JPH0334978B2 - - Google Patents

Info

Publication number
JPH0334978B2
JPH0334978B2 JP56141719A JP14171981A JPH0334978B2 JP H0334978 B2 JPH0334978 B2 JP H0334978B2 JP 56141719 A JP56141719 A JP 56141719A JP 14171981 A JP14171981 A JP 14171981A JP H0334978 B2 JPH0334978 B2 JP H0334978B2
Authority
JP
Japan
Prior art keywords
louver
sub
main
particles
louvers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP56141719A
Other languages
Japanese (ja)
Other versions
JPS5843231A (en
Inventor
Tsukasa Nishimura
Osamu Kanda
Shigeru Nozawa
Kozo Obata
Norio Arashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Power Ltd
Original Assignee
Babcock Hitachi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Hitachi KK filed Critical Babcock Hitachi KK
Priority to JP14171981A priority Critical patent/JPS5843231A/en
Publication of JPS5843231A publication Critical patent/JPS5843231A/en
Publication of JPH0334978B2 publication Critical patent/JPH0334978B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Description

【発明の詳細な説明】 本発明は移動層反応装置に関し、特に粒子を上
方から下方へ移動させる移動層をルーバにより側
方から支持し、該ルーバ間の移動層を横切るよう
にガスを通過させる移動層反応装置に関するもの
である。この種の移動層反応装置は、例えばボイ
ラ等の排ガス中に含まれる亜硫酸ガスを吸着剤移
動層によつて吸着除去するために用いられる。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a moving bed reactor, in particular a moving bed in which particles are moved from above to below is laterally supported by louvers, and a gas is passed across the moving bed between the louvers. This invention relates to a moving bed reactor. This type of moving bed reactor is used, for example, to adsorb and remove sulfur dioxide gas contained in exhaust gas from a boiler or the like using an adsorbent moving bed.

従来、粒子状の吸着剤、触媒あるいはその他の
粒子の充填層にガスを通気し、ガス中の成分と粒
子を接触させ、反応あるいは捕集を行う場合、第
1図に示すようなルーバ1を垂直方向に多数並べ
この一対のルーバ1によつて粒子2を支持した移
動層型の充填層が使われている。排ガス3は、反
応器4内に導入され、ルーバ1の側方から移動層
を通り、粒子と接触反応した後、他方のルーバを
出て反応器4外に排出される。
Conventionally, when gas is aerated through a packed bed of particulate adsorbent, catalyst, or other particles, and the components in the gas are brought into contact with the particles for reaction or collection, a louver 1 as shown in Fig. 1 is used. A moving bed type packed bed is used in which particles 2 are supported by a pair of louvers 1 arranged vertically in large numbers. The exhaust gas 3 is introduced into the reactor 4, passes through the moving bed from the side of the louver 1, comes into contact with the particles, and then exits the other louver and is discharged to the outside of the reactor 4.

しかし、このようなルーバ1によつて支持した
移動層では第2図に示すようにルーバ1上に粒子
非移動部分1Aが形成される。そのため、取扱う
ガスが、例えば石炭ボイラの排ガスのように多量
のダストを含んでいる場合には、上記の非移動部
分1Aにダストが次第に蓄積し通風損失を増大さ
せるという欠点がある。また、ガス中の亜硫酸ガ
スを活性炭などの炭素系吸着剤で吸着するような
場合には、非移動部分1Aにある吸着剤は長時間
にわたつて亜硫酸ガスを飽和以上に吸着し、吸着
剤の表面が吸着した亜硫酸ガスより生成した硫酸
で濡れてくるようになり、ルーバ1を腐蝕させる
という問題がある。
However, in the moving layer supported by such a louver 1, a part 1A where particles do not move is formed on the louver 1, as shown in FIG. Therefore, when the gas to be handled contains a large amount of dust, such as the exhaust gas of a coal boiler, there is a drawback that the dust gradually accumulates in the non-moving portion 1A, increasing ventilation loss. In addition, when sulfur dioxide gas in gas is adsorbed with a carbon-based adsorbent such as activated carbon, the adsorbent in the non-moving part 1A adsorbs sulfur dioxide gas to more than saturation level over a long period of time, causing the adsorbent to absorb There is a problem in that the surface becomes wet with sulfuric acid generated from the adsorbed sulfur dioxide gas, corroding the louver 1.

本発明の目的は、ルーバ上に粒子が滞留するこ
となく、ルーバ上の粒子を良好に移動させ、ガス
の通風損失を防止することができる移動層反応装
置を提供することにある。
An object of the present invention is to provide a moving bed reactor that can satisfactorily move particles on the louvers without causing particles to remain on the louvers, and can prevent gas ventilation loss.

本発明は、従来のルーバ1では第2図に示すよ
うに主流の粒子群5が水平方向に及ぼす荷重と非
移動部分1Aの荷重が釣り合うために結果的に非
移動部分1Aにある粒子が主流の粒子群5の中に
流れ込まなくなることを着色粒子の流れにより明
らかにし、この荷重の釣合いを破壊するために、
ルーバ1の内側により傾斜角度の大きいサブルー
バを設け、このサブルーバを介して非移動部分
1Aの粒子を主流の中に効果的に流れ込ませるよ
うにしたものである。
In the conventional louver 1, as shown in FIG. 2, the load exerted in the horizontal direction by the mainstream particle group 5 balances the load on the non-moving part 1A, so that as a result, the particles in the non-moving part 1A become the main stream. In order to make it clear by the flow of colored particles that they no longer flow into the particle group 5, and to destroy this load balance,
A sub-louver with a larger inclination angle is provided inside the louver 1, and the non-moving part is moved through this sub-louver.
It is designed to effectively flow 1A particles into the mainstream.

本発明は、粒子を上方から下方へ移動させる移
動層をメインルーバとその内側に設けられたサブ
ルーバにより側方から支持し、該ルーバ間の移動
層を横切るようにガスを通過させる移動層反応装
置において、上下方向に垂直に一列に並んだメイ
ンルーバの内側に、同じく上下方向に垂直に並ん
だサブルーバを前記メインルーバの高さ方向の中
間に位置するように配置し、前記メインルーバお
よびサブルーバの水平となす角度が40〜80°で、
かつサブルーバの水平となす角度がメインルーバ
のそれより大きく、前記サブルーバの長さがメイ
ンルーバのそれの2/3〜4/5であることを特徴とす
る。
The present invention provides a moving bed reactor in which a moving bed that moves particles from above to below is supported from the side by a main louver and a sub-louver provided inside the main louver, and a gas is passed across the moving bed between the louvers. A sub-louver, which is also vertically aligned in the vertical direction, is arranged inside the main louver which is vertically aligned in a line, so as to be located in the middle of the main louver in the height direction, and between the main louver and the sub-louver. The angle with the horizontal is 40 to 80 degrees,
The sublouver is characterized in that the angle it makes with the horizontal is larger than that of the main louver, and the length of the sublouver is 2/3 to 4/5 of that of the main louver.

本発明において、サブルーバの傾斜角度をメイ
ンルーバより大きくしたのは、粒子の滞留が特に
メインルーバ下部で生じ易いため、サブルーバを
下方に向つてメインルーバにより近接するように
配置し、メインルーバ下部の粒子の荷重を上部よ
り軽減するためである。上記サブルーバの長さB
は、メインルーバの2/3〜4/5程度(特に3/4前後)
が好適である。なお前記両ルーバの水平となす角
度は、粒子の安息角より以上、通常は約40〜80°
の範囲が適当である。
In the present invention, the inclination angle of the sub-louver is made larger than that of the main louver because particles tend to accumulate particularly at the bottom of the main louver. This is to reduce the load of particles from the upper part. The length of the above sublouver B
is about 2/3 to 4/5 of the main louver (especially around 3/4)
is suitable. Note that the angle between the two louvers and the horizontal is greater than the angle of repose of the particles, usually about 40 to 80 degrees.
A range of is appropriate.

以下、本発明を図面によりさらに詳細に説明す
る。
Hereinafter, the present invention will be explained in more detail with reference to the drawings.

第3図は非煙脱硫用の吸着剤充填層に本発明の
反応装置を適用した実施例を示す説明図、第4図
は、そのルーバ部の拡大側面図である。吸着塔20
の中には塔の底部から頂部まで垂直にメインルー
バ6およびサブルーバ7が組になつて配列されて
おり、この組が一定の距離を置いて2列配置さ
れ、この2列のルーバの間に吸着剤8が充填され
ている。さらに吸着塔底部の最下端ルーバには垂
直案内板14が、さらにその下部には案内板15
が設けられ、デツドスペースによる吸着剤の滞留
が防止される。なお、整流体16がホツパ部に設
けられ、流れの円滑化を促進している。ボイラ等
の排ガス9はガス入口10から吸着塔20に流入
し、ルーバの間隙から吸着剤充填層に入り、もう
一方のルーバの間隙を経てガス出口11から流出
する。この間にガス中の亜硫酸ガスが吸着除去さ
れる。時間の経過に伴い吸着剤は飽和に達するの
で、吸着塔底部に達した吸着剤は、抜き出し器1
2により一定量ずつ連続的に抜き出され、再生装
置(ここでは図示していない)で再生された後、
ホツパから充填層内へ供給され、循環再使用され
る。
FIG. 3 is an explanatory view showing an embodiment in which the reaction apparatus of the present invention is applied to an adsorbent-filled bed for non-smoke desulfurization, and FIG. 4 is an enlarged side view of the louver portion thereof. Adsorption tower 20
Inside the tower, main louvers 6 and sub-louvers 7 are arranged vertically in pairs from the bottom to the top of the tower, and these pairs are arranged in two rows at a certain distance, and between these two rows of louvers. Adsorbent 8 is filled. Further, a vertical guide plate 14 is provided on the lowest louver at the bottom of the adsorption tower, and a guide plate 15 is further provided below the vertical guide plate 14.
is provided to prevent stagnation of adsorbent due to dead space. Note that a flow regulator 16 is provided at the hopper portion to promote smooth flow. Exhaust gas 9 from a boiler or the like flows into the adsorption tower 20 from the gas inlet 10, enters the adsorbent packed bed through the gap in the louver, and flows out from the gas outlet 11 through the gap in the other louver. During this time, sulfur dioxide gas in the gas is adsorbed and removed. As the adsorbent reaches saturation as time passes, the adsorbent that has reached the bottom of the adsorption tower is removed from the extractor 1.
2, a certain amount is continuously extracted, and after being regenerated by a regenerating device (not shown here),
It is supplied from the hopper into the packed bed and recycled.

このルーバシステムの詳細は、第4図に示すよ
うに、上下方向に垂直に一列に並んだメインルー
バ6の内側に、同じく上下方向に垂直に並んだサ
ブルーバ7を前記メインルーバの高さ方向の中間
に位置するように配置し、かつ前記サブルーバの
水平方向となす角度θ2をメインルーバの角度θ1
りも大きくしたものである。上記ルーバ各部の寸
法は、メインルーバ6のA部が200mm、サブルー
バ7のB部が150mm、θ1が60度、θ2が74度、メイ
ンルーバ6の間隙Cが200mm、メインルーバ6の
下端とサブルーバ上端の垂直距離Dが28.1mm、メ
インルーバ6の下端とサブルーバ7の上端の水平
距離Eが0〜10mm、メインルーバ6の下端とサブ
ルーバ7の下端の水平距離Fが35.5mmである。こ
のルーバーの間に、粒径5〜10mmの破砕した炭素
系吸着剤を充填して、下方より抜き出し、移動を
行つたところ、メインルーバ上の非移動部分は全
くなく、サブルーバ上にも非移動部分はほとんど
認められなかつた。またサブルーバをメインルー
バと平行に配置した場合と比較しても、吸着剤粒
子のルーバ上の移動がより円滑になることが認め
られた。また第3図に示すように案内板14、1
5を設けたことにより、この部分のデツドスペー
スがなくなり、塔底部の粒子堆積も防止すること
ができた。
The details of this louver system are as shown in Fig. 4. Inside the main louvers 6, which are vertically lined up in a row, sub-louvers 7, which are also vertically lined up, are arranged in the height direction of the main louvers. It is arranged so as to be located in the middle, and the angle θ 2 between the sub louver and the horizontal direction is larger than the angle θ 1 of the main louver. The dimensions of each part of the louver are as follows: A part of the main louver 6 is 200 mm, B part of the sub louver 7 is 150 mm, θ 1 is 60 degrees, θ 2 is 74 degrees, the gap C of the main louver 6 is 200 mm, and the lower end of the main louver 6 The vertical distance D between the upper end of the main louver 6 and the upper end of the sub louver 7 is 28.1 mm, the horizontal distance E between the lower end of the main louver 6 and the upper end of the sub louver 7 is 0 to 10 mm, and the horizontal distance F between the lower end of the main louver 6 and the lower end of the sub louver 7 is 35.5 mm. When we filled the space between these louvers with crushed carbon-based adsorbent with a particle size of 5 to 10 mm, pulled it out from below, and moved it, there was no non-movable part on the main louver, and there was no non-movable part on the sub-louver either. Parts were barely recognizable. It was also found that the adsorbent particles moved more smoothly on the louver compared to the case where the sub-louver was arranged parallel to the main louver. In addition, as shown in FIG.
5, there was no dead space in this part, and particle accumulation at the bottom of the column could be prevented.

次に第5図は、本発明の他の実施例を示す吸着
剤充填塔のルーバ部の側面図を示したものである
が、第4図の実施例と異なる点は、サブルーバ7
の傾斜角度θ2を76°として若干下方に移動し、ま
た垂直距離Dを30mm、水平距離Fを40mmとしたこ
とである。このようなルーバ配置とすることによ
り、メインルーバ上の吸着剤の移動がより円滑に
なり、粒子の滞留は全く見られなくなつた。
Next, FIG. 5 shows a side view of the louver portion of an adsorbent packed tower showing another embodiment of the present invention, but the difference from the embodiment of FIG. 4 is that the sublouver 7
The inclination angle θ 2 of is set to 76°, and the vertical distance D is set to 30 mm, and the horizontal distance F is set to 40 mm. By arranging the louvers in this manner, the movement of the adsorbent on the main louver was made smoother, and no accumulation of particles was observed.

なお、第6図は、サブルーバの長さB、および
メインルーバ6下端とサブルーバ上端の垂直距離
Dと充填水平圧との関係を示すが、ルーバ長Bが
大きく、また垂直距離Dが小さくなる程、充填水
平圧が増加することが分かる。上記実施例では充
填水平圧が約500Kg/m2になるように上記ルーバ
長Bおよび垂直距離Dが選定された。
FIG. 6 shows the relationship between the length B of the sub-louver, the vertical distance D between the lower end of the main louver 6 and the upper end of the sub-louver, and the filling horizontal pressure. , it can be seen that the filling horizontal pressure increases. In the above example, the louver length B and vertical distance D were selected so that the horizontal filling pressure was approximately 500 kg/m 2 .

以上、本発明によれば、移動層型充填層におい
てメインルーバの上方に水平角度のより大きいサ
ブルーバを配置することにより、ルーバ上の粒子
の非移動部をなくすことができ、特にサブルーバ
を平行に配置した場合よりも粒子の移動をより円
滑化することができる。このため、ルーバ上に排
ガス中のダストが堆積し続けることなく、また、
吸着剤でガス中の亜硫酸ガスを吸着させる場合に
も、吸着剤が飽和以上に亜硫酸ガスを吸着しない
うちに下方へ移動させることができるので、ルー
バの腐食を防止することができる。
As described above, according to the present invention, by arranging the sub-louver with a larger horizontal angle above the main louver in a moving bed type packed bed, it is possible to eliminate the part where particles do not move on the louver, and in particular, the sub-louver can be arranged in parallel. The movement of particles can be made smoother than in the case where the particles are arranged. Therefore, dust in the exhaust gas does not continue to accumulate on the louver, and
Even when the adsorbent adsorbs sulfur dioxide gas in the gas, the adsorbent can be moved downward before it adsorbs more than the saturated amount of sulfur dioxide gas, so corrosion of the louvers can be prevented.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はルーバーを支持体とする粒子状物質の
充填層の従来の構造を示す説明図、第2図は従来
のルーバーを使用した場合の充填層内の粒子の流
れを示す説明図、第3図は本発明の一実施例を示
す説明図、第4図は第3図の実施例におけるルー
バ部のひとつの実施例を示す説明図、第5図はル
ーバ部の他の実施例を示す説明図である。第6図
は、本発明の実施例における充填水平とルーバ長
等との関係を示す図である。 6……メインルーバ、7……サブルーバ、8…
…吸着剤、9……排ガス、20……吸着塔。
Figure 1 is an explanatory diagram showing the conventional structure of a packed bed of particulate matter using a louver as a support; Figure 2 is an explanatory diagram showing the flow of particles in the packed bed when a conventional louver is used; 3 is an explanatory diagram showing one embodiment of the present invention, FIG. 4 is an explanatory diagram showing one embodiment of the louver section in the embodiment of FIG. 3, and FIG. 5 is an explanatory diagram showing another embodiment of the louver section. It is an explanatory diagram. FIG. 6 is a diagram showing the relationship between filling level, louver length, etc. in an embodiment of the present invention. 6...Main louver, 7...Sub louver, 8...
...Adsorbent, 9...Exhaust gas, 20...Adsorption tower.

