JPH0332326B2 - - Google Patents
Info
- Publication number
- JPH0332326B2 JPH0332326B2 JP58246100A JP24610083A JPH0332326B2 JP H0332326 B2 JPH0332326 B2 JP H0332326B2 JP 58246100 A JP58246100 A JP 58246100A JP 24610083 A JP24610083 A JP 24610083A JP H0332326 B2 JPH0332326 B2 JP H0332326B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- film
- vinyl chloride
- hydroxy
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims description 30
- 239000011347 resin Substances 0.000 claims description 30
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 27
- 239000004925 Acrylic resin Substances 0.000 claims description 10
- 229920000178 Acrylic resin Polymers 0.000 claims description 10
- 239000004014 plasticizer Substances 0.000 claims description 5
- JMHSCWJIDIKGNZ-UHFFFAOYSA-N 4-carbamoylbenzoic acid Chemical compound NC(=O)C1=CC=C(C(O)=O)C=C1 JMHSCWJIDIKGNZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 2
- 230000000903 blocking effect Effects 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- -1 polyethylene, ethylene-vinyl acetate Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FVUKYCZRWSQGAS-UHFFFAOYSA-N 3-carbamoylbenzoic acid Chemical compound NC(=O)C1=CC=CC(C(O)=O)=C1 FVUKYCZRWSQGAS-UHFFFAOYSA-N 0.000 description 2
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- FOZDUYPQLBGEKB-CLFAGFIQSA-N n,n'-bis[(z)-octadec-9-enyl]hexanediamide Chemical compound CCCCCCCC\C=C/CCCCCCCCNC(=O)CCCCC(=O)NCCCCCCCC\C=C/CCCCCCCC FOZDUYPQLBGEKB-CLFAGFIQSA-N 0.000 description 2
- NWZZFAQUBMRYNU-UHFFFAOYSA-N n-octadecylnonadec-18-en-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC=C NWZZFAQUBMRYNU-UHFFFAOYSA-N 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- POLSVAXEEHDBMJ-UHFFFAOYSA-N (2-hydroxy-4-octadecoxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 POLSVAXEEHDBMJ-UHFFFAOYSA-N 0.000 description 1
- SXJSETSRWNDWPP-UHFFFAOYSA-N (2-hydroxy-4-phenylmethoxyphenyl)-phenylmethanone Chemical compound C=1C=C(C(=O)C=2C=CC=CC=2)C(O)=CC=1OCC1=CC=CC=C1 SXJSETSRWNDWPP-UHFFFAOYSA-N 0.000 description 1
- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 1
- AMYKXJAXRJCLCV-UHFFFAOYSA-N (4-methylphenyl) 2-hydroxybenzoate Chemical compound C1=CC(C)=CC=C1OC(=O)C1=CC=CC=C1O AMYKXJAXRJCLCV-UHFFFAOYSA-N 0.000 description 1
- VNFXPOAMRORRJJ-UHFFFAOYSA-N (4-octylphenyl) 2-hydroxybenzoate Chemical compound C1=CC(CCCCCCCC)=CC=C1OC(=O)C1=CC=CC=C1O VNFXPOAMRORRJJ-UHFFFAOYSA-N 0.000 description 1
- OMWSZDODENFLSV-UHFFFAOYSA-N (5-chloro-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=C(Cl)C=C1C(=O)C1=CC=CC=C1 OMWSZDODENFLSV-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- MQQKTNDBASEZSD-UHFFFAOYSA-N 1-(octadecyldisulfanyl)octadecane Chemical compound CCCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC MQQKTNDBASEZSD-UHFFFAOYSA-N 0.000 description 1
- UPYPTOCXMIWHSG-UHFFFAOYSA-N 1-dodecylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCCCC UPYPTOCXMIWHSG-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- IHWDIGHWDQPQMQ-UHFFFAOYSA-N 1-octadecylsulfanyloctadecane Chemical compound CCCCCCCCCCCCCCCCCCSCCCCCCCCCCCCCCCCCC IHWDIGHWDQPQMQ-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- OCSIKZYSDOXRPA-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-3-octadecylhenicosane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC OCSIKZYSDOXRPA-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- DHMNTHVOLJVHPF-UHFFFAOYSA-N 2-(3,5-dimethyl-2-octadecoxyphenyl)-5-methylbenzotriazole Chemical compound CCCCCCCCCCCCCCCCCCOC1=C(C)C=C(C)C=C1N1N=C2C=C(C)C=CC2=N1 DHMNTHVOLJVHPF-UHFFFAOYSA-N 0.000 description 1
- LOPXIGZYSAOSOK-UHFFFAOYSA-N 2-(5,6-dichlorobenzotriazol-2-yl)-4-methylphenol Chemical compound CC1=CC=C(O)C(N2N=C3C=C(Cl)C(Cl)=CC3=N2)=C1 LOPXIGZYSAOSOK-UHFFFAOYSA-N 0.000 description 1
- LMFQVOYNAXDCQT-UHFFFAOYSA-N 2-(5-chlorobenzotriazol-2-yl)-4-phenylphenol Chemical compound C1=C(N2N=C3C=C(Cl)C=CC3=N2)C(O)=CC=C1C1=CC=CC=C1 LMFQVOYNAXDCQT-UHFFFAOYSA-N 0.000 description 1
- LGTOWDJWJQJQAO-UHFFFAOYSA-N 2-(5-methoxybenzotriazol-2-yl)-4,6-dimethylphenol Chemical compound N1=C2C=C(OC)C=CC2=NN1C1=CC(C)=CC(C)=C1O LGTOWDJWJQJQAO-UHFFFAOYSA-N 0.000 description 1
