JPH03275860A - Contamination-preventing method for vinyl chloride wallpaper - Google Patents
Contamination-preventing method for vinyl chloride wallpaperInfo
- Publication number
- JPH03275860A JPH03275860A JP2071827A JP7182790A JPH03275860A JP H03275860 A JPH03275860 A JP H03275860A JP 2071827 A JP2071827 A JP 2071827A JP 7182790 A JP7182790 A JP 7182790A JP H03275860 A JPH03275860 A JP H03275860A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- oxide
- reactive group
- chloride wallpaper
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 12
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- LOUICXNAWQPGSU-UHFFFAOYSA-N 2,2,3,3-tetrafluorooxirane Chemical compound FC1(F)OC1(F)F LOUICXNAWQPGSU-UHFFFAOYSA-N 0.000 claims abstract description 3
- IYRWEQXVUNLMAY-UHFFFAOYSA-N carbonyl fluoride Chemical compound FC(F)=O IYRWEQXVUNLMAY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000003373 anti-fouling effect Effects 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000002932 luster Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- SLGOCMATMKJJCE-UHFFFAOYSA-N 1,1,1,2-tetrachloro-2,2-difluoroethane Chemical compound FC(F)(Cl)C(Cl)(Cl)Cl SLGOCMATMKJJCE-UHFFFAOYSA-N 0.000 description 1
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000006551 perfluoro alkylene group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、塩化ビニル製壁紙の防汚方法に関するちので
ある。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a stain-proofing method for vinyl chloride wallpaper.
［従来の技術及び発明が解決しようとする課題］従来塩
ビ壁紙の防汚方法としてアクリル系もしくはアクリル−
ウレタン系樹脂をコーティングする方法が採用されてい
た。しがし本方法では、壁紙の表面に塗膜を形成させる
ため光沢が生じ室内用として用いにくいこと、及び発泡
塩ビを用いた場合発生したガスが塗膜を通して発散しに
くく、塗膜のフクレが生じ実用性が無かった。[Prior art and problems to be solved by the invention] Conventionally, acrylic or acrylic-based stain-proofing methods for PVC wallpaper have been used.
A method of coating with urethane resin was adopted. However, in this method, a coating film is formed on the surface of the wallpaper, which creates a gloss that makes it difficult to use for indoor use.In addition, when foamed PVC is used, the gas generated is difficult to diffuse through the coating film, causing blistering of the coating film. It was not practical.
［課題を解決するための手段］
本発明は前述の問題点を解決すべくなされたものであり
ポリパーフルオロアルキレンオキサイド及び反応性基を
有する化合物を塗布することを特徴とする塩化ビニル製
壁紙の防汚方法に関するものである。[Means for Solving the Problems] The present invention has been made to solve the above-mentioned problems, and is directed to a vinyl chloride wallpaper coated with polyperfluoroalkylene oxide and a compound having a reactive group. The present invention relates to an antifouling method.
本発明における、ポリバーフルオロアルキレンオキサイ
ド及び反応性基を有する化合物は、分子量が１０００〜
５ｏｏｏｏ、好ましくは２０００〜１００００さらに好
ましくは２０００〜６０００の常温で液状のものが適当
である。ポリパーフルオロアルキレンオキサイドとして
は、パーフルオロプロピレンオキサイド、パーフルオロ
エチレンオキサイド又はパーフルオロメチレンオキサイ
ド等のいずれでもよく、又、これらを２種以上を組み合
せた共重合構造でもよい。In the present invention, the compound having a polyfluoroalkylene oxide and a reactive group has a molecular weight of 1000 to
5oooo, preferably from 2,000 to 10,000, more preferably from 2,000 to 6,000, which is liquid at room temperature. The polyperfluoroalkylene oxide may be perfluoropropylene oxide, perfluoroethylene oxide or perfluoromethylene oxide, or may have a copolymer structure in which two or more of these are combined.
反応性基としては、−ＣＯＯＨ，−ＯＨ，−ＣＯＯＲ。As the reactive group, -COOH, -OH, -COOR.
−ＮＣＯ，−５ｔ（ＯＲ）ａ、 −ＣＨｚＣＨＣＨｔ等
を挙げることが＼１
でき、これらの２種以上を同一化合物中に同時に有する
ものでもよい。Ｒは炭素数１〜２０のアルキル基又はフ
ェニル基等のアリール基であり、エチル基やプロピル基
等の低級アルキル基が好ましい。Examples include -NCO, -5t(OR)a, -CHzCHCHt, etc., and two or more of these may be present simultaneously in the same compound. R is an alkyl group having 1 to 20 carbon atoms or an aryl group such as a phenyl group, and preferably a lower alkyl group such as an ethyl group or a propyl group.
本発明における化合物の具体例は以下の通りである。Specific examples of the compounds in the present invention are as follows.
・ＨＯＯＣＣＦ！ ４０Ｃ２Ｆ４ ） 、（ＯＣＦ、
）−！ＩＯＣＦｍＣＯＯＨ・Ｈ？Ｃ１００ＣＣＦ２イ０
ＣＪ−）−（ＯＣＦＪゎＯＣＦ、Ｃ００Ｃ，Ｈ。・HOOCCF! 40C2F4) , (OCF,
)-! IOCFmCOOH・H? C100CCF2i0
CJ-)-(OCFJゎOCF,C00C,H.
・ＨＯＣＨ＊ＣＦｇ （ＯＣ，Ｆ、） 、（ＯＣＦ、）
−１１ＯＣＦＩＣＨ，ＯＨ・ （Ｃ，Ｈ，Ｏ）’ ｓ
Ｓｔ ＋ＣＨｘ ） ５ＮＨｃＯｃＦｚ （ＯＣＪ４
） −−（ｏｃＦｇ ）−、ＯＣＦ、Ｃ０ＮＨ（’Ｃ１
，）−Ｉ Ｓｉ＋ＯＣ，Ｈ，）。・HOCH*CFg (OC,F,) , (OCF,)
-11OCFICH,OH・(C,H,O)'s
St +CHx ) 5NHcOcFz (OCJ4
) --(ocFg)-, OCF, C0NH('C1
,)-I Si+OC,H,).
１”ＩＩＪ−
塩ビ壁紙への塗布の際にはこれらの化合物を適当な溶媒
例えば、１，１．２−１−リクロロトリフルオロエタン
、テトラクロロジフルオロエタン、ジクロロペンタフル
オロプロパン、メタキシレンへキサフルオライド等のフ
ッ素系溶媒で希釈しグラビアコーター、スプレー、浸漬
法等の使用が可能である。1"IIJ- When applying to PVC wallpaper, these compounds are mixed with a suitable solvent such as 1,1,2-1-lichlorotrifluoroethane, tetrachlorodifluoroethane, dichloropentafluoropropane, meta-xylene hexafluoro It can be diluted with a fluorine-based solvent such as Ride and used with a gravure coater, spray, dipping method, etc.
［作用］
本発明において、ポリパーフルオロアルキレンオキサイ
ドはその反応性基を介して基材又は分子間で反応し架橋
することにより基材表面にパーフルオロアルキレンオキ
サイドの膜を形成する。[Function] In the present invention, polyperfluoroalkylene oxide reacts and crosslinks between the substrate or molecules via its reactive groups, thereby forming a film of perfluoroalkylene oxide on the surface of the substrate.
この膜は０．１μ以下の非常に薄い膜であるため塩ビ壁
紙を作る際に発泡させたガスがスムースに揮散するため
膜のフクレが無く美しい外観を有した膜を形成させるこ
とが可能である。またパーフルオロアルキレン基の持つ
低表面エネルギー性を基材に付与できるため汚れの原因
である水や油をハジキ防汚性を発揮できる。This film is extremely thin, less than 0.1μ, so the gas bubbled when making PVC wallpaper evaporates smoothly, making it possible to form a film with a beautiful appearance without blistering. . Furthermore, since the low surface energy properties of the perfluoroalkylene group can be imparted to the base material, it can exhibit repellent stain resistance against water and oil, which are the causes of stains.
［実施例］
市販塩化ビニル製壁紙に第１表に例示する化合物１〜■
の化合物をロールやへケ等で塗布し乾燥させる。尚、塗
布に際しては適当な濃度となるようにフロンＲ−１１３
（１，１，２−トリクロロトリフルオロエタン）、メタ
キシレンへキサフロライド等の溶剤にて希釈する。防汚
性は黒色マジックインキによる筆記性及び筆記後の除去
性で判断した。尚、その効果の度合は下記基準で示す。[Example] Compounds 1 to 2 shown in Table 1 were applied to commercially available vinyl chloride wallpaper.
Apply the compound with a roll or spatula and let it dry. In addition, when applying, add Freon R-113 to the appropriate concentration.
(1,1,2-trichlorotrifluoroethane), metaxylene hexafluoride, or other solvent. The stain resistance was judged by the ease of writing with black marker ink and the removability after writing. Incidentally, the degree of the effect is shown according to the following criteria.
第１表
（：ＣＨｘ）ｓ Ｓｔ （ＯＣＪｓ）ｉ
Ｍ−＝２，０００ｒＶ ： （Ｈ，Ｃ，０３−
，５Ｌ（ＣＨす、ＮＨＣＯＣＦオ〇−４Ｃ，Ｆ、Ｏチ、
（ＣＦ、０３−。ＣＦ、−ＣＯＮＨ−（ＣＨ−）−
Ｓｉ 【ＯＣｘｆ（ｓ）ｍ Ｍ−”４
，０００［発明の効果］
本発明の化合物は０．１μ以下の膜厚で塗膜を形成する
ため光沢や表面のフクレが生ぜず、また本化合物の末端
に有した反応性基が基材の塩ビと反応し又自己架橋する
ことにより強固に接着する。Table 1 (:CHx)s St (OCJs)i
M-=2,000rV: (H,C,03-
, 5L (CH, NHCOCF O〇-4C, F, Ochi,
(CF, 03-. CF, -CONH-(CH-)-
Si [OCxf(s)m M-”4
,000 [Effects of the Invention] The compound of the present invention forms a coating film with a thickness of 0.1μ or less, so gloss and surface blistering do not occur, and the reactive group at the end of the present compound forms a coating film with a thickness of 0.1μ or less. It reacts with PVC and forms a strong bond by self-crosslinking.
従って耐久性の高い防汚加工が可能となる。Therefore, highly durable antifouling processing becomes possible.
化合物 Ｍｗ；分子量Ｉ ：
ＨＯＣＩ（、ＣＦ、Ｏ＋′Ｃ，Ｆ２Ｏ）−、（ＣＦ２０
）ゎＣＦ、ＣＨ，０ＨＬ＝２．０００
ＩＩ ： Ｈ，Ｃ０ＣＯＣＦ、０（’Ｃ，Ｆ、０″＋、
（ＣＦ、Ｏ）−、ＣＦ、Ｃ００ＣＲ。Compound Mw; molecular weight I:
HOCI(,CF,O+'C,F2O)-,(CF20
)ゎCF,CH,0HL=2.000 II: H,COCF,0('C,F,0″+,
(CF, O)-, CF, C00CR.
Ｌ＝２．０００ ■ ：L=2.000 ■:
Claims (1)
基を有する化合物を塗布することを特徴とする塩化ビニ
ル製壁紙の防汚方法。 ２、ポリパーフルオロアルキレンオキサイドがパーフル
オロプロピレンオキサイド、パーフルオロエチレンオキ
サイド又はパーフルオロメチレンオキサイドから選ばれ
る少なくとも１種である請求項１に記載の防汚方法。 ３、反応性基が−ＣＯＯＨ、−ＯＨ、−ＣＯＯＲ、−Ｎ
ＣＯ、▲数式、化学式、表等があります▼又は▲数式、
化学式、表等があります▼［Ｒ；アルキル基 又はアリール基］から選ばれる少なくとも１種である請
求項１に記載の防汚方法。[Scope of Claims] 1. An antifouling method for vinyl chloride wallpaper, which comprises applying a polyperfluoroalkylene oxide and a compound having a reactive group. 2. The antifouling method according to claim 1, wherein the polyperfluoroalkylene oxide is at least one selected from perfluoropropylene oxide, perfluoroethylene oxide, and perfluoromethylene oxide. 3. Reactive group is -COOH, -OH, -COOR, -N
CO, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas,
The antifouling method according to claim 1, wherein the antifouling method is at least one selected from chemical formulas, tables, etc. ▼ [R; alkyl group or aryl group].
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2071827A JPH03275860A (en) | 1990-03-23 | 1990-03-23 | Contamination-preventing method for vinyl chloride wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2071827A JPH03275860A (en) | 1990-03-23 | 1990-03-23 | Contamination-preventing method for vinyl chloride wallpaper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03275860A true JPH03275860A (en) | 1991-12-06 |
Family
ID=13471773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2071827A Pending JPH03275860A (en) | 1990-03-23 | 1990-03-23 | Contamination-preventing method for vinyl chloride wallpaper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03275860A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000044575A2 (en) * | 1999-02-01 | 2000-08-03 | Rjf International Corporation | Write-on/wipe-off wall covering |
| EP1201698A1 (en) * | 2000-10-27 | 2002-05-02 | The Procter & Gamble Company | Compositions and methods for treating surfaces |
-
1990
- 1990-03-23 JP JP2071827A patent/JPH03275860A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000044575A2 (en) * | 1999-02-01 | 2000-08-03 | Rjf International Corporation | Write-on/wipe-off wall covering |
| WO2000044575A3 (en) * | 1999-02-01 | 2000-12-28 | Rjf Internat Corp | Write-on/wipe-off wall covering |
| US6251500B1 (en) | 1999-02-01 | 2001-06-26 | Rjf International Corporation | Write-on/wipe off wall covering |
| EP1201698A1 (en) * | 2000-10-27 | 2002-05-02 | The Procter & Gamble Company | Compositions and methods for treating surfaces |
| WO2002034815A3 (en) * | 2000-10-27 | 2002-08-15 | Procter & Gamble | Compositions and methods for treating surfaces |
| US7186300B2 (en) | 2000-10-27 | 2007-03-06 | The Procter & Gamble Company | Compositions and methods for treating surfaces |
| JP2007314798A (en) * | 2000-10-27 | 2007-12-06 | Procter & Gamble Co | Method for treating or cleaning surfaces in household |
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