JPH03277000A - Diaphragm for electroacoustic transducer - Google Patents

Diaphragm for electroacoustic transducer

Info

Publication number
JPH03277000A
JPH03277000A JP7725990A JP7725990A JPH03277000A JP H03277000 A JPH03277000 A JP H03277000A JP 7725990 A JP7725990 A JP 7725990A JP 7725990 A JP7725990 A JP 7725990A JP H03277000 A JPH03277000 A JP H03277000A
Authority
JP
Japan
Prior art keywords
diaphragm
inorganic
organic
organic composite
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7725990A
Other languages
Japanese (ja)
Other versions
JP2886607B2 (en
Inventor
Shuichi Ichikawa
秀一 市川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foster Electric Co Ltd
Original Assignee
Foster Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foster Electric Co Ltd filed Critical Foster Electric Co Ltd
Priority to JP7725990A priority Critical patent/JP2886607B2/en
Publication of JPH03277000A publication Critical patent/JPH03277000A/en
Application granted granted Critical
Publication of JP2886607B2 publication Critical patent/JP2886607B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a diaphragm equipped with a high elasticity and durability by forming inorganic/organic composite materials on the substrate of the diaphragm by applying or impregnating a ceramic coating agent to the substrate of the diaphragm with cold or hot drying. CONSTITUTION:The ceramic coating agent is applied to a substrate 1 of the diaphragm by the sol-gel method, and inorganic/organic composite materials 2 and 2a are adhered by surface-coating or impregnating it to the substrate of the diaphragm with cold or hot drying. The inorganic/organic composite material formed by the sol-gel method is formed by mixing metal-alkoxide and organic monomer and reacting these. Since the inorganic/organic composite material is the one formed by connecting a inorganic bond by a covalent bond with organic polymer according to polymerization reaction, the material can be controlled freely by the ratio of inorganic and organic components. In short, the coalescence containing much inorganic components shows the properties of ceramics, and the characteristics of the coalescence containing much organic components is close to the material of synthetic resin. Thus, the high elastic and durable diaphragm equipped with the high elasticity and durability can be obtained at low cost.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、振動板に無機−有機複合体を表面コートまた
は含浸させてなる電気音響変換器用振動板に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a diaphragm for an electroacoustic transducer, which is formed by surface-coating or impregnating the diaphragm with an inorganic-organic composite.

(従来の技術) 従来、電気音響変換器に使用される振動板は、プラスチ
ックフィルム、金属板、織布等を成形加工して作るか、
あるいは天然繊維、合成繊維等に樹脂加工等を施し、そ
れを成形加工したものが多く用いられている。
(Prior Art) Conventionally, diaphragms used in electroacoustic transducers have been made by molding plastic films, metal plates, woven fabrics, etc.
Alternatively, natural fibers, synthetic fibers, etc. are often treated with resin and then molded.

しかし、これらは比弾性率が小さいため、良好な周波数
特性を得ることができなかった。
However, since these have a small specific elastic modulus, it has not been possible to obtain good frequency characteristics.

これらを改善するために、チタンやアルミナを基材とし
、ダイヤモンド状炭素膜やダイヤモンド膜を基材表面に
形成させた振動板がある。
In order to improve these problems, there is a diaphragm that uses titanium or alumina as a base material and has a diamond-like carbon film or a diamond film formed on the surface of the base material.

一方、紙製の振動板において、内部損失が比較的大きく
、高弾性の振動板を得る方法として、実開昭63−15
6198号に示されるように、紙基材の表面にセラミッ
ク系のコーティング剤を塗布したものもある。
On the other hand, as a method for obtaining a paper diaphragm with relatively large internal loss and high elasticity,
As shown in No. 6198, there is also one in which a ceramic coating agent is applied to the surface of a paper base material.

(発明が解決しようとする課Ifり しかしながら、前者のものでは基材を100〜900°
C程度に加熱してプラズマCVD法で表面コーティング
しているため、コーテイング膜の厚さは最大でも2μm
程度となり、振動板として十分な効果が得られないこと
と、大形基材へのコーティングが困難となり、コストア
ップの要因となる、といった課題がある。
(If the problem that the invention seeks to solve) However, in the former case, the base material is
Since the surface is coated using the plasma CVD method after being heated to about C, the thickness of the coating film is at most 2 μm.
However, there are problems such as not being able to obtain a sufficient effect as a diaphragm, and making it difficult to coat large substrates, which increases costs.

また、後者のものは、コーティング剤としてセラミック
を主原料としているが、セラミック物質の相互間はエポ
キシ樹脂等の有機物質で結合されているため、結局、所
望の高弾性を有する振動板を得ることはできず、かつ三
層構造で構成されるので、構造が複雑であるなどの課題
がある。
In addition, the latter uses ceramic as the main raw material as a coating agent, but since the ceramic materials are bonded together with an organic material such as epoxy resin, it is difficult to obtain a diaphragm with the desired high elasticity. However, since it is composed of three layers, there are problems such as a complicated structure.

本発明は、上記のことに鑑み提案されたもので、その目
的とするところは、振動板基材に無機−有機複合体を付
着し、所望の剛性などを備え、耐久性があり、製造が容
品で安価な電気音響変換器用振動板を提供することにあ
る。
The present invention has been proposed in view of the above, and its purpose is to attach an inorganic-organic composite to a diaphragm base material to provide desired rigidity, durability, and manufacturing ease. An object of the present invention is to provide a compact and inexpensive diaphragm for an electroacoustic transducer.

(課題を解決するための手段) 本発明は、天然繊維等の繊維状物質、合成樹脂発泡体ま
たはフィルム、金属発泡体または金属板、セラミック発
泡体またはセラミック板等で構成された振動板基材に、
ゾル−ゲル法にてセラミック系コーティング剤を塗布し
、振動板基材に対して表面コートまたは含浸させ常温ま
たは加熱乾燥にて無機−有機複合体を付着させて振動板
を構成することにより、上記目的を達成している。
(Means for Solving the Problems) The present invention provides a diaphragm base material made of a fibrous material such as natural fiber, a synthetic resin foam or film, a metal foam or metal plate, a ceramic foam or a ceramic plate, etc. To,
By applying a ceramic coating agent using the sol-gel method, surface coating or impregnating the diaphragm base material, and attaching the inorganic-organic composite at room temperature or heat drying, the diaphragm is constructed. has achieved its purpose.

また、セラミック系コーティング剤として無機有機複合
体に金属粉等の無機フィラーを添加して構成したものを
用いても良く、−これによっても上記目的を達成してい
る。
Furthermore, a ceramic coating agent made by adding an inorganic filler such as metal powder to an inorganic-organic composite may also be used, and this also achieves the above object.

(作 用) 本発明では上記のように、皮膜形成剤または添加物の結
合剤(バインダー)にはエポキシ樹脂などの有機物を用
いず、皮膜形成剤または結合剤として、ゾル−ゲル法に
よる無機−有機複合体を使用しているため、高弾性で耐
久性のある振動板を安価に得ることができる。
(Function) As described above, in the present invention, an organic material such as an epoxy resin is not used as a film-forming agent or a binder for additives, but an inorganic material using a sol-gel method is used as a film-forming agent or binder. Since an organic composite is used, a highly elastic and durable diaphragm can be obtained at low cost.

ゾル−ゲル法による無機−有機複合体は、金属アルコキ
シドと有機モノマーを混合し、それらを反応させて作ら
れる。この無機−有機複合体は重合反応によっ□て無機
の結合を有機の高分子で共有結合によってつないだ形の
無機−有m複合体であるため、無機成分と有機成分の相
違並びにそれらの比率によって無機−有機複合体の物性
は任意にコントロールすることができる。つまり、無機
成分の含有量の多い無機−有機複合体はセラミックの性
質を発現し、有機成分の含有量の多い無機有機複合体は
耐熱性の高い合成樹脂の物性に近くなる。
An inorganic-organic composite by the sol-gel method is produced by mixing a metal alkoxide and an organic monomer and reacting them. This inorganic-organic composite is an inorganic-organic composite in which inorganic bonds are linked by covalent bonds with organic polymers through a polymerization reaction, so there are differences between the inorganic and organic components and their ratio. The physical properties of the inorganic-organic composite can be controlled arbitrarily. In other words, an inorganic-organic composite with a high content of inorganic components exhibits the properties of a ceramic, and an inorganic-organic composite with a high content of organic components has physical properties close to that of a synthetic resin with high heat resistance.

また、ゾル−ゲル法を使用しているため、上記セラミッ
ク系コーティング剤は次のような特徴を有している。
Further, since the sol-gel method is used, the ceramic coating agent has the following characteristics.

(1)  低温で無機−有機複合体合成が可能である。(1) Inorganic-organic composite synthesis is possible at low temperatures.

(2)溶液から出発しているので、多成分系であっても
、分子、原子レベルで混合ができるため均一性が良い。
(2) Since it starts from a solution, even if it is a multi-component system, it can be mixed at the molecular or atomic level, resulting in good uniformity.

(3)新しい組成の物質の合成が容易である。(3) It is easy to synthesize substances with new compositions.

さらに、セラミック系コーティング剤を基材の表面に塗
布する場合、特別な装置を用いなくて良いため、コスト
パフォーマンスに優れ、安価な振動板を実現している。
Furthermore, when applying the ceramic coating agent to the surface of the base material, there is no need to use special equipment, making it possible to realize a diaphragm with excellent cost performance and low cost.

(実施例) 以下に本発明の詳細な説明する。ゾル−ゲル法による無
機−有l5IFA合体は前記のように容易に種々の物質
を合成することができるが、本実施例では、紙基材に、
シリコン−チタニウム系の無機有機複合体にアルミニウ
ム粉を混入した皮膜を形成した場合のものを一例として
記す。
(Example) The present invention will be described in detail below. As mentioned above, various substances can be easily synthesized by combining inorganic-organic IFA using the sol-gel method, but in this example, the paper base material was
An example will be described in which a film is formed by mixing aluminum powder into a silicon-titanium-based inorganic-organic composite.

紙基材は、NBKP80%、マニラ麻バルブ20%をビ
ータ−に投入し叩解度が23”SRになるまで叩解し、
叩解後のバルブを染料とサイズ剤とで染色、サイズ処理
をした。処理されたパルプ材は水道水で希釈し、抄紙機
にて所定の形状に抄紙し、乾燥して作製した。
For the paper base material, 80% NBKP and 20% Manila hemp valve were put into a beater and beaten until the degree of beating reached 23"SR.
After beating, the bulbs were dyed and sized using a dye and a sizing agent. The treated pulp material was diluted with tap water, made into a predetermined shape using a paper machine, and dried.

コーティング剤の主成分としては金属酸化物系ポリマー
の一種である金属アルコキシドを用い、この金属アルコ
キシドとしては下記の(1)と(2)を用いた。
A metal alkoxide, which is a type of metal oxide polymer, was used as the main component of the coating agent, and the following (1) and (2) were used as the metal alkoxide.

Ti (OC4H9) 4           ・ 
・ ・ ・ ・(2)(1)と(2)の配合比率はセラ
ミックとしてのSingとTiO□の重量比でStow
/Ti0z=74/26である。
Ti (OC4H9) 4 ・
・ ・ ・ ・(2) The blending ratio of (1) and (2) is the weight ratio of Sing and TiO□ as ceramics.
/Ti0z=74/26.

溶剤としては、トルエン、キシレン、n−ブタノールの
混合溶剤を用い上記(1)と(2)の混合物とした。混
合後の固形分は25%であり、このようにして製造され
たセラマー剤の固形分と同量のアルミニウム粉を添加し
てセラミック系コーティング剤とした。
As a solvent, a mixed solvent of toluene, xylene, and n-butanol was used to prepare a mixture of (1) and (2) above. The solid content after mixing was 25%, and the same amount of aluminum powder as the solid content of the ceramer agent thus produced was added to prepare a ceramic coating agent.

セラミック系コーティング剤の反応物質は、反応の過程
でゾルの状態、ゲルの状態を経過して、無機の結合(S
t−0、Ti−0)を有機の高分子で共有結合によって
つないだ形の無機−有機複合体となって固化体となる。
The reactants of ceramic coating agents pass through the sol state and gel state during the reaction process, forming inorganic bonds (S
t-0, Ti-0) are connected by covalent bonds with organic polymers to form an inorganic-organic composite, which becomes a solidified body.

この無機−有機複合体をこの種技術分野でハイブリッド
またはセラマーとも称している。
This inorganic-organic composite is also called a hybrid or a ceramer in this technical field.

塗布方法としては、上記紙基材表面に基材重量に対して
重量比で15%の上記セラミック系コーティング剤をエ
アースプレーで均一に塗布した。
As a coating method, the ceramic coating agent was uniformly applied to the surface of the paper base material by air spray in a weight ratio of 15% based on the weight of the base material.

塗布されたものは室温で5分間放置後、150°Cで4
0分間強制乾燥した。なお、乾燥手段としては、常温で
約10日放置したままでも、あるいは強制乾燥でも良く
、これらは製造時間の問題である。
The coated material was left at room temperature for 5 minutes, then heated to 150°C for 4 minutes.
Forced drying was performed for 0 minutes. The drying method may be left at room temperature for about 10 days or forced drying, both of which are a matter of manufacturing time.

得られた無機−有機複合体の皮膜は硬度が鉛筆硬度で6
〜7Hであり、フレキシブル性のあるセラミック系皮膜
となった。振動板としては高弾性で適度の内部損失を有
し、機械的疲労がなく、耐水性、耐熱性、耐候性が優れ
、かつ電気導電性なく難燃性であワた。
The obtained inorganic-organic composite film has a hardness of 6 on the pencil hardness scale.
~7H, resulting in a flexible ceramic film. As a diaphragm, it has high elasticity, moderate internal loss, no mechanical fatigue, excellent water resistance, heat resistance, and weather resistance, and is flame retardant with no electrical conductivity.

紙基材に塗布された振動板の部分断面を第1図に示す、
すなわち、第1図において1は振動板基材、2はその表
面に形成された無機−有機複合体、2aは振動板基材l
中に含浸された無機−有機複合体である。
A partial cross section of the diaphragm coated on the paper base material is shown in Figure 1.
That is, in FIG. 1, 1 is the diaphragm base material, 2 is the inorganic-organic composite formed on its surface, and 2a is the diaphragm base material l.
It is an inorganic-organic composite impregnated inside.

第3図は本実施例で作製した振動板を用いた1610径
のスピーカの周波数特性を示し、Aは本発明のもの、B
は従来の紙製振動板である。
Figure 3 shows the frequency characteristics of a speaker with a diameter of 1610 using the diaphragm manufactured in this example, where A is the one of the present invention and B is the one of the present invention.
is a conventional paper diaphragm.

なお、第1回では暴動仮基材1の一方の面のみに無機−
有機複合体2を形成した例について示したが、両面に形
成しても良いことは勿論である。
In addition, in the first trial, inorganic material was applied only to one side of the riot temporary base material 1.
Although an example in which the organic composite 2 is formed has been shown, it goes without saying that it may be formed on both sides.

また、第3図に示すように、振動板基材1の表面に適宜
の配合比の上記コーティング剤をエアースプレーで吹き
付けるなどして無機−有機複合体を含浸させた振動板で
あっても良く、この場合も優れた緒特性を有する振動板
を得ることができる。
Alternatively, as shown in FIG. 3, the diaphragm may be impregnated with an inorganic-organic composite by spraying the above-mentioned coating agent at an appropriate mixing ratio onto the surface of the diaphragm base material 1 using air spray. In this case as well, a diaphragm having excellent vibration characteristics can be obtained.

なお、上記実施例では、セラミック系コーティング剤を
無機−有機複合体とアルミニウム粉とで構成した例につ
いて説明したが、アルミニウム粉以外の無機質フィラー
を用いたものであっても良(、この場合、セラミック特
有の脆さがなくなり、耐久性を大巾に向上させることが
できる。
In the above example, an example was explained in which the ceramic coating agent was composed of an inorganic-organic composite and aluminum powder, but it is also possible to use an inorganic filler other than aluminum powder (in this case, The brittleness peculiar to ceramics is eliminated, and durability can be greatly improved.

また、振動板基材1としては紙基材を用い、これを所定
の形状に抄紙・乾燥させてなる天然繊維の繊維状物質の
ほかに、例えば合成樹脂発泡体またはフィルム、金属発
泡体または金属板、セラミック発泡体またはセラミック
板等を用い、これにゾル−ゲル法により無機−有機複合
体を形成しても良い。
Furthermore, as the diaphragm base material 1, a paper base material is used, and in addition to a natural fiber fibrous material obtained by paper-making and drying this into a predetermined shape, for example, a synthetic resin foam or film, a metal foam, or a metal An inorganic-organic composite may be formed on a plate, ceramic foam, ceramic plate, or the like by a sol-gel method.

(発明の効果) 以上のように、本発明によれば、振動板基材にセラミッ
ク系コーティング剤を塗布または含浸し、常温乾燥また
は加熱乾燥して前記振動板基材に無機−有機複合体を形
成したので、高弾性で耐久性の良い振動板を得ることが
できる。
(Effects of the Invention) As described above, according to the present invention, a ceramic coating agent is coated or impregnated on a diaphragm base material, and an inorganic-organic composite is coated on the diaphragm base material by drying at room temperature or heating. As a result, a highly elastic and durable diaphragm can be obtained.

さらに、耐熱性の低い合成樹脂基材であっても、通常の
塗装のように、セラミック系コーティング剤を塗布させ
、乾燥させるといった簡易構成としたから、特別の特殊
な装置が不要で製造が容品となり、かつ量産性に優れ、
安価な振動板を得ることができる等の効果がある。
Furthermore, even if the base material is a synthetic resin with low heat resistance, the simple structure of applying a ceramic coating agent and drying it, just like regular painting, eliminates the need for special equipment and makes manufacturing easy. product, and has excellent mass productivity.
There are effects such as being able to obtain an inexpensive diaphragm.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の振動板の部分断面図、第2図は本発明
と従来例とを比較した周波数特性図、第3図は本発明の
振動板の他の例を示す。 1・・・振動板基材、2・・・無機−有機複合体、2a
・・・含浸されたセラマー
FIG. 1 is a partial sectional view of the diaphragm of the present invention, FIG. 2 is a frequency characteristic diagram comparing the present invention and a conventional example, and FIG. 3 is a diagram showing another example of the diaphragm of the present invention. 1... Vibration plate base material, 2... Inorganic-organic composite, 2a
...impregnated ceramer

Claims (2)

【特許請求の範囲】[Claims] (1)天然繊維等の繊維状物質、合成樹脂発泡体または
フィルム、金属発泡体または金属板、セラミック発泡体
またはセラミック板等で構成された振動板基材に、ゾル
−ゲル法にてセラミック系コーティング剤を塗布し、振
動板基材に対して表面コートまたは含浸させ常温または
加熱乾燥にて無機−有機複合体を付着させたことを特徴
とする電気音響変換器用振動板。
(1) A ceramic material is applied to a diaphragm base material made of a fibrous material such as natural fibers, a synthetic resin foam or film, a metal foam or metal plate, a ceramic foam or a ceramic plate, etc. using the sol-gel method. A diaphragm for an electroacoustic transducer, characterized in that an inorganic-organic composite is adhered to a diaphragm base material by coating or impregnating the surface of the diaphragm substrate with a coating agent and drying at room temperature or by heating.
(2)セラミック系コーティング剤は上記無機−有機複
合体に金属粉等の無機フィラーを添加して構成したこと
を特徴とする請求項(1)記載の電気音響変換器用振動
板。
(2) The diaphragm for an electroacoustic transducer according to claim (1), wherein the ceramic coating agent is formed by adding an inorganic filler such as metal powder to the inorganic-organic composite.
JP7725990A 1990-03-27 1990-03-27 Diaphragm for electroacoustic transducer Expired - Fee Related JP2886607B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7725990A JP2886607B2 (en) 1990-03-27 1990-03-27 Diaphragm for electroacoustic transducer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7725990A JP2886607B2 (en) 1990-03-27 1990-03-27 Diaphragm for electroacoustic transducer

Publications (2)

Publication Number Publication Date
JPH03277000A true JPH03277000A (en) 1991-12-09
JP2886607B2 JP2886607B2 (en) 1999-04-26

Family

ID=13628856

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7725990A Expired - Fee Related JP2886607B2 (en) 1990-03-27 1990-03-27 Diaphragm for electroacoustic transducer

Country Status (1)

Country Link
JP (1) JP2886607B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997022566A1 (en) * 1995-12-15 1997-06-26 Westinghouse Electric Corporation Oxide ceramic composite for high temperature environment device, method and system
JP2016051991A (en) * 2014-08-29 2016-04-11 パイオニア株式会社 Diaphragm for speaker, and speaker device
WO2017046874A1 (en) * 2015-09-15 2017-03-23 パイオニア株式会社 Speaker diaphragm, speaker device and mobile unit

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997022566A1 (en) * 1995-12-15 1997-06-26 Westinghouse Electric Corporation Oxide ceramic composite for high temperature environment device, method and system
JP2016051991A (en) * 2014-08-29 2016-04-11 パイオニア株式会社 Diaphragm for speaker, and speaker device
WO2017046874A1 (en) * 2015-09-15 2017-03-23 パイオニア株式会社 Speaker diaphragm, speaker device and mobile unit
JPWO2017046874A1 (en) * 2015-09-15 2018-06-28 パイオニア株式会社 Speaker diaphragm, speaker device, and moving body

Also Published As

Publication number Publication date
JP2886607B2 (en) 1999-04-26

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