- XTARNDCHFFABBE-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,5-dichlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C=C1N1N=C2C=CC=CC2=N1 XTARNDCHFFABBE-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- ODVBRJXPJKVLCZ-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1N1N=C2C=CC=CC2=N1 ODVBRJXPJKVLCZ-UHFFFAOYSA-N 0.000 description 1
- MJFOVRMNLQNDDS-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dimethylphenol Chemical compound CC1=CC(C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MJFOVRMNLQNDDS-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- YOCQRIHCGMHFNF-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(6,6-dichlorohexyl)phenol Chemical compound OC1=CC=C(CCCCCC(Cl)Cl)C=C1N1N=C2C=CC=CC2=N1 YOCQRIHCGMHFNF-UHFFFAOYSA-N 0.000 description 1
- PITPRNOGWXAZAW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-methoxyphenol Chemical compound COC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 PITPRNOGWXAZAW-UHFFFAOYSA-N 0.000 description 1
- KGVHAZMHOQLBEQ-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-phenylphenol Chemical compound C1=C(N2N=C3C=CC=CC3=N2)C(O)=CC=C1C1=CC=CC=C1 KGVHAZMHOQLBEQ-UHFFFAOYSA-N 0.000 description 1
- NLWDAUDWBLSJGK-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butyl-6-methylphenol Chemical compound CC1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O NLWDAUDWBLSJGK-UHFFFAOYSA-N 0.000 description 1
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 1
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 1
- BXCRLBBIZJSWNS-UHFFFAOYSA-N 2-hydroxyethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCO BXCRLBBIZJSWNS-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- HAGWKEPMQDPMDR-UHFFFAOYSA-N 2-methoxy-5-(4-methoxybenzoyl)benzenesulfonic acid Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C(S(O)(=O)=O)=C1 HAGWKEPMQDPMDR-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical class OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- OUWPEHOSUWXUFV-UHFFFAOYSA-N 4-(benzotriazol-2-yl)-3-methylphenol Chemical compound CC1=CC(O)=CC=C1N1N=C2C=CC=CC2=N1 OUWPEHOSUWXUFV-UHFFFAOYSA-N 0.000 description 1
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 description 1
- LRMNYFKQWAZJQP-UHFFFAOYSA-N 4-amino-2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=C(C=C(C=C1)N)C1=CC=CC=2NN=NC=21 LRMNYFKQWAZJQP-UHFFFAOYSA-N 0.000 description 1
- RZZQDQUZAANRKE-UHFFFAOYSA-N 4-methoxy-2-(5-methylbenzotriazol-2-yl)phenol Chemical compound COC1=CC=C(O)C(N2N=C3C=C(C)C=CC3=N2)=C1 RZZQDQUZAANRKE-UHFFFAOYSA-N 0.000 description 1
- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 description 1
- IEMHIOUNBGZEAG-UHFFFAOYSA-N 4-tert-butyl-2-(5-chlorobenzotriazol-2-yl)phenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=C(Cl)C=CC3=N2)=C1 IEMHIOUNBGZEAG-UHFFFAOYSA-N 0.000 description 1
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
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- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
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- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- PRURWEOTCWKAMA-UHFFFAOYSA-N butyl 2-(2-hydroxy-4,5-dimethylphenyl)benzotriazole-5-carboxylate Chemical compound N1=C2C=C(C(=O)OCCCC)C=CC2=NN1C1=CC(C)=C(C)C=C1O PRURWEOTCWKAMA-UHFFFAOYSA-N 0.000 description 1
- AJTTZLJQVUMOBD-UHFFFAOYSA-N butyl 2-(2-hydroxy-5-methylphenyl)benzotriazole-5-carboxylate Chemical compound N1=C2C=C(C(=O)OCCCC)C=CC2=NN1C1=CC(C)=CC=C1O AJTTZLJQVUMOBD-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
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- 150000002019 disulfides Chemical class 0.000 description 1
- UWLPCYBIJSLGQO-UHFFFAOYSA-N dodecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCC(O)=O UWLPCYBIJSLGQO-UHFFFAOYSA-N 0.000 description 1
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- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
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- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
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- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
