JPH0343242B2 - - Google Patents
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- Publication number
- JPH0343242B2 JPH0343242B2 JP9114382A JP9114382A JPH0343242B2 JP H0343242 B2 JPH0343242 B2 JP H0343242B2 JP 9114382 A JP9114382 A JP 9114382A JP 9114382 A JP9114382 A JP 9114382A JP H0343242 B2 JPH0343242 B2 JP H0343242B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- carbon atoms
- present
- eye
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 238000009835 boiling Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 150000005690 diesters Chemical class 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 210000004400 mucous membrane Anatomy 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 206010057385 Eyelid irritation Diseases 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 2
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 229940078545 isocetyl stearate Drugs 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 229940116422 propylene glycol dicaprate Drugs 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- ITPJXPXPEXDRLG-UHFFFAOYSA-N 2-octyldodecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)C(CC)CCCC ITPJXPXPEXDRLG-UHFFFAOYSA-N 0.000 description 1
- 241000283977 Oryctolagus Species 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- BOUIEBMBWBCUPB-UHFFFAOYSA-N decyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCC BOUIEBMBWBCUPB-UHFFFAOYSA-N 0.000 description 1
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- 231100001032 irritation of the eye Toxicity 0.000 description 1
- 239000007951 isotonicity adjuster Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- -1 salt Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Description
本発明は、アイライナー・マスカラ等のアイメ
イクアツプ化粧料の除去料に関し、眼の周囲に塗
布された化粧料を除去するに際して、眼やその周
辺の皮膚に対して刺激を与えない製品を提供する
ことを目的としている。
近年、マスカラ・アイライナー等のアイメイク
アツプ化粧料の機能として、汗や海水等の水分、
皮脂などの油分に対して化粧くずれしにくいこと
が重要視されている。この機能を得るために、低
沸点イソパラフイン系炭化水素と油剤を主成分と
する非水系タイプ、合成樹脂エマルジヨンと水を
主成分とする皮膜形成タイプなどの製品が実用化
されている。
しかしながら、化粧くずれしにくいという特性
が重視された結果、最近のアイメイクアツプ化粧
料は、これを除去する場合に簡単に除去し難いと
いう欠点を有するに至つた。このため、当該化粧
料を落とするための除去料の開発が急務となつて
いる。ところが、充分な除去能力を有する除去料
は眼粘膜・皮膚等に対する刺激性が強く、一方低
刺激性を主眼に置いたものは除去能力が劣るとい
うのが従来の除去料の問題点であつた。
本発明者等は、斯る問題を鑑みて鋭意研究を続
けた結果、充分な除去能力を有すると共に、眼粘
膜・皮膚等に対する刺激性を有さない極めて優れ
たアイメイクアツプ除去料を得るに及び、本発明
を完成した。
すなわち、本発明は炭素数23〜28のモノエステ
ルまたはジエステルの一種または二種以上を10〜
40重量％と、低沸点イソパラフイン系炭化水素
0.5〜５重量％と、一般式
または
（式中、Ｒは炭素数11〜17のアルキル基）で示
されるアルキルイミダゾリニウムベタインの一種
または二種以上を0.2〜２重量％と、水を30〜85
重量％とを必須に含有することを特徴としたアイ
メイクアツプ除去料である。
以下、本発明の構成について詳述する。本発明
に用いられるモノエステルまたはジエステルは炭
素数が23〜28のものである必要があり、好ましく
は24〜26である。炭素数22以下では眼粘膜・皮膚
に対する刺激性があり、炭素数29以上では除去能
力の点で劣る。これらモノエステルまたはジエス
テルとしては、ミリスチン酸デシル、２−エチル
ヘキサン酸２−オクチルドデシル、アジピン酸ジ
デシル、ジカプリン酸プロピレングリコール、２
−エチルヘキサン酸セチル等を挙げることができ
る。これらの配合量としては10〜40重量％、好ま
しくは15〜30重量％である。10重量％以下では充
分な除去効果が発現されず、40重量％以上では感
触的に好ましくない。また、本発明に用いられる
低沸点イソパラフイン系炭化水素は、アイソパ
ー、シエルソル等の商品名で知られるものであ
る。アイソパーはハンブル オイル アンド リ
フアイニング カンパニー製造のイソパラフイン
である。シエルソンは同様にしてシエル化学社製
