-19 JP JP15112183A patent/JPS6043653A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5664334A (en) * | 1979-10-29 | 1981-06-01 | Ricoh Co Ltd | Manufacture of diazo type multicolor copied drawing |
| JPS58102229A (en) * | 1981-11-23 | 1983-06-17 | オセ−ネ−デルランド・ベ−・ヴエ− | Diazo-type material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6043653A (en) | 1985-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH08187934A (en) | Full-range ink jet recording medium | |
| JPS5947987B2 (en) | Matsuto film that can be added/edited | |
| JPS6087324A (en) | Diffusion transfer type photosensitive material | |
| US2873207A (en) | Diazotype reproduction material and method | |
| EP0125866B1 (en) | Narrow band light absorbing filter | |
| JPH0345814B2 (en) | ||
| US4241134A (en) | Electrostatically imageable drafting film | |
| JPS58102229A (en) | Diazo-type material | |
| JPS5846011B2 (en) | Light-shielding masking film | |
| US2963366A (en) | Photosensitive material | |
| JPH07239530A (en) | Supporting body for photogrpahic print paper | |
| JPS6044141B2 (en) | Design laminate | |
| JPS6398655A (en) | Photochromic film | |
| JPS6215549A (en) | Electrostatic recording body and its production | |
| JP2692642B2 (en) | Correction tape | |
| JPS6244492A (en) | Thermal recording material | |
| JPH0629970B2 (en) | Electrostatic recording material for plate making having mask layer | |
| JPS6043302B2 (en) | Design laminate | |
| JPH083520A (en) | Light-shielding tacky adhesive sheet | |
| GB2026201A (en) | Photographic material having a writing quality-imparting layer | |
| SU781747A1 (en) | Vesicular photographic material | |
| JPH09151359A (en) | Sheet for forming surface protecting film | |
| JPH0192744A (en) | Films for both of reflection and transmission | |
| JPS6237185A (en) | Transparency film for overhead projector | |
| JPS6152647A (en) | Electrostatic recording film having scribability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |