JPH0334798B2 - - Google Patents
Info
- Publication number
- JPH0334798B2 JPH0334798B2 JP60129317A JP12931785A JPH0334798B2 JP H0334798 B2 JPH0334798 B2 JP H0334798B2 JP 60129317 A JP60129317 A JP 60129317A JP 12931785 A JP12931785 A JP 12931785A JP H0334798 B2 JPH0334798 B2 JP H0334798B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- fatty acid
- salt
- salts
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 19
- 229930195729 fatty acid Natural products 0.000 claims description 19
- 239000000194 fatty acid Substances 0.000 claims description 19
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical class CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 4
- AYRBHTOSHJHALD-UHFFFAOYSA-N 1-amino-2-methylpropan-1-ol Chemical class CC(C)C(N)O AYRBHTOSHJHALD-UHFFFAOYSA-N 0.000 claims 1
- -1 alkyl sulfate salts Chemical class 0.000 description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 229930195712 glutamate Natural products 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000011734 sodium Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241001116389 Aloe Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical class [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Chemical class 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Description
〔産業上の利用分野〕
本発明は、新規な洗浄剤組成物に関する。更に
詳しくは、Ｎ−アシルグルタミン酸塩と脂肪酸の
２−アミノ−２−メチルプロパノール塩（以下、
AMP塩と称する）とを含有する洗浄剤組成物に
関し、その目的とするところは、安全性が高く、
皮膚及び毛髪及び毛髪に対して温和であつて、且
つ洗浄力、起泡力の優れた洗浄剤組成物を提供す
ることにある。
〔従来の技術〕
従来、各種洗浄剤の主基剤として、種々の界面
活性剤が用いられているが、なかでもＮ−アシル
グルタミン酸塩は刺激が少なく皮膚及び毛髪に対
して温和であること、液性が皮膚のPHと同じ弱酸
性であること等の点から多用されて来た。
〔発明が解決使用とする問題点〕
然し乍ら、Ｎ−アシルグルタミン酸塩は、過度
の油汚れに対しては、洗浄力、起泡力がやや不足
し、その改善が望まれていた。
本発明者らは、Ｎ−アシルグルタミン酸塩と脂
肪酸のAMP塩とを組み合わせることにより、前
記のＮ−アシルグルタミン酸塩の長所を減ずるこ
となく、洗浄力、起泡力が改善されることを見い
出し、本発明を完成するに至つた。
〔問題点を解決するための手段〕
すなわち、本発明はＮ−アシルグルタミン酸塩
と、脂肪酸のAMP塩とを含有し、かつＮ−アシ
ルグルタミン酸塩と脂肪酸のAMP塩の重量比が
３／１〜１／１であることを特徴とする洗浄剤組
成物である。
本発明で用いられるＮ−アシルグルタミン酸塩
のアシル基としては、炭素数８〜22の脂肪酸残
基、例えば、ラウロイル、ミリストイル、ステア
ロイル、オレオイル等の単一脂肪酸アシル基の
他、ヤシ油脂肪酸アシル、硬化牛脂脂肪酸アシル
等の混合脂肪酸アシルが用いられ、塩としては、
リチウム、ナトリウム、カリウム、アンモニウ
ム、塩基性アミノ酸などの塩が適宜選択される。
本発明においては、これらの一種又は二種以上
が任意に選択されて用いられる。
もう一方の成分である脂肪酸のAMP塩として
は、炭素数８〜22の脂肪酸、例えば、ラウリン
酸、パルミチン酸のイソステアリン酸、オレイン
酸等の単一脂肪酸の他、ヤシ油脂肪酸、牛脂脂肪
酸等の混合脂肪酸のAMP塩が使用される。
弱塩基塩のなかでも２−アミノ−２−メチルプ
ロパノール塩が、熱履歴による褐変が少なく好ま
しい。
本発明においては、これら脂肪酸のAMP塩の
うちから任意の一種又は二種以上が選ばれて用い
られる。
Ｎ−アシルグルタミン酸塩と脂肪酸のAMP塩
との配合比は、通常、重量比にして、３／１〜
１／１の範囲で優れた相乗効果が認められる。両
者の合計配合量は目的とする洗浄剤の剤型によつ
て異なるが、概ね液状洗浄剤で、組成物中の３〜
30重量％、ペースト状洗浄剤で15〜70重量％、固
状洗浄剤で70〜95％重量である。
本発明の洗浄剤組成物には、その他の界面活性
剤、例えば、POEアルキル硫酸エステル塩、Ｎ
−アシルサルコシン塩、Ｎ−アシル−Ｎ−メチル
タウリン酸、リン酸エステル塩、スルホコハク酸
塩、α−オレフインスルホン酸塩、高級脂肪酸エ
ステルスルホン酸塩、脂肪酸石鹸等のアニオン界
面活性剤、アルカノールアミド、POEアルキル
エーテル等のノニオン界面活性剤、イミダゾリン
系、ベタイン系の両性界面活性剤を含ませること
ができる。更に、その他の添加物としては、プル
ラン、カルボキシメチルセルロース、カルボキシ
ビニルポリマー、カチオン性ポリマー、ケイ酸
AlMg等の水溶性高分子、多価アルコール、PCA
−Na、ヒアルロン酸、POEアルキルグルコシド
エーテル等の保湿剤、レシチン、サポニン、アロ
エ、アルメロ等の天然抽出物、NaCl、KCl、ク
エン酸、リンゴ酸等の電解質、香料、色剤等を含
ませることが出来る。
〔発明の効果〕
以下、試験例により、本発明の効果を具体的に
説明する。
試験例１ 液体洗浄剤組成物
Ｎ−ココイルグルタミン酸
モノNa塩
ラウリン酸のAMP塩＊ 合計15重量％
ダイナマイトグリセリン ５
イオン交換水 残余
＊AMP：２−アミノ−２−メチルプロパノール
前記組成にて、Ｎ−アシルグルタミン酸塩と、
脂肪酸AMP塩の配合割合を変化し、洗浄力を測
定した。
（洗浄力の測定条件）
油脂とカーボンブラツクにて調製した人工汚垢
を塗布したプラスチツクフイルムを試料の0.2％
溶液１に浸漬し、30℃にて定速撹拌した後、人
工汚垢の除去率を色差計にて測定、汚垢除去率を
算出した。
[Industrial Field of Application] The present invention relates to a novel cleaning composition. More specifically, N-acylglutamate and 2-amino-2-methylpropanol salt of fatty acid (hereinafter referred to as
The purpose of cleaning compositions containing AMP salts is to be highly safe,
It is an object of the present invention to provide a detergent composition that is mild to the skin, hair, and has excellent detergency and foaming power. [Prior Art] Conventionally, various surfactants have been used as the main base of various detergents, but among them, N-acylglutamate is less irritating and gentle to the skin and hair; It has been widely used because its liquid is slightly acidic, the same as the pH of the skin. [Problems to be Solved and Used by the Invention] However, N-acylglutamic acid salts are somewhat insufficient in cleaning power and foaming power against excessive oil stains, and improvement thereof has been desired. The present inventors have discovered that by combining N-acylglutamate and an AMP salt of a fatty acid, the detergency and foaming power can be improved without reducing the advantages of the N-acylglutamate, The present invention has now been completed. [Means for Solving the Problems] That is, the present invention contains an N-acyl glutamate and an AMP salt of a fatty acid, and the weight ratio of the N-acyl glutamate to the AMP salt of a fatty acid is 3/1 to 3/1. 1/1. The acyl group of the N-acylglutamate used in the present invention includes fatty acid residues having 8 to 22 carbon atoms, such as single fatty acid acyl groups such as lauroyl, myristoyl, stearoyl, and oleoyl, as well as coconut oil fatty acid acyl groups. , mixed fatty acid acyl such as hardened beef tallow fatty acid acyl is used, and as a salt,
Salts of lithium, sodium, potassium, ammonium, basic amino acids, etc. are selected as appropriate. In the present invention, one or more of these may be arbitrarily selected and used. The other component, fatty acid AMP salt, includes fatty acids with 8 to 22 carbon atoms, such as single fatty acids such as lauric acid, palmitic acid, isostearic acid, and oleic acid, as well as coconut oil fatty acids, beef tallow fatty acids, etc. AMP salts of mixed fatty acids are used. Among the weak base salts, 2-amino-2-methylpropanol salt is preferred because it causes less browning due to heat history. In the present invention, one or more of these AMP salts of fatty acids are selected and used. The blending ratio of N-acyl glutamate and fatty acid AMP salt is usually 3/1 to 3/1 by weight.
Excellent synergistic effects are observed within the range of 1/1. The total blending amount of both varies depending on the formulation of the intended cleaning agent, but in general, it is a liquid cleaning agent, and 3 to 3% of the composition is
30% by weight, 15-70% by weight for pasty detergents, and 70-95% by weight for solid detergents. The cleaning composition of the present invention may contain other surfactants, such as POE alkyl sulfate salts, N
- Anionic surfactants such as acyl sarcosine salts, N-acyl-N-methyltauric acid, phosphate ester salts, sulfosuccinates, α-olefin sulfonates, higher fatty acid ester sulfonates, fatty acid soaps, alkanolamides, A nonionic surfactant such as POE alkyl ether, an amphoteric surfactant such as imidazoline type or betaine type can be included. Furthermore, other additives include pullulan, carboxymethylcellulose, carboxyvinyl polymer, cationic polymer, and silicic acid.
