JPH03266641A - Film having metallizable surface - Google Patents
Film having metallizable surfaceInfo
- Publication number
- JPH03266641A JPH03266641A JP6395090A JP6395090A JPH03266641A JP H03266641 A JPH03266641 A JP H03266641A JP 6395090 A JP6395090 A JP 6395090A JP 6395090 A JP6395090 A JP 6395090A JP H03266641 A JPH03266641 A JP H03266641A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- copolyester
- core layer
- film according
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims abstract description 36
- 229920001634 Copolyester Polymers 0.000 claims abstract description 26
- 239000012792 core layer Substances 0.000 claims abstract description 22
- 239000002985 plastic film Substances 0.000 claims abstract description 12
- 229920006255 plastic film Polymers 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- -1 polypropylene Polymers 0.000 claims description 6
- 238000001465 metallisation Methods 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000002318 adhesion promoter Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000003851 corona treatment Methods 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229920005674 ethylene-propylene random copolymer Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 230000035699 permeability Effects 0.000 abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 abstract description 4
- 229920001519 homopolymer Polymers 0.000 abstract description 3
- 229920005604 random copolymer Polymers 0.000 description 6
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000012793 heat-sealing layer Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006344 thermoplastic copolyester Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Physical Vapour Deposition (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は金属化可能な配向プラスチックフィルムに関し
、より詳細には、本発明はすぐれた積層結合力およびヒ
ートシール適性を有する該フィルムならびに金属被覆の
該フィルムに関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to metallizable oriented plastic films, and more particularly, the present invention relates to such films having excellent lamination bond strength and heat sealability, and to metallized such films.
アルミニウム、銀およびクロムのような金属をプラスチ
ンクフィルムに付着させることによって、ブラスチンク
フィルムの多くの用途において該フィルムを金属箔に置
き換えることを可能とした。The attachment of metals such as aluminum, silver and chromium to plastic film has made it possible to replace the film with metal foil in many applications of plastic film.
フィルムのたわみ性は強力な金属−プラスチック結合の
形成を必要とし、該結合を付与するための多くの方法が
開発された。Film flexibility requires the formation of a strong metal-plastic bond, and many methods have been developed for imparting that bond.
本発明は、透明性と積層結合力がすぐれ、水蒸気および
酸素透過度が低く、がっヒートシール可能なプラスチン
クフィルムで、金属付着および金属の均一性にすぐれる
金属化可能な配向プラスチックフィルムを提供しようと
するものである。The present invention is a heat-sealable plastic film with excellent transparency and lamination bonding strength, low water vapor and oxygen permeability, and a metallizable oriented plastic film with excellent metal adhesion and metal uniformity. This is what we are trying to provide.
本発明の第1の態様によれば
(i)イソタクチックポリプロピレンよりなるコア層、
(ii )コア層の一つの面に付着する同時押出コポリ
エステル層、および
(ii)コア層の反対面に付着する同時押出ヒートシー
ル可能な層よりなる金属化可能な配向プラスチックフィ
ルムが提供される。According to a first aspect of the invention, (i) a core layer comprising isotactic polypropylene; (ii) a coextruded copolyester layer adhered to one side of the core layer; A metallizable oriented plastic film is provided that comprises adhered coextruded heat sealable layers.
本発明は、また同時押出コポリエステル層(i1)上に
(jv )金属被覆を有する本明細書にいう金属化可能
なフィルムを含んでなる金属被覆の配向プラスチックフ
ィルムをも提供する0本発明は、また金属被覆(iv
)をポリプロピレンコア層い)に付着させる際のコポリ
エステル層(ii)の使用をも提供する。The present invention also provides a metallized oriented plastic film comprising a metallizable film as herein referred to with (jv) metallization on the coextruded copolyester layer (i1). , and metallization (iv
Also provided is the use of the copolyester layer (ii) in attaching a polypropylene core layer (ii) to a polypropylene core layer (ii).
高立体規則性のポリプロピレンホモポリマーよりなるコ
ア層(i)を含む多層の金属化可能な配向プラスチック
フィルムが提供される。このインタクチツクポリマーは
包装業界で周知であって、0、90ないし0.91の光
度、160″′ないし165℃の結晶融点、および2.
0ないし6グラム/10分、好ましくは3ないし4グラ
ム/10分のメルトインデックスを有している。該ポリ
マーは80ないし100χイソタクチツク、好ましくは
95ないし96%イソタクチンクである。この層の中に
付着増進剤を含むのが望ましい、適当な付着増進剤は、
異質の物質を相互に付着させるカップリング剤として働
くマレイン酸を少量含有する乳化可能なポリオレフィン
ワックスである。該ワックスはイーストマンケミカルプ
ロダクツ社からEPOLENE E−43という商品名
で市販されている。A multilayer metallizable oriented plastic film is provided that includes a core layer (i) of highly stereoregular polypropylene homopolymer. This interactive polymer is well known in the packaging industry and has a luminous intensity of 0.90 to 0.91, a crystalline melting point of 160'' to 165°C, and 2.
It has a melt index of 0 to 6 grams/10 minutes, preferably 3 to 4 grams/10 minutes. The polymer is 80 to 100 χ isotactic, preferably 95 to 96% isotactic. It is desirable to include an adhesion promoter in this layer; suitable adhesion promoters include:
It is an emulsifiable polyolefin wax containing a small amount of maleic acid, which acts as a coupling agent to attach dissimilar materials to each other. The wax is commercially available from Eastman Chemical Products Company under the trade name EPOLENE E-43.
ポリエステル層(i1)によって金属化可能な表面が便
供される。ポリプロピレンホモポリマーコア層とコポリ
エステル層は通常の状態では相溶せず、離層することが
あるので、コア層をコポリエステル層と結び付けるのに
ホモプロピレンホモポリマー中に付着増進剤が必要であ
る。A metallizable surface is provided by the polyester layer (i1). Since the polypropylene homopolymer core layer and the copolyester layer are not compatible under normal conditions and may delaminate, an adhesion promoter is required in the homopropylene homopolymer to bind the core layer to the copolyester layer. .
コポリエステル類は1つ以上の二塩基酸および/または
グリコールからつくられる。コポリエステル類はブリス
ター包装用、時にはびん用の押出シートとして用いられ
ることが多い。1−エチレン、4−シクロヘキシレン−
ジメチルテレフタレートのような無定形(非結晶性)の
熱可塑性コポリエステル物質は、本明細書で開示される
フィルムに、たとえば、光沢、透明性、剛性といった適
切な性質を付与させることが見出されている。この物質
はKODAII PE丁G C0POLYESTER6
763という商品名で市販されている。酸コポリエステ
ルはそれ自身サラン(PνDC) 塗料と付着すること
ができる。Copolyesters are made from one or more dibasic acids and/or glycols. Copolyesters are often used as extruded sheets for blister packaging and sometimes bottles. 1-ethylene, 4-cyclohexylene-
Amorphous (non-crystalline) thermoplastic copolyester materials, such as dimethyl terephthalate, have been found to impart suitable properties to the films disclosed herein, such as gloss, transparency, and stiffness. ing. This substance is KODAII PE Ding G C0POLYESTER6
It is commercially available under the trade name 763. The acid copolyester itself can be attached with Saran (PvDC) paint.
100グラム/インチに近い付着強度を得ることができ
る。Adhesive strengths approaching 100 grams/inch can be obtained.
エチレン−プロピレンランダムコポリマーまたはエチレ
ンーブチレンープロピレンターボリマーのヒートシール
可能な層をコポリエステル層と反射のコア層面にコア層
と同時押出するのが適当である。EPココポリマー類通
常1ないし7重量%のエチレンを含み、残余はプロピレ
ンである。このコポリマーは5.5ないし6.5重量%
のエチレンを含むのが好ましい。コポリマーの融点はポ
リプロピレンホモポリマーの融点よりも低くかつ幅広い
。Suitably, a heat-sealable layer of ethylene-propylene random copolymer or ethylene-butylene-propylene turbopolymer is coextruded with the core layer onto the surface of the copolyester layer and the reflective core layer. EP cocopolymers usually contain 1 to 7% by weight ethylene, the balance being propylene. This copolymer is 5.5 to 6.5% by weight.
Preferably, it contains ethylene. The melting point of the copolymer is lower and broader than that of polypropylene homopolymer.
その結晶融点は通常125ないし130℃である。23
0°Cのメルトインデンクスは通常、2ないし15、好
ましくは3ないし8である。分子量は25.000ない
し100.000で密度はは0.89ないし0.92で
ある。ランダムコポリマーは、ホモポリマーと比べて透
明性および剛性にすぐれ、融点が低いためにランダムコ
ポリマーはヒートシール層として使用することができる
。Its crystal melting point is usually 125 to 130°C. 23
The melt index at 0°C is usually between 2 and 15, preferably between 3 and 8. The molecular weight is 25,000 to 100,000 and the density is 0.89 to 0.92. Random copolymers have better transparency and rigidity than homopolymers, and have lower melting points, so random copolymers can be used as heat-sealing layers.
EPランダムコポリマー層は、押出前に、粘着防止剤を
配合しておくことが望ましい。この目的には、シリカ、
クレー、タルクおよびガラスのような物質を使用するこ
とができる。球形または低アスペクト比の粒子が好まれ
ることが多い。好適な粘着防止剤は3400ないし46
00pp−の量を添加したクレー(Kへ0POLITE
5F−0)である。かなりの数の粒子がEPランダム
コポリマー層の露出面外にも及ぶ部分を有するであろう
。It is desirable that an anti-blocking agent be added to the EP random copolymer layer before extrusion. For this purpose, silica,
Materials such as clay, talc and glass can be used. Spherical or low aspect ratio particles are often preferred. A suitable antiblocking agent is 3400 to 46
Clay (0POLITE to K) added in an amount of 00pp-
5F-0). A significant number of particles will have portions extending beyond the exposed surface of the EP random copolymer layer.
下記の実施例は本発明を具体的に説明するものである。The following examples illustrate the invention.
実施例
前記のコア層、コポリエステル層、およびEPランダム
コポリマー層を含む多層フィルムを同時押出して、流延
用ドラム上で110ないし135下で急冷させ、次いで
再加熱して配向させる。コポリエステル層は約170″
Fに再加熱するか、EPランダムコポリマー層は230
?に再加熱する。フィルムを、異なる速度で回転する運
搬ロールによって、縦方向に延伸させる。縦方向の延伸
は約4ないし8の延伸比で行う。縦方向の配向後、適切
に加熱したオーブンおよびテンター中で、フィルムを横
方向に延伸させる。延伸比は7:1ないし9:1である
。(好ましい範囲は5:1ないし10:1である)、。EXAMPLE A multilayer film comprising the core layer, copolyester layer, and EP random copolymer layer as described above is coextruded and quenched on a casting drum at between 110 and 135°C, then reheated and oriented. Copolyester layer is approximately 170″
Reheat to F or EP random copolymer layer to 230
? Reheat. The film is stretched in the machine direction by transport rolls rotating at different speeds. Stretching in the machine direction is carried out at a stretch ratio of about 4 to 8. After orientation in the machine direction, the film is stretched in the transverse direction in a suitably heated oven and tenter. The stretching ratio is between 7:1 and 9:1. (The preferred range is 5:1 to 10:1).
生成フィルム構造物は全体の厚さが約0.80ミルであ
る。コア層は約0.66ミル、コポリエステル層は約0
.10ミル、およびEPコポリマーシーラント層は約0
.04ミルである。コポリエステル層に公知の方法でコ
ロナ放電処理を行い、その後に金属化被覆を施す。(電
気めっき、スパッターおよび真空蒸着のような技術を用
いることができる)。コロナ放電処理によって、湿潤張
力は、無処理の場合の35−36ダイン/センチメート
ルに比べて約56ダイン/センチメートルを上回るもの
になる。処理は二輪延伸後にコポリエステル表面のみに
行う。The resulting film structure has a total thickness of about 0.80 mil. The core layer is approximately 0.66 mil and the copolyester layer is approximately 0.
.. 10 mil, and the EP copolymer sealant layer is approximately 0
.. It is 04 mil. The copolyester layer is subjected to a corona discharge treatment in a known manner and then a metallized coating is applied. (Techniques such as electroplating, sputtering and vacuum deposition can be used). Corona discharge treatment increases the wet tension to greater than about 56 dynes/cm compared to 35-36 dynes/cm without treatment. The treatment is carried out only on the surface of the copolyester after two-wheel stretching.
上記のようにして調製した試料は、両表面層が、230
下で約300グラム、7インチのシール強度を有するこ
とが判明した。金属の均一性は、15インチのフィルム
片の両端で光学的濃度が0.20単位未満のバラツキで
ある。コロナ処理した面の良好な金属付着も得られる。In the sample prepared as described above, both surface layers had a
It was found to have a seal strength of about 300 grams under 7 inches. The uniformity of the metal is less than 0.20 unit variation in optical density across a 15 inch piece of film. Good metal adhesion on corona-treated surfaces is also obtained.
金属化前には、透湿度(−VTR)は100下の温度お
よび90%相対湿度で約0.51 g /100in”
/dayである。Prior to metallization, the moisture vapor transmission rate (-VTR) is approximately 0.51 g/100 in at temperatures below 100 and 90% relative humidity.
/day.
この透湿度は金属化後に約0.05に減少する。酸素透
過率にも同様の減少が得られ、金属化基質は、無処理フ
ィルムの71cc/100in”/dayに比べて0.
39cc/100in”/dayの酸素透過率を示す。This moisture permeability decreases to approximately 0.05 after metallization. A similar reduction in oxygen permeability was obtained, with the metallized substrate achieving a 0.5 cc/100 in”/day compared to 71 cc/100 in”/day for the untreated film.
It shows an oxygen permeability of 39cc/100in''/day.
(外4名)(4 other people)
Claims (13)
層; (ii)コア層の一方の面に付着した同時押出コポリエ
ステル層;および (iii)コア層の反対側の面に付着した同時押出ヒー
トシール可能な層; からなる金属化可能な配向プラスチックフィルム。1. (i) a core layer consisting of isotactic polypropylene; (ii) a coextruded copolyester layer attached to one side of the core layer; and (iii) a coextruded heat sealable layer attached to the opposite side of the core layer. A metallizable oriented plastic film consisting of a layer;
ィルム。2. A film according to claim 1, wherein the core layer (i) comprises an adhesion promoter.
る請求項1または請求項2記載のフィルム。3. 3. The film according to claim 1 or 2, wherein the copolyester constituting layer (ii) is amorphous.
クロヘキシレン−ジメチレンテレフタレートからなる前
記請求項のいずれか1つの項に記載のフィルム。4. A film according to any one of the preceding claims, wherein the copolyester layer (ii) comprises 1-ethylene, 4-cyclohexylene-dimethylene terephthalate.
る前記請求項のいずれか1つの項に記載のフィルム。5. A film according to any one of the preceding claims, wherein the copolyester layer (ii) is subjected to a corona discharge treatment.
ポリマー被覆を含む前記請求項のいずれか1つの項に記
載のフィルム。6. A film according to any one of the preceding claims, comprising a vinylidene chloride copolymer coating on the copolyester layer (ii).
ロピレンランダムコポリマーからなる請求項1記載のフ
ィルム。7. The film of claim 1, wherein the coextrusion sealable layer (iii) comprises an ethylene-propylene random copolymer.
止剤を含む請求項1ないし請求項7記載のフィルム。8. 8. A film according to claims 1 to 7, wherein the coextruded heat sealable layer (iii) comprises an antiblocking agent.
フィルム。10. The film according to claim 1, which is stretched 4 to 8 times in the machine direction.
ずれか1つの項に記載のフィルム。11. A film according to any one of the preceding claims, which is stretched 7 to 9 times in the transverse direction.
金属被覆を有する前記請求項のいずれか1つの項に記載
のフィルムを含んでなる金属被覆の配向プラスチックフ
ィルム。12. (iv) on the coextruded copolyester layer (ii)
A metallized oriented plastic film comprising a film according to any one of the preceding claims having a metallization.
に付着させる場合のコポリエステル層(ii)の使用。13. Polypropylene core layer (i) with metal coating (iv)
Use of copolyester layer (ii) when deposited on.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6395090A JPH03266641A (en) | 1990-03-14 | 1990-03-14 | Film having metallizable surface |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6395090A JPH03266641A (en) | 1990-03-14 | 1990-03-14 | Film having metallizable surface |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03266641A true JPH03266641A (en) | 1991-11-27 |
Family
ID=13244125
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6395090A Pending JPH03266641A (en) | 1990-03-14 | 1990-03-14 | Film having metallizable surface |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03266641A (en) |
-
1990
- 1990-03-14 JP JP6395090A patent/JPH03266641A/en active Pending
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