JPH03266610A - Heating method for thermoplastic resin film - Google Patents

Heating method for thermoplastic resin film

Info

Publication number
JPH03266610A
JPH03266610A JP6639890A JP6639890A JPH03266610A JP H03266610 A JPH03266610 A JP H03266610A JP 6639890 A JP6639890 A JP 6639890A JP 6639890 A JP6639890 A JP 6639890A JP H03266610 A JPH03266610 A JP H03266610A
Authority
JP
Japan
Prior art keywords
rubber
roll
heating
film
thermoplastic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6639890A
Other languages
Japanese (ja)
Other versions
JP2782007B2 (en
Inventor
Takatoshi Miki
崇利 三木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Diafoil Co Ltd
Original Assignee
Diafoil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Diafoil Co Ltd filed Critical Diafoil Co Ltd
Priority to JP6639890A priority Critical patent/JP2782007B2/en
Publication of JPH03266610A publication Critical patent/JPH03266610A/en
Application granted granted Critical
Publication of JP2782007B2 publication Critical patent/JP2782007B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

PURPOSE:To heat a thermoplastic resin film without trouble of static electricity by applying rubber having specified volume resistivity on the surface of a metallic roll and utilizing this rubber roll as a heating roll. CONSTITUTION:A thermoplastic resin film unstretched or orientated at least in the uniaxial direction is heated at the temp. for stretching or heat treatment by utilizing a plurality of heating rolls. A rubber roll wherein rubber having <=10<7>OMEGA cm volume resistivity is applied on the surface of a metallic roll is utilized as the heating roll. As the rubber substance of the rubber roll, silicone, chloroprene, acryl, natural rubber, chlorosulfonated polyethylene, etc., can be utilized. Especially silicon-based and fluorine-based rubber are preferably utilized. When thickness of rubber coating in the rubber roll is made excessively thin, effect of a mandrel affects the surface and hardness of the surface of the rubber roll is made high. Therefore this thickness of rubber coating is preferably regulated to >= 0.5 mm. Further when hardness of rubber is low and the surface is made excessively soft, possibilities are caused wherein friction due to elastic deformation is generated when the rubber roll is brought into contact with the film. Accordingly hardness of rubber is preferably regulated to >= 50 degrees.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、熱可塑性樹脂フィルムの加熱方法に関するも
のであり、詳しくは、熱可塑性樹脂フィルムを延伸又は
熱処理温度まで加熱する際に問題となる、静電気障害を
解消した熱可塑性樹脂フィルムの加熱方法に関するもの
である。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for heating a thermoplastic resin film, and more specifically, it relates to a method for heating a thermoplastic resin film, and more specifically, it relates to a heating method for a thermoplastic resin film, and more specifically, it relates to a method for heating a thermoplastic resin film, and more specifically, it is a method for heating a thermoplastic resin film to a stretching or heat treatment temperature. , relates to a method of heating a thermoplastic resin film that eliminates static electricity interference.

〔従来の技術〕[Conventional technology]

一般的に、フィルムを延伸又は熱処理するに適した温度
まで予熱する方法には、複数個の加熱ロールが用いられ
る。そして、予熱されたフィルムは、延伸工程において
は、複数個のロール間の周速差によって延伸され、熱処
理工程においては、複数個のロール間のフィルムの張力
を制御する等して熱処理される。
Generally, a plurality of heating rolls are used in the method of preheating a film to a temperature suitable for stretching or heat treating. In the stretching process, the preheated film is stretched by a difference in circumferential speed between the plurality of rolls, and in the heat treatment process, it is heat-treated by controlling the tension of the film between the plurality of rolls.

従来より、上記の加熱ロールには、金属ロール、金属ロ
ール表面にセラミックや樹脂をコーティングしたロール
、同じく表面にゴムを被覆したロール(ゴムロール)等
が適宜使用されており、実際には、所望の予熱温度にお
いてフィルムとロールが粘着しないようなロール表面材
質が選定される。
Conventionally, metal rolls, rolls whose surfaces are coated with ceramic or resin, rolls whose surfaces are coated with rubber (rubber rolls), etc., have been used as appropriate for the above-mentioned heating rolls. The roll surface material is selected so that the film and roll do not stick together at the preheating temperature.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

ところが、ゴムロールの場合、−船釣に、熱可塑性樹脂
フィルム及びゴムの両者は、電気伝導度が悪いため、フ
ィルムとゴムロールの表面が接触することにより、双方
に静電気が帯電し、その結果、種々の静電気障害が生じ
る。
However, in the case of rubber rolls - for boat fishing, both the thermoplastic resin film and rubber have poor electrical conductivity, so when the surfaces of the film and rubber roll come into contact, both are charged with static electricity, and as a result, various Electrostatic damage will occur.

例えば、フィルム表面に帯電した場合は、フィルムの製
造工程内に存在するゴミやホコリがフィルム面上に付着
する。そして、磁気記録用ポリエステルフィルムにおい
ては、このホコリが付着したフィルムに磁気記録層がコ
ーティングされた場合、その部分が異常に高い突起を形
成し、信号の正常な記録及び再生が出来なくなるといっ
た重大な品質問題を引き起こす。更に、表面が非常に平
坦なフィルムを巻き上げる際には、ホコリの付着した部
分が盛り上がり、その盛り上がりが製品の上巻きにまで
及ぶ。その結果、盛り上がり部分がシワとなって永久歪
となるため、例えば、OHP用ポリエステルフィルムに
おいては、盛り上がり部分がスクリーン上に欠陥として
投影され、製品の品質を著しく損ねるという問題がある
For example, if the film surface is charged, dirt and dust present during the film manufacturing process will adhere to the film surface. In polyester film for magnetic recording, if the magnetic recording layer is coated on the film with this dust attached, abnormally high protrusions will be formed in those areas, causing serious problems such as the inability to properly record and reproduce signals. causing quality problems. Furthermore, when a film with a very flat surface is rolled up, the dust-covered area bulges out, and the bulge extends to the top of the product. As a result, the raised portions become wrinkled and permanently deformed, so that, for example, in OHP polyester films, the raised portions are projected as defects on the screen, which significantly impairs the quality of the product.

一方、ゴムロールに帯電した場合は、それがゴムの絶縁
破壊電圧を超える場合には、ゴムロールの表面にひび割
れが突然入ったりすることがある。そして、この場合、
延伸ロールのように表面にせん断力が作用している場合
には、金属ロールの表層に巻かれたゴムが割れてゴム片
が飛び散り、付近の機械の摺動部に巻き込まれ、機械が
破損したり、フィルムが破断してロールに巻き付く等と
いった問題がある。
On the other hand, if the rubber roll is charged and the electrical charge exceeds the dielectric breakdown voltage of the rubber, cracks may suddenly appear on the surface of the rubber roll. And in this case,
When shearing force is applied to the surface of a metal roll, such as on a stretching roll, the rubber wrapped around the surface layer of the metal roll will crack and pieces of rubber will fly off and get caught in the sliding parts of nearby machines, causing damage to the machine. There are also problems such as the film breaking and winding around the roll.

そこで、本発明は、ゴムロールにおける上記のような問
題に着目し、静電気障害のない熱可塑性樹脂フィルムの
加熱方法を提案するものである。
Therefore, the present invention focuses on the above-mentioned problems with rubber rolls and proposes a method for heating a thermoplastic resin film that is free from static electricity damage.

〔課題を解決するための手段〕[Means to solve the problem]

すなわち、本発明の要旨は、未延伸あるいは少なくとも
一軸方向に配向された熱可塑性樹脂フィルムを複数の加
熱ロールを用いて、延伸又は熱処理温度まで加熱する方
法において、前記加熱ロールとして、金属ロール表面に
体積抵抗率が107Ω−以下であるゴムを被覆してなる
ゴムロールを用いることを特徴とする熱可塑性樹脂フィ
ルムの加熱方法に存する。
That is, the gist of the present invention is to provide a method for heating an unstretched or at least uniaxially oriented thermoplastic resin film to a stretching or heat treatment temperature using a plurality of heating rolls. A method for heating a thermoplastic resin film, characterized by using a rubber roll coated with rubber having a volume resistivity of 10<7 >[Omega]- or less.

本発明で使用するゴムロールのゴム材質は、特に制限さ
れず、シリコン、クロロプレン、アクリル、エチレンプ
ロピレンタポリマー、フッ素、天然ゴム、タロロスルホ
ン化ポリエチレン等が使用し得るが、特に、シリコン系
、フッ素系ゴムを用いるのが好ましい。
The rubber material of the rubber roll used in the present invention is not particularly limited, and silicone, chloroprene, acrylic, ethylene propylene tapolymers, fluorine, natural rubber, talolosulfonated polyethylene, etc. can be used, but in particular, silicone-based and fluorine-based rubbers can be used. It is preferable to use

本発明で使用するゴムロールは、体積抵抗率が107Ω
■以下であることが必要であり、通常、上記のゴム材質
は、それ自体では上記体積抵抗率を満足せず、従って、
適宜、導電性を付与する必要がある。導電性を付与する
手段としては、特に限定されないが、ゴム材質中に導電
剤として導電性カーボン、金属成分等を練り込むのがよ
い。これらの添加物は、ゴム材質と性質を異にする物質
であるため、ロール表面より脱離する可能性がある。従
って、例えば磁気テープ用ポリエステルフィルムの製造
においては、仮に、フィルムに付着したとしても信号の
記録に実害を及ぼさないように、極力小さな粒径のもの
を使用するのが好ましい。
The rubber roll used in the present invention has a volume resistivity of 107Ω.
■It is necessary for the above-mentioned rubber material to satisfy the above-mentioned volume resistivity by itself, and therefore,
It is necessary to impart conductivity as appropriate. The means for imparting conductivity is not particularly limited, but it is preferable to knead conductive carbon, a metal component, etc. as a conductive agent into the rubber material. Since these additives are substances that have different properties from the rubber material, there is a possibility that they will come off from the roll surface. Therefore, for example, in the production of polyester films for magnetic tapes, it is preferable to use particles with as small a particle size as possible so that even if they adhere to the film, they will not cause any actual damage to signal recording.

本発明で使用するゴムロールのゴム被覆の厚みは、特に
限定されないが、余りにも薄い場合は、芯金の影響が表
面にまで及びゴムロール表面の硬度が高゛くなるので、
0,5關以上とするのが好ましい。また、ゴム硬度も、
特に限定されないが、硬度が低く表面が柔らか過ぎる場
合は、フィルムと接触する際の塑性変形による摩擦が発
生する恐れがあるので、50度以上にするのが好ましい
。更に、摩擦係数も、特に限定されないが、延伸部や熱
処理部においては、延伸力やフィルムの収縮力によって
フィルムがロール上で滑らないように設定する必要があ
り、従って、フィルムがロール表面に粘着することのな
いようなゴム材質が選定される。
The thickness of the rubber coating of the rubber roll used in the present invention is not particularly limited, but if it is too thin, the influence of the core metal will extend to the surface and the hardness of the rubber roll surface will become high.
It is preferable to set it to 0.5 degrees or more. In addition, the rubber hardness
Although not particularly limited, if the hardness is low and the surface is too soft, friction may occur due to plastic deformation when it comes into contact with the film, so it is preferably 50 degrees or more. Furthermore, the coefficient of friction is not particularly limited, but in the stretching section and heat treatment section, it must be set so that the film does not slip on the roll due to the stretching force or shrinkage force of the film, and therefore, the coefficient of friction must be set so that the film does not stick to the roll surface. A rubber material is selected that will not cause any damage.

そして、帯電現象は、条件によらず、フィルムとロール
が接することによって惹起されるものであるから、本発
明のゴムロールは、加熱ロールとして使用する場合のみ
ならず、加熱ロール自体が同時に延伸あるいは熱処理ロ
ールとして作用する場合にも有効に使用し得る。
Since the charging phenomenon is caused by the contact between the film and the roll regardless of the conditions, the rubber roll of the present invention is useful not only when used as a heating roll, but also when the heating roll itself is stretched or heat-treated at the same time. It can also be effectively used when acting as a roll.

本発明の加熱方法は、代表的には、ポリエステルフィル
ムの延伸又は熱処理の際に使用されるが、他の熱可塑性
フィルムにおける同様の加熱にも適用し得ることは勿論
のことである。また、フィルムは未延伸又は延伸フィル
ムであってもよい。
The heating method of the present invention is typically used during stretching or heat treatment of polyester films, but it goes without saying that it can also be applied to similar heating of other thermoplastic films. Further, the film may be an unstretched or stretched film.

〔実施例〕〔Example〕

以下、本発明を実施例により更に詳細に説明する。 Hereinafter, the present invention will be explained in more detail with reference to Examples.

なお、使用したゴムロールのゴム材質の体積抵抗率は次
の方法により測定した。
The volume resistivity of the rubber material of the rubber roll used was measured by the following method.