Water-soluble polymers such as AlMg, polyhydric alcohols, PCA
-Contain moisturizers such as Na, hyaluronic acid, and POE alkyl glucoside ether, natural extracts such as lecithin, saponin, aloe, and armello, electrolytes such as NaCl, KCl, citric acid, and malic acid, fragrances, coloring agents, etc. I can do it. [Effects of the Invention] The effects of the present invention will be specifically explained below using test examples. Test Example 1 Liquid detergent composition N-cocoylglutamic acid monosodium salt AMP salt of lauric acid *Total 15% by weight Dynamite glycerin 5 Ion exchange water Remaining *AMP: 2-amino-2-methylpropanol In the above composition, N- Acyl glutamate and
The detergency was measured by changing the blending ratio of fatty acid AMP salt. (Cleaning power measurement conditions) A plastic film coated with artificial dirt prepared from oil and carbon black was used as 0.2% of the sample.
After immersing in Solution 1 and stirring at a constant speed at 30°C, the removal rate of artificial stains was measured using a color difference meter, and the stain removal rate was calculated.
次に実施例を挙げる。 Next, examples will be given.
【表】【table】
【表】
上記の液状洗浄組成物は、皮膚に温和で、起泡
力、洗浄力の優れたものであつた。これらは熱履
歴による褐変もなかつた。[Table] The above liquid cleaning composition was gentle on the skin and had excellent foaming power and cleaning power. These did not brown due to heat history.
Claims (1)
アミノ−２−メチルプロパノール塩とを含有し、
かつＮ−アシルグルタミン酸塩と脂肪酸の２−ア
ミノ−２−メチルプロパノール塩との重量比が
３／１〜１／１であることを特徴とする洗浄剤組
成物。1 N-acylglutamate and 2-
and amino-2-methylpropanol salt,
A cleaning composition characterized in that the weight ratio of N-acylglutamate to 2-amino-2-methylpropanol salt of fatty acid is 3/1 to 1/1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12931785A JPS61287992A (en) | 1985-06-14 | 1985-06-14 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12931785A JPS61287992A (en) | 1985-06-14 | 1985-06-14 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61287992A JPS61287992A (en) | 1986-12-18 |
| JPH0334798B2 true JPH0334798B2 (en) | 1991-05-23 |
Family
ID=15006585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12931785A Granted JPS61287992A (en) | 1985-06-14 | 1985-06-14 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61287992A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4316242A1 (en) * | 1993-05-14 | 1994-11-17 | Henkel Kgaa | Hair treatment products |
| JP2006273770A (en) * | 2005-03-30 | 2006-10-12 | Nof Corp | Body detergent composition |
| US7332463B2 (en) * | 2005-04-22 | 2008-02-19 | On Legal Grounds, Inc. | Colloidal cleaning system comprising a saponified fatty acid and an anionic/nonionic surfactant mixture |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54135805A (en) * | 1978-04-14 | 1979-10-22 | Lion Corp | Shampoo composition |
| JPS55151100A (en) * | 1979-05-12 | 1980-11-25 | Toho Yushi Kk | Shampoo composition |
| JPS5780498A (en) * | 1980-11-10 | 1982-05-20 | Seiichi Miyazaki | Solid detergent |
| JPS5792098A (en) * | 1980-11-28 | 1982-06-08 | Lion Corp | Powder detergent composition |
| JPS5827636A (en) * | 1981-08-13 | 1983-02-18 | Shiseido Co Ltd | Oil-in-water-type emulsifier composition |
-
1985
- 1985-06-14 JP JP12931785A patent/JPS61287992A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54135805A (en) * | 1978-04-14 | 1979-10-22 | Lion Corp | Shampoo composition |
| JPS55151100A (en) * | 1979-05-12 | 1980-11-25 | Toho Yushi Kk | Shampoo composition |
| JPS5780498A (en) * | 1980-11-10 | 1982-05-20 | Seiichi Miyazaki | Solid detergent |
| JPS5792098A (en) * | 1980-11-28 | 1982-06-08 | Lion Corp | Powder detergent composition |
| JPS5827636A (en) * | 1981-08-13 | 1983-02-18 | Shiseido Co Ltd | Oil-in-water-type emulsifier composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61287992A (en) | 1986-12-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |