JPH03253400A - Light-emitting pen - Google Patents
Light-emitting penInfo
- Publication number
- JPH03253400A JPH03253400A JP2051369A JP5136990A JPH03253400A JP H03253400 A JPH03253400 A JP H03253400A JP 2051369 A JP2051369 A JP 2051369A JP 5136990 A JP5136990 A JP 5136990A JP H03253400 A JPH03253400 A JP H03253400A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- light
- chemical
- delivery valve
- chip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 claims abstract description 48
- 239000000126 substance Substances 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 abstract description 7
- FRDAATYAJDYRNW-UHFFFAOYSA-N 3-methyl-3-pentanol Chemical compound CCC(C)(O)CC FRDAATYAJDYRNW-UHFFFAOYSA-N 0.000 abstract description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract description 4
- FCNCGHJSNVOIKE-UHFFFAOYSA-N 9,10-diphenylanthracene Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1 FCNCGHJSNVOIKE-UHFFFAOYSA-N 0.000 abstract description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- GEVPIWPYWJZSPR-UHFFFAOYSA-N tcpo Chemical compound ClC1=CC(Cl)=CC(Cl)=C1OC(=O)C(=O)OC1=C(Cl)C=C(Cl)C=C1Cl GEVPIWPYWJZSPR-UHFFFAOYSA-N 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 6
- 239000000976 ink Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VOKMITCYEOGVHS-UHFFFAOYSA-N 2-oxo-2-(2,4,6-trichlorophenoxy)acetic acid Chemical compound OC(=O)C(=O)OC1=C(Cl)C=C(Cl)C=C1Cl VOKMITCYEOGVHS-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- -1 tetrabutylammonium salicylate-hydrogen peroxide Chemical compound 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
- F21K2/06—Non-electric light sources using luminescence; Light sources using electrochemiluminescence using chemiluminescence
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K5/00—Pens with ink reservoirs in holders, e.g. fountain-pens
- B43K5/02—Ink reservoirs
- B43K5/14—Exchangeable ink cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K5/00—Pens with ink reservoirs in holders, e.g. fountain-pens
- B43K5/18—Arrangements for feeding the ink to the nibs
- B43K5/1818—Mechanical feeding means, e.g. valves; Pumps
- B43K5/1827—Valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K8/00—Pens with writing-points other than nibs or balls
- B43K8/02—Pens with writing-points other than nibs or balls with writing-points comprising fibres, felt, or similar porous or capillary material
- B43K8/03—Ink reservoirs; Ink cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K8/00—Pens with writing-points other than nibs or balls
- B43K8/02—Pens with writing-points other than nibs or balls with writing-points comprising fibres, felt, or similar porous or capillary material
- B43K8/04—Arrangements for feeding ink to writing-points
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は１発光ペンに関する。更に詳しくは、自己発光
し、暗所でも視認できる発光ペンに関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a one-luminescent pen. More specifically, the present invention relates to a light-emitting pen that emits light by itself and is visible even in the dark.
〔従来の技術〕および〔発明が解決しようとする課題〕
油性または水性のインクを用いたマーキングペン（フェ
ルトペン）としては、湿潤式および液体式のものがそれ
ぞれ広く用いられている。[Prior art] and [Problem to be solved by the invention]
As marking pens (felt pens) using oil-based or water-based inks, wet-type and liquid-type marking pens are widely used.
湿潤式のマーキングペンは、プラスチック、ガラス、金
属製などの容器内に、速乾性の油性インクまたは染料を
水に溶かし込んだインクを含ませた中綿（フェルト、綿
など）を入れ、チップ（繊維またはプラスチック製のペ
ン先）を取付けたものである。Wet-type marking pens are made by placing a filling (felt, cotton, etc.) impregnated with quick-drying oil-based ink or dye dissolved in water into a container made of plastic, glass, or metal. or a plastic nib).
