JPH03234872A - Preparation of anti-stain fiber - Google Patents
Preparation of anti-stain fiberInfo
- Publication number
- JPH03234872A JPH03234872A JP2028827A JP2882790A JPH03234872A JP H03234872 A JPH03234872 A JP H03234872A JP 2028827 A JP2028827 A JP 2028827A JP 2882790 A JP2882790 A JP 2882790A JP H03234872 A JPH03234872 A JP H03234872A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- polyester
- stain
- oil
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 28
- 229920000728 polyester Polymers 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 238000011282 treatment Methods 0.000 claims abstract description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 14
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 239000011737 fluorine Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 238000000034 method Methods 0.000 abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 9
- 239000004744 fabric Substances 0.000 abstract description 9
- 238000001035 drying Methods 0.000 abstract description 8
- 238000005406 washing Methods 0.000 abstract description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 229920001515 polyalkylene glycol Polymers 0.000 abstract description 2
- -1 fluoro compound Chemical class 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野 〕 本発明は防汚性繊維の製造方法に関するものである。[Detailed description of the invention] [Industrial application field] The present invention relates to a method for producing stain-resistant fibers.
カーペラ１〜、テーブルクロス、スポーツ着なと繊維製
品を液体汚れや乾燥汚れから守るには、含フッ素化合物
で表面処理する方法が最も有効であることは知られてい
る。It is known that surface treatment with a fluorine-containing compound is the most effective way to protect fiber products such as carpellers, tablecloths, and sportswear from liquid stains and dry stains.
しかし、通常繊維製品の抗水、抗油付与剤として用いら
れるフッ素化合物て処理されたものは、−度汚れがけ着
すると除去することは殆ど不可能であった。However, when treated with a fluorine compound, which is normally used as a water and oil resistant agent for textile products, it was almost impossible to remove stains once they were deposited on them.
最近では、４発水、机油性と共に汚れ除去性を兼ね備え
たフッ素系化合物も上布されているが、効果の耐洗濯性
が不充分であるなど問題点が多い。Recently, fluorine-based compounds that have both water repellency, machine oil resistance, and stain removal properties have been used on fabrics, but there are many problems such as insufficient washing resistance.
本発明者らは、これらの実情に鑑み、撓水、抗油性と共
に汚れ除去性を耐久性良く繊維製品に付与することを目
的に鋭意検討を重ねた結果、特定のポリエステル共重合
体と含フッ素化合物の組み合わせによって目的の効果が
得られることが判明した。In view of these circumstances, the inventors of the present invention have conducted intensive studies with the aim of imparting water repellency, oil resistance, and stain removal properties to textile products with good durability. It has been found that the desired effect can be achieved by combining compounds.
本発明防汚性繊維の製造方法は、ポリエステル共重合体
を繊維に固着させた後、含フッ素化合物の固着処理を行
うことを特徴とするものである。The method for producing stain-resistant fibers of the present invention is characterized in that after a polyester copolymer is fixed to fibers, a fluorine-containing compound is fixed thereon.
本発明においてポリエステル共重合体とは、ジカルボン
酸成分とグリコール成分とからなるポリエステルセグメ
ントにポリアルキレングリコールを共重合せしめてなる
ポリエステル共重合体である。In the present invention, the polyester copolymer is a polyester copolymer obtained by copolymerizing polyalkylene glycol with a polyester segment consisting of a dicarboxylic acid component and a glycol component.
ジカルボン酸成分としては、テレフタル酸及びイソフタ
ル酸又はそれらのエステル形成性誘導体てあり、グリコ
ール成分としては、エチレングリコール又は１４−ブタ
ンジオールである。The dicarboxylic acid component is terephthalic acid and isophthalic acid or ester-forming derivatives thereof, and the glycol component is ethylene glycol or 14-butanediol.
これらからなるポリエステルセグメントに分子量が８０
０〜３，０００のポリエチレングリコールを共重合して
なるポリエステルエーテル共重合体が代表的なものであ
る。特にこれらの生成ポリマーの分子量か２０，０００
以上であるものが好ましい。The polyester segment consisting of these has a molecular weight of 80
A typical example is a polyester ether copolymer obtained by copolymerizing 0 to 3,000 polyethylene glycols. In particular, the molecular weight of these produced polymers is 20,000.
The above is preferable.
本発明において含フッ素化合物とは、通常繊維製品の抗
水、抗油付与剤として用いられるフッ素系化合物を意味
するが、下記一般式で表される重合性化音物からの重合
体が好適である。In the present invention, the fluorine-containing compound refers to a fluorine-containing compound that is normally used as a water- and oil-resistant imparting agent for textile products, but a polymer made from a polymerizable compound represented by the following general formula is preferred. be.
ＣＨ２＝ Ｃｌ（○○（２Ｒ＋
（５ＣＨ２＝ ＣＩ（ＣＨ２００ＣＲ＋
（６ＣＨ２−ＣＩ４ ＯＲ４（７
ＣＨ２＝ ＣＨＣＨ２ＯＲ＋ （
８ＣＨ２＝ Ｃｉ（ＣＯＲす
（９ＣＨ□−ＣＨＣＨ２ＣＯＲ，（１，０
）（ここて、Ｒ１は水素又は、メチル基を、Ｒ２は炭素
原子数１〜１０のアルキレン基、シクロアルキレン基、
アリレーン基又はアラルキレン基を、Ｒ３は水素原子又
は炭素数１〜１０の炭化水素基を、Ｒ４は炭素原子１〜
１７の炭化水素基を、Ｒ３はその炭素原子上の水素原子
の一部又は全部をフッ素原子で置換した炭素原子数５〜
３０のフルオロアルキル基を示す。CH2= Cl(○○(2R+
(5CH2= CI(CH200CR+
(6CH2-CI4 OR4(7 CH2= CHCH2OR+ (
8CH2= Ci(COR)
(9CH□-CHCH2COR, (1,0
) (Here, R1 is hydrogen or a methyl group, R2 is an alkylene group having 1 to 10 carbon atoms, a cycloalkylene group,
arylene group or aralkylene group, R3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, and R4 is 1 to 1 carbon atoms.
17 hydrocarbon group, R3 has 5 to 5 carbon atoms, with some or all of the hydrogen atoms on the carbon atoms substituted with fluorine atoms.
30 fluoroalkyl groups are shown.
又、Ｒ２−Ｒ４の炭素原子上の水素原子は一部又は全部
がフッ素原子又は塩素原子で置換されていてもよい。）
又、これらの重合体は繊維上に形成される皮膜の抗水性
、抗油性、柔軟性、耐久性なとのバラン４
スをとるため、又汚れ除去性をイ」す、するために他の
成分を添加共重合したものてあってもよい。Furthermore, some or all of the hydrogen atoms on the carbon atoms of R2 to R4 may be substituted with fluorine atoms or chlorine atoms. ) These polymers are also used to balance the water resistance, oil resistance, flexibility, and durability of the film formed on the fibers, and to improve stain removability. It is also possible to add and copolymerize the following components.
本発明におけるポリエステル共重合体の繊維への固着方
法としては特に限定されるものてはなく、ポリエステル
共重合体の乳化分散溶液を作成し、任意に希釈したちの
ての液中処理、パラドル乾燥処理、スプレー−乾燥処理
等任意てよい。又乾燥後、１５０８Ｃ以上ての熱処理す
ることが好ましい
本発明における含フッ素化合物の繊維への固着方法もポ
リエステル共重合体の固着方法と同様、特に限定される
ものてはない。The method of fixing the polyester copolymer to the fibers in the present invention is not particularly limited, and may include preparing an emulsified dispersion solution of the polyester copolymer, diluting it as desired, and then immediately processing it in a liquid or drying it in a parasol. Any treatment such as spray-drying treatment may be used. Further, the method of fixing the fluorine-containing compound to the fibers in the present invention, which is preferably heat-treated at 1508 C or higher after drying, is also not particularly limited, similar to the method of fixing the polyester copolymer.
本発明の対象となる繊維は、特に限定されるものではな
いか、ポリエステルのような合成繊維の単独又は混用繊
維、複合繊維、これらからなる糸状、綿状、編織物、不
織布、縫製品などに対して効果かある。。The fibers to which the present invention is applied are not particularly limited, and may include synthetic fibers such as polyester alone or mixed fibers, composite fibers, thread-like, cotton-like, knitted fabrics, non-woven fabrics, sewn products, etc. It has some effect on it. .
本発明は、ポリエステル共重合体を液中処理、パット〜
乾燥処理等の方法で繊維に固着した後に含フッ素化合物
を同様の方法で固着することによって良好な抗水、抗油
と汚れ除去性を兼ね備えた防汚性繊維を得ることがてき
る。The present invention involves processing polyester copolymers in liquid, putting
By fixing the fluorine-containing compound to the fibers by a method such as drying, and then fixing the fluorine-containing compound by a similar method, it is possible to obtain stain-resistant fibers that have good water resistance, oil resistance, and stain removability.
これは２段階処理することにより、前処理されたポリエ
ステル共重合体が持つ汚れ除去性と、後処理された含フ
ッ素化合物が持つ抗水、撓油性の両性能が低下すること
なく付与されるためである。This is because the two-step treatment provides both the stain removal properties of the pre-treated polyester copolymer and the water and oil repellency properties of the post-treated fluorine-containing compound without deteriorating. It is.
又、ポリエステル共重合体を前処理することにより、ポ
リエステル繊維等の疎水性繊維に吸水性が付与され、後
に処理される含フッ素化合物が繊維の細部にまで浸透し
やすくなり、含フッ素化合物か繊維内部にまで均一に付
着する手助けをすると考えられる。この効果により性能
の耐洗濯性が向上する。In addition, by pre-treating the polyester copolymer, water absorbency is imparted to hydrophobic fibers such as polyester fibers, and the fluorine-containing compound treated later can easily penetrate into the fine details of the fibers. It is thought that this helps the particles adhere evenly to the inside. This effect improves the washing resistance performance.
本発明は、ポリエステル共重合体と含フッ素化合物を２
段階処理することにより、耐洗濯性のある抗水性、溌油
性及び汚れ除去性を兼ね備えた防汚性繊維を得ることが
できる。The present invention combines a polyester copolymer and a fluorine-containing compound into two
By carrying out the stepwise treatment, it is possible to obtain stain-resistant fibers that have washing resistance, water resistance, oil repellency, and stain removability.
実施例］
ポリエステル１００％加工糸織物を表−１に示すような
処理剤の組み合わせて処理し、試験布を得な。試験布の
性能評価結果については表−２に示す。Example] A 100% polyester textured yarn fabric was treated with a combination of treatment agents as shown in Table 1 to obtain a test cloth. The performance evaluation results of the test fabrics are shown in Table-2.
表−１
前処理及び後処理の加工条件は、いずれもパラドルマン
グル脱水（絞り率７０ ％ Ｂ＆、１００°Ｃて３分間
乾燥し、］８０°Ｃて１分間の熱処理を行った。Table 1 The processing conditions for pre-treatment and post-treatment were Parador Mangle dehydration (squeezing ratio 70% B&, drying at 100°C for 3 minutes, followed by heat treatment at 80°C for 1 minute).
、ト１ ポリエステル共重合体の水分散物（高松油脂（
株）製）
＊２ポリエステル共重合体の水分散物（高松油脂（株〉
製）
＊３無機塩系触媒（高松油脂（株）製）＊４ フッ素系
抗水抗油剤（高松油脂（株）製）１・５ フッ素系抗
水抗油ＳＲ剤（高松油脂（株）製）実施例２
ポリエステル１００％加工糸織物に対して、下記の条件
にて前処理を行った後、Ｔ Ｋガード５０５の１０％水
溶液てパッドし、マングル脱水（絞り率７０％）後、１
．ＯＯ’Ｃて３分間の乾燥を行い、その後１．８００Ｃ
て１分間の熱処理を行って試験布を得た。, T1 Aqueous dispersion of polyester copolymer (Takamatsu Oil (
*2 Aqueous dispersion of polyester copolymer (manufactured by Takamatsu Yushi Co., Ltd.)
*3 Inorganic salt catalyst (manufactured by Takamatsu Yushi Co., Ltd.) *4 Fluorine-based water/oil resistant agent (manufactured by Takamatsu Yushi Co., Ltd.) 1, 5 Fluorine-based water/oil resistant SR agent (manufactured by Takamatsu Yushi Co., Ltd.) ) Example 2 A 100% polyester textured yarn fabric was pretreated under the following conditions, padded with a 10% aqueous solution of T K Guard 505, and after mangle dehydration (squeezing ratio 70%),
．． Dry at OO'C for 3 minutes, then at 1.800C.
A test cloth was obtained by heat treatment for 1 minute.
試験布の性能評価結果については表−２に示す。The performance evaluation results of the test fabrics are shown in Table-2.
又前処理のみのものを比較品とした。In addition, a product with only pretreatment was used as a comparative product.
（前処理条件）
Ｄ １ａｎｉｘ Ｂ ｌｕｅ Ｋ Ｂ−Ｆ Ｓ
２％ｏｕ＋ｆニューレベリン ＲＤ−１，Ｏ＊５ ０．
５ｇ／ｆｆ酢酸（９０％） ０．５ｃ
ｃ／β５Ｒ−１０００５％ｏＩＩＩｆ
浴比 １２０
１３０°Ｃて２０分間染色処理を行っｆＳ後、ハイドロ
１ｇ／ｌ、ソータ灰２ｇ／り、浴比１．２０て還元洗
浄を行い、水洗、脱水（絞り率７０％）し、１００°Ｃ
で３分間の乾燥後、１８０°Ｃで１分間の熱処理を行っ
た。(Pre-treatment conditions) D 1anix Blue K B-F S
2%ou+f Neurevelin RD-1,O*5 0.
5g/ff Acetic acid (90%) 0.5c
c/β5R-10005%oIIIf Bath ratio 120 After dyeing at 130°C for 20 minutes, reduction cleaning was performed using hydro 1g/l, sorter ash 2g/litre, bath ratio 1.20, washing with water, dehydration (squeezing) 70%) and 100°C
After drying for 3 minutes at , heat treatment was performed at 180°C for 1 minute.
＊５ ポリエステル用分散均染剤（高松油脂（株）製）
実施例３
ポリエステル１００％綿（５ｄｘ ５０ ｍｍ）を５Ｒ
−１０００の５り／β（浴比 １１０）の溶液に１３０
°Ｃて２０分浸漬後、水洗、遠心脱水（絞り率３０％〉
し、１００°Ｃて５分間の乾燥処理を行った。その後、
ＴＫガード ５０５の１００ｇ／ｌの溶液に常温て］０
分間の浸漬処理を行い、遠心脱水（絞り率３０％）し、
１００°Ｃて５分間の乾燥後、１８０°Ｃで１分間の熱
処理を行って試験綿を得た。*5 Dispersion leveling agent for polyester (manufactured by Takamatsu Yushi Co., Ltd.)
Example 3 5R polyester 100% cotton (5dx 50mm)
-130 in a solution of 5/β (bath ratio 110) of 1000
After soaking at °C for 20 minutes, washing with water and centrifugal dehydration (squeezing ratio 30%)
Then, a drying process was performed at 100°C for 5 minutes. after that,
Add 100g/l solution of TK Guard 505 at room temperature]0
After soaking for 1 minute, centrifugal dehydration (squeezing ratio 30%),
After drying at 100°C for 5 minutes, a heat treatment was performed at 180°C for 1 minute to obtain test cotton.
試験綿の性能評価結果に−）いては表−２に示ず。The performance evaluation results of the test cotton are not shown in Table 2.
又前処理のみのものを比較品とした。In addition, a product with only pretreatment was used as a comparative product.
表−２
性能評価方法
抗水性 実施例（１）（２）については、ＪＩＳＴ、、
−１０７９、Ａ法（スプレー法）実施例（３）について
は、綿２ｇを丸めて常温水に落下し、水面下に沈むまて
の時間（秒）を測定
抗油性 ３Ｍ社法
実施例（３）については、綿を平らにならした状態で測
定
汚れ除去性・ダーティオイル（エンジン廃油）の一定量
（ピペッＩ・で２滴）を付着し、室温で一夜放置後、家
庭洗濯し、その脱
落度合を９段階て測定
１・はとんど落ちてない。Table-2 Performance evaluation method Water resistance For Examples (1) and (2), JIST,
-1079, A method (spray method) Example (3): 2g of cotton is rolled up and dropped into room temperature water, and the time (seconds) it takes for it to sink below the water surface is measured.Oil-resistant 3M company method Example (3) ), measure stain removability by applying a certain amount (2 drops with a pipette I) of dirty oil (waste engine oil) to a flat piece of cotton, leaving it at room temperature overnight, then washing it at home to see if it comes off. Measured in 9 levels, 1. has not dropped at all.
１〜２・・１〜２割程度落ちている。1-2... It has fallen by about 1-20%.
２・３割程度落ちている。It has fallen by about 2.3%.
２〜３・・・４割程度落ちている。It has fallen by about 2-3...40%.
３・ ５割程度落ちている。3. It has fallen by about 50%.
３〜４・・・６割程度落ちている。3-4... It's down about 60%.
４・７割程度落ちている。It has fallen by about 4.7%.
４〜５・・・８〜９割程度落ちている。4-5... It's down about 8-90%.
５・・完全に落ちている。5. Completely fallen.
Claims (1)
化合物の固着処理を行うことを特徴とする防汚性繊維の
製造方法。A method for producing stain-resistant fibers, which comprises fixing a polyester copolymer to fibers and then subjecting the fibers to fixation treatment with a fluorine-containing compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2028827A JPH03234872A (en) | 1990-02-08 | 1990-02-08 | Preparation of anti-stain fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2028827A JPH03234872A (en) | 1990-02-08 | 1990-02-08 | Preparation of anti-stain fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03234872A true JPH03234872A (en) | 1991-10-18 |
Family
ID=12259225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2028827A Pending JPH03234872A (en) | 1990-02-08 | 1990-02-08 | Preparation of anti-stain fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03234872A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011047085A (en) * | 2009-08-28 | 2011-03-10 | Suminoe Textile Co Ltd | Facing material for vehicle seat with high antistaining performance, and method for producing the facing material |
| RU2469141C2 (en) * | 2008-08-22 | 2012-12-10 | Сэнт-Гобэн Перформанс Пластикс Корпорейшн | Item for polymericfluorine coating and method of its manufacturing |
-
1990
- 1990-02-08 JP JP2028827A patent/JPH03234872A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2469141C2 (en) * | 2008-08-22 | 2012-12-10 | Сэнт-Гобэн Перформанс Пластикс Корпорейшн | Item for polymericfluorine coating and method of its manufacturing |
| JP2011047085A (en) * | 2009-08-28 | 2011-03-10 | Suminoe Textile Co Ltd | Facing material for vehicle seat with high antistaining performance, and method for producing the facing material |
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