造のイソパラフインである。この低沸点イソパラ
フインは沸点が240℃以下のものが望ましく、そ
の配合量は、0.5〜５重量％であつた。好ましく
は１〜３重量％である。配合量が0.5重量％以下
では、除去効果に寄与せず、５重量％以上では匂
いの点で好ましくない。さらに、本発明において
用いられるアルキルイミダゾリニウムベタイン
は、一般式
または
（式中、Ｒは炭素数11〜17のアルキル基）で示
されるもので、これを50％水溶液としたものが、
ミラノール・シー・ツー・エム・コンク
（Miranol C2M Conc）またはミラノール・シ
ー・エム・コンク（Miranol CM Conc.）等の名
称でミラノール社から市販されている。上記のア
ルキルイミダリニウムベタインは、所謂両性界面
活性剤の一種であるが、眼粘膜や皮膚等に対する
刺激性を有さず、しかも優れた洗浄作用を有して
いる。このものの配合量は0.2〜２重量％、好ま
しくは0.4〜1.5重量％である。0.2重量％以下で
は、洗浄作用が不充分であり、２重量％以上で
は、使用時、使用後の感触がベタつくので不適で
ある。また、本発明において用いられる水は30〜
85重量％の範囲で配合される。
本発明に係るアイメイクアツプ除去料は、上記
の構成であり、その外観は二層の液体状または乳
液状を呈するものである。なお、必要に応じて本
発明の必須構成物質以外の油分、活性剤、高分子
化合物、香料、色素、防腐剤、食塩等の等張剤等
を適宜加えてもよい。
次に、実施例に基づき本発明の効果を説明す
る。本発明の効果を示すにあたり、従来のアイメ
イクアツプ除去料を比較例として用い、除去効果
と眼瞼刺激性とについて比較を行つた。
実施例 重量％
ジカプリン酸プロピレングリコール 15
ステアリン酸イソセチル ５
イソパラフイン ２
２−ココイル−Ｎ−カルボキシメチル−Ｎ−ヒ
ドロキシエチルイミダゾリニウムベタイン 50
％水溶液 ２
食 塩 0.4
プロピレングリコール 10
防腐剤 0.1
精製水 65.5
比較例 重量％
流動パラフイン 70
ステアリン酸イソセチル 28
イソパラフイン ２
比較例 重量％
ポリオキシエチレンソルビタン（20E.O.） ３
食 塩 0.4
プロピレングリコール 10
防腐剤 0.1
精製水 86.5
上記の実施例及び２種の比較例のアイメイクア
ツプ除去料の除去効果と眼瞼刺激性の比較を次の
方法で行つた。
除去効果：女性15名からなるパネルにより、三
種類のタイプのアイライナー（非水系
型、皮膜形成型、乳化型）に対する各除
去料の除去効果を五段階評価（５：よ
い、４：ややよい、３：ふつう、２：や
やわるい、１：わるい）で評価した。
眼瞼刺激性：オスの白色種家兎の眼にサンプル
0.1mlを点眼し、放置後、結膜・角膜・
虹彩に対する刺激強度をドレーズ法で肉
眼により観察した。
結果を表１，２に示した。
The present invention relates to a removal agent for eye makeup cosmetics such as eyeliner and mascara, and provides a product that does not cause irritation to the eyes or the skin around them when removing cosmetics applied around the eyes. It is intended to. In recent years, eye make-up cosmetics such as mascara and eyeliner have been developed to remove moisture such as sweat and seawater.
It is important that makeup does not easily come off due to oils such as sebum. In order to obtain this function, products such as non-aqueous types whose main ingredients are low-boiling isoparaffinic hydrocarbons and oil agents, and film-forming types whose main ingredients are synthetic resin emulsions and water have been put into practical use. However, as a result of emphasis on the property that makeup does not easily come off, recent eye makeup cosmetics have come to have the disadvantage that they are difficult to remove. Therefore, there is an urgent need to develop a removal agent for removing the cosmetics. However, the problem with conventional removers is that removers that have sufficient removal ability are highly irritating to eye mucous membranes, skin, etc., while those that are designed to be hypoallergenic have poor removal ability. . As a result of intensive research in view of these problems, the present inventors have succeeded in obtaining an extremely excellent eye makeup remover that has sufficient removal ability and is not irritating to the eye mucous membranes, skin, etc. And, the present invention was completed. That is, the present invention uses one or more monoesters or diesters having 23 to 28 carbon atoms in combination with 10 to 28 carbon atoms.
40% by weight, low boiling isoparaffinic hydrocarbons
0.5-5% by weight and general formula or (In the formula, R is an alkyl group having 11 to 17 carbon atoms) 0.2 to 2% by weight of one or more alkylimidazolinium betaines represented by the formula (R is an alkyl group having 11 to 17 carbon atoms) and 30 to 85% of water
This is an eye makeup remover characterized by essentially containing % by weight. Hereinafter, the configuration of the present invention will be explained in detail. The monoester or diester used in the present invention must have 23 to 28 carbon atoms, preferably 24 to 26 carbon atoms. If the number of carbon atoms is less than 22, it is irritating to the eye mucous membranes and skin, and if the number of carbon atoms is more than 29, the removal ability is inferior. These monoesters or diesters include decyl myristate, 2-octyldodecyl 2-ethylhexanoate, didecyl adipate, propylene glycol dicaprate,
- Cetyl ethylhexanoate, etc. can be mentioned. The blending amount of these is 10 to 40% by weight, preferably 15 to 30% by weight. If it is less than 10% by weight, a sufficient removal effect will not be achieved, and if it is more than 40% by weight, it is not pleasant to the touch. Further, the low boiling point isoparaffinic hydrocarbon used in the present invention is known under trade names such as Isopar and Cielsol. Isopar is an isoparaffin manufactured by Humble Oil and Refining Company. Sielson is an isoparaffin manufactured by Siel Kagaku Co., Ltd. This low boiling point isoparaffin preferably has a boiling point of 240° C. or lower, and its blending amount is 0.5 to 5% by weight. Preferably it is 1 to 3% by weight. If the amount is less than 0.5% by weight, it will not contribute to the removal effect, and if it is more than 5% by weight, it will be unfavorable in terms of odor. Furthermore, the alkylimidazolinium betaine used in the present invention has the general formula or (In the formula, R is an alkyl group having 11 to 17 carbon atoms), and a 50% aqueous solution of this is
It is commercially available from Milanol Company under the names Miranol C2M Conc or Miranol CM Conc. The above-mentioned alkylimidalinium betaine is a type of so-called amphoteric surfactant, but has no irritation to eye mucous membranes, skin, etc., and has an excellent cleaning effect. The amount of this compound is 0.2 to 2% by weight, preferably 0.4 to 1.5% by weight. If it is less than 0.2% by weight, the cleaning action will be insufficient, and if it is more than 2% by weight, it will feel sticky during and after use, which is unsuitable. In addition, the water used in the present invention is
It is blended in a range of 85% by weight. The eye makeup remover according to the present invention has the above-mentioned structure, and has a two-layered liquid-like or emulsion-like appearance. Note that, if necessary, oils, active agents, polymer compounds, fragrances, pigments, preservatives, isotonic agents such as salt, etc. other than the essential constituents of the present invention may be added as appropriate. Next, the effects of the present invention will be explained based on Examples. In order to demonstrate the effects of the present invention, a conventional eye makeup remover was used as a comparative example, and the removal effect and eyelid irritation were compared. Examples Weight % Propylene glycol dicaprate 15 Isocetyl stearate 5 Isoparaffin 2 2-Cocoyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 50
% aqueous solution 2 Salt 0.4 Propylene glycol 10 Preservative 0.1 Purified water 65.5 Comparative example Weight % Liquid paraffin 70 Isocetyl stearate 28 Isoparaffin 2 Comparative example Weight % Polyoxyethylene sorbitan (20E.O.) 3 Salt 0.4 Propylene glycol 10 Preservative: 0.1 Purified water: 86.5 The removal effects and eyelid irritation of the eye makeup removers of the above examples and two comparative examples were compared in the following manner. Removal effect: A panel of 15 women evaluated the removal effect of each remover on three types of eyeliner (non-aqueous type, film-forming type, and emulsion type) on a five-point scale (5: good, 4: fair). , 3: Fair, 2: Slightly poor, 1: Poor). Eyelid irritation: sample in the eye of a male white domestic rabbit
After putting 0.1ml into the eye and leaving it for a while, the conjunctiva, cornea,
The intensity of stimulation to the iris was observed visually using the Draize method. The results are shown in Tables 1 and 2.
【表】【table】
【表】
以上の結果から明らかな如く、本発明に係るア
イメイクアツプ除去料は、除去効果、安全性とも
に優れている。[Table] As is clear from the above results, the eye makeup remover according to the present invention is excellent in both removal effect and safety.
Claims (1)
ルの一種または二種以上を10〜40重量％と、低沸
点イソパラフイン系炭化水素を0.5〜５重量％と、
一般式 または （式中、Ｒは炭素数11〜17のアルキル基）で示
されるアルキルイミダゾリニウムベタインの一種
または二種以上を0.2〜２重量％と、水を30〜85
重量％とを必須に含有することを特徴とするアイ
メイクアツプ除去料。[Claims] 1. 10 to 40% by weight of one or more monoesters or diesters having 23 to 28 carbon atoms, and 0.5 to 5% by weight of a low boiling point isoparaffinic hydrocarbon;
general formula or (In the formula, R is an alkyl group having 11 to 17 carbon atoms) 0.2 to 2% by weight of one or more alkylimidazolinium betaines represented by the formula (R is an alkyl group having 11 to 17 carbon atoms) and 30 to 85% of water
An eye makeup remover characterized by essentially containing % by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9114382A JPS58206510A (en) | 1982-05-27 | 1982-05-27 | Agent for removing eye makeup |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9114382A JPS58206510A (en) | 1982-05-27 | 1982-05-27 | Agent for removing eye makeup |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58206510A JPS58206510A (en) | 1983-12-01 |
| JPH0343242B2 true JPH0343242B2 (en) | 1991-07-01 |
Family
ID=14018298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9114382A Granted JPS58206510A (en) | 1982-05-27 | 1982-05-27 | Agent for removing eye makeup |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58206510A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072618B2 (en) * | 1985-12-09 | 1995-01-18 | 株式会社小林コ−セ− | Makeup remover |
| JP2775154B2 (en) * | 1988-04-26 | 1998-07-16 | 株式会社資生堂 | Anti-skin and anti-aging agents |
| JP5053560B2 (en) * | 2006-03-31 | 2012-10-17 | 株式会社コーセー | Double layer makeup remover |
| JP5086150B2 (en) * | 2008-03-26 | 2012-11-28 | 株式会社コーセー | Makeup remover |
-
1982
- 1982-05-27 JP JP9114382A patent/JPS58206510A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58206510A (en) | 1983-12-01 |
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