また、液体式のマーキングペンは、容器内にインクを直
接入れ、チップを押すとチップとインクとの間に設けら
れた弁が開き、インクがチップに流れ出る仕組みとなっ
ている。Liquid marking pens have a mechanism in which ink is poured directly into the container, and when the tip is pressed, a valve installed between the tip and the ink opens, allowing the ink to flow into the tip.
これらの各種のマーキングペンにおいて、筆記されたも
のが暗所でも視認できるペンとしては。Among these various marking pens, this pen allows what is written to be seen even in the dark.
蛍光剤を利用した蛍光ペンが実用化されている。Highlighter pens using fluorescent agents have been put into practical use.
しかしながら、これは外部からの光が入射して初めて発
光を生ずるものであり、光が全く存在しない暗所ではそ
の効力を発揮しない。However, this method only emits light when light from the outside is incident on it, and does not exhibit its effectiveness in a dark place where there is no light at all.
本発明の目的は、自己発光し、光が全く存在しない暗所
でも筆記されたものが視認できる発光ペンを液体式マー
キングペンとして提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a liquid marking pen that is self-luminous and allows writing to be seen even in a dark place where there is no light.
かかる本発明の目的は、チップを取付けた液体式マーキ
ングペンの容器内に、第１の液状薬品およびこれと反応
して発光する第２の液状薬品をそれぞれ充填したカート
リッジが収容され、これらのカートリッジとチップとの
間には液送出弁が設けられており、チップを押すことに
より開かれた液送出弁から第１および第２の液状薬品が
流れ出て互いに反応し、チップに化学発光体を湿潤せし
める発光ペンによって達成される。An object of the present invention is to store cartridges each filled with a first liquid chemical and a second liquid chemical that reacts with the first liquid chemical and emit light in a container of a liquid marking pen equipped with a chip. A liquid delivery valve is provided between the chip and the chip, and the first and second liquid chemicals flow out from the liquid delivery valve opened by pushing the chip, react with each other, and wet the chip with chemiluminescent material. This is achieved by a luminescent pen.
図面の第１図は、本発明に係る発光ペンの基本的な態様
を中心線縦断面図として示したものである。即ち、繊維
あるいは樹脂多孔質体などからなるペン先であるチップ
ｌを取付けた液体式マーキングペンの容器２内には、２
個のカートリッジ３゜４が収容されており、これらのカ
ートリッジにはそれぞれ第１の液状薬品５および第２の
液状薬品６が充填されている。これらのカートリッジ５
，６とチップ１との間には、第１および第２の液状薬品
を同時に送り出す液送出弁７が設けられており、チップ
１を押すことによりこの弁７が開き、それぞれのカート
リッジから流れ出た第１および第２の液状薬品が互いに
反応し、化学発光体（未反応の液状薬品混合物を含む）
を形成させてチップ１を湿潤させ、筆記を可能とさせる
。FIG. 1 of the drawings shows a basic aspect of the luminescent pen according to the present invention as a longitudinal cross-sectional view along the center line. That is, in the container 2 of the liquid marking pen to which the tip l, which is a pen tip made of fiber or resin porous material, is attached, there are 2 pens.
A plurality of cartridges 3 and 4 are housed therein, each of which is filled with a first liquid medicine 5 and a second liquid medicine 6. These cartridges 5
, 6 and the chip 1 is provided with a liquid delivery valve 7 that simultaneously sends out the first and second liquid chemicals, and when the chip 1 is pushed, this valve 7 opens and the liquids flow out from the respective cartridges. the first and second liquid chemicals react with each other, and the chemiluminescent material (including the unreacted liquid drug mixture)
is formed to moisten the tip 1 and enable writing.
カートリッジ内には、予め圧縮ガスを微量充填しておく
ことも、各液状薬品の円滑なる流れ出しを助け、またカ
ートリッジを交換式とすることも実用上からは好ましい
。交換式の一態様は第２図に示されており、交換式カー
トリッジ１１．１２を収容するために容器を上下２つに
分けてネジ込み式とし、液送出弁１３の上部にはカッタ
１４．１５が設置されており、液状薬品を充填したカー
トリッジの底部にカッタを突きさすことにより交換式カ
ートリッジの交換が行われ、また液送出弁１３と連設さ
れたピン１６．１７によって各液状薬品の流れ出しを可
能とさせている。It is preferable from a practical point of view that the cartridge be filled with a small amount of compressed gas in advance to help the liquid chemicals flow out smoothly, and that the cartridge be replaceable. One embodiment of the replaceable type is shown in FIG. 2, in which the container is divided into upper and lower halves to accommodate the replaceable cartridges 11, 12, and is a screw-in type, with a cutter 14. 15 is installed, and the replaceable cartridge is replaced by inserting a cutter into the bottom of the cartridge filled with liquid chemicals, and pins 16 and 17 connected to the liquid delivery valve 13 are used to release each liquid medicine. It allows for outflow.
第１の液状薬品と第２の液状薬品とは、互いに反応して
発光する化学発光体を形成し得るものであり、例えば第
１の液状薬品として２，４．６− トリクロロフェニル
オキザレートおよび９，１０−ジフェニルアントラセン
の混合物のジブチルフタレート溶液が用いられた場合に
は、これに対応して第２の液状薬品としてサリチル酸テ
トラブチルアンモニウム−過酸化水素水混合物の３−メ
チル−３−ペンタノール溶液が用いられる。また、圧縮
ガスが用いられる場合には、ＬＰＧなどが一般に用いら
れる。The first liquid chemical and the second liquid chemical can react with each other to form a chemiluminescent substance that emits light. For example, the first liquid chemical may include 2,4.6-trichlorophenyl oxalate and If a dibutyl phthalate solution of a mixture of 9,10-diphenylanthracene is used, correspondingly 3-methyl-3-pentanol of a tetrabutylammonium salicylate-hydrogen peroxide mixture is used as the second liquid chemical. A solution is used. Furthermore, when compressed gas is used, LPG or the like is generally used.
本発明に係る発光ペンは、第１の液状薬品と第２の液状
薬品とが反応して形成される。自己発光する化学発光体
または液状薬品混合物をチップに湿潤せしめるようにし
ており、これを用いて筆記したものは暗所でしかも全く
光が存在しなくとも視認することができる。The luminous pen according to the present invention is formed by a reaction between a first liquid medicine and a second liquid medicine. The chip is wetted with a self-luminous chemiluminescent material or a liquid chemical mixture, which allows writing to be seen in the dark or even in the absence of any light.
更に、化学発光体を形成する２種類の液状薬品が、それ
ぞれのカートリッジ内に充填されて保存されており、筆
記時に初めて混合反応させるため、長期の保存および必
要な場合での使用を可能としている。また、使用に際し
ても、このペンで筆記されたものは、２種類の薬品の間
の反応が終わる迄自己発光するため、少なくとも数時間
以上視認状態が維持される。Furthermore, the two types of liquid chemicals that form the chemiluminescent material are stored in each cartridge, and the mixture reacts only when writing, allowing for long-term storage and use when necessary. . In addition, even when in use, anything written with this pen emits light by itself until the reaction between the two types of chemicals is completed, so it remains visible for at least several hours.
第１図は、本発明に係る発光ペンの基本的な態様の中心
線縦断面図である。また、第２図は、交換式カートリッ
ジを用いた発光ペンの要部縦断面図である。
（符号の説明）
１・・・・・・・チップ
２・・・・・・・容器
３．４・・・・カートリッジ
５・・・・・・・第１の液状薬品
６・・・・・・・第２の液状薬品
７．１３・・・・液送出弁
１１．１２・・・・交換式カートリッジ弔
璽
図
第２図FIG. 1 is a longitudinal cross-sectional view along the center line of a basic embodiment of a light-emitting pen according to the present invention. Moreover, FIG. 2 is a longitudinal cross-sectional view of a main part of a light-emitting pen using a replaceable cartridge. (Explanation of symbols) 1... Chip 2... Container 3.4... Cartridge 5... First liquid chemical 6... ...Second liquid chemical 7.13...Liquid delivery valve 11.12...Replaceable cartridge Funeral Seal Figure 2
Claims (1)
、第１の液状薬品およびこれと反応して発光する第２の
液状薬品をそれぞれ充填したカートリッジが収容され、
これらのカートリッジとチップとの間には液送出弁が設
けられており、チップを押すことにより開かれた液送出
弁から第１および第２の液状薬品が流れ出て互いに反応
し、チップに化学発光体を湿潤せしめる発光ペン。 ２、各カートリッジが交換式である請求項１記載の発光
ペン。[Claims] 1. A cartridge filled with a first liquid chemical and a second liquid chemical that reacts with the liquid and emits light is housed in a container of a liquid marking pen equipped with a chip,
A liquid delivery valve is provided between these cartridges and the chip, and the first and second liquid chemicals flow out from the liquid delivery valve opened by pushing the chip, react with each other, and cause the chip to emit chemiluminescence. A luminescent pen that moisturizes your body. 2. The light-emitting pen according to claim 1, wherein each cartridge is replaceable.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2051369A JPH03253400A (en) | 1990-03-02 | 1990-03-02 | Light-emitting pen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2051369A JPH03253400A (en) | 1990-03-02 | 1990-03-02 | Light-emitting pen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03253400A true JPH03253400A (en) | 1991-11-12 |
Family
ID=12885029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2051369A Pending JPH03253400A (en) | 1990-03-02 | 1990-03-02 | Light-emitting pen |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03253400A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020046252A (en) * | 2002-04-27 | 2002-06-20 | 김명원 | a multi-tank style of a ball pen core |
| WO2005087510A1 (en) * | 2004-03-18 | 2005-09-22 | Liang Wang | Writing instruments |
| WO2007052848A1 (en) * | 2005-11-07 | 2007-05-10 | Lumica Co., Ltd. | Light emitting writing instrument and light emitting indicator employing it |
| GB2457154A (en) * | 2008-02-11 | 2009-08-12 | Crayola Llc | Chemiluminescent marking system |
| EP2349912A4 (en) * | 2008-10-14 | 2012-07-25 | Inc Photonix | Chemiluminescent aerosol spray |
| JP2014501921A (en) * | 2010-12-17 | 2014-01-23 | サイリューム・テクノロジーズ・インコーポレイテッド | Viscous chemiluminescent components and distribution means |
| US9303820B2 (en) | 2008-10-14 | 2016-04-05 | Harris Richard Miller | Chemiluminescent aerosol spray |
-
1990
- 1990-03-02 JP JP2051369A patent/JPH03253400A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020046252A (en) * | 2002-04-27 | 2002-06-20 | 김명원 | a multi-tank style of a ball pen core |
| WO2005087510A1 (en) * | 2004-03-18 | 2005-09-22 | Liang Wang | Writing instruments |
| WO2007052848A1 (en) * | 2005-11-07 | 2007-05-10 | Lumica Co., Ltd. | Light emitting writing instrument and light emitting indicator employing it |
| JP4888813B2 (en) * | 2005-11-07 | 2012-02-29 | 株式会社ルミカ | Luminescent writing instrument and luminescent display instrument using luminous writing instrument |
| GB2457154A (en) * | 2008-02-11 | 2009-08-12 | Crayola Llc | Chemiluminescent marking system |
| EP2349912A4 (en) * | 2008-10-14 | 2012-07-25 | Inc Photonix | Chemiluminescent aerosol spray |
| US9303820B2 (en) | 2008-10-14 | 2016-04-05 | Harris Richard Miller | Chemiluminescent aerosol spray |
| JP2014501921A (en) * | 2010-12-17 | 2014-01-23 | サイリューム・テクノロジーズ・インコーポレイテッド | Viscous chemiluminescent components and distribution means |
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