Claims (1)

【特許請求の範囲】 1 粒子を上方から下方へ移動させる移動層をメ
インルーバとその内側に設けられたサブルーバに
より側方から支持し、該ルーバ間の移動層を横切
るようにガスを通過させる移動層反応装置におい
て、上下方向に垂直に一列に並んだメインルーバ
の内側に、同じく上下方向に垂直に並んだサブル
ーバを前記メインルーバの高さ方向の中間に位置
するように配置し、前記メインルーバおよびサブ
ルーバの水平となす角度が40〜80°で、かつサブ
ルーバの水平となす角度がメインルーバのそれよ
りも大きく、前記サブルーバの長さがメインルー
バのそれの2/3〜4/5であることを特徴とする移動
層反応装置。 2 特許請求の範囲第1項において、前記垂直に
配置されたメインルーバ下端に案内板を設けたこ
とを特徴とする移動層反応装置。
[Claims] 1. Movement in which a moving layer that moves particles from above to below is laterally supported by a main louver and a sub-louver provided inside the louver, and a gas is passed across the moving layer between the louvers. In the layered reaction device, a sub-louver, which is also vertically aligned in the vertical direction, is arranged inside the main louver which is vertically aligned in a vertical direction so as to be located in the middle of the main louver in the height direction. and the angle of the sub-louver with the horizontal is 40 to 80°, and the angle of the sub-louver with the horizontal is larger than that of the main louver, and the length of the sub-louver is 2/3 to 4/5 of that of the main louver. A moving bed reactor characterized by: 2. The moving bed reactor according to claim 1, characterized in that a guide plate is provided at the lower end of the vertically arranged main louver.
JP14171981A 1981-09-10 1981-09-10 Moving bed type reactor Granted JPS5843231A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14171981A JPS5843231A (en) 1981-09-10 1981-09-10 Moving bed type reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14171981A JPS5843231A (en) 1981-09-10 1981-09-10 Moving bed type reactor

Publications (2)

Publication Number Publication Date
JPS5843231A JPS5843231A (en) 1983-03-12
JPH0334978B2 true JPH0334978B2 (en) 1991-05-24

Family

ID=15298602

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14171981A Granted JPS5843231A (en) 1981-09-10 1981-09-10 Moving bed type reactor

Country Status (1)

Country Link
JP (1) JPS5843231A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0620509B2 (en) * 1988-07-27 1994-03-23 住友重機械工業株式会社 Dry desulfurization or denitration equipment
JP4653423B2 (en) * 2004-06-22 2011-03-16 新日本製鐵株式会社 Exhaust gas treatment equipment
JP4563129B2 (en) * 2004-10-04 2010-10-13 株式会社タクマ Gasification system
US20080152551A1 (en) * 2006-12-21 2008-06-26 Senetar John J Screenless moving bed reactor

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51143738U (en) * 1975-05-12 1976-11-18

Also Published As

Publication number Publication date
JPS5843231A (en) 1983-03-12

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