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- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
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- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Protection Of Plants (AREA)
- Greenhouses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
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The present invention relates to an agricultural vinyl chloride resin film, and more particularly to an agricultural vinyl chloride resin film that has improved adhesion resistance between adjacent films in the overlapping portion, that is, blocking property. BACKGROUND ART In recent years, with the aim of increasing the added value of agricultural products, facility cultivation such as greenhouse cultivation and tunnel cultivation has been actively carried out. As covering materials used for greenhouse cultivation and tunnel cultivation, films of synthetic resins such as vinyl chloride resin, polyethylene, ethylene-vinyl acetate copolymer, and polyethylene terephthalate are used. Among them, agricultural soft vinyl chloride resin films are currently the most widely used because they have overall superior physical properties such as weather resistance, transparency, heat retention, and strength compared to other synthetic resin films. Agricultural soft vinyl chloride resin films containing plasticizers have various desirable physical properties as mentioned above, but on the other hand, when films overlap, they tend to adhere to each other at the overlapped portions. (hereinafter referred to as "stickiness") is large, and this tendency is particularly strong when water droplets adhere and dry. As a result, not only is the work efficiency reduced when spreading the film on greenhouses or tunnels or bonding the film using high-frequency adhesive, but also
There are drawbacks such as reduced workability when rolling up or pulling the film for ventilation in a house or tunnel. Many techniques have been proposed to reduce the tackiness of agricultural soft vinyl chloride resin films, but none of them have a sufficient tackiness-reducing effect (hereinafter referred to as "non-blocking effect"). Also, recently, in Japanese Patent Application Laid-Open No. 58-69240, N,N'-dioleyladipamide, N,N'-dioleyladipamide,
An agricultural vinyl chloride resin film containing at least one of N,N'-distearyl adipamide and ethylene bislauryl amide has been proposed, but even this film does not allow for ventilation during ventilation. The tackiness (hereinafter referred to as ``drip-proof blocking'') of the material is improved to some extent, but the tackiness during spreading or high-frequency bonding (hereinafter referred to as ``original fabric blocking'') is not improved and is unsatisfactory. Therefore, the present inventors conducted extensive research in search of a soft vinyl chloride resin film for agricultural use with further improved non-blocking effects.As a result, we found that a new N, N,
The vinyl chloride resin film obtained by blending a specific amount of N'-distearyl terephthalic acid amide and/or N,N'-distearyl isophthalic acid amide has a significantly improved non-blocking effect, and is suitable for agricultural use. It has been found that it is suitable as a covering material. According to the present invention, N,N'-distearyl terephthalic acid amide and/or N,
There is provided an agricultural vinyl chloride resin film characterized in that N'-distearylisophthalic acid amide is blended in a range of 0.01 to 1.0 parts by weight per 100 parts by weight of vinyl chloride resin. The film of the present invention is a soft vinyl chloride resin film, and the basic composition of the resin composition constituting the film is polyvinyl chloride having a number average degree of polymerization of about 800 to about 2000, preferably about 1000 to about 1500; or a film-forming copolymer mainly composed of vinyl chloride (e.g., ethylene-vinyl chloride copolymer, vinyl acetate-vinyl chloride copolymer, vinyl chloride-halogenated olefin copolymer, or these polyvinyl chloride or chloride Other compatible resins mainly composed of vinyl copolymers (e.g. polyester resins, epoxy resins, acrylic resins, vinyl acetate resins, urethane resins,
Acrylonitrile-styrene-butadiene copolymer resin, partially saponified polyvinyl alcohol, etc.) [hereinafter collectively referred to as vinyl chloride resins], 30 to 70 parts by weight per 100 parts by weight of these vinyl chloride resins. , preferably 40 to 60 parts by weight of plasticizer; 0.05 to 7 parts by weight, preferably 1.0 to 5.0 parts by weight
Parts by weight of heat stabilizer; 0 to 5.0 parts by weight, preferably
1.0 to 4.0 parts by weight of antifogging agent (or surfactant); 0
~3.0 parts by weight, preferably 0.1 to 0.5 parts by weight of an ultraviolet absorber; 0 to 5.0 parts by weight, preferably 0.1 to 1.0 parts by weight of an antiblocking agent; further, an antioxidant, Other conventional resin additives such as antistatic agents, fillers, colorants, etc. can also be included if desired. Examples of plasticizers that can be blended include G-n-
Phthalic acid derivatives such as octyl phthalate, di-2-ethylhexyl phthalate, and diisodecyl phthalate; Isophthalic acid derivatives such as diisooctylisophthalate; Adipic acid derivatives such as dioctyl adipate; Other tricresyl phosphate and tricylenyl phosphate Phate, epoxidized soybean oil and the like are included, among which dioctyl phthalate, tricresyl phosphate, dioctyl adipate and epoxidized soybean oil are suitable. In addition, examples of heat stabilizers that can be included in the vinyl chloride resin include chelators such as zinc stearate, barium stearate, calcium stearate, barium ricinoleate, organic phosphites, epoxy resins, etc. Examples of the agent (or surfactant) include sorbitan surfactants such as sorbitan monostearate, sorbitan monopalmitate, and sorbitan monobehenate; glycerin monolaurate, diglycerin monopalmitate, and glycerin monostearate; Glycerin-based surfactants: Polyethylene glycol-based surfactants such as polyethylene glycol monostearate and polyethylene glycol monopalmitate; alkylene oxide adducts of alkylphenols; esters of sorbitan/glycerin condensates and organic acids, etc. , as the ultraviolet absorber, for example, 2-hydroxy-
4-methoxybenzophenone, 2-hydroxy-
4-n-octyloxybenzophenone, 2-hydroxy-4-n-dodecyloxybenzophenone, 2-hydroxy-4-n-octadecyloxybenzophenone, 2-hydroxy-4-benzyloxybenzophenone, 2-hydroxy-4-
Methoxy-2'-carboxybenzophenone, 2-
Hydroxy-4-methoxy-5-sulfobenzophenone, 2-hydroxy-5-chlorobenzophenone, 2,4-dihydroxybenzophenone,
2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-di-methoxybenzophenone, 2,2'-dihydroxy-
Benzophenone ultraviolet absorbers such as 4,4'-di-methoxy-5-sulfobenzophenone and 2,2',4,4'-tetrahydroxybenzophenone; 2-
(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-5'-tert-
butylphenyl)benzotriazole, 2-
(2'-hydroxy-3',5'-dimethylphenyl)benzotriazole, 2-(2'-methyl-4'-hydroxyphenyl)benzotriazole, 2-
(2'-hydroxy-3'-methyl-5'-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, 2-(2'- hydroxy-3â²,
5'-di-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-dimethylphenyl)-5-methoxybenzotriazole, 2
-(2'-n-octadecyloxy-3',5'-dimethylphenyl)-5-methylbenzotriazole,
2-(2'-hydroxy-5'-methoxyphenyl)
Benzotriazole, 2-(2'-hydroxy-
4â²-octoxyphenyl)benzotriazole,
2-(2'-hydroxy-5'-methoxyphenyl)-
5-Methylbenzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5,6-dichlorobenzotriazole, 2-(2'-hydroxy-
5'-tert-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3',5'-di-
tert-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-5'-phenylphenyl)-5-chlorobenzotriazole, 2
-(2'-hydroxy-5'-dichlorohexylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-dichlorophenyl)benzotriazole, 2-(2'-hydroxy-4', 5'-dichlorophenyl)benzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)-5-
Chlorobenzotriazole, 2-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5
-chlorobenzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5-butoxycarbonylbenzotriazole, 2-(2'-hydroxy-4',5'-dimethylphenyl)-5-butoxycarbonylbenzo Triazole, 2-(2'-hydroxy)-5-ethoxycarbonylbenzotriazole, 2-(2'-acetoxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5- Ethylsulfonebenzotriazole, 2-(2'-hydroxy-3',
5'-dimethylphenyl)-5-ethylsulfonebenzotriazole, 2-(2'-hydroxy-5'-
Phenylphenyl)benzotriazole, 2-
Benzotriazole UV absorbers such as (2'-hydroxy-5'-aminophenyl)benzotriazole; salicylic acids such as phenyl salicylate, p-tert-butyl phenyl salicylate, p-methylphenyl salicylate, and p-octylphenyl salicylate Examples include ester-based ultraviolet absorbers. In addition, anti-blocking agents include, for example, fatty acid amides such as methylene bis stearylamide; higher fatty acids and their derivatives such as butyl stearate; higher alcohols such as stearyl alcohol; and metal soaps such as calcium stearate. be done. Furthermore, examples of antioxidants that may be added as necessary include phenolic antioxidants, such as 2,6-di-t-butyl-p-cresol, 4,
4'-thiobis-(3-methyl-6-t-butylphenol), 2,2-di(4-hydroxyphenyl)propane, 1,1,3-tris-(2-methyl-4-hydroxy-5 -t-butylphenyl)
Butane, octadecyl-3-(3,5-di-t-
butyl-4-hydroxyphenyl)propionate, pentaerystol-tetra-(3,5-di-t-butyl-4-hydroxyphenyl)-propionate, 1,3,5-tris(4-t-butyl- 3-Hydroxy-2,6-dimethylbenzyl)isocyanurate, tris-(3,5-di-
t-Butyl-4-hydroxybenzyl) isocyanurate; thiodipropionic acid esters such as di-n-dodecyl-thiodipropionate,
di-n-octadecyl-thiodipropionate,
Fatty acid sulfides and disulfides such as di-n-dodecyl sulfide, di-n-octadecyl sulfide, di-n-octadecyl disulfide; fatty acid, aromatic or fatty acid-aromatic phosphites and thiophosphites, such as:
Tri-n-dodecyl-phosphite, tri-(n
-nonylphenyl) phosphite, tri-n-dodecyl-trithiophosphite, phenyl-di-
Examples of antistatic agents include n-decyl phosphite and di-n-octadecyl-pentaerythritol diphosphite. Examples of antistatic agents include quaternary ammonium salts, amines, imidazolines, amine oxidized ethylene adducts, and polyethylene glycols. , sorbitan esters, and the like. In addition, silica, talc, calcium carbonate, etc. can be used as fillers, and examples of colorants include titanium oxide, ultramarine blue, phthalocyanine blue, and quinacridone red. The agricultural soft vinyl chloride resin film of the present invention is characterized by:
The point is that N,N'-distearyl terephthalic acid amide and/or N,N'-distearylisophthalic acid amide is blended. N-N'-distearyl phthalic acid amide and N,
Nâ²-distearyl isophthalic acid amide has the following formula:
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以äžIt is an aromatic bisamide represented by the formula: These may be blended individually or in combination. The amount of the compound is generally
Vinyl chloride resin (contains no plasticity, etc.)
0.01 to 1.0 parts by weight per 100 parts by weight, preferably 0.05 parts by weight
It can be within the range of ~0.5 parts by weight. In addition to the above-mentioned specific aromatic bisamide, the film of the present invention may contain an appropriate amount of a conventionally known lubricant such as stearic acid, methylene bis stearylamide, ethylene bis stearyl amide, etc. The agricultural film of the present invention is produced by mixing the basic ingredients of the soft vinyl chloride resin described above, the aromatic bisamide, the lubricant, etc., in a roll type, Banbury type, Henschel type mixer or extruder. After mixing or kneading, it can be manufactured by molding into a film according to a conventional molding method such as a calendar method, a T-die method, or an inflation method. The appropriate thickness of the film in this case is generally in the range of 50 to 200 microns, preferably 50 to 150 microns. The film thus formed may be subjected to a surface treatment such as a normal dust-proof coating, if necessary. Resins suitable for dust-proof coating processing include acrylic resins, for example, any acrylic resins conventionally used for dust-proofing soft vinyl chloride resin films in the field of agricultural coating materials, such as acrylic acid or methacrylic acid. Copolymers mainly composed of esters are included, such as those disclosed in Japanese Patent Publication No. 46-28194.
Publication No. 52-6214, Special Publication No. 57-
You can choose as appropriate from those disclosed in Publication No. 15608, Japanese Unexamined Patent Publication No. 1392/1980, etc.
In particular, as described in Japanese Patent Publication No. 57-15608,
Mainly based on an acrylic resin obtained by copolymerizing 4 to 13% by weight of N-methylolacrylamide and 87 to 96% by weight of at least one C 1 to C 12 alkyl ester of acrylic acid or methacrylic acid. It is suitable because it has excellent dust resistance and non-blocking properties, as well as flexibility and high frequency adhesion. Among them, methyl methacrylate 35-55
Mainly based on acrylic resin obtained by copolymerization of 10-30% by weight of ethyl methacrylate, 10-25% by weight of methyl acrylate, 0-10% by weight of butylacrylate, and 4-13% by weight of N-methylolacrylamide. It is particularly preferable to
Furthermore, the above five copolymerized monomers and at least one selected from butyl methacrylate, ethyl acrylate, acrylic acid, methacrylic acid, etc.
It is also effective to copolymerize with a small amount (0.01 to 2% by weight) of a seed monomer in an appropriate combination. In order to provide a coating layer made of such an acrylic resin on the surface of the above-mentioned vinyl chloride resin film, the acrylic resin as described above is dissolved in a suitable organic solvent and used for coating, for example, in the same manner as in the usual dustproofing method. A composition is prepared and coated on the surface of a vinyl chloride resin film. In addition to the acrylic resin, the coating composition may optionally contain other materials such as cellulose acetate butitate, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyurethane, ethylene-vinyl acetate copolymer, etc. A compatible resin may be included in an amount of 40 parts by weight or less, preferably 30 parts by weight or less, more preferably 25 parts by weight or less per 100 parts by weight of the acrylic resin, and if necessary, Appropriate amounts of light stabilizers such as ultraviolet absorbers, antistatic agents, colorants, anti-blocking agents, plasticizers, etc. can also be blended. Coating with the above-mentioned coating composition can be carried out according to conventional methods, such as roll coating, knife coating, spray coating, dip coating, curtain flow coating, etc., and the thickness of the coating layer is strictly limited. However, it is generally advantageous to range from 1 to 5 microns, preferably from 1 to 3 microns. The above-described agricultural film of the present invention has an excellent non-blocking effect, as is clear from the Examples described later, and can be widely used for spreading agricultural greenhouses and the like. Next, the present invention will be further explained by examples. Examples 1 to 7 and Comparative Examples 1 to 6 Basic formulation: Polychloride film (1300) 100 parts by weight Dioctyl phthalate (DOP) 45 Tricresyl phosphate (TCP) 5 parts by weight Epoxy resin stabilizer (Epicoat 828 )
2.0 parts by weight Zinc stearate 1.0 ã Barium stearate 1.0 ã Sorbitan monostearate 1.5 ã The ingredients shown in Table 1 below were further blended with each component of the above basic formulation, and after stirring and mixing with a Henschel mixer for 10 minutes, The mixture was kneaded on a roll heated to 165° C., and a film with a thickness of 75 ÎŒm was obtained using an inverted L-shaped calender (Examples 1 to 6 and Comparative Examples 1 to 5). Further, the film produced as described above was coated with a dustproof coating as described below. Composition formulation for dustproof coating: Methyl methacrylate 39.0 parts by weight Ethyl methacrylate 28.0 ã Methyl acrylate 18.0 parts by weight Butyl acrylate 10.0 ã N-methylol acrylamide 5.0 ã 0.5 parts by weight of benzoyl peroxide and 100 parts by weight of isobutyl acetate were added to the above monomer formulation. and polymerized at 80°C for 10 hours. To 100 parts by weight of the obtained polymer solution, 20 parts by weight of cellulose acetate butyrate (1/2 second CAB) was added,
The mixture was further diluted with ethyl acetate/sec-butyl alcohol (weight ratio 1/1) to obtain a coating composition having a solid content of 20% by weight. (C) The coating composition obtained in (B) above was applied to one side of the film prepared in (A) above using a bar coater #7, and dried in a gear oven at 155±5°C for 60 seconds. The coating amount is approximately 2.0g/m 2 (approximately 2Ό thick)
Dustproof treated films were obtained (Example 7 and Comparative Example 6). The blocking value and appearance of the thus obtained film were evaluated by the following methods, and the results are shown in Table 1 below. (1) Blocking value Original film blocking value Two film samples of the following sizes were overlapped with the inner and outer surfaces of the film, and JIS-Z-
1528, crimped with the crimping device specified in Section 6.7.2, placed in a 70â gear oven for 16 hours,
Further, after being left at room temperature at 25°C for 24 hours, the 180° peelability of the two sheets was measured using a load cell type tensile testing machine in a constant temperature room at 25°C. To measure, peel off approximately 10 cm and read the average value. Sample size: 5cm width x 20cm length Pulling speed: 200mm/min Anti-blocking value By covering the top of a water tank containing 40°C hot water with a film sample with a 30° inclination and holding it for 24 hours. After wetting the inner surface of the film, the blocking value is measured in the same manner as described above. (2) Appearance (degree of cloudiness) Measure the degree of cloudiness with a haze meter (manufactured by Suga Test Instruments Co., Ltd.) six months after the film was created. Evaluation: ãâŠless than 10% ÃâŠ10% or more
Claims (1)
ç©ã«ãïŒNâ²âãžã¹ãã¢ãªã«ãã¬ãã¿ã«é žã¢ã
ãåã³ïŒåã¯ïŒ®ïŒNâ²âãžã¹ãã¢ãªã«ã€ãœãã¿ã«
é žã¢ãããå¡©åããã«ç³»æš¹è100éééšåœã0.01
ã1.0éééšã®ç¯å²å ã§é åããããšãç¹åŸŽãšã
ã蟲æ¥çšå¡©åããã«ç³»æš¹èãã€ã«ã ã ïŒ ãã€ã«ã ã®äžé¢ãã¢ã¯ãªã«ç³»æš¹èã«ãã€ãŠé²
塵被èŠå å·¥ãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®èŸ²æ¥çšå¡©åããã«ç³»æš¹èãã€ã«ã ã[Scope of Claims] 1. N,N'-distearyl terephthalic acid amide and/or N,N'-distearylisophthalic acid amide is added to a soft vinyl chloride resin composition containing a plasticizer to form a vinyl chloride resin composition containing 100% of vinyl chloride resin. 0.01 per part by weight
An agricultural vinyl chloride resin film, characterized in that the film is blended within a range of 1.0 parts by weight. 2. The agricultural vinyl chloride resin film according to claim 1, wherein one side of the film is coated with an acrylic resin to prevent dust.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58246100A JPS60141747A (en) | 1983-12-29 | 1983-12-29 | Vinyl resin film for agricultural use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58246100A JPS60141747A (en) | 1983-12-29 | 1983-12-29 | Vinyl resin film for agricultural use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60141747A JPS60141747A (en) | 1985-07-26 |
| JPH0332326B2 true JPH0332326B2 (en) | 1991-05-10 |
Family
ID=17143485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58246100A Granted JPS60141747A (en) | 1983-12-29 | 1983-12-29 | Vinyl resin film for agricultural use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60141747A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62197442A (en) * | 1986-02-25 | 1987-09-01 | Achilles Corp | Agricultural dripping polyvinyl chloride film |
| KR0176286B1 (en) * | 1995-06-12 | 1999-05-15 | ìŽì¢ í | Method of manufacturing agricultural pvc tubural film |
| JP2003064233A (en) * | 2001-08-27 | 2003-03-05 | C I Kasei Co Ltd | Polyvinyl chloride-based resin film for agriculture and polyvinyl chloride-based resin composition |
-
1983
- 1983-12-29 JP JP58246100A patent/JPS60141747A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60141747A (en) | 1985-07-26 |
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