〈体積抵抗率の測定方法〉 縦100m、横100M、厚さ3mmのゴム試験片を用
い、第2図および第3図に示すように、試験片(10)
の片面に上部電極として主電極(20)及びガード電極
(30)を設け、他面に下部電極(40)を設ける。
<Method for measuring volume resistivity> Using a rubber test piece with a length of 100 m, a width of 100 m, and a thickness of 3 mm, as shown in Figures 2 and 3, test piece (10)
A main electrode (20) and a guard electrode (30) are provided as upper electrodes on one side, and a lower electrode (40) is provided on the other side.

電極はいずれも金属箔を用い、導電塗料(藤倉電線■製
ドータイト)にて中心を一致させて貼り合わせる。そし
て、主電極(20)の直径は50±0゜5InIn、ガ
ード電極(30)の内径は70土0.5mm、外径は8
0±0.5mm、下部電極(40)の直径は70±0.
5mmとする。
All electrodes are made of metal foil and pasted together with conductive paint (Dotite, manufactured by Fujikura Electric Wire ■) with their centers aligned. The diameter of the main electrode (20) is 50±0°5InIn, the inner diameter of the guard electrode (30) is 0.5mm, and the outer diameter is 8mm.
0±0.5mm, and the diameter of the lower electrode (40) is 70±0.
The length shall be 5 mm.

温度20℃、相対湿度65%の大気中において、主電極
および下部電極間に、500vの直流電圧を1分間印加
して充電した後、抵抗値を測定し、次式により、体積抵
抗率(ρ)を算出する。
After charging by applying a DC voltage of 500 V for 1 minute between the main electrode and the lower electrode in an atmosphere with a temperature of 20°C and a relative humidity of 65%, the resistance value was measured and the volume resistivity (ρ ) is calculated.

ρ=19.6  R/l(ΩCf[l)上記式中、Rは
抵抗測定値(Ω)、tは試験片の厚さ(mm )を表わ
す。
ρ=19.6 R/l (ΩCf[l) In the above formula, R represents the measured resistance value (Ω), and t represents the thickness (mm 2 ) of the test piece.

実施例 第1図に示すロール配置よりなるフィルムの延伸、熱処
理工程において、ポリエチレンテレフタレート未延伸フ
ィルム(シート)の延伸、熱処理を行った。
EXAMPLE In the film stretching and heat treatment process consisting of the roll arrangement shown in FIG. 1, an unstretched polyethylene terephthalate film (sheet) was stretched and heat treated.

第1図において、未延伸フィルム(A)は、加熱ロール
(1)〜(4)、延伸ロール(5) 、(5’ )、熱
処理ロール(6)、(6゛)及び冷却ロール(7)、(
7′)を通過して処理された。
In FIG. 1, the unstretched film (A) includes heating rolls (1) to (4), stretching rolls (5), (5'), heat treatment rolls (6), (6'), and cooling roll (7). ,(
7') and processed.

ロール(1)、(2)及び(7)、(7゛)には、硬質
クロムメツキ仕上げの金属ロールを使用し、他のロール
には、いずれも、導電性カーボンを配合して体積固有抵
抗率を1×105 (0口)としたタロロスルホン化ポ
リエチレンを金属ロール表面に3mn厚みで被覆したゴ
ムロールを使用した。
Rolls (1), (2), (7), and (7゛) are metal rolls with a hard chrome plating finish, and the other rolls are all mixed with conductive carbon to improve the volume resistivity. A rubber roll was used in which the surface of the metal roll was coated with talolosulfonated polyethylene of 1×10 5 (0 openings) to a thickness of 3 mm.

処理条件は、以下の通りとし、被処理フィルム及び各ロ
ールにニッカリコを吹き付け、付着状況の観察から帯電
の有無を評価した。
The processing conditions were as follows, Nikkariko was sprayed onto the film to be processed and each roll, and the presence or absence of charging was evaluated by observing the adhesion state.

ロール表面温度:1  2)   85°C34)  
100°C 55’)100°C 66’)   98°C 7,7’)20°C :3.5倍 :150kg :延伸前   800μm 延伸後   100μ■ 尚、比較のために、第1図に示す工程において、ゴムロ
ールとして、体積固有抵抗率が本発明の規定値外のゴム
ロールを一部に使用した以外は、上記実施例と同様の方
法により、ポリエチレンテレフタレート未延伸フィルム
の処理を行い、フィルム及び各ロールに対する帯電の有
無を評価した。
Roll surface temperature: 1 2) 85°C34)
100°C 55') 100°C 66') 98°C 7,7') 20°C: 3.5 times: 150 kg: 800 μm before stretching 100 μm after stretching In the process, an unstretched polyethylene terephthalate film was treated in the same manner as in the above example, except that some rubber rolls whose volume resistivity was outside the specified value of the present invention were used, and the film and each The presence or absence of electrical charge on the roll was evaluated.

評価結果をまとめて表−1に示した。The evaluation results are summarized in Table-1.

延伸倍率 弛緩張力 フィルム厚み 表−1の結果から明らかなように、体積抵抗率が本発明
の規定値を満足するゴムロールでは、ロール及びフィル
ムのいずれに対しても、静電気の帯電が認められない。
As is clear from the results of Stretching Ratio Relaxed Tension Film Thickness Table 1, in the rubber roll whose volume resistivity satisfies the specified value of the present invention, no electrostatic charging is observed in either the roll or the film.

〔発明の効果〕〔Effect of the invention〕

以上説明した本発明によれば、加熱ロールとして、特定
の体積抵抗率のゴムを被覆したゴムロールを使用すると
いう簡単な構成により、熱可塑性フィルムの加熱におい
て問題となる静電気障害を一挙に解決することができ、
従って、本発明の工業的価値は顕著である。
According to the present invention as described above, by using a simple configuration in which a rubber roll coated with rubber having a specific volume resistivity is used as the heating roll, it is possible to solve the static electricity problem that is a problem in heating thermoplastic films at once. is possible,
Therefore, the industrial value of the present invention is significant.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、フィルムの延伸、熱処理工程のロール配置の
説明図であり、(A)は未延伸フィルム、(1)〜(4
)は加熱ロール、(5)、(5°)は延伸ロール、(6
)、(6°)は熱処理ロール、(7)、(7°)は冷却
ロールである。 第2図および第3図は、ゴム材質の体積抵抗率の測定方
法を示す説明図であり、(10)はゴム試験片、(20
)は主電極、(30)はガイド電極、(40)は下部電
極である。
FIG. 1 is an explanatory diagram of the roll arrangement in the film stretching and heat treatment process, in which (A) is an unstretched film, (1) to (4)
) is a heating roll, (5), (5°) is a stretching roll, (6
) and (6°) are heat treatment rolls, and (7) and (7°) are cooling rolls. FIGS. 2 and 3 are explanatory diagrams showing a method for measuring the volume resistivity of rubber materials, where (10) is a rubber test piece, (20
) is the main electrode, (30) is the guide electrode, and (40) is the lower electrode.

Claims (1)

【特許請求の範囲】[Claims] (1)未延伸あるいは少なくとも一軸方向に配向された
熱可塑性樹脂フィルムを複数の加熱ロールを用いて、延
伸又は熱処理温度まで加熱する方法において、前記加熱
ロールとして、金属ロール表面に体積抵抗率が10^7
Ωcm以下であるゴムを被覆してなるゴムロールを用い
ることを特徴とする熱可塑性樹脂フィルムの加熱方法。
(1) In a method of heating an unstretched or at least uniaxially oriented thermoplastic resin film to a stretching or heat treatment temperature using a plurality of heating rolls, the heating roll may have a volume resistivity of 10 on the surface of a metal roll. ^7
A method for heating a thermoplastic resin film, characterized by using a rubber roll coated with rubber having a resistance of Ωcm or less.
JP6639890A 1990-03-16 1990-03-16 Heating method of thermoplastic resin film Expired - Fee Related JP2782007B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6639890A JP2782007B2 (en) 1990-03-16 1990-03-16 Heating method of thermoplastic resin film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6639890A JP2782007B2 (en) 1990-03-16 1990-03-16 Heating method of thermoplastic resin film

Publications (2)

Publication Number Publication Date
JPH03266610A true JPH03266610A (en) 1991-11-27
JP2782007B2 JP2782007B2 (en) 1998-07-30

Family

ID=13314666

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6639890A Expired - Fee Related JP2782007B2 (en) 1990-03-16 1990-03-16 Heating method of thermoplastic resin film

Country Status (1)

Country Link
JP (1) JP2782007B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017039291A (en) * 2015-08-21 2017-02-23 富士フイルム株式会社 Method for manufacturing optical film
KR20220167587A (en) * 2021-06-14 2022-12-21 프리미어 주식회사 Manufacturing method of Hard Coating Film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017039291A (en) * 2015-08-21 2017-02-23 富士フイルム株式会社 Method for manufacturing optical film
KR20220167587A (en) * 2021-06-14 2022-12-21 프리미어 주식회사 Manufacturing method of Hard Coating Film

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