JPH0329201A - Reflection mirror for lighting system of vehicle - Google Patents

Reflection mirror for lighting system of vehicle

Info

Publication number
JPH0329201A
JPH0329201A JP1160808A JP16080889A JPH0329201A JP H0329201 A JPH0329201 A JP H0329201A JP 1160808 A JP1160808 A JP 1160808A JP 16080889 A JP16080889 A JP 16080889A JP H0329201 A JPH0329201 A JP H0329201A
Authority
JP
Japan
Prior art keywords
layer
light
top coat
present
lamp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1160808A
Other languages
Japanese (ja)
Other versions
JPH07120482B2 (en
Inventor
Masashi Iinuma
飯沼 眞佐志
Koichi Isokawa
磯川 宏一
Keiichi Inaba
稲葉 恵一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koito Manufacturing Co Ltd
Original Assignee
Koito Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koito Manufacturing Co Ltd filed Critical Koito Manufacturing Co Ltd
Priority to JP1160808A priority Critical patent/JPH07120482B2/en
Publication of JPH0329201A publication Critical patent/JPH0329201A/en
Publication of JPH07120482B2 publication Critical patent/JPH07120482B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Non-Portable Lighting Devices Or Systems Thereof (AREA)

Abstract

PURPOSE:To provide a color light with stability for a long time by including a ultraviolet ray absorbing agent and light stabilizing agent in a top coat layer. CONSTITUTION:A top coat layer 7 of a reflection mirror 1 is composed of an (a)-layer 7a and (b)-layer 7b. The layer 7a has a function to compensate free radical causing luminous group of color to the component of coat made of acrylic resin and the like. A light stabilizer such as of hindered amine-based is included. The layer 7b has in its coat component a compound of benzotriazole-based, benzophenon-based, ariester-based. With this preparation, change in color caused by ultraviolet ray derives from natural light and lamp light is restrained effectively, that enables the stability of colored light for a long time.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は自動車等の車輌に用いられる灯具に関し、特に
、カラーコーティングを施こされた反射鏡に閣ずるもの
である。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a lamp used in a vehicle such as an automobile, and is particularly applicable to a color-coated reflector.

(従来の技術とその課題) 灯具反射鏡は通常、金属、樹脂等の支持体上にAI!.
等を蒸着して製造される。そして、灯具ランプの光から
所望あるいは規格の色光(ブルー,イエロー, etc
)を得るためにAj2蒸着層上に所定の染料を含むトッ
プコート層を設けることが行われている。
(Prior art and its problems) Light reflectors are usually made of AI! on a support such as metal or resin. ..
It is manufactured by vapor-depositing. Then, the desired or standard color light (blue, yellow, etc.) is extracted from the light of the lamp.
), a top coat layer containing a predetermined dye is provided on the Aj2 vapor deposited layer.

このような灯具を使用している間に、該染料が紫外線に
より酸化・変化(褪色)し、引いては所定の色光が永続
して得られないという課題があった。
While such lamps are used, the dyes are oxidized and changed (faded) by ultraviolet rays, resulting in a problem that a predetermined colored light cannot be obtained permanently.

従って、本発明の目的は、長期間使用しても一定した色
光が得られる灯具反射鏡を提供することにある。
SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide a lamp reflector that can provide constant colored light even when used for a long period of time.

(課題を解決するための手段) 本発明は、支持体、Al蒸着層およびトップコ−ト層か
らなる車輌灯具用反射鏡において、該トップコート層が
、染料、紫外線吸収剤および光安定化剤を含有すること
を特徴とする車輌灯具用反射鏡であり、これにより上記
課題を解決し、本発明を達成することができる。
(Means for Solving the Problems) The present invention provides a reflector for a vehicle lamp comprising a support, an Al vapor deposited layer and a top coat layer, in which the top coat layer contains a dye, an ultraviolet absorber and a light stabilizer. This is a reflecting mirror for a vehicle lamp characterized by containing the above-mentioned components, thereby solving the above problems and achieving the present invention.

本発明のトップコート層はAl蒸着層上に設けられるが
単層でも2層以上の複層から構成されていてもよい。又
、染料、紫外線吸収剤および光安定化剤は、同一層に共
存してもそうでなくとも良いが、少なくとも染料は、光
安定化剤と同一層に共存することが好ましい。
Although the top coat layer of the present invention is provided on the Al vapor deposited layer, it may be composed of a single layer or a multilayer of two or more layers. Further, the dye, the ultraviolet absorber, and the light stabilizer may or may not coexist in the same layer, but it is preferable that at least the dye coexists with the light stabilizer in the same layer.

トップコート層は通常、結合剤として、アクリル樹脂、
メラミン樹脂等が、エステル系、ケトン系、脂肪族又は
芳香族炭化水素系等の溶剤により分散された塗料戒分に
適宜、該吸収剤、光安定化剤、染料を選択含有させて塗
布することにより設けられる。例えば、染料含有塗料又
は染料及び光安定化剤含有塗料をA2蒸着層上に塗設し
、その上に更に、該紫外線吸収剤および光安定化剤含有
塗料或いは紫外線吸収剤単独含有塗料を塗設してトップ
コート層を形成することも、染料、紫外線吸収剤および
光安定化剤含有塗料をAl層上に塗設してトップコート
層を形成することも、その他の方法で形或することもで
きる。トップコート層は所望によりその他公知の添加剤
、例えばレベリング剤、消泡剤等を含有することができ
る。塗料の結合剤及び溶剤の各成分は、後述の支持体の
種類に応じて適宜変更することが好ましい。
The top coat layer usually contains acrylic resin,
Melamine resin, etc. is dispersed in a solvent such as ester, ketone, aliphatic, or aromatic hydrocarbon, and then the absorbent, light stabilizer, and dye are selectively added to the paint and applied. provided by For example, a paint containing a dye or a paint containing a dye and a light stabilizer is coated on the A2 vapor deposited layer, and a paint containing the ultraviolet absorber and a light stabilizer or a paint containing only an ultraviolet absorber is further coated thereon. The top coat layer may be formed by coating the Al layer with a paint containing a dye, an ultraviolet absorber, and a light stabilizer, or by other methods. can. The top coat layer may contain other known additives, such as a leveling agent and an antifoaming agent, if desired. It is preferable that each component of the binder and solvent of the coating material be changed as appropriate depending on the type of support described below.

本発明に用いられる染料としては、業界公知のものが使
用できるが、具体的には、フタロシアニン系、アンスラ
キノン系、コバルト系、インダンスレン系等である。
As the dye used in the present invention, dyes known in the industry can be used, and specific examples include phthalocyanine-based, anthraquinone-based, cobalt-based, and indanthrene-based dyes.

本発明に用いられる紫外線吸収剤としては、ペンゾトリ
アゾール系、ペンゾフェノン系、アリールエステル系等
が用いられ、特に好ましくは、ペンゾトリアゾール系で
あり、具体的には、2−〔2−ヒドロキシ−3.5−ジ
(α.α−ジメチルヘンジル)フェニル〕−2Hベンゾ
トリアゾール等が挙げられ、これら化合物は単独あるい
は組合わせて用いられる。コート層での含有量は、コー
ト層形成塗料の不揮発分に対して、好ましくは、1〇一
t%前後の範囲である。
As the ultraviolet absorber used in the present invention, penzotriazole type, penzophenone type, aryl ester type, etc. are used, and penzotriazole type is particularly preferable. Specifically, 2-[2-hydroxy- Examples include 3,5-di(α.α-dimethylhenzyl)phenyl]-2H benzotriazole, and these compounds may be used alone or in combination. The content in the coating layer is preferably in the range of about 101 t% based on the nonvolatile content of the coating material forming the coating layer.

本発明に用いられる光安定化剤としては、染料の発色団
に惹起するフリーラジカルを捕獲する機能を有すれば、
特に限定されるものではないが、好ましくはヒンダート
アξン系であり、具体的には、2−(3.5−ジーL−
プチル−4−ヒトロキシベンジル)−2−n−プチルマ
ロン酸ビス(1,2,2,6.6−ペンタメチル−4−
ピペリジル)等が挙げられ、これら化合物は単独あるい
は組合わせて用いられる。トップコート層での含有量は
、トップコート層形戒塗料の不揮発分に対して、18w
t%〜20w t%、好ましくは、20−t%である。
As the photostabilizer used in the present invention, as long as it has the function of capturing free radicals caused by the chromophore of the dye,
Although not particularly limited, it is preferably a hindered amine, specifically a 2-(3.5-Z-L-
Bis(1,2,2,6.6-pentamethyl-4-butyl-4-hydroxybenzyl)-2-n-butylmalonate
piperidyl), and these compounds may be used alone or in combination. The content in the top coat layer is 18w based on the nonvolatile content of the top coat layered paint.
t% to 20wt%, preferably 20-t%.

本発明に用いられる八1蒸着層が形成される支持体とし
ては、特に限定されず当業界で公知のものが使用される
。具体的には、金属、例えば、鉄SUS、銅等、樹脂、
例えば、アクリル樹脂、ポリプロピレン樹脂、ABS等
を反射鏡状に威型したもの、あるいは、金属威形品上に
柑脂塗膜を設けたもの、PRP等の強化樹脂威型品等が
使用される.実施例 以下、本発明の具体的実施例を図面を参照して説明する
が、本発明はこれに限定されるものではない。
The support on which the 81 vapor deposited layer used in the present invention is formed is not particularly limited, and any support known in the art may be used. Specifically, metals such as iron SUS, copper, etc., resins,
For example, acrylic resin, polypropylene resin, ABS, etc. shaped into a reflecting mirror, metal shaped articles with a citrus coating, reinforced resin shaped articles such as PRP, etc. are used. .. EXAMPLES Specific examples of the present invention will be described below with reference to the drawings, but the present invention is not limited thereto.

(実施例−1) 第1図は本発明に係る反射鏡1を有する灯其の切欠き側
面図である。この灯具は遮光部材8およびランプ9を具
備している。
(Example 1) FIG. 1 is a cutaway side view of a lamp having a reflecting mirror 1 according to the present invention. This lamp includes a light shielding member 8 and a lamp 9.

第2図は第1図のI−1’に沿う断面図を示す。FIG. 2 shows a cross-sectional view taken along line I-1' in FIG.

2は鉄基板である。3及び4は鉄基板2の表裏表面に形
成された電着塗面であり、電着塗料として、ポリブタジ
エン系、エボキシ系、アクリル系等が用いられ膜厚は1
5〜25μである。5は内面側の電着塗面3の上に形成
されたアンダーコート層であり顔料を含有しない合戒樹
脂系塗料をスプレー法等により膜厚40〜60μに設け
たものである。
2 is an iron substrate. 3 and 4 are electrodeposition coating surfaces formed on the front and back surfaces of the iron substrate 2, and polybutadiene, epoxy, acrylic, etc. are used as the electrodeposition paint, and the film thickness is 1.
It is 5 to 25μ. Reference numeral 5 denotes an undercoat layer formed on the electrodeposited surface 3 on the inner surface side, and is formed by applying a pigment-free resin-based paint to a thickness of 40 to 60 .mu.m by spraying or the like.

6はA1蒸着層であり、約1000人の膜厚を有する。6 is an A1 vapor deposited layer and has a thickness of about 1000 layers.

7は本発明のトップコート層であり、下記処方の塗料戒
分に光安定化剤(2−(3.5−ジーLブチルー4−ヒ
ドロキシベンジル)−2−n−7’チルマロン酸−ビス
(1,2,2,6.6−ペンタメチル4−ピペリジル)
 1.13重量部及び染料(フタロシアニンブルー) 
0.0375重量部を含有させたものをスプレー、ディ
ッピング等の方法によって膜厚5μm前後に設けたトッ
プコートa層7aと下記処方の塗料成分に紫外線吸収剤
、2−〔2−ヒドロキシー3.5−ジ(α,α−ジメチ
ルベンジル)フ工ニル〕−2Hヘンゾトリアゾール2.
66重量部を含有させたものを上記と同様な方法によっ
て膜厚5μm前後に設けたトンプコートb層7bとから
構成したものである。
7 is the top coat layer of the present invention, in which a light stabilizer (2-(3.5-di-L-butyl-4-hydroxybenzyl)-2-n-7' tilmalonic acid-bis( 1,2,2,6.6-pentamethyl4-piperidyl)
1.13 parts by weight and dye (phthalocyanine blue)
A top coat layer 7a containing 0.0375 parts by weight was formed to a thickness of around 5 μm by spraying, dipping, etc., and the coating components of the following formulation included an ultraviolet absorber, 2-[2-hydroxy-3.5 -di(α,α-dimethylbenzyl)phenyl]-2Hhenzotriazole2.
66 parts by weight of the Tompcoat b layer 7b, which was formed to a thickness of about 5 μm by the same method as above.

塗料戒分:             重量部樹脂 アクリル樹脂          13.3?容媒 酢酸エチル           28.9ジイソブチ
ルケトン       22.2脂肪族炭化水素   
      22.2トルエン           
 6.0キシレン             4.0ノ
ルマルブチルアルコール    3.4次にこの第1図
に示した灯具の色光の経時変化を以下の方法により調べ
た。尚、比較例として上記塗料m戊中、紫外線吸収剤及
び光安定化剤を除いた他は同様の塗料を用いてトップコ
ート層を設けた反射鏡を作威した。
Paint precepts: Part by weight Resin Acrylic resin 13.3? Vehicle Ethyl acetate 28.9 Diisobutyl ketone 22.2 Aliphatic hydrocarbon
22.2 Toluene
6.0 xylene 4.0 n-butyl alcohol 3.4 Next, the change in color light of the lamp shown in FIG. 1 over time was investigated by the following method. As a comparative example, a reflecting mirror provided with a top coat layer was prepared using the same paint as above except that the ultraviolet absorber and light stabilizer were omitted.

試験方法: 本発明反射鏡の灯具及び比較灯具をフェードメータ内に
入れカーボン電極によるアークランプ光を400時間照
射した後、灯具を点灯し目視によってその色光を比較し
た。尚、両灯只の当初の色光は共に正常なブルー光であ
った。
Test method: The lamp of the reflector of the present invention and the comparison lamp were placed in a fade meter, and arc lamp light from a carbon electrode was irradiated for 400 hours.The lamps were then turned on and the color light was visually compared. The initial colored light of both lamps was normal blue light.

結果: 比較品は本発明の灯具に比べ赤味の強い光であったが、
本灯具は当初のブルー光を維持していた。
Results: The comparative product had a stronger reddish light than the lamp of the present invention, but
This lamp maintained its original blue light.

(実施例−2) 実施例−1で用いた支持体を鉄基板2のみとし、かつ前
記本発明コート層形戒塗料成分を下記威分に代えた以外
は実施例−1と同様に1蒸着層、トップコートa層、ト
ップコー}b層を順次設けた本発明の反射鏡及び上記比
較例と同様に比較品を作威し、実施例−1と同様に試験
した結果、実施例1と同様に、比較品は本発明の灯具に
比べ赤味の強い光であったが、本灯具は当初のブルー光
を維持していた。
(Example 2) One vapor deposition was carried out in the same manner as in Example 1, except that the support used in Example 1 was only the iron substrate 2, and the components of the coated layered paint of the present invention were replaced with the ingredients below. A comparative product was produced in the same manner as the reflective mirror of the present invention and the above-mentioned comparative example, and was tested in the same manner as in Example-1. Similarly, the light of the comparative product was more reddish than that of the lamp of the present invention, but the present lamp maintained its original blue light.

塗料成分: 重量部 樹脂 アクリル樹脂          14.0メラミン樹
脂          1.4溶媒 プチルセロソルブ        28.9芳香族炭化
水素         49.6(発明の効果) 本発明は、主に自然光及びランプ由来の紫外線による染
料の変化を効果的に抑制するので、長期的に安定した色
光が得られる反射鏡を提供することができる。
Paint components: Parts by weight Resin acrylic resin 14.0 Melamine resin 1.4 Solvent butyl cellosolve 28.9 Aromatic hydrocarbon 49.6 (Effects of the invention) The present invention mainly focuses on changes in dyes caused by natural light and ultraviolet rays derived from lamps. Since this effectively suppresses the phenomenon, it is possible to provide a reflecting mirror that can provide stable colored light over a long period of time.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は灯具の切欠側面図であり、本発明の反射鏡を示
す図、第2図は、第1図の1−1’に沿う本発明反射鏡
の層構戒を示す断面図である。 符号の説明: l:本発明の反射鏡、2:鉄基板、3.4=電着塗面、
5:アンダーコート層、6: ^l蒸着層、7;本発明
のトップコート層、7a:本発明のトップコー1−a層
、7b:本発明のトップコートb(ほか3名) −4−
Fig. 1 is a cutaway side view of the lamp, showing the reflecting mirror of the present invention, and Fig. 2 is a sectional view showing the layer structure of the reflecting mirror of the present invention along line 1-1' in Fig. 1. . Explanation of symbols: 1: Reflector of the present invention, 2: Iron substrate, 3.4 = Electrodeposition coating surface,
5: Undercoat layer, 6: ^l vapor deposited layer, 7: Top coat layer of the present invention, 7a: Top coat 1-a layer of the present invention, 7b: Top coat b of the present invention (3 others) -4-

Claims (1)

【特許請求の範囲】[Claims] (1)支持体、Al蒸着層およびトップコート層からな
る車輌灯具用反射鏡において、該トップコート層が、染
料、紫外線吸収剤および光安定化剤を含有することを特
徴とする車輌灯具用反射鏡。
(1) A reflective mirror for a vehicle lamp comprising a support, an Al vapor deposited layer and a top coat layer, wherein the top coat layer contains a dye, an ultraviolet absorber and a light stabilizer. mirror.
JP1160808A 1989-06-26 1989-06-26 Reflector for vehicle lighting Expired - Lifetime JPH07120482B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1160808A JPH07120482B2 (en) 1989-06-26 1989-06-26 Reflector for vehicle lighting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1160808A JPH07120482B2 (en) 1989-06-26 1989-06-26 Reflector for vehicle lighting

Publications (2)

Publication Number Publication Date
JPH0329201A true JPH0329201A (en) 1991-02-07
JPH07120482B2 JPH07120482B2 (en) 1995-12-20

Family

ID=15722879

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1160808A Expired - Lifetime JPH07120482B2 (en) 1989-06-26 1989-06-26 Reflector for vehicle lighting

Country Status (1)

Country Link
JP (1) JPH07120482B2 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5727501A (en) * 1980-07-28 1982-02-13 Iwasaki Electric Co Ltd Illuminator
JPS6224409U (en) * 1985-07-25 1987-02-14
JPS641764A (en) * 1987-06-04 1989-01-06 Ciba Geigy Ag Photostabilized polymer microparticles containing epoxy group, their production and dispersion system containing the same and coating composition containing dispersion system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5727501A (en) * 1980-07-28 1982-02-13 Iwasaki Electric Co Ltd Illuminator
JPS6224409U (en) * 1985-07-25 1987-02-14
JPS641764A (en) * 1987-06-04 1989-01-06 Ciba Geigy Ag Photostabilized polymer microparticles containing epoxy group, their production and dispersion system containing the same and coating composition containing dispersion system

Also Published As

Publication number Publication date
JPH07120482B2 (en) 1995-12-20

Similar Documents

Publication Publication Date Title
ATE25099T1 (en) COATING COMPOUND, COATING PROCESS AND COATING SUBSTRATE.
US3099637A (en) Reflex-reflectorizing composition
KR900014043A (en) Cladding system with metal underdrawing showing dichroic shift effect
EP3634650B1 (en) Multi-layered finishes for can ends
JPH0329201A (en) Reflection mirror for lighting system of vehicle
US20040091629A1 (en) Coated substrate with metallic surface impression, method for adhesively coating substrates with corrosive optical layers and use of said coated substrate and products obtained from a method for adhesively coating with corrosive optical layers
US5049442A (en) Opalescent coatings containing foamed metal oxides
US5147689A (en) Method for forming a coating film with a relief pattern
JPH0465796B2 (en)
AU8625198A (en) Transparent coating agents and the use thereof to produce multi-layered coatings
JPH03270769A (en) Metallic laminated coating film structure
JP5916659B2 (en) Vehicle wheel
KR910014475A (en) Subtle patina metallic coating containing guanine
JP2020179512A (en) Multilayer coating film
JP4127212B2 (en) Painting method
US2156694A (en) Wood-sealing composition
JP2621550B2 (en) Variable color coating
JPS62125347A (en) Package of photographic sensitive material
JPH0565546B2 (en)
JPH09290213A (en) Metallic material surface coating film structure and its formation
Corrêa et al. Brand New Technology: Chromed Plate Appearance Painting with Potential Use in Internal and External Automotive Parts
JP2000042482A (en) Formation of double layer coating film
JP2005199216A (en) Bright light alloy-made part
KR900014634A (en) Multilayer coating systems, methods of applying such coating systems and the resulting coated articles
CA2390901A1 (en) Xerographic paper and coating